arXiv subjects

N. A. Teanby

Publications and source records attributed to N. A. Teanby.

17 recordsLinked to original sources

arXiv2026

An unidentified absorption feature at 5.11 $μ$m on the surface of Titan and Pluto from JWST spectroscopy

Titan possesses a thick N$_2$-CH$_4$ atmosphere that makes it difficult to study its surface spectroscopically. The chemical composition of the solid surface of Titan thus remains very uncertain. By leveraging JWST's high sensitivity and large spectral coverage, we searched for any signature from Titan's surface in the broad and less explored 5-$μ$m atmospheric window. We also investigated the JWST spectrum of Pluto which has a thin Titan-like atmosphere. We made selections of JWST NIRSpec and MIRI spectra around Titan's disk center and compared the NIRSpec average spectrum with a radiative transfer model including gas and haze opacity. We detected an unidentified absorption in both NIRSpec and MIRI spectra of Titan centered at 5.113 $μ$m (1956 cm$^{-1}$) and 6-7% deep. The width of the feature is 0.024$\pm$0.0008 $μ$m (9.2$\pm$0.3 cm$^{-1}$) in the NIRSpec spectrum recorded on the trailing side and is possibly 25% narrower in the MIRI spectrum of the leading side. This absorption most likely originates from the surface. We could not identify this signature among published laboratory spectra of ices relevant to Titan's atmospheric compounds but present a few plausible candidates. A 4-5% deep absorption is also present in the MIRI spectrum of Pluto but is about 3 times broader than on Titan's trailing side.

astro-ph.EP↗

arXiv2025

Improved Carbon and Nitrogen Isotopic Ratios for CH$_3$CN in Titan's Atmosphere Using ALMA

Titan, Saturn's largest satellite, maintains an atmosphere composed primarily of nitrogen (N$_2$) and methane (CH$_4$) that leads to a complex organic chemistry. Some of the nitriles (CN-bearing organics) on Titan are known to have substantially enhanced $^{15}$N abundances compared to Earth and to Titan's dominant nitrogen (N$_2$) reservoir. The $^{14}$N/$^{15}$N isotopic ratio in Titan's nitriles can provide better constraints on the synthesis of nitrogen-bearing organics in planetary atmospheres as well as insights into the origin of Titan's large nitrogen abundance. Using high signal-to-noise ratio ($>13$), disk-integrated observations obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) Band 6 receiver (211-275 GHz), we measure the $^{14}$N/$^{15}$N and $^{12}$C/$^{13}$C isotopic ratios of acetonitrile (CH$_3$CN) in Titan's stratosphere. Using the Nonlinear optimal Estimator for MultivariatE spectral analySIS (NEMESIS), we derived the CH$_3$CN/$^{13}$CH$_3$CN ratio to be 89.2 $\pm$ 7.0 and the CH$_3$CN/CH$_3$$^{13}$CN ratio to be 91.2 $\pm$ 6.0, in agreement with the $^{12}$C/$^{13}$C ratio in Titan's methane, and other Solar System species. We found the $^{14}$N/$^{15}$N isotopic ratio to be 68.9 $\pm$ 4.2, consistent with previously derived values for HCN and HC$_3$N, confirming an enhanced $^{15}$N abundance in Titan's nitriles compared with the bulk atmospheric N$_2$ value of $^{14}$N/$^{15}$N = 168, in agreement with chemical models incorporating isotope-selective photodissociation of N$_2$ at high altitudes.

astro-ph.EP↗

arXiv2024

Variability in Titan's Mesospheric HCN and Temperature Structure as Observed by ALMA

The temperature structure of Titan's upper atmosphere exhibits large variability resulting from numerous spatially and temporally irregular external energy sources, seasonal changes, and the influence of molecular species produced via photochemistry. In particular, Titan's relatively abundant HCN is thought to provide substantial cooling to the upper atmosphere through rotational emission, balancing UV/EUV heating and thermal conduction. Here, we present the analysis of ALMA observations of Titan from 2012, 2014, 2015, and 2017, corresponding to planetocentric solar longitudes of ~34-89$^{\circ}$, including vertical HCN and temperature profiles retrieved from the lower mesosphere through the thermosphere (~350-1200 km; $3\times10^{-2}$-$2\times10^{-8}$ mbar). Throughout the atmosphere, temperature profiles differ by 10 to 30 K between observations approximately one Earth year apart, particularly from 600-900 km. We find evidence for a large imbalance in Titan's upper atmospheric energy budget between 2014 and 2015, where the mesospheric thermal structure changes significantly and marks the transition between a mesopause located at ~600 km ($2\times10^{-4}$ mbar) and at ~800 km ($3\times10^{-6}$ mbar). The retrieved HCN abundances vary dramatically during the 2012 to 2017 time period as well, showing close to 2 orders of magnitude difference in abundance at 1000 km. However, the change in HCN abundance does not appear to fully account for the variation in mesospheric temperatures over the $L_S\sim$34-89$^{\circ}$ period. These measurements provide additional insight into the variability of Titan's mesospheric composition and thermal structure following its 2009 vernal equinox, and motivate continued investigation of the origins of such rapid changes in Titan's atmosphere throughout its seasonal cycle.

astro-ph.EP↗

arXiv2021

Detection of Dynamical Instability in Titan's Thermospheric Jet

Similar to Earth, Saturn's largest moon, Titan, possesses a system of high-altitude zonal winds (or jets) that encircle the globe. Using the Atacama Large Millimeter/submillimeter Array (ALMA) in August 2016, Lellouch et al. (2019) discovered an equatorial jet at much higher altitudes than previously known, with a surprisingly fast speed of up to ~340 m/s, but the origin of such high velocities is not yet understood. We obtained spectrally and spatially resolved ALMA observations in May 2017 to map Titan's 3D global wind field and compare our results with a reanalysis of the August 2016 data. Doppler wind velocity maps were derived in the altitude range ~300-1000 km (from the upper stratosphere to the thermosphere). At the highest, thermospheric altitudes, a 47% reduction in the equatorial zonal wind speed was measured over the 9-month period (corresponding to L_s = 82-90 degrees on Titan). This is interpreted as due to a dramatic slowing and loss of confinement (broadening) of the recently-discovered thermospheric equatorial jet, as a result of dynamical instability. These unexpectedly-rapid changes in the upper-atmospheric dynamics are consistent with strong variability of the jet's primary driving mechanism.

astro-ph.EP↗

arXiv2021

Latitudinal variation of methane mole fraction above clouds in Neptune's atmosphere from VLT/MUSE-NFM: Limb-darkening reanalysis

We present a reanalysis of visible/near-infrared (480-930 nm) observations of Neptune, made in 2018 with the MUSE instrument at the Very Large Telescope (VLT) in Narrow Field Adaptive Optics mode, reported by Irwin et al., Icarus, 311, 2019. We find that the inferred variation of methane abundance with latitude in our previous analysis, which was based on central meridian observations only, underestimated the retrieval errors when compared with a more complete assessment of Neptune's limb darkening. In addition, our previous analysis introduced spurious latitudinal variability of both the abundance and its uncertainty, which we reassess here. Our reanalysis of these data incorporates the effects of limb-darkening based upon the Minnaert approximation, which provides a much stronger constraint on the cloud structure and methane mole fraction, makes better use of the available data and is more computationally efficient. We find that away from discrete cloud features, the observed reflectivity spectrum from 800-900 nm is very well approximated by a background cloud model that is latitudinally varying, but zonally symmetric, consisting of a H$_2$S cloud layer, based at 3.6-4.7 bar with variable opacity and scale height, and a stratospheric haze. The background cloud model matches the observed limb darkening seen at all wavelengths and latitudes and we find that the mole fraction of methane at 2-4 bar, above the H$_2$S cloud, but below the methane condensation level, varies from 4-6\% at the equator to 2-4\% at near the south pole, consistent with previous analyses, with a equator/pole ratio of $1.9 \pm 0.2$ for our assumed cloud/methane model. The spectra of discrete cloudy regions are fitted, to a very good approximation, by the addition of a single vertically thin methane ice cloud with opacity ranging from 0 - 0.75 and pressure less than $\sim 0.4$ bar.

astro-ph.EP↗

arXiv2020

Detection of CH$_3$C$_3$N in Titan's Atmosphere

Titan harbors a dense, organic-rich atmosphere primarily composed of N$_2$ and CH$_4$, with lesser amounts of hydrocarbons and nitrogen-bearing species. As a result of high sensitivity observations by the Atacama Large Millimeter/submillimeter Array (ALMA) in Band 6 ($\sim$230-272 GHz), we obtained the first spectroscopic detection of CH$_3$C$_3$N (methylcyanoacetylene or cyanopropyne) in Titan's atmosphere through the observation of seven transitions in the $J = 64\rightarrow63$ and $J = 62\rightarrow61$ rotational bands. The presence of CH$_3$C$_3$N on Titan was suggested by the Cassini Ion and Neutral Mass Spectrometer detection of its protonated form: C$_4$H$_3$NH$^+$, but the atmospheric abundance of the associated (deprotonated) neutral product is not well constrained due to the lack of appropriate laboratory reaction data. Here, we derive the column density of CH$_3$C$_3$N to be (3.8-5.7)$\times10^{12}$ cm$^{-2}$ based on radiative transfer models sensitive to altitudes above 400 km Titan's middle atmosphere. When compared with laboratory and photochemical model results, the detection of methylcyanoacetylene provides important constraints for the determination of the associated production pathways (such as those involving CN, CCN, and hydrocarbons), and reaction rate coefficients. These results also further demonstrate the importance of ALMA and (sub)millimeter spectroscopy for future investigations of Titan's organic inventory and atmospheric chemistry, as CH$_3$C$_3$N marks the heaviest polar molecule detected spectroscopically in Titan's atmosphere to date.

astro-ph.EP↗

arXiv2019

ALMA Spectral Imaging of Titan Contemporaneous with Cassini's Grand Finale

The Cassini mission performed 127 targeted flybys of Titan during its 13-year mission to Saturn, culminating in the Grand Finale between April-September 2017. Here we demonstrate the use of the Atacama Large Millimeter/submillimeter Array (ALMA) to continue Cassini's legacy for chemical and climatological studies of Titan's atmosphere. Whole-hemisphere, interferometric spectral maps of HCN, HNC, HC3N, CH3CN, C2H3CN, C2H5CN and C3H8 were obtained using ALMA in May 2017 at moderate (~0.2'', or 1300 km) spatial resolution, revealing the effects of seasonally-variable chemistry and dynamics on the distribution of each species. The ALMA sub-mm observations of HCN and HC3N are consistent with Cassini infrared data on these species, obtained in the same month. Chemical/dynamical lifetimes of a few years are inferred for C2H3CN and C2H5CN, in reasonably close agreement with the latest chemical models incorporating sticking of C2H5CN to stratospheric aerosol particles. ALMA radial limb flux profiles provide column density information as a function of altitude, revealing maximum abundances in the thermosphere (above 600 km) for HCN, HNC, HC3N and C2H5CN. This constitutes the first detailed measurement of the spatial distribution of HNC, which is found to be confined predominantly to altitudes above 730 $\pm$ 60 km. The HNC emission map shows an east-west hemispheric asymmetry of (13$\pm$3)%. These results are consistent with very rapid production (and loss) of HNC in Titan's uppermost atmosphere, making this molecule an effective probe of short-timescale (diurnal) ionospheric processes.

astro-ph.EP↗

arXiv2019

Seasonal evolution of temperatures in Titan's lower stratosphere

The Cassini mission offered us the opportunity to monitor the seasonal evolution of Titan's atmosphere from 2004 to 2017, i.e. half a Titan year. The lower part of the stratosphere (pressures greater than 10 mbar) is a region of particular interest as there are few available temperature measurements, and because its thermal response to the seasonal and meridional insolation variations undergone by Titan remains poorly known. In this study, we measure temperatures in Titan's lower stratosphere between 6 mbar and 25 mbar using Cassini/CIRS spectra covering the whole duration of the mission (from 2004 to 2017) and the whole latitude range. We can thus characterize the meridional distribution of temperatures in Titan's lower stratosphere, and how it evolves from northern winter (2004) to summer solstice (2017). Our measurements show that Titan's lower stratosphere undergoes significant seasonal changes, especially at the South pole, where temperature decreases by 19 K at 15 mbar in 4 years.

astro-ph.EP↗

arXiv2018

Spatial Variations in Titan's Atmospheric Temperature: ALMA and Cassini Comparisons from 2012 to 2015

Submillimeter emission lines of carbon monoxide (CO) in Titan's atmosphere provide excellent probes of atmospheric temperature due to the molecule's long chemical lifetime and stable, well constrained volume mixing ratio. Here we present the analysis of 4 datasets obtained with the Atacama Large Millimeter/Submillimeter Array (ALMA) from 2012 to 2015 that contain strong CO rotational transitions. Utilizing ALMA's high spatial resolution in the 2012, 2014, and 2015 observations, we extract spectra from 3 separate regions on Titan's disk using datasets with beam sizes of ~0.3''. Temperature profiles retrieved by the NEMESIS radiative transfer code are compared to Cassini Composite Infrared Spectrometer (CIRS) and radio occultation science results from similar latitude regions. Small seasonal variations in atmospheric temperature are present from 2012 to 2015 in the stratosphere and mesosphere (~100-500 km) of spatially resolved regions. We measure the stratopause (320 km) to increase in temperature by 5 K in northern latitudes from 2012-2015, while temperatures rise throughout the stratosphere at lower latitudes. While retrieved temperature profiles cover a range of latitudes in these observations, deviations from CIRS nadir maps and radio occultation measurements convolved with the ALMA beam-footprint are not found to be statistically significant, and discrepancies are often found to be less than 5 K throughout the atmosphere. ALMA's excellent sensitivity in the lower stratosphere (60-300 km) provides a highly complementary dataset to contemporary CIRS and radio science observations. The demonstrated utility of CO emission lines in the submillimeter as a tracer of Titan's atmospheric temperature lays the groundwork for future studies of other molecular species, as temperature profiles are found to consistently vary with latitude in all three years by up to 15 K.

astro-ph.EP↗

arXiv2018

Abundance Measurements of Titan's Stratospheric HCN, HC$_3$N, C$_3$H$_4$, and CH$_3$CN from ALMA Observations

Previous investigations have employed more than 100 close observations of Titan by the Cassini orbiter to elucidate connections between the production and distribution of Titan's vast, organic-rich chemical inventory and its atmospheric dynamics. However, as Titan transitions into northern summer, the lack of incoming data from the Cassini orbiter presents a potential barrier to the continued study of seasonal changes in Titan's atmosphere. In our previous work (Thelen et al., 2018), we demonstrated that the Atacama Large Millimeter/submillimeter Array (ALMA) is well suited for measurements of Titan's atmosphere in the stratosphere and lower mesosphere (~100-500 km) through the use of spatially resolved (beam sizes <1'') flux calibration observations of Titan. Here, we derive vertical abundance profiles of four of Titan's trace atmospheric species from the same 3 independent spatial regions across Titan's disk during the same epoch (2012 to 2015): HCN, HC$_3$N, C$_3$H$_4$, and CH$_3$CN. We find that Titan's minor constituents exhibit large latitudinal variations, with enhanced abundances at high latitudes compared to equatorial measurements; this includes CH$_3$CN, which eluded previous detection by Cassini in the stratosphere, and thus spatially resolved abundance measurements were unattainable. Even over the short 3-year period, vertical profiles and integrated emission maps of these molecules allow us to observe temporal changes in Titan's atmospheric circulation during northern spring. Our derived abundance profiles are comparable to contemporary measurements from Cassini infrared observations, and we find additional evidence for subsidence of enriched air onto Titan's south pole during this time period. Continued observations of Titan with ALMA beyond the summer solstice will enable further study of how Titan's atmospheric composition and dynamics respond to seasonal changes.

astro-ph.EP↗

arXiv2018

Interferometric imaging of Titan's HC$_3$N, H$^{13}$CCCN and HCCC$^{15}$N

We present the first maps of cyanoacetylene isotopologues in Titan's atmosphere, including H$^{13}$CCCN and HCCC$^{15}$N, detected in the 0.9 mm band using the Atacama Large Millimeter/submillimeter array (ALMA) around the time of Titan's (southern winter) solstice in May 2017. The first high-resolution map of HC$_3$N in its $v_7=1$ vibrationally excited state is also presented, revealing a unique snapshot of the global HC$_3$N distribution, free from the strong optical depth effects that adversely impact the ground-state ($v=0$) map. The HC$_3$N emission is found to be strongly enhanced over Titan's south pole (by a factor of 5.7 compared to the north pole), consistent with rapid photochemical loss of HC$_3$N from the summer hemisphere combined with production and transport to the winter pole since the April 2015 ALMA observations. The H$^{13}$CCCN/HCCC$^{15}$N flux ratio is derived at the southern HC$_3$N peak, and implies an HC$_3$N/HCCC$^{15}$N ratio of $67\pm14$. This represents a significant enrichment in $^{15}$N compared with Titan's main molecular nitrogen reservoir, which has a $^{14}$N/$^{15}$N ratio of 167, and confirms the importance of photochemistry in determining the nitrogen isotopic ratio in Titan's organic inventory.

astro-ph.EP↗

arXiv2017

Mapping Vinyl Cyanide and Other Nitriles in Titan's Atmosphere Using ALMA

Vinyl cyanide (C$_2$H$_3$CN) is theorized to form in Titan's atmosphere via high-altitude photochemistry and is of interest regarding the astrobiology of cold planetary surfaces due to its predicted ability to form cell membrane-like structures (azotosomes) in liquid methane. In this work, we follow up on the initial spectroscopic detection of C$_2$H$_3$CN on Titan by Palmer et al. (2017) with the detection of three new C$_2$H$_3$CN rotational emission lines at submillimeter frequencies. These new, high-resolution detections have allowed for the first spatial distribution mapping of C$_2$H$_3$CN on Titan. We present simultaneous observations of C$_2$H$_5$CN, HC$_3$N, and CH$_3$CN emission, and obtain the first (tentative) detection of C$_3$H$_8$ (propane) at radio wavelengths. We present disk-averaged vertical abundance profiles, two-dimensional spatial maps, and latitudinal flux profiles for the observed nitriles. Similarly to HC$_3$N and C$_2$H$_5$CN, which are theorized to be short-lived in Titan's atmosphere, C$_2$H$_3$CN is most abundant over the southern (winter) pole, whereas the longer-lived CH$_3$CN is more concentrated in the north. This abundance pattern is consistent with the combined effects of high-altitude photochemical production, poleward advection, and the subsequent reversal of Titan's atmospheric circulation system following the recent transition from northern to southern winter. We confirm that C$_2$H$_3$CN and C$_2$H$_5$CN are most abundant at altitudes above 200 km. Using a 300 km step model, the average abundance of C$_2$H$_3$CN is found to be $3.03\pm0.29$ ppb, with a C$_2$H$_5$CN/C$_2$H$_3$CN abundance ratio of $2.43\pm0.26$. Our HC$_3$N and CH$_3$CN spectra can be accurately modeled using abundance gradients above the tropopause, with fractional scale-heights of $2.05\pm0.16$ and $1.63\pm0.02$, respectively.

astro-ph.EP↗

arXiv2017

Seasonal evolution of $\mathrm{C_2N_2}$, $\mathrm{C_3H_4}$, and $\mathrm{C_4H_2}$ abundances in Titan's lower stratosphere

We study the seasonal evolution of Titan's lower stratosphere (around 15~mbar) in order to better understand the atmospheric dynamics and chemistry in this part of the atmosphere. We analysed Cassini/CIRS far-IR observations from 2006 to 2016 in order to measure the seasonal variations of three photochemical by-products: $\mathrm{C_4H_2}$, $\mathrm{C_3H_4}$, and $\mathrm{C_2N_2}$. We show that the abundances of these three gases have evolved significantly at northern and southern high latitudes since 2006. We measure a sudden and steep increase of the volume mixing ratios of $\mathrm{C_4H_2}$, $\mathrm{C_3H_4}$, and $\mathrm{C_2N_2}$ at the south pole from 2012 to 2013, whereas the abundances of these gases remained approximately constant at the north pole over the same period. At northern mid-latitudes, $\mathrm{C_2N_2}$ and $\mathrm{C_4H_2}$ abundances decrease after 2012 while $\mathrm{C_3H_4}$ abundances stay constant. The comparison of these volume mixing ratio variations with the predictions of photochemical and dynamical models provides constraints on the seasonal evolution of atmospheric circulation and chemical processes at play.

astro-ph.EP↗

arXiv2016

Reanalysis of Uranus' cloud scattering properties from IRTF/SpeX observations using a self-consistent scattering cloud retrieval scheme

We have developed a new retrieval approach to modelling near-infrared spectra of Uranus that represents a significant improvement over previous modelling methods. We reanalysed IRTF/SpeX observations of Uranus observed in 2009 covering the wavelength range 0.8 to 1.8 microns and reported by Tice et al. (2013). By retrieving the imaginary refractive index spectra of cloud particles we are able to consistently define the real part of the refractive index spectra, through a Kramers-Kronig analysis, and thus determine self-consistent extinction cross-section, single-scattering and phase-function spectra for the clouds and hazes in Uranus' atmosphere. We tested two different cloud-modelling schemes used in conjunction with the temperature/methane profile of Baines et al. (1995), a reanalysis of the Voyager-2 radio-occultation observations performed by Sromovsky, Fry and Tomasko (2011), and a recent determination from Spitzer (Orton et al., 2014). We find that both cloud-modelling schemes represent the observed centre-of-disc spectrum of Uranus well, and both require similar cloud scattering properties of the main cloud residing at approximately 2 bars. However, a modified version of the Sromovsky, Fry and Tomasko (2011) model, with revised spectral properties of the lowest cloud layer, fits slightly better at shorter wavelengths and is more consistent with the expected vertical position of Uranus' methane cloud. We find that the bulk of the reflected radiance from Uranus arises from a thick cloud at approximately the 2 bar level, composed of particles that are significantly more absorbing at wavelengths > 1.0 micron than they are at wavelengths < 1.0 micron. This spectral information provides a possible constraint on the identity of the main particle type.

astro-ph.EP↗

arXiv2015

Ethyl cyanide on Titan: Spectroscopic detection and mapping using ALMA

We report the first spectroscopic detection of ethyl cyanide (C$_2$H$_5$CN) in Titan's atmosphere, obtained using spectrally and spatially resolved observations of multiple emission lines with the Atacama Large Millimeter/submillimeter array (ALMA). The presence of C$_2$H$_5$CN in Titan's ionosphere was previously inferred from Cassini ion mass spectrometry measurements of C$_2$H$_5$CNH$^+$. Here we report the detection of 27 rotational lines from C$_2$H$_5$CN (in 19 separate emission features detected at $>3σ$ confidence), in the frequency range 222-241 GHz. Simultaneous detections of multiple emission lines from HC$_3$N, CH$_3$CN and CH$_3$CCH were also obtained. In contrast to HC$_3$N, CH$_3$CN and CH$_3$CCH, which peak in Titan's northern (spring) hemisphere, the emission from C$_2$H$_5$CN is found to be concentrated in the southern (autumn) hemisphere, suggesting a distinctly different chemistry for this species, consistent with a relatively short chemical lifetime for C$_2$H$_5$CN. Radiative transfer models show that most of the C$_2$H$_5$CN is concentrated at altitudes 300-600 km, suggesting production predominantly in the mesosphere and above. Vertical column densities are found to be in the range (2-5)$\times10^{14}$ cm$^{-2}$.

astro-ph.EP↗

arXiv2014

ALMA measurements of the HNC and HC$_3$N distributions in Titan's atmosphere

We present spectrally and spatially-resolved maps of HNC and HC$_3$N emission from Titan's atmosphere, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) on 2013 November 17. These maps show anisotropic spatial distributions for both molecules, with resolved emission peaks in Titan's northern and southern hemispheres. The HC$_3$N maps indicate enhanced concentrations of this molecule over the poles, consistent with previous studies of Titan's photochemistry and atmospheric circulation. Differences between the spectrally-integrated flux distributions of HNC and HC$_3$N show that these species are not co-spatial. The observed spectral line shapes are consistent with HNC being concentrated predominantly in the mesosphere and above (at altitudes $z\gtrsim 400$ km), whereas HC$_3$N is abundant at a broader range of altitudes ($z\approx70$-600 km). From spatial variations in the HC$_3$N line profile, the locations of the HC$_3$N emission peaks are shown to be variable as a function of altitude. The peaks in the integrated emission from HNC and the line core (upper-atmosphere) component of HC$_3$N (at $z\gtrsim300$ km) are found to be asymmetric with respect to Titan's polar axis, indicating that the mesosphere may be more longitudinally-variable than previously thought. The spatially-integrated HNC and HC$_3$N spectra are modeled using the NEMESIS planetary atmosphere code and the resulting best-fitting disk-averaged vertical mixing ratio (VMR) profiles are found to be in reasonable agreement with previous measurements for these species. Vertical column densities of the best-fitting gradient models for HNC and HC$_3$N are $1.9\times10^{13}$ cm$^{-2}$ and $2.3\times10^{14}$ cm$^{-2}$, respectively.

astro-ph.EP↗

arXiv2009

Titan's Prolific Propane: The Cassini CIRS Perspective

In this paper we select large spectral averages of data from the Cassini Composite Infrared Spectrometer (CIRS) obtained in limb-viewing mode at low latitudes (30S--30N), greatly increasing the path length and hence signal-to-noise ratio for optically thin trace species such as propane. By modeling and subtracting the emissions of other gas species, we demonstrate that at least six infrared bands of propane are detected by CIRS, including two not previously identified in Titan spectra. Using a new line list for the range 1300-1400cm -1, along with an existing GEISA list, we retrieve propane abundances from two bands at 748 and 1376 cm-1. At 748 cm-1 we retrieve 4.2 +/- 0.5 x 10(-7) (1-sigma error) at 2 mbar, in good agreement with previous studies, although lack of hotbands in the present spectral atlas remains a problem. We also determine 5.7 +/- 0.8 x 10(-7) at 2 mbar from the 1376 cm-1 band - a value that is probably affected by systematic errors including continuum gradients due to haze and also an imperfect model of the n6 band of ethane. This study clearly shows for the first time the ubiquity of propane's emission bands across the thermal infrared spectrum of Titan, and points to an urgent need for further laboratory spectroscopy work, both to provide the line positions and intensities needed to model these bands, and also to further characterize haze spectral opacity. The present lack of accurate modeling capability for propane is an impediment not only for the measurement of propane itself, but also for the search for the emissions of new molecules in many spectral regions.

astro-ph.EP↗