arXiv subjects

N. Kowalski

Publications and source records attributed to N. Kowalski.

4 recordsLinked to original sources

arXiv2025

Charge gap and charge redistribution among copper and oxygen orbitals in the normal state of the Emery model

Unraveling the behavior of the electrons in the copper-oxygen planes of cuprate superconductors remains a challenge. Here we examine the electronic charge redistribution among planar copper and oxygen orbitals and the charge gap using the Emery model in the normal state, solved with cellular dynamical mean-field theory at finite temperature. We quantify the charge redistribution as a function of the onsite Coulomb repulsion on the copper orbitals, the bare copper-oxygen energy difference, and the hole or electron doping. We find that the position relative to the metal to insulator boundary of the Zaanen-Sawatzky-Allen diagram determines the charge redistribution among copper and oxygen orbitals. For a fixed bare Cu-O energy difference, an increase in the Cu electron repulsion leads to a transfer of the electronic charge from Cu to O orbitals. For a fixed charge gap size of the undoped state, as the system evolves from a charge-transfer to a Mott-Hubbard regime, the electronic charge is transferred from Cu to O orbitals. Our findings posit the Coulomb repulsion and the bare charge-transfer energy as key drivers of the microscopic process of charge redistribution in the CuO$_2$ plane. They quantify the anticorrelation between the charge gap size and oxygen hole content. They show that for fixed band-structure parameters, the charge gap and the charge redistribution between Cu and O orbitals provide a way to understand observed trends in cuprates.

cond-mat.str-el↗

arXiv2025

Ambipolar doping of a charge-transfer insulator in the Emery model

Understanding the similarities and differences between adding or removing electrons from a charge-transfer insulator may provide insights about the origin of the electron-hole asymmetry found in cuprates. Here we study with cellular dynamical mean-field theory the Emery model set in the charge-transfer insulator regime, and dope it with either electrons or holes. We consider the normal state only and focus on the doping evolution of the orbital character of the dopants and on the nature of the doping driven transition. Regarding the orbital character of the dopants, we found an electron-hole asymmetry: doped electrons mostly enter the copper orbitals, whereas doped holes mostly enter the oxygen orbitals. Regarding the nature of the doping driven transition, we found no qualitative electron-hole asymmetry: upon either electron or hole doping, there is a two-stage transition from a charge-transfer insulator to a strongly correlated pseudogap and then to a metal. This shows that a strongly correlated pseudogap is an emergent feature of doped correlated insulators in two dimensions, in qualitative agreement with recent experiments on ambipolar Sr$_{1-x}$La$_{x}$CuO$_{2+y}$ cuprate films. Our results indicate that merely doping with holes or electrons a charge-transfer insulator is not sufficient for explaining the electron-hole asymmetry observed in the normal state phase diagram of cuprates. Our work reinforces the view that actual hole-doped cuprates are more correlated than their electron-doped counterparts.

cond-mat.str-el↗

arXiv2023

Entangleware Sequencer: A Control Platform for Atomic Physics Experiments

Experimental quantum physics and computing platforms rely on sophisticated computer control and timing systems that must be deterministic. An exemplar is the sequence used to create a Bose-Einstein condensate at the University of Illinois, which involves 46,812 analog and digital transitions over 100 seconds with 20 ns timing precision and nanosecond timing drift. We present a control and sequencing platform, using industry-standard National Instruments hardware to generate the necessary digital and analog signals, that achieves this level of performance. The system uses a master 10 MHz reference clock that is conditioned to the Global Positioning Satellite constellation and leverages low-phase-noise clock distribution hardware for timing stability. A Python-based user front-end provides a flexible language to describe experimental procedures and easy-to-implement version control. A library of useful peripheral hardware that can be purchased as low-cost evaluation boards provides enhanced capabilities. We provide a GitHub repository containing example python sequences and libraries for peripheral devices as a resource for the community.

quant-ph↗

arXiv2021

Oxygen hole content, charge-transfer gap, covalency, and cuprate superconductivity

Experiments have shown that the families of cuprate superconductors that have the largest transition temperature at optimal doping also have the largest oxygen hole content at that doping. They have also shown that a large charge-transfer gap, a quantity accessible in the normal state, is detrimental to superconductivity. We solve the three-band Hubbard model with cellular dynamical mean-field theory and show that both of these observations follow from the model. Cuprates play a special role amongst doped charge-transfer insulators of transition metal oxides because copper has the largest covalent bonding with oxygen.

cond-mat.supr-con↗