arXiv subjects

N. Johansson

Publications and source records attributed to N. Johansson.

4 recordsLinked to original sources

arXiv2012

The electronic structure of poly(pyridine-2,5-diyl) investigated by soft x-ray absorption and emission spectroscopies

The electronic structure of the poly-pyridine conjugated polymer has been investigated by resonant and nonresonant inelastic X-ray scattering and X-ray absorption spectroscopies using synchrotron radiation. The measurements were made for both the carbon and nitrogen contents of the polymer. The analysis of the spectra has been carried out in comparison with molecular orbital calculations taking the repeat-unit cell as a model molecule of the polymer chain. The simulations indicate no significant differences in the absorption and in the non-resonant X-ray scattering spectra for the different isomeric geometries, while some isomeric dependence of the resonant spectra is predicted. The resonant emission spectra show depletion of the π electron bands in line with symmetry selection and momentum conservation rules. The effect is most vizual for the carbon spectra; the nitrogen spectra are dominated by lone pair n orbital emission of σ symmetry and are less frequency dependent.

cond-mat.soft↗

arXiv2012

Resonant inelastic soft-x-ray scattering spectra at the N1s and C1s edges of poly(pyridine-2,5-diyl)

Resonant inelastic scattering measurements of poly(pyridine-2,5-diyl) have been performed at the N1s and C1s edges using synchrotron radiation. For comparison, molecular orbital calculations of the spectra have been carried out with the repeat unit as a model molecule of the polymer chain. The resonant emission spectra show depletion of the p electron bands which is consistent with symmetry selection and momentum conservation rules. The depletion is most obvious in the resonant inelastic scattering spectra of carbon while the nitrogen spectra are dominated by lone pair n orbital emission of s symmetry and are less excitation energy dependent. By comparing the measurements to calculations an isomeric dependence of the resonant spectra is found giving preference to two of the four possible isomers in the polymer.

cond-mat.soft↗

arXiv2011

Holograms of Conformal Chern-Simons Gravity

We show that conformal Chern-Simons gravity in three dimensions has various holographic descriptions. They depend on the boundary conditions on the conformal equivalence class and the Weyl factor, even when the former is restricted to asymptotic Anti-deSitter behavior. For constant or fixed Weyl factor our results agree with a suitable scaling limit of topologically massive gravity results. For varying Weyl factor we find an enhancement of the asymptotic symmetry group, the details of which depend on certain choices. We focus on a particular example where an affine u(1) algebra related to holomorphic Weyl rescalings shifts one of the central charges by 1. The Weyl factor then behaves as a free chiral boson in the dual conformal field theory.

hep-th↗

arXiv2008

Canonical analysis of cosmological topologically massive gravity at the chiral point

Wolfgang Kummer was a pioneer of two-dimensional gravity and a strong advocate of the first order formulation in terms of Cartan variables. In the present work we apply Wolfgang Kummer's philosophy, the `Vienna School approach', to a specific three-dimensional model of gravity, cosmological topologically massive gravity at the chiral point. Exploiting a new Chern-Simons representation we perform a canonical analysis. The dimension of the physical phase space is two per point, and thus the theory exhibits a local physical degree of freedom, the topologically massive graviton.

hep-th↗