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N. A. Babushkina

Publications and source records attributed to N. A. Babushkina.

8 recordsLinked to original sources
arXiv2014

Effect of Eu doping and partial oxygen isotope substitution on magnetic phase transitions in (Pr$_{1-y}$Eu$_y$)$_{0.7}$Ca$_{0.3}$CoO$_3$ cobaltites

We study experimentally and theoretically the effect of Eu doping and partial oxygen isotope substitution on the transport and magnetic characteristics and spin-state transitions in (Pr$_{1-y}$Eu$_y$)$_{0.7}$Ca$_{0.3}$CoO$_3$ cobaltites. The Eu doping level $y$ is chosen in the range of the phase diagram near the crossover between the ferromagnetic and spin-state transitions ($0.10 < y < 0.20$). We prepared a series of samples with different degrees of enrichment by the heavy oxygen isotope $^{18}$O, namely, containing 90%, 67%, 43%, 17%, and 0% of $^{18}$O. Based on the measurements of ac magnetic susceptibility $χ(T)$ and electrical resistivity $ρ(T)$, we analyze the evolution of the sample properties with the change of Eu and $^{18}$O content. It is demonstrated that the effect of increasing $^{18}$O content on the system is similar to that of increasing the Eu content. The band structure calculations of the energy gap between $t_{2g}$ and $e_g$ bands including the renormalization of this gap due to the electron-phonon interaction reveal the physical mechanisms underlying such similarity.

cond-mat.str-el↗
arXiv2010

Phase diagram and isotope effect in (PrEu)_0.7Ca_0.3CoO_3 cobaltites exhibiting spin-state transitions

We present the study of magnetization, thermal expansion, specific heat, resistivity, and a.c. susceptibility of (Pr$_{1-y}$Eu$_y$)$_{0.7}$Ca$_{0.3}$CoO$_3$ cobaltites. The measurements were performed on ceramic samples with $y = 0.12 - 0.26$ and $y = 1$. Based on these results, we construct the phase diagram, including magnetic and spin-state transitions. The transition from the low- to intermediate-spin state is observed for the samples with $y > 0.18$, whereas for a lower Eu-doping level, there are no spin-state transitions, but a crossover between the ferromagnetic and paramagnetic states occurs. The effect of oxygen isotope substitution along with Eu doping on the magnetic/spin state is discussed. The oxygen-isotope substitution ($^{16}$O by $^{18}$O) is found to shift both the magnetic and spin-state phase boundaries to lower Eu concentrations. The isotope effect on the spin-state transition temperature ($y > 0.18$) is rather strong, but it is much weaker for the transition to a ferromagnetic state ($y < 0.18$). The ferromagnetic ordering in the low-Eu doped samples is shown to be promoted by the Co$^{4+}$ ions, which favor the formation of the intermediate-spin state of neighboring Co$^{3+}$ ions.

cond-mat.str-el↗
arXiv2005

Oxygen isotope effect and phase separation in the optical conductivity of (La$_{0.5}$Pr$_{0.5}$)$_{0.7}$Ca$_{0.3}$MnO$_3$ thin films

The optical conductivities of films of (La$_{0.5}$Pr$_{0.5}$)$_{0.7}$Ca$_{0.3}$MnO$_3$ with different oxygen isotopes ($^{16}$O and $^{18}$O) have been determined in the spectral range from 0.3 to 4.3 eV using a combination of transmission in the mid-infrared and ellipsometry from the near-infrared to ultra-violet regions. We have found that the isotope exchange strongly affects the optical response in the ferromagnetic phase in a broad frequency range, in contrast to the almost isotope-independent optical conductivity above $T_C$. The substitution by $^{18}$O strongly suppresses the Drude response and a mid-infrared peak while enhancing the conductivity peak at 1.5 eV. A qualitative explanation can be given in terms of the phase separation present in these materials. Moreover, the optical response is similar to the one extracted from measurements in polished samples and other thin films, which signals to the importance of internal strain.

cond-mat.str-el↗
arXiv2004

Quenched disorder induced magnetization jumps in (Sm,Sr)MnO$_3$

Magnetic field induced step-like changes in magnetization and resistivity of SmSr manganites were studied. A strong dependence of these features on the cooling rate was observed. Magnetostriction, however, does not show the presence of large strain in our samples. From all these features we can rule out the conventional explanation of magnetization jumps as a consequence of martensitic transition. We propose instead that quenched by fast cooling disorder leads to the formation of an inhomogeneous metastable state and to subsequent magnetization jumps.

cond-mat.str-el↗
arXiv2002

Modification of the ground state in Sm-Sr manganites by oxygen isotope substitution

The effect of $^{16}$O $\to$ $^{18}$O isotope substitution on electrical resistivity and magnetic susceptibility of Sm$_{1-x}$Sr$_x$MnO$_3$ manganites is analyzed. It is shown that the oxygen isotope substitution drastically affects the phase diagram at the crossover region between the ferromagnetic metal state and that of antiferromagnetic insulator (0.4 $< x <$ 0.6), and induces the metal-insulator transition at for $x$ = 0.475 and 0.5. The nature of antiferromagnetic insulator phase is discussed.

cond-mat.str-el↗
arXiv1999

Two-dimensional quantum interference contributions to the magnetoresistance of Nd{2-x}Ce{x}CuO{4-d} single crystals

The 2D weak localization effects at low temperatures T = (0.2-4.2)K have been investigated in nonsuperconducting sample Nd{1.88}Ce{0.12}CuO{4-d} and in the normal state of the superconducting sample Nd{1.82}Ce{0.18}CuO{4-d} for B>B_c2. The phase coherence time and the effective thickness $d$ of a conducting CuO_2 layer have been estimated by the fitting of 2D weak localization theory expressions to the magnetoresistivity data for the normal to plane and the in-plane magnetic fields.

cond-mat.supr-con↗
arXiv1998

Metal-insulator transition induced by 16O -18O oxygen isotope exchange in colossal negative magnetoresistance manganites

The effect of 16O-18O isotope exchange on the electric resistivity was studied for (La(1-y)Pr(y))0.7Ca0.3MnO3 ceramic samples. Depending on y, this mixed perovskite exhibited different types of low-temperature behavior ranging from ferromagnetic metal (FM) to charge ordered (CO) antiferromagnetic insulator. It was found that at y=0.75, the substitution of 16O by 18O results in the reversible transition from a FM to a CO insulator at zero magnetic field. The applied magnetic field (H >= 2 T) transformed the sample with 18O again to the metallic state and caused the increase in the FM transition temperature Tc of the 16O sample. As a result, the isotope shift of Tc at H = 2 T was as high as 63 K. Such unique sensitivity of the system to oxygen isotope exchange, giving rise even to the metal-insulator transition, is discussed in terms of the isotope dependence of the effective electron bandwidth which shifts the balance between the CO and FM phases.

cond-mat.str-el↗