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N. Grevesse

Publications and source records attributed to N. Grevesse.

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Solar chemical composition

The Sun is one of the fundamental benchmarks in astronomy, and there is ever growing interest in precise and accurate determinations of its chemical composition. We present the current state-of-the-art in spectroscopic determinations of the solar elemental abundances, that now routinely employ three-dimensional (3D) radiative-hydrodynamic simulations of the solar photosphere and post-processing in non-local thermodynamic equilibrium (non-LTE). We critically review the recent literature and present recommended present-day and protosolar abundances of the 83 long-lived elements, and discuss their implications vis-\`a-vis primitive meteorites, helioseismology, neutrino fluxes, and the Solar Modelling Problem.

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A data-driven estimate of the protosolar helium mass fraction

The protosolar helium mass-fraction is a key ingredient of solar, planetary models and enrichment laws. However, the assumed values often rely on simplified descriptions of the transport of chemicals in solar models. They are also based on the inferred helium mass fraction in the solar convective envelope, which is itself sensitive to uncertainties in the solar equation of state. We update the reference protosolar helium abundance by including the effects of macroscopic mixing at the base of the convective zone and more recent determinations of the helium mass fraction in the convective envelope. We combine results from our inversions to spectroscopic abundances, as well as literature values to provide a robust interval of the current helium mass fraction in the convective zone. We combine this measurement to models including light element depletion to provide an udpated protosolar helium abundance. We show that macroscopic mixing at the base of the envelope is key to infer protosolar helium. We find a revised interval of primordial helium mass fraction of 0.27575 +- 0.00315 slightly lower than previous estimates when combining our latest estimate of surface helium mass fraction and spectroscopic abundances. We find that the effects of macroscopic mixing are partially compensated by an increase in the inferred solar helium mass fraction in recent studies. We also derive more precise estimates based on various reference works in the litterature. Using the usual surface helium mass fraction, the primordial helium mass fraction drops to 0.2669 +- 0.00415 due to the inclusion of macroscopic mixing. The dominant source of uncertainty is found the surface helium abundance inferred from helioseismic constraints and more specifically, the impact on the equation of state of the solar material on this inference result.

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The solar sulphur abundance in view of large-scale atomic structure calculations and 3D non-LTE models

The solar chemical composition is a fundamental yardstick in astrophysics and the topic of heated debate in recent literature. We re-evaluate the abundance of sulphur in the photosphere by studying seven S I lines in the solar disc-centre intensity spectrum. Our analysis considers independent sets of experimental and theoretical oscillator strengths together with, for the first time, three-dimensional non-local thermodynamic equilibrium (3D non-LTE) S I spectrum synthesis. Our best estimate is $A(\mathrm{S})=7.06\pm0.04$, which is $0.06$ dex to $0.10$ dex lower than that in commonly-used compilations of the solar chemical composition. Our lower solar sulphur abundance deviates from that in CI chondrites, and thereby supports the case for a systematic difference between the composition of the solar photosphere and of CI chondrites that is correlated with $50\%$ condensation temperature. We suggest that precise laboratory measurements of S I oscillator strengths and abundance analyses using 3D magnetohydrodynamic models of the solar photosphere be conducted to further substantiate our conclusions.

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Constraints on the properties of macroscopic transport in the Sun from combined lithium and beryllium depletion

Context. The Sun is a privileged laboratory of stellar evolution, thanks to the quality and complementary nature of available constraints. Using these observations, we are able to draw a detailed picture of its internal structure and dynamics which form the basis of the successes of solar modelling. Amongst such constraints, the depletion of lithium and beryllium are key tracers of the required efficiency and extent of macroscopic mixing just below the solar convective envelope. Thanks to revised determinations of these abundances, we may use them in conjunction with other existing spectroscopic and helioseismic constraints to study in detail the properties of macroscopic transport. Aims. We aim at constraining the efficiency of macroscopic transport at the base of the convective envelope and determining the compatibility of the observations with a suggested candidate linked with the transport of angular momentum in the solar radiative interior. Methods. We use recent spectroscopic observations of lithium and beryllium abundance and include them in solar evolutionary model calibrations. We test the agreement of such models in terms of position of the convective envelope, helium mass fraction in convective zone, sound speed profile inversions and neutrino fluxes. Results. We constrain the required efficiency and extent of the macroscopic mixing at the base of the solar convective envelope, finding that a power law of density with an index n between 3 and 6 would reproduce the data, with efficiencies at the base of the envelope of about 6000 cm2 /s, depending on the value of n. We also confirm that macroscopic mixing worsens the agreement with neutrino fluxes and that the current implementations of the magnetic Tayler instability are unable to explain the observations.

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The solar beryllium abundance revisited with 3D non-LTE models

The present-day abundance of beryllium in the solar atmosphere provides clues about mixing mechanisms within stellar interiors. However, abundance determinations based on the Be II 313.107 nm line are prone to systematic errors due to imperfect model spectra. These errors arise from missing continuous opacity in the UV, a significant unidentified blend at 313.102 nm, departures from local thermodynamic equilibrium (LTE), and microturbulence and macroturbulence fudge parameters associated with one-dimensional (1D) hydrostatic model atmospheres. Although these factors have been discussed in the literature, no study has yet accounted for all of them simultaneously. To address this, we present 3D non-LTE calculations for neutral and ionised beryllium in the Sun. We used these models to derive the present-day solar beryllium abundance, calibrating the missing opacity on high resolution solar irradiance data and the unidentified blend on the centre-to-limb variation. We find a surface abundance of 1.21 $\pm$ 0.05 dex, which is significantly lower than the value of 1.38 dex that has been commonly adopted since 2004. Taking the initial abundance via CI chondrites, our result implies that beryllium has been depleted from the surface by an extra 0.11 $\pm$ 0.06 dex, or 22 $\pm$ 11%, on top of any effects of atomic diffusion. This is in tension with standard solar models, which predict negligible depletion, as well as with contemporary solar models that have extra mixing calibrated on the abundances of helium and lithium, which predict excessive depletion. These discrepancies highlight the need for further improvements to the physics in solar and stellar models.

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In-depth analysis of solar models with high-metallicity abundances and updated opacity tables

Due to the high quality constraints available for the Sun, we can carry out combined analyses using neutrino, spectroscopic and helioseismic observations. Such studies lay the ground for future improvements of key physical components of solar and stellar models, such as the equation of state, radiative opacities or prescriptions for macroscopic transport processes of chemicals which are then used to study other stars in the Universe. We study the existing degeneracies in solar models using the recent high-metallicity spectroscopic abundances by comparing them to helioseismic and neutrino data and discuss how their properties are impacted by changes in various physical ingredients. We carry out a detailed study of solar models computed with a high-metallicity composition from the literature based on averaged-3D models that was claimed to solve the solar problem. The properties of the solar models are significantly affected by using the recent OPLIB opacities and the inclusion of macroscopic transport. The properties of the standard solar models computed using the OPAL opacities are similar to those using the OP opacities. We show that a modifying the temperature gradient just below the base of the convective zone is required to erase the discrepancies in solar models, particularly in the presence of macroscopic mixing. This can be simulated by a local increase of opacity of a few percent. We conclude that the existing degeneracies and issues in solar modelling are not erased by an increase in the solar metallicity in contradiction to was suggested in recent papers. Therefore, standard solar models cannot be used as an argument for a high metallicity composition. While further work is required to improve solar models, we note that direct helioseismic inversions indicate a low metallicity in the convective envelope, in agreement with spectroscopic analyses based on full 3D models.

astro-ph.SR

Helioseismic determination of the solar metal mass fraction

Context. The metal mass fraction of the Sun Z is a key constraint in solar modelling, but its value is still under debate. The standard solar chemical composition of the late 2000s have the ratio of metals to hydrogen Z/X = 0.0181, with a small increase to 0.0187 in 2021, as inferred from 3D non-LTE spectroscopy. However, more recent work on a horizontally and temporally averaged <3D> model claim Z/X = 0.0225, consistent with the high values of twenty-five years ago based on 1D LTE spectroscopy. Aims. We aim to determine a precise and robust value of the solar metal mass fraction from helioseismic inversions, thus providing independent constraints from spectroscopic methods. Methods. We devise a detailed seismic reconstruction technique of the solar envelope, combining multiple inversions and equations of state to accurately and precisely determine the metal mass fraction value. Results. We show that a low value of the solar metal mass fraction corresponding to Z/X = 0.0187 is favoured by helioseismic constraints and that a higher metal mass fraction corresponding to Z/X = 0.0225 are strongly rejected by helioseismic data. Conclusions. We conclude that direct measurement of the metal mass fraction in the solar envelope favours a low metallicity, in line with the 3D non-LTE spectroscopic determination of 2021. A high metal mass fraction as measured using a <3D> model in 2022 is disfavoured by helioseismology for all modern equations of state used to model the solar convective envelope.

astro-ph.SR

Higher metal abundances do not solve the solar problem

Context. The Sun acts as a cornerstone of stellar physics. Thanks to spectroscopic, helioseismic and neutrino flux observations, we can use the Sun as a laboratory of fundamental physics in extreme conditions. The conclusions we draw are then used to inform and calibrate evolutionary models of all other stars in the Universe. However, solar models are in tension with helioseismic constraints. The debate on the ``solar problem'' has hitherto led to numerous publications discussing potential issues with solar models and abundances. Aims. Using the recently suggested high-metallicity abundances for the Sun, we investigate whether standard solar models, as well as models with macroscopic transport reproducing the solar surface lithium abundances and analyze their properties in terms of helioseismic and neutrino flux observations. Methods. We compute solar evolutionary models and combine spectroscopic and helioseismic constraints as well as neutrino fluxes to investigate the impact of macroscopic transport on these measurements. Results. When high-metallicity solar models are calibrated to reproduce the measured solar lithium depletion, tensions arise with respect to helioseismology and neutrino fluxes. This is yet another demonstration that the solar problem is also linked to the physical prescriptions of solar evolutionary models and not to chemical composition alone. Conclusions. A revision of the physical ingredients of solar models is needed in order to improve our understanding of stellar structure and evolution. The solar problem is not limited to the photospheric abundances if the depletion of light elements is considered. In addition, tighter constraints on the solar beryllium abundance will play a key role in the improvement of solar models.

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The solar carbon, nitrogen, and oxygen abundances from a 3D LTE analysis of molecular lines

Carbon, nitrogen, and oxygen are the fourth, sixth, and third most abundant elements in the Sun. Their abundances remain hotly debated due to the so-called solar modelling problem that has persisted for almost $20$ years. We revisit this issue by presenting a homogeneous analysis of $408$ molecular lines across $12$ diagnostic groups, observed in the solar intensity spectrum. Using a realistic 3D radiative-hydrodynamic model solar photosphere and LTE (local thermodynamic equilibrium) line formation, we find $\log\epsilon_{C} = 8.47\pm0.02$, $\log\epsilon_{N} = 7.89\pm0.04$, and $\log\epsilon_{O} = 8.70\pm0.04$. The stipulated uncertainties mainly reflect the sensitivity of the results to the model atmosphere; this sensitivity is correlated between the different diagnostic groups, which all agree with the mean result to within $0.03$ dex. For carbon and oxygen, the molecular results are in excellent agreement with our 3D non-LTE analyses of atomic lines. For nitrogen, however, the molecular indicators give a $0.12$ dex larger abundance than the atomic indicators, and our best estimate of the solar nitrogen abundance is given by the mean: $7.83$ dex. The solar oxygen abundance advocated here is close to our earlier determination of $8.69$ dex, and so the present results do not significantly alleviate the solar modelling problem.

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The chemical make-up of the Sun: A 2020 vision

The chemical composition of the Sun is a fundamental yardstick in astronomy, relative to which essentially all cosmic objects are referenced. We reassess the solar abundances of all 83 long-lived elements, using highly realistic solar modelling and state-of-the-art spectroscopic analysis techniques coupled with the best available atomic data and observations. Our new improved analysis confirms the relatively low solar abundances of C, N, and O obtained in our previous 3D-based studies: $\log\epsilon_{\text{C}}=8.46\pm0.04$, $\log\epsilon_{\text{N}}=7.83\pm0.07$, and $\log\epsilon_{\text{O}}=8.69\pm0.04$. The revised solar abundances for the other elements also typically agree well with our previously recommended values with just Li, F, Ne, Mg, Cl, Kr, Rb, Rh, Ba, W, Ir, and Pb differing by more than $0.05$ dex. The here advocated present-day photospheric metal mass fraction is only slightly higher than our previous value, mainly due to the revised Ne abundance from Genesis solar wind measurements: $X_{\rm surface}=0.7438\pm0.0054$, $Y_{\rm surface}=0.2423\pm 0.0054$, $Z_{\rm surface}=0.0139\pm 0.0006$, and $Z_{\rm surface}/X_{\rm surface}=0.0187\pm 0.0009$. Overall the solar abundances agree well with those of CI chondritic meteorites but we identify a correlation with condensation temperature such that moderately volatile elements are enhanced by $\approx 0.04$ dex in the CI chondrites and refractory elements possibly depleted by $\approx 0.02$ dex, conflicting with conventional wisdom of the past half-century. Instead the solar chemical composition resembles more closely that of the fine-grained matrix of CM chondrites. The so-called solar modelling problem remains intact with our revised solar abundances, suggesting shortcomings with the computed opacities and/or treatment of mixing below the convection zone in existing standard solar models.

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The 3D non-LTE solar nitrogen abundance from atomic lines

Nitrogen is an important element in various fields of stellar and Galactic astronomy, and the solar nitrogen abundance is crucial as a yardstick for comparing different objects in the cosmos. In order to obtain a precise and accurate value for this abundance, we carried out N i line formation calculations in a 3D radiative-hydrodynamic STAGGER model solar atmosphere, in full 3D non-local thermodynamic equilibrium (non-LTE), using a model atom that includes physically-motivated descriptions for the inelastic collisions of N i with free electrons and with neutral hydrogen. We selected five N i lines of high excitation energy to study in detail, based on their strengths and on their being relatively free of blends. We found that these lines are slightly strengthened from non-LTE photon losses and from 3D granulation effects, resulting in negative abundance corrections of around $-0.01$ dex and $-0.04$ dex respectively. Our advocated solar nitrogen abundance is $\log\epsilon_{\mathrm{N}} = 7.77$, with the systematic $1\sigma$ uncertainty estimated to be $0.05$ dex. This result is consistent with earlier studies after correcting for differences in line selections and equivalent widths.

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3D non-LTE line formation of neutral carbon in the Sun

Carbon abundances in late-type stars are important in a variety of astrophysical contexts. However C i lines, one of the main abundance diagnostics, are sensitive to departures from local thermodynamic equilibrium (LTE). We present a model atom for non-LTE analyses of C i lines, that uses a new, physically-motivated recipe for the rates of neutral hydrogen impact excitation. We analyse C i lines in the solar spectrum, employing a three-dimensional (3D) hydrodynamic model solar atmosphere and 3D non-LTE radiative transfer. We find negative non-LTE abundance corrections for C i lines in the solar photosphere, in accordance with previous studies, reaching up to around 0.1 dex in the disk-integrated flux. We also present the first fully consistent 3D non-LTE solar carbon abundance determination: we infer log $\epsilon_{\text{C}}$ = $8.44\pm0.02$, in good agreement with the current standard value. Our models reproduce the observed solar centre-to-limb variations of various C i lines, without any adjustments to the rates of neutral hydrogen impact excitation, suggesting that the proposed recipe may be a solution to the long-standing problem of how to reliably model inelastic collisions with neutral hydrogen in late-type stellar atmospheres.

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The solar model problem resurrected

The new solar composition, when applied to compute a model of the Sun, leads to serious disagreement between the predictions of the model and the observations obtained by helioseismology. New measurements of the coronal Ne/O abundance ratio in nearby stars using X-ray spectra typically find high values of Ne/O=0.4 rather than 0.15 normally adopted for the Sun. Drake & Testa (2005) suggest that this high Ne/O ratio is appropriate also for the Sun, which would bring the solar models back in agreement with the helioseismological observations. Here we present arguments why the high Ne/O ratio is unlikely to be applicable to the Sun.

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Line formation in solar granulation VI. [C I], C I, CH and C2 lines and the photospheric C abundance

The solar photospheric carbon abundance has been determined from [C I], C I, CH vibration-rotation, CH A-X electronic and C2 Swan electronic lines by means of a time-dependent, 3D, hydrodynamical model of the solar atmosphere. Departures from LTE have been considered for the C I lines. These turned out to be of increasing importance for stronger lines and are crucial to remove a trend in LTE abundances with the strengths of the lines. Very gratifying agreement is found among all the atomic and molecular abundance diagnostics in spite of their widely different line formation sensitivities. The mean of the solar carbon abundance based on the four primary abundance indicators ([C I], C I, CH vibration-rotation, C_2 Swan) is log C = 8.39 +/- 0.05, including our best estimate of possible systematic errors. Consistent results also come from the CH electronic lines, which we have relegated to a supporting role due to their sensitivity to the line broadening. The new 3D based solar C abundance is significantly lower than previously estimated in studies using 1D model atmospheres.

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Solar model with CNO revised abundances

Recent three-dimensional, NLTE analyses of the solar spectrum have shown a significant reduction in the C, N, O and Ne abundances leading to a Z/X ratio of the order of 0.0177. We have computed solar models with this new mixture in the OPAL opacity tables. The present He abundance we find seems rather consistent with the helioseismic value. However, the convective envelope is too shallow, and diffusion, even if it reduces the discrepancy, is not able to give the current value. We present some numerical experiments consisting in changing the diffusion velocities and/or the value of opacity at the base of the convective envelope.

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Line formation in solar granulation: IV. [O I], OI and OH lines and the photospheric O abundance

The solar photospheric oxygen abundance has been determined from [OI], OI, OH vibration-rotation and OH pure rotation lines by means of a realistic time-dependent, 3D, hydrodynamical model of the solar atmosphere. In the case of the OI lines, 3D non-LTE calculations have been performed, revealing significant departures from LTE as a result of photon losses in the lines. We derive a solar oxygen abundance of log O = 8.66 +/- 0.05. All oxygen diagnostics yield highly consistent abundances, in sharp contrast with the results of classical 1D model atmospheres. This low value is in good agreement with measurements of the local interstellar medium and nearby B stars. This low abundance is also supported by the excellent correspondence between lines of very different line formation sensitivities, and between the observed and predicted line shapes and center-to-limb variations. Together with the corresponding down-ward revisions of the solar carbon, nitrogen and neon abundances, the resulting significant decrease in solar metal mass fraction to Z = 0.0126 can, however, potentially spoil the impressive agreement between predicted and observed sound speed in the solar interior determined from helioseismology.

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Analysis of the 3d6 4s(6D)4f-5g Supermultiplet of Fe I in Laboratory and Solar Infrared Spectra

The combined laboratory and solar analysis of the highly-excited subconfigurations 4f and 5g of Fe I has allowed us to classify 87 lines of the 4f-5g supermultiplet in the spectral region 2545-2585 cm-1. The level structure of these JK-coupled configurations is predicted by semiempirical calculations and the quadrupolic approximation. Semiempirical gf-values have been calculated and are compared to gf values derived from the solar spectrum. The solar analysis has shown that these lines, which should be much less sensitive than lower excitation lines to departures from LTE and to temperature uncertainties, lead to a solar abundance of iron which is consistent with the meteoritic value (A_Fe = 7.51).

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