N. Guo | Searcharxiv

arXiv2025

Correlation-driven 3d Heavy Fermion behavior in LiV2O4

LiV2O4 is a spinel-structured compound that stands out as the first known 3d-electron system exhibiting typical heavy fermion behavior. A central question is how such strong mass renormalization emerges in the absence of f-electrons. In this work, we investigate the three-dimensional electronic structure of LiV2O4 thin films using angle-resolved photoemission spectroscopy (ARPES). We identify that an electron-like flat band is derived from a1g orbitals, along with a highly dispersive e'g band strongly coupled with phonons. The overall agreement with dynamical mean-field theory (DMFT) calculations highlights the essential role of inter-orbital Hund's coupling in reducing the a1g bandwidth to 25 meV, approaching a Mott state. Notably, we find that heavy-fermion behavior arises from additional renormalization at the a1g band near the Fermi level, likely driven by many-body interactions at energy scales down to a few meV and potentially linked to geometric frustration inherent to the spinel lattice. These results provide crucial insights into the origin of the heavy fermion behavior in 3d-electron systems.

cond-mat.str-el↗

arXiv2024

Cuprate-like Electronic Structures in Infinite-Layer Nickelates with Substantial Hole Dopings

The superconducting infinite-layer (IL) nickelates offer a new platform for investigating the long-standing problem of high-temperature superconductivity. Many models were proposed to understand its superconducting mechanisms based on the calculated electronic structure, and the multiple Fermi surfaces and multiple orbitals involved create complications and controversial conclusions. Over the past 5 years, the lack of direct measurements of the electronic structure has hindered the understanding of nickelate superconductors. Here we fill this gap by directly resolving the electronic structures of the parent compound LaNiO$_2$ and superconducting La$_{0.8}$Ca$_{0.2}$NiO$_2$ using angle-resolved photoemission spectroscopy (ARPES). We find that their Fermi surfaces consist of a quasi-two-dimensional (quasi-2D) hole pocket and a three-dimensional (3D) electron pocket at the Brillouin zone corner, whose volumes change upon Ca doping. The Fermi surface topology and band dispersion of the hole pocket closely resemble those observed in hole-doped cuprates. However, the cuprate-like band exhibits significantly higher hole doping in superconducting La$_{0.8}$Ca$_{0.2}$NiO$_2$ compared to superconducting cuprates, highlighting the disparities in the electronic states of the superconducting phase. Our observations highlight the novel aspects of the IL nickelates, and pave the way toward the microscopic understanding of the IL nickelate family and its superconductivity.

cond-mat.supr-con↗