arXiv subjects

N. C. Sterling

Publications and source records attributed to N. C. Sterling.

At least 19 recordsLinked to original sources

arXiv2026

The JWST Proto-PAH Project: Detection of the methyl radical CH$_{3}$ in the highly evolved C-rich object SMP LMC 011

We report the first detection of the neutral methyl radical CH$_3$ in a highly evolved C-rich object, SMP LMC 011, using JWST MIRI/MRS. CH$_3$ is well fitted by an excitation temperature of $T_{\rm ex} \simeq$~190\,K and a column density of $N_{\rm tot}(\mathrm{CH_3}) \simeq 5.6\times10^{17}$ cm$^{-2}$. We also report the non-detection of ethane (C$_2$H$_6$), consistent with CH$_3$ reacting preferentially with unsaturated radicals rather than self-recombination, which may be inefficient in SMP LMC 011. Combined with the exceptionally large benzene column density of SMP LMC 011, this supports a methyl-addition route from benzene towards alkyl-substituted aromatics. We propose that the high CH$_3$ abundance is driven by the erosion of hydrogenated amorphous carbon (HAC) dust grains in the dense warm torus by UV photons from the central star and/or by shocks, which release CH$_3$ directly into the gas phase. These results establish CH$_3$ as a key reactive intermediate in the formation of complex hydrocarbons in C-rich circumstellar environments. Chemical models that incorporate methyl-addition reactions are needed for a better understanding of PAH formation pathways in evolved stars. The potential detection of alkyl-substituted aromatics such as toluene (C$_7$H$_8$) and ethylbenzene (C$_8$H$_{10}$) in C-rich evolved stars would provide direct confirmation of CH$_3$-driven aromatic growth in circumstellar environments.

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arXiv2026

The s-process at Subsolar Metallicity: Insights from High-Resolution Infrared Spectroscopy of Magellanic Cloud Planetary Nebulae

We present observations of 12 Magellanic Cloud planetary nebulae (PNe) obtained with the high-resolution near-infrared spectrometer IGRINS on Gemini South. In 10 targets we detect multiple neutron(n)-capture elements that can be synthesized by the s-process during the preceding asymptotic giant branch (AGB) phase, including the widely-observed species Se and Kr, and first detections of Rb, Cd, and Te in extragalactic PNe. The derived abundances significantly expand the inventory of trans-iron element abundance determinations from PNe in subsolar metallicity stellar populations. Seven targets exhibit s-process enrichments relative to the metallicity references O and Ar, with abundances elevated by factors of up to ~40-50 for Te and Kr. We compare these results with AGB nucleosynthesis predictions, using a machine-learning algorithm to find the best-fitting Monash, FRUITY, and NuGrid models. For five of the PNe, Monash and FRUITY models with 2-4 solar masses and metallicities from 1/3 solar to near-solar match the observations well, although the Monash models more successfully fit the largest Kr enhancements. NuGrid models predict smaller s-process enrichments than observed, but the limited number of available models makes it difficult to assess their ability to reproduce the observed abundances. We were unable to find models that provide good fits to three other enriched PNe, including the most metal-poor objects in our sample. These comparisons address uncertainties in mass loss, convection, and other mixing mechanisms during the late evolution of low- and intermediate-mass stars, and improve the accuracy of s-process yields of AGB stars, which are key parameters for modeling galactic chemical evolution.

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arXiv2026

Detection of C$_{60}$ Combination Bands in the Near-IR Spectrum of Tc 1

We report the detection of a set of new near-infrared emission features between 3.5 and 5.2 $μ$m in JWST/NIRSpec observations of Tc 1, the planetary nebula known for displaying the cleanest and most prominent mid-infrared cosmic fullerene spectrum. These broad features share the same spatial distribution as the well-known C$_{60}$ and C$_{70}$ mid-infrared emission bands, peaking in an asymmetric ring approximately 5-6" from the central star. Through comparison with new anharmonic quantum chemical calculations, we demonstrate that these features arise from C$_{60}$ combination bands, marking their first detection in an astrophysical environment. The total energy radiated in the combination bands amounts to ~17% of the total energy emitted from all C$_{60}$ modes, with direct implications for fullerene cooling models. These near-infrared combination bands offer a promising new window for identifying and studying the molecular astrophysics of C$_{60}$ in sources where mid-infrared spectra are more complex.

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arXiv2026

Detection of CO$_2$ ice in the planetary nebula NGC 6302

Using JWST/MIRI observations, we report the detection of CO$_2$ ice in the dusty torus of the planetary nebula NGC 6302, an environment generally considered hostile to fragile molecular species and ices due to intense UV irradiation. This detection accompanies cold (20-50 K) gas-phase CO$_2$ along the same sightlines. The ice absorption profile exhibits a double-peak profile, a characteristic of pure, crystalline CO$_2$ ice. The CO$_2$ gas-to-ice ratio is more than an order of magnitude higher than in young stellar objects, pointing to distinct ice formation or processing mechanisms in evolved stellar environments. This discovery demonstrates that the dusty torus provides sufficient shielding to harbour ice chemistry, and that ice-mediated surface reactions must be incorporated into chemical models of planetary nebulae.

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arXiv2025

Detection of CH3+ in the O-rich planetary nebula NGC 6302

Planetary nebulae are sites where ejected stellar material evolves into complex molecules, but the precise physical conditions and chemical routes that govern these processes are unclear. The presence of abundant carbon-rich molecules in O-rich environments poses particular challenges. Here we report the first detection of methyl cation (CH3+) in any planetary nebula, observed in the O-rich nebula NGC 6302 using JWST MIRI/MRS observations. CH3+ is a key driver of organic chemistry in UV-irradiated environments. Spatially resolved observations reveal that CH3+ is co-located with 12CO, H2, H II, HCO+, and Polycyclic aromatic hydrocarbons (PAHs). LTE modelling of the CH3+ emission yields excitation temperatures of 500-800K in the inner bubble and torus, rising to 1000-2000K in the outer bubble of NGC 6302, with column densities ranging from ~10^11 to 10^13 cm^-2. This detection demonstrates that hydrocarbon radical chemistry must be incorporated into planetary nebulae chemical models. Further near-IR observations are crucial to map different chemical networks operating in these environments.

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arXiv2025

The JWST/MIRI view of the planetary nebula NGC 6302 I.: a UV irradiated torus and a hot bubble triggering PAH formation

NGC 6302 is a spectacular bipolar planetary nebula (PN) whose spectrum exhibits fast outflows and highly ionized emission lines, indicating the presence of a very hot central star (~220,000 K). Its infrared spectrum reveals a mixed oxygen and carbon dust chemistry, displaying both silicate and polycyclic aromatic hydrocarbon (PAH) features. Using the JWST Mid-Infrared Instrument (MIRI) and Medium Resolution Spectrometer, a mosaic map was obtained over the core of NGC 6302, covering the wavelength range of 5--28 micron and spanning an area of ~18.5 arcsec x15 arcsec. The spatially resolved spectrum reveals ~200 molecular and ionized lines from species requiring ionisation potentials of up to 205 eV. The spatial distributions highlight a complex structure at the nebula's centre. Highly ionized species such as Mg VII and Si VII show compact structures, while lower-ionization species such as H^+ extend much farther outwards, forming filament-defined rims that delineate a bubble. Within the bubble, the H^+ and H_2 emission coincide, while the PAH emission appears farther out, indicating an ionization structure distinct from typical photodissociation regions, such as the Orion Bar. This may be the first identification of a PAH formation site in a PN. This PN appears to be shaped not by a steady, continuous outflow, but by a series of dynamic, impulsive bubble ejections, creating local conditions conducive to PAH formation. A dusty torus surrounds the core, primarily composed of large (micron-sized) silicate grains with crystalline components. The long-lived torus contains a substantial mass of material, which could support an equilibrium chemistry and a slow dust-formation process.

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arXiv2022

Chemical Abundances of Eight Highly Extincted Milky Way Planetary Nebulae

Low- and intermediate-mass ($\rm 0.8~M_\odot < M < 8~M_\odot$) stars that evolve into planetary nebulae (PNe) play an important role in tracing and driving Galactic chemical evolution. Spectroscopy of PNe enables access to both the initial composition of their progenitor stars and products of their internal nucleosynthesis, but determining accurate ionic and elemental abundances of PNe requires high-quality optical spectra. We obtained new optical spectra of eight highly-extincted PNe with limited optical data in the literature using the Low Resolution Spectrograph 2 (LRS2) on the Hobby-Eberly Telescope (HET). Extinction coefficients, electron temperatures and densities, and ionic and elemental abundances of up to 11 elements (He, N, O, Ne, S, Cl, Ar, K, Fe, Kr, and Xe) are determined for each object in our sample. Where available, astrometric data from Gaia eDR3 is used to kinematically characterize the probability that each object belongs to the Milky Way's thin disk, thick disk, or halo. Four of the PNe show kinematic and chemical signs of thin disk membership, while two may be members of the thick disk. The remaining two targets lack Gaia data, but their solar O, Ar, and Cl abundances suggest thin disk membership. Additionally, we report the detection of broad emission features from the central star of M 3-35. Our results significantly improve the available information on the nebular parameters and chemical compositions of these objects, which can inform future analyses.

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arXiv2020

Neutron-Capture Element Abundances in Planetary Nebulae

Nebular spectroscopy is a valuable tool for assessing the production of heavy elements by slow neutron(n)-capture nucleosynthesis (the s-process). Several transitions of n-capture elements have been identified in planetary nebulae (PNe) in the last few years, with the aid of sensitive high-resolution near-infrared spectrometers. Combined with optical spectroscopy, the newly discovered near-infrared lines enable more accurate abundance determinations than previously possible, and provide access to elements that had not previously been studied in PNe or their progenitors. Neutron-capture elements have also been detected in PNe in the Sagittarius Dwarf galaxy and in the Magellanic Clouds. In this brief review, I discuss developments in observational studies of s-process enrichments in PNe, with an emphasis on the last five years, and note some open questions and preliminary trends.

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arXiv2019

First evidence of enhanced recombination in astrophysical environments and the implications for plasma diagnostics

We report the first unambiguous observational evidence of Rydberg Enhanced Recombination (RER), a potentially important recombination mechanism that has hitherto been unexplored in low-temperature photoionized plasmas. RER shares similarities with dielectronic recombination, with the difference that the electron is captured into a highly excited state below the ionization threshold -- rather than above the threshold -- of the recombining ion. We predict transitions of carbon and oxygen ions that are formed via the RER process, and their relative strengths with collisional-radiative spectral models. Optical C II RER features are detected in published high-resolution spectra of eight planetary nebulae, and a C III transition has been found in the ultraviolet spectrum in a symbiotic star system. The relative intensities of these lines are consistent with their production by this recombination mechanism. Because RER has not previously been accounted for in photoionized plasmas, its inclusion in models can significantly impact the predicted ionization balance and hence abundance calculations of important astrophysical species. Calculations for C+ suggest that the enhancement in the total recombination rate can amount to a factor of 2.2 at 8100 K, increasing to 7.5 at T = 3500 K. These results demonstrate the importance of including RER in models of photoionized astrophysical plasmas and in elemental abundance determinations.

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arXiv2017

Neutron-capture element abundances in the planetary nebula NGC 5315 from deep optical and near-infrared spectrophotometry

We analyze the chemical composition of the planetary nebula (PN) NGC 5315, through high-resolution (R = 40000) optical spectroscopy with UVES at the Very Large Telescope, and medium-resolution (R = 4800) near-infrared spectroscopy with FIRE at Magellan Baade Telescope, covering a wide spectral range from 0.31 to 2.50 micron. The main aim of this work is to investigate neutron (n)-capture element abundances to study the operation of the slow n-capture ("s-process") in the AGB progenitor of NGC 5315. We detect more than 700 emission lines, including ions of the n-capture elements Se, Kr, Xe, and possibly Br. We compute physical conditions from a large number of diagnostic line ratios, and derive ionic abundances for species with available atomic data. The total abundances are computed using recent ionization correction factors (ICFs) or by summing ionic abundances. Total abundances of common elements are in good agreement with previous work on this object. Based on our abundance analysis of NGC 5315, including the lack of s-process enrichment, we speculate that the most probable scenario is that the progenitor star is in a binary system as hinted at by radial velocity studies, and interactions with its companion truncated the AGB before s-process enrichment could occur. However there are other two possible scenarios for its evolution, that cannot be ruled out: i) the progenitor is a low-mass single star that did not undergo third dredge-up; ii) the progenitor star of NGC 5315 had an initial mass of 4--6 solar masses, and any s-process enhancements were heavily diluted by the massive envelope during the AGB phase.

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arXiv2017

Identification of Near-Infrared [Se III] and [Kr VI] Emission Lines in Planetary Nebulae

We identify [Se III] 1.0994 micron in the planetary nebula (PN) NGC 5315 and [Kr VI] 1.2330 micron in three PNe, from spectra obtained with the FIRE spectrometer on the 6.5-m Baade Telescope. Se and Kr are the two most widely-detected neutron-capture elements in astrophysical nebulae, and can be enriched by s-process nucleosynthesis in PN progenitor stars. The detection of [Se III] 1.0994 micron is particularly valuable when paired with observations of [Se IV] 2.2858 micron, as it can be used to improve the accuracy of nebular Se abundance determinations, and allows Se ionization correction factor (ICF) schemes to be empirically tested for the first time. We present new effective collision strength calculations for Se^{2+} and Kr^{5+}, which we use to compute ionic abundances. In NGC 5315, we find that the Se abundance computed from Se^{3+}/H^+ is lower than that determined with ICFs that incorporate Se^{2+}/H^+. We compute new Kr ICFs that take Kr^{5+}/H^+ into account, by fitting correlations found in grids of Cloudy models between Kr ionic fractions and those of more abundant elements, and use these to derive Kr abundances in four PNe. Observations of [Se III] and [Kr VI] in a larger sample of PNe, with a range of excitation levels, are needed to rigorously test the ICF prescriptions for Se and our new Kr ICFs.

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arXiv2016

Atomic Data and Neutron-Capture Element Abundances in Planetary Nebulae

Neutron(n)-capture elements are produced by s-process nucleosynthesis in low- and intermediate-mass AGB stars, and therefore can be enriched in planetary nebulae (PNe). In the last ten years, n-capture elements have been detected in more than 100 PNe in the Milky Way and nearby galaxies. In some objects, several different n-capture elements have been detected, providing valuable constraints to models of AGB nucleosynthesis and evolution. These detections have motivated theoretical and experimental investigations of the atomic data needed to derive accurate n-capture element abundances. In this review, I discuss the methods and results of these atomic data studies, and their application to abundance determinations in PNe.

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arXiv2016

Neutron-capture element abundances in the planetary nebula NGC 5315 from deep high-resolution optical and near-IR spectrophotometry

We have done a spectroscopical analysis of the type I planetary nebula (PN) NGC 5315, through high-resolution (R$\sim$40000) optical spectroscopy with UVES at the 8.2m Very Large Telescope, and medium-resolution (R$\sim$4800) near-IR spectroscopy with FIRE at the 6.5m Magellan Baade telescope, covering a wide spectral range from 0.31 $μ$m to 2.50 $μ$m. The main aim of this work is to investigate the slow neutron(n)-capture process (the s-process) in the Asymptotic Giant Branch (AGB) star progenitor of a type I PNe. We detected and identified about 700 features, including lines from the n-capture elements Kr, Se, and possibly Br and Xe. We compute physical conditions using line ratios of common ions. Ionic abundances are computed for the species with available atomic data. We calculate total abundances using recent ionization correction factors (ICFs) or by summing ionic abundances. Our results for common elements are in good agreement with previous works on the same object. We do not find a substantial s-process enrichment in NGC 5315, which is typical for type I PNe.

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arXiv2016

Neutron-Capture Element Abundances in Magellanic Cloud Planetary Nebulae

We present near-infrared spectra of ten planetary nebulae (PNe) in the Large and Small Magellanic Clouds (LMC and SMC), acquired with the FIRE and GNIRS spectrometers on the 6.5-m Baade and 8.1-m Gemini South Telescopes, respectively. We detect Se and/or Kr emission lines in eight of these objects, the first detections of n-capture elements in Magellanic Cloud PNe. Our abundance analysis shows large s-process enrichments of Kr (0.6-1.3 dex) in the six PNe in which it was detected, and Se is enriched by 0.5-0.9 dex in five objects. We also estimate upper limits to Rb and Cd abundances in these objects. Our abundance results for the LMC are consistent with the hypothesis that PNe with 2--3 M$_{\odot}$ progenitors dominate the bright end of the PN luminosity function in young gas-rich galaxies. We find no significant correlations between s-process enrichments and other elemental abundances, central star temperature, or progenitor mass, though this is likely due to our small sample size. We determine S abundances from our spectra and find that [S/H] agrees with [Ar/H] to within 0.2 dex for most objects, but is lower than [O/H] by 0.2-0.4 dex in some PNe, possibly due to O enrichment via third dredge-up. Our results demonstrate that n-capture elements can be detected in PNe belonging to nearby galaxies with ground-based telescopes, allowing s-process enrichments to be studied in PN populations with well-determined distances.

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arXiv2016

Discovery of Rubidium, Cadmium, and Germanium Emission Lines in the Near-Infrared Spectra of Planetary Nebulae

We identify [Rb IV] 1.5973 and [Cd IV] 1.7204 micron emission lines in high-resolution (R=40,000) near-infrared spectra of the planetary nebulae (PNe) NGC 7027 and IC 5117, obtained with the IGRINS spectrometer on the 2.7-m telescope at McDonald Observatory. We also identify [Ge VI] 2.1930 $μ$m in NGC 7027. Alternate identifications for these features are ruled out based on the absence of other multiplet members and/or transitions with the same upper levels. Ge, Rb, and Cd can be enriched in PNe by s-process nucleosynthesis during the asymptotic giant branch (AGB) stage of evolution. To determine ionic abundances, we calculate [Rb IV] collision strengths and use approximations for those of [Cd IV] and [Ge VI]. Our identification of [Rb IV] 1.5973 $μ$m is supported by the agreement between Rb3+/H+ abundances found from this line and the 5759.55 A feature in NGC 7027. Elemental Rb, Cd, and Ge abundances are derived with ionization corrections based on similarities in ionization potential ranges between the detected ions and O and Ne ionization states. Our analysis indicates abundances 2-4 times solar for Rb and Cd in both nebulae. Ge is subsolar in NGC 7027, but its abundance is uncertain due to the large and uncertain ionization correction. The general consistency of the measured relative s-process enrichments with predictions from models appropriate for these PNe (2.0-2.5 M_sun, [Fe/H]= -0.37) demonstrates the potential of using PN compositions to test s-process nucleosynthesis models.

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arXiv2015

A window on the efficiency of the s-process in AGB stars: chemical abundances of n-capture elements in the planetary nebula NGC 3918

The chemical content of the planetary nebula NGC 3918 is investigated through deep, high-resolution (R~40000) UVES at VLT spectrophotometric data. We identify and measure more than 750 emission lines, making ours one of the deepest spectra ever taken for a planetary nebula. Among these lines we detect very faint lines of several neutron-capture elements (Se, Kr, Rb, and Xe), which enable us to compute their chemical abundances with unprecedented accuracy, thus constraining the efficiency of the s-process and convective dredge-up in the progenitor star of NGC 3918.

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arXiv2015

S-process enrichment in the planetary nebula NGC 3918. Results from deep echelle spectrophotometry

(Abridged) The chemical content of the planetary nebula NGC 3918 is investigated through deep, high-resolution UVES at VLT spectrophotometric data. We identify and measure more than 750 emission lines, making ours one of the deepest spectra ever taken for a planetary nebula. Among these lines we detect very faint lines of several neutron-capture elements (Se, Kr, Rb, and Xe), which enable us to compute their chemical abundances with unprecedented accuracy, thus constraining the efficiency of the s-process and convective dredge-up in the progenitor star of NGC 3918. We find that Kr is strongly enriched in NGC 3918 and that Se is less enriched than Kr, in agreement with the results of previous papers and with predicted s-process nucleosynthesis. We also find that Xe is not as enriched by the s-process in NGC 3918 as is Kr and, therefore, that neutron exposure is typical of modestly sub-solar metallicity AGB stars. A clear correlation is found when representing [Kr/O] vs. log(C/O) for NGC 3918 and other objects with detection of multiple ions of Kr in optical data, confirming that carbon is brought to the surface of AGB stars along with s-processed material during third dredge-up episodes, as predicted by nucleosynthesis models. We also detect numerous refractory element lines (Ca, K, Cr, Mn, Fe, Co, Ni, and Cu). We compute physical conditions from a large number of diagnostics. Thanks to the high ionization of NGC 3918 we detect a large number of recombination lines of multiple ionization stages of C, N, O and Ne. The abundances obtained for these elements by using recently-determined state-of-the-art ICF schemes or simply adding ionic abundances are in very good agreement, demonstrating the quality of the recent ICF scheme for high ionization planetary nebulae.

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arXiv2015

The Abundances of Light Neutron-Capture Elements in Planetary Nebulae III. The Impact of New Atomic Data on Nebular Selenium and Krypton Abundance Determinations

The detection of neutron(n)-capture elements in several planetary nebulae (PNe) has provided a new means of investigating s-process nucleosynthesis in low-mass stars. However, a lack of atomic data has inhibited accurate trans-iron element abundance determinations in astrophysical nebulae. Recently, photoionization and recombination data were determined for Se and Kr, the two most widely detected n-capture elements in nebular spectra. We have incorporated these new data into the photoionization code Cloudy. To test the atomic data, numerical models were computed for 15 PNe that exhibit emission lines from multiple Kr ions. We found systematic discrepancies between the predicted and observed emission lines that are most likely caused by inaccurate photoionization and recombination data. These discrepancies were removed by adjusting the Kr$^+$--Kr$^{3+}$ photoionization cross sections within their cited uncertainties and the dielectronic recombination rate coefficients by slightly larger amounts. From grids of models spanning the physical conditions encountered in PNe, we derive new, broadly applicable ionization correction factor (ICF) formulae for calculating Se and Kr elemental abundances. The ICFs were applied to our previous survey of near-infrared [Kr III] and [Se IV] emission lines in 120 PNe. The revised Se and Kr abundances are 0.1-0.3 dex lower than former estimates, with average values of [Se/(O, Ar)]=0.12$\pm$0.27 and [Kr/(O, Ar)]=0.82$\pm$0.29, but correlations previously found between their abundances and other nebular and stellar properties are unaffected. We also find a tendency for high-velocity PNe that can be associated with the Galactic thick disk to exhibit larger s-process enrichments than low-velocity PNe belonging to the thin disk population.

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