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N. L. J. Cox

Publications and source records attributed to N. L. J. Cox.

At least 19 recordsLinked to original sources

MUSE Imaging Spectroscopy of the Fullerene Planetary Nebula Tc 1

The planetary nebula Tc 1 (PN G345.2 -08.8), one of the rare group of Galactic PNe showing fullerene emission in the infrared, was observed with MUSE wide field mode with adaptive optics, wavelength range 4750-9300A. Extinction, electron temperature (T_e) and density (N_e) images are presented from collisionally excited and recombination line ratios. The nebula has a high surface brightness 12 arcsec core, an elliptical ring of major axis 2.8 arcsec around the central star and some low ionization knots, and an extended halo 55 arcsec in size; between the core and halo is an annulus with intermediate properties, including higher T_e and lower N_e than in the core. The image of optical extinction from H Balmer line ratios is highly structured, and shows an annulus, adjacent to the core, of low extinction, lower than the line-of-sight interstellar extinction. Instrumental effects to account for this anomalously low extinction area are investigated and intrinsic effects from the scattering properties of nebular dust; neither can entirely explain the low-extinction region and the most likely cause is a local non-standard dust reddening law. This low extinction region also shows an anomalously high He I 7281/6678A line ratio, possibly caused by a contaminating line, but none were conclusively identified. The spectrum of the central star was extracted and fitted by a 31000K model atmosphere and is of type O7.5I(f). Over extended regions an enhancement of the detected continuum above the nebular continuum was found, as also seen in some other PNe observed with MUSE. The annulus of low extinction occurs outside the region of strongest fullerene emission, in the zone where N_e declines and T_e rises. A change in dust properties linked to conditions in this transition region between the higher density core nebula and lower density halo is deduced. (Abridged)

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The EDIBLES survey. X. The 6196 Å diffuse interstellar band: Identification of side DIBs as an indication of a small carrier molecule

Context: Numerous studies of diffuse interstellar band (DIB) profiles have detected substructures, which in turn suggests that large molecules are acting as their carriers. However, some of the narrowest DIBs generally do not show such substructures, suggesting the possibility of very small carriers. Aims: Based on the previously found tight correlation of the three narrow DIBs at 6196, 6440 and 6623 A and the present detection of weaker side DIBs to each of them in the extensive data set from the ESO Diffuse Interstellar Bands Large Exploration Survey, we investigated whether they may stem from small linear carrier molecules. This approach can lead to concrete DIB carrier suggestions, which can be tested in laboratory measurements in future studies. Methods: We suggest that the DIBs we studied here represent individual rotational transitions of a small molecule. We determined the molecular constants from observations and compared them with data from a large set of quantum-chemical calculations to constrain possible carrier candidates. Furthermore, we determined the rotational temperatures by fitting line ratios using the fitted molecular models. Results: We determined molecular constants for three DIB systems and the corresponding transition types. The fitted rotational temperatures lie within the range of known interstellar diatomic molecules. We identified several DIB carrier candidates, almost all of them molecular ions. Some of them are metastable species, indicating the possibility of collision complexes as DIB carriers. Conclusions: If our hypothesis holds, this would be a major step towards the identification of a carrier molecule of the 6196 A DIB, the strongest among the narrow DIBs.

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Diffuse interstellar bands as dust indicators: the contribution from 3D maps

We used 3D maps of 862nm DIB equivalent width (EW) and extinction, DIB catalogues, and measured parameters of dust extinction law and dust emission to study relationships between DIB and extinction level, total-to-selective extinction ratio Rv, dust emission spectral index beta. We revisited the link between several DIBs and the 220nm absorption bump. The ratio, DIBn862, between the 862nm DIB carrier density and the extinction density is increasing in low density clouds, confirming with local values the line-of-sight data. A fitted power law ranks this DIB in the high increase range among the 20 bands measured toward SDSS targets. Using map-integrated 862nm DIB EWs and extinctions along the paths to APOGEE targets with proxies R'v for Rv, we found that DIBn862 increases with R'v for low to moderate extinctions (Av<2-3 mag). Based on stars outside the thin disk, DIBn862 is found to be globally anti-correlated with the Planck opacity spectral index beta. In the light of a recent result on the variability of the carbon/silicate ratio in dust grains as a source of the Rv-beta anti-correlation, it suggests that DIBn862 increases with this ratio, in agreement with the carbonaceous nature of carriers and recent evidences for a spatial correlation between DIBn862 and carbon-rich ejecta of AGBs. At higher Av, both trends disappear. We found that two factors explain the absence of clear results on the link between the UV absorption bump height and DIBs: the correlation disappears when we move from sigma- to zeta-type DIBs and/or from single-cloud lines of sight to paths crossing multiple clouds distant from each other. We show examples of simple models of the bump height based on DIBs. We found an anti-correlation between DIBn and the bump width, similarly disappearing from sigma- to zeta-type DIBs. This suggests that a fraction of the bump is generated outside the dense molecular clouds.

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Volume density maps of the 862nm DIB carrier and interstellar dust: a hint for the role of carbon-rich ejecta from AGB stars?

The carbonaceous macromolecules imprinting in astronomical spectra the numerous absorptions called Diffuse Interstellar Bands (DIBs) are omnipresent in the Galaxy and beyond and represent a considerable reservoir of organic matter. However, their chemical formulae, formation and destruction sites remain open questions. Their spatial distribution and the local relation to other interstellar species is paramount to unravel their role in the lifecycle of organic matter. Volume density maps bring local instead of line-of-sight distributed information, and allow for new diagnostics. We present the first large-scale volume (3D) density map of a DIB carrier and compare it with an equivalent map of interstellar dust. The DIB carrier map is obtained through hierarchical inversion of about 202,000 measurements of the 8621 nm DIB obtained with the Gaia-RVS instrument. It covers about 4000 pc around the Sun in the Galactic plane. A dedicated interstellar dust map is built based on extinction towards the same target stars. At the 50 pc resolution of the maps, the 3D DIB distribution is found remarkably similar in shape to the 3D distribution of dust. On the other hand, the DIB-to-dust local density ratio increases in low-dust areas. It is also increasing away from the disk, however, the minimum ratio is found to be shifted above the Plane to Z = +50pc. Finally, the average ratio is also surprisingly found to increase away from the Galactic Center. We suggest that the three latter trends may be indications of a dominant contribution of material from the carbon-rich category of dying giant stars to the formation of the carriers. Our suggestion is based on recent catalogues of AGB stars and estimates of their mass fluxes of C-rich and O-rich ejecta.

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The EDIBLES Survey. VIII. Band profile alignment of diffuse interstellar bands

Context: There have been many attempts to identify families of diffuse interstellar bands (DIBs) with perfectly correlating band strengths. Although major efforts have been made to classify broadly based DIB families and important insights have been gained, no family has been identified with sufficient accuracy or statistical significance to prove that a series of selected DIBs originates from the same carrier. This can be attributed in part to the exclusive use of equivalent widths to establish DIB families. Aims: In a change of strategy, we search for DIBs that are highly correlated in both band strength and profile shape. This approach increases the chance of correlating DIBs being members of one family and originating from the same carrier molecule. We also search for correlations between DIB profile families and atomic interstellar lines, with the goal of further chemically constraining possible DIB carriers. Methods: We adapted the well-known method of time-series alignment to perform a spectral alignment; that is, DIB alignment. In a second step, we analysed the alignment results using a clustering analysis. This method required a statistically significant data set of DIB sight lines. The ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) data were perfectly suited for this application. Results: We report eight DIB families with correlating strengths and profiles, as well as four previously unreported DIBs in the visual range, found using DIB alignment. All profile family members show Pearson correlation coefficients in band strength higher than 0.9. In particular, we report the 6614 - 6521 AA DIB pair, in which both DIBs show the same triple-peak substructure and an unprecedented band strength Pearson correlation coefficient of 0.9935. The presented approach opens up new perspectives that can guide the laboratory search for DIB carriers.

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A high resolution study of near-IR diffuse interstellar bands, search for small scale structure, time variability and stellar features

Diffuse interstellar bands comprise hundreds of absorption features in the ISM. Most DIBs are observed in the optical, but some are in the IR. We observed 76 early-type stars at R=50,000 and S/N ratios of several hundreds using CRIRES. We measure DIBs around 1318, 1527, 1561, 1565, 1567, 1574 and/or 1624 nm. We detect a total of 6 DIB features and 17 likely stellar features assisted by a CMFGEN model. We also measured the DIBs at 1318 and 1527 nm using X-shooter towards ten Ceph. variables with 3.2 < E(B-V) < 6.5 and 4 stars at low values of water vapour. Correlation coeffs. of 0.73-0.96 are found comparing NIRDIB eq. width vs. E(B-V) and with r > 0.8 when comparing the NIR and optical DIBs 5705, 5780, 6203, 6283 and 6269 A. The 5797 A DIB is less well correlated with the NIDIBs. The "C60+" DIB at 9632 A is not well correlated with the 1318 nm DIB. Partial correlation coefficients using E(B-V) as the covariate were also determined. For stars earlier than B2, the 1318 nm DIB is affected by an emission line on its blue wing, likely stellar in nature, although we cannot rule out interstellar/circumstellar origin for example caused by by a DIB in emission. The 1318 nm DIB has a red wing and is reasonably well fitted by two gaussians. Neither the component ratios nor separation are correlated with 5780/5797 or E(B-V). EW(1318 nm) correlates with HI with EW(1318 nm)/E(B-V) decreasing with f(H2). Five pairs of stars within 1 am show similar 1318 nm DIB profiles. Variation in 1318 nm is seen in HD 145501/145502 and HD 168607/168625 pairs. CRIRES data for 17 stars separated by 6-14 months and 2 X-shooter sightlines separated by 9.9 yr were analysed. No time-variability is detected in the 5780, 5797 A, 1318 nm or 1527 nm DIBs. Tentative time variation is observed in the C60+ DIBs at 9577 and 9632 A towards HD 183143 although very close to the noise level with confirmation required.

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Three-dimensional extinction maps: Inverting inter-calibrated extinction catalogues

3D maps of the extinction density in the Galaxy can be built through the inversion of catalogues of distance-extinction pairs for individual target stars. The spatial resolution of the maps that can be achieved increases with the spatial density of the targets, and subsequently with the combination of catalogues. However, this requires their careful inter-calibration. Our aim is to develop methods of inter-calibration of two different catalogues. We used as reference a spectrophotometric catalogue. A principal component analysis was performed in G,GB,GR,J,H,K multi-colour space for the second catalog. The subspace constituted by the two first components was split into cells in which we estimated deviations from the reference. The deviations were computed using all targets from the reference located at a short spatial distance of each secondary target. Corrections and filtering were deduced for each cell in the multi-colour space. We applied the technique to two different datasets: on the one hand, the spectrophotometric catalogue, and, on the other hand, a catalogue of extinctions based on photometry of Gaia eDR3 and 2MASS. After calibration, the dispersion of the extinction among neighbouring points in the second catalogue is reduced, regardless of whether reference targets are present locally. Weak structures are then more apparent. The extinction of high Galactic latitude targets is more tightly correlated with the dust emission, a property acquired from the first catalogue. A hierarchical inversion technique was applied to the two merged inter-calibrated catalogues to produce 3D extinction density maps corresponding to different volumes and maximum spatial resolution. The maximum resolution is 10pc for a 3000x3000x800pc3 volume around the Sun, and the maximum size of the maps is 10x10x0.8 kpc3 for a resolution of 50pc. Maps can be downloaded or used by means of on-line tools.

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Updated Gaia-2MASS 3D maps of Galactic interstellar dust

Three-dimensional (3D) maps of Galactic interstellar dust are a tool for a wide range of uses. We aim to construct 3D maps of dust extinction in the Local Arm and surrounding regions. Gaia EDR3 photometric data were combined with 2MASS measurements to derive extinction towards stars with accurate photometry and relative uncertainties on parallaxes of less than 20%. We applied our hierarchical inversion algorithm adapted to inhomogeneous spatial distributions of target stars to this catalogue of extinctions. We present the updated 3D dust extinction distribution and provide an estimate of the error on integrated extinctions from the Sun to each area in the 3D map. The computational area is similar to the one of the previous DR2 map, a 6 kpc x 6 kpc x 0.8 kpcAstrophysics volume around the Sun. Due to the addition of fainter target stars, the volume in which the clouds can be reconstructed has increased. Due to the improved accuracy of the parallaxes and photometric data in EDR3, extinctions among neighbouring targets are more consistent, allowing one to reach an increased contrast in the dense areas, while cavity contours are more regular. We show several comparisons with recent results on dust and star distributions. The wavy pattern around the Plane of the dust concentrations is better seen and exists over large regions. Its mean vertical peak-to-peak amplitude is of the order of 300 pc; interestingly, it is similar to the vertical period of the spectacular snail-shaped stellar kinematical pattern discovered in Gaia data. The Gaia EDR3 catalogue allows for a significant improvement of the extinction maps to be made and the hierarchical technique confirms its efficiency for massive datasets. Future comparisons between 3D maps of interstellar matter and stellar distributions may help to understand which mergers or internal perturbations have shaped the Galaxy within the first 3 kpc.

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Optical/near-infrared observations of the Fried Egg Nebula: Multiple shell ejections on a 100 yr timescale from a massive yellow hypergiant

Context. The fate of a massive star during the latest stages of its evolution is highly dependent on its mass-loss rate/geometry and therefore knowing the geometry of the circumstellar material close to the star and its surroundings is crucial. Aims. We aim to study the nature (i.e. geometry, rates) of mass-loss episodes. In this context, yellow hypergiants are great targets. Methods. We analyse a large set of optical/near-infrared data, in spectroscopic and photometric (X-shooter/VLT), spectropolarimetric (ISIS/WHT), and interferometric GRAVITY-AMBER/VLTI) modes, toward the yellow hypergiant IRAS 17163-3907. We present the first model-independent reconstructed images of IRAS 17163-3907 at these wavelengths at milli-arcsecond scales. Lastly, we apply a 2D radiative transfer model to fit the dereddened photometry and the radial profiles of published VISIR images at 8.59 μm, 11.85 μm and 12.81 μm simultaneously, adopting the revised Gaia distance (DR2). Results. The interferometric observables around 2 μm show that the Brγ emission is more extended and asymmetric than the Na i and the continuum emission. In addition to the two known shells surrounding IRAS 17163-3907 we report on the existence of a third hot inner shell with a maximum dynamical age of only 30 yr. Conclusions. The interpretation of the presence of Na i emission at closer distances to the star compared to Brγ has been a challenge in various studies. We argue that the presence of a pseudophotosphere is not needed, but it is rather an optical depth effect. The three observed distinct mass-loss episodes are characterised by different mass-loss rates and can inform the theories on mass-loss mechanisms, which is a topic still under debate. We discuss these in the context of photospheric pulsations and wind bi-stability mechanisms.

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Confirming interstellar C$_{60}^+$ using the Hubble Space Telescope

Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C60+) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C60+ requires a match between the wavelengths and the expected strengths of all absorption features detectable in the laboratory and in space. Here we present Hubble Space Telescope (HST) spectra of the region covering the C60+ 9348, 9365, 9428 and 9577 Å absorption bands toward seven heavily-reddened stars. We focus in particular on searching for the weaker laboratory C60+ bands, the very presence of which has been a matter for recent debate. Using the novel STIS-scanning technique to obtain ultra-high signal-to-noise spectra without contamination from telluric absorption that afflicted previous ground-based observations, we obtained reliable detections of the (weak) 9365, 9428 Å and (strong) 9577 Å C60+ bands. The band wavelengths and strength ratios are sufficiently similar to those determined in the latest laboratory experiments that we consider this the first robust identification of the 9428 Å band, and a conclusive confirmation of interstellar C60+.

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A remarkable change of the spectrum of the magnetic Of?p star HD 148937 reveals evidence of an eccentric, high-mass binary

We report new spectroscopic observations of the magnetic Of?p star HD 148937 obtained since 2015 that differ qualitatively from its extensive historical record of weak, periodic spectral variations. This remarkable behaviour represents clear evidence for an unprecedented change in the character of variability of the star. In this paper we describe the new spectral properties and compare them to the previous line profiles. Based on measurements of the radial velocities of the C iii/N iii} emission lines near 4640 Å and the C iv absorption lines near 5800 Å, we infer that HD 148937 is likely a high-mass, double-lined spectroscopic binary. Combining the spectroscopic orbit with an archival interferometric measurement of the apparent separation of the equal-brightness components, we tentatively conclude that HD 148937 consists of two O-type stars with masses of approximately 34 and $49~M_\odot$, orbiting in an eccentric ($e=0.75$), long-period ($P_{\rm orb}\sim 26$ y) orbit. We discuss the potential relationship of the binary system to the peculiar properties of HD 148937, and propose future observations to refine the orbital and stellar properties.

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Diffuse interstellar bands in the HII region M17: Insights into their relation with the total-to-selective visual extinction $R_V$

Diffuse interstellar bands (DIBs) are broad absorption features measured in sightlines probing the diffuse interstellar medium. Although large carbon-bearing molecules have been proposed as the carriers producing DIBs, their identity remains unknown. The sight line to the young massive star-forming region M17 shows anomalous extinction in the sense that the total-to-selective extinction parameter differs significantly from the average Galactic value and may reach values $R_{V} > 4$. Given the high $R_V$ values, we investigate whether the DIBs in sight lines towards young OB stars in M17 show a peculiar behaviour. We measure the properties of the most prominent DIBs in M17 and study these as a function of $E(B-V)$ and $R_{V}$. The DIB strengths in M17 concur with the observed relations between DIB equivalent width and reddening $E(B-V)$ in Galactic sight lines. For several DIBs we discover a linear relation between the normalised DIB strength EW/$A_{V}$ and $R_{V}^{-1}$. These trends suggest two groups: (i) a group of ten moderately strong DIBs that show a sensitivity to changes in $R_{V}$ that is modest and proportional to DIB strength, and (ii) a group of four very strong DIBs that react sensitively and to a similar degree to changes in $R_{V}$, but in a way that does not appear to depend on DIB strength. The DIB behaviour as a function of reddening is not peculiar in sight lines to M17. Also, we do not detect anomalous DIB profiles as seen in Her 36. DIBs are stronger, per unit visual extinction, in sight lines characterised by a smaller value of $R_{V}$ (large fraction of small dust particles). New relations between extinction normalised DIB strengths, EW/$A_V$, and $R_V$ support the idea that DIB carriers and interstellar dust are connected. Given the distinct behaviour of two groups of DIBs, different types of carriers do not necessarily relate to the dust grains in a similar way.

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The EDIBLES survey III. C2-DIBs and their profiles

The so-called C2-DIBs are a class of very weak bands that fall in the blue part of the optical spectrum and are associated with high column densities of the C2 molecule. DIB profile structures constrain potential molecular carriers, but their measurement requires high S/N and spectra and the use of sightlines without Doppler splitting, as typical for a single-cloud situation. Spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) conducted at the VLT (ESO/Paranal) were explored to identify single-cloud and high C2 column sightlines, extract the corresponding C2-DIBs and study their strengths and profiles, and to investigate in detail any sub-structures. The target selection was made based on profile-fitting of the Sodium doublets and the detection of C2 lines. The C2 (2-0) Phillips system was fitted using a physical model of the host cloud. C2 column densities, temperatures as well as gas densities were derived for each sightline. 18 known C2-DIBs and 8 strong non-C2 DIBs were extracted towards 8 targets, comprising 7 single-cloud and one multi-cloud line-of-sights. Correlational studies revealed a tight association of the former group with the C2 columns, whereas the non-C2 DIBs are primarily correlated with reddening. We report three new weak diffuse band candidates. We show for the first time that at least 14 C2-DIBs exhibit spectral sub-structures which are consistent with unresolved rotational branches of molecular carriers. The variability of their peak separations among the bands for a given sightline implies that their carriers are different molecules with quite different sizes. We also illustrate how profiles of the same DIB vary among targets and as a function of physical parameters and provide tables defining the sub-structures to be compared with future models and experimental results.

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EDIBLES II. On the detectability of C60+ bands

Gas phase spectroscopic laboratory experiments for the buckminsterfullerene cation C60+ resulted in accurate rest wavelengths for five C60+ transitions that have been compared with diffuse interstellar bands (DIBs) in the near infra-red. Detecting these in astronomical spectra is difficult due to the strong contamination of ground-based spectra by atmospheric water vapor, to the presence of weak and shallow stellar lines and/or blending with other weak DIBs. The detection of the two strong bands has been claimed by several teams, and the three additional and weaker bands have been detected in a few sources. Certain recent papers have argued against the identification of C60+ based on spectral analyses claiming (i) a large variation in the ratio between the equivalent widths of the 9632 and 9577Å\: bands, (ii) a large redshift of the 9632Å\: band for the Orion star HD 37022, and (iii) the non-detection of the weaker 9428Å~DIB. Here we address these three points. (i) We show that the model stellar line correction for the 9632Å~DIB overestimates the difference between the strengths of the lines in giant and dwarf star spectra, casting doubts on the conclusions about the ratio variability. (ii) Using high quality stellar spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES), recorded with the ESO/Paranal Ultraviolet Echelle Spectrograph (UVES) in about the same atmospheric conditions, we find no wavelength shift in the 9632Å band towards HD 37022. (iii) Using EDIBLES spectra and data from the Echelle SpectroPolarimetric Device for the Observation of Stars (ESPaDOnS) at CFHT we show that the presence of a weak 9428Å band cannot be ruled out, even in the same observations that a previous study claimed it was not present.

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Large Interstellar Polarisation Survey II. UV/optical study of cloud-to-cloud variations of dust in the diffuse ISM

It is well known that the dust properties of the diffuse interstellar medium exhibit variations towards different sight-lines on a large scale. We have investigated the variability of the dust characteristics on a small scale, and from cloud-to-cloud. We use low-resolution spectro-polarimetric data obtained in the context of the Large Interstellar Polarisation Survey (LIPS) towards 59 sight-lines in the Southern Hemisphere, and we fit these data using a dust model composed of silicate and carbon particles with sizes from the molecular to the sub-micrometre domain. Large (> 6 nm) silicates of prolate shape account for the observed polarisation. For 32 sight-lines we complement our data set with UVES archive high-resolution spectra, which enable us to establish the presence of single-cloud or multiple-clouds towards individual sight-lines. We find that the majority of these 35 sight-lines intersect two or more clouds, while eight of them are dominated by a single absorbing cloud. We confirm several correlations between extinction and parameters of the Serkowski law with dust parameters, but we also find previously undetected correlations between these parameters that are valid only in single-cloud sight-lines. We find that interstellar polarisation from multiple-clouds is smaller than from single-cloud sight-lines, showing that the presence of a second or more clouds depolarises the incoming radiation. We find large variations of the dust characteristics from cloud-to-cloud. However, when we average a sufficiently large number of clouds in single-cloud or multiple-cloud sight-lines, we always retrieve similar mean dust parameters. The typical dust abundances of the single-cloud cases are [C]/[H] = 92 ppm and [Si]/[H] = 20 ppm.

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The 15273 Å diffuse interstellar band in the dark cloud Barnard 68

High obscuration of background stars behind dark clouds precludes the detection of optical diffuse interstellar bands (DIBs) and hence our knowledge of DIB carriers in these environments. Taking advantage of the reduced obscuration of star-light in the near-infrared (NIR) we used one of the strongest NIR DIBs at 15273 AA to probe the presence and properties of its carrier throughout the nearby interstellar dark cloud Barnard 68. Equivalent widths (EW) have been measured for different ranges of visual extinction AV, using VLT-KMOS H-band (1.46-1.85 micron) moderate-resolution (R = 4000) spectra of 43 stars situated behind the cloud. To do so we fitted the data using synthetic stellar spectra from the APOGEE project and TAPAS synthetic telluric transmissions appropriate for the observing site and time period. The results show an increase of DIB EW with increasing AV. However, the rate of increase is much flatter than expected from the EW-AV quasi-proportionality established for this DIB in the Galactic diffuse interstellar medium. Based on a simplified inversion assuming sphericity, it is found that the volume density of the DIB carrier is 2.7 and 7.9 times lower than this expected average value in the external and central regions of the cloud which have n(H)= 0.4 and 3.5 x 105 cm3, respectively. Further measurements with multiplex NIR spectrographs should allow detailed modeling of such an edge effect of this DIB and other bands and help to clarify its actual origin.

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Detection of Buckminsterfullerene emission in the diffuse interstellar medium

Emission of fullerenes in their infrared vibrational bands has been detected in space near hot stars. The proposed attribution of the diffuse interstellar bands at 9577 and 9632 Å to electronic transitions of the buckminsterfullerene cation (i.e. C$_{60}^+$ ) was recently supported by new laboratory data, confirming the presence of this species in the diffuse interstellar medium (ISM). In this letter, we present the detection, also in the diffuse ISM, of the 17.4 and 18.9 $μ$m emission bands commonly attributed to vibrational bands of neutral C$_{60}$. According to classical models that compute the charge state of large molecules in space, C$_{60}$ is expected to be mostly neutral in the diffuse ISM. This is in agreement with the abundances of diffuse C$_{60}$ we derive here from observations.

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Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy

Due to recent advances in laboratory spectroscopy, the first optical detection of a very large molecule has been claimed in the diffuse interstellar medium (ISM): C60+ (ionized Buckminsterfullerene). Confirming the presence of this molecule would have significant implications regarding the carbon budget and chemical complexity of the ISM. Here we present results from a new method for ultra-high signal-to-noise (S/N) spectroscopy of background stars in the near infrared (at wavelengths 0.9-1 micron), using the Hubble Space Telescope Imaging Spectrograph (STIS) in a previously untested `STIS scan' mode. The use of HST provides the crucial benefit of eliminating the need for error-prone telluric correction methods in the part of the spectrum where the C60+ bands lie, and terrestrial water vapor contamination is severe. Our STIS spectrum of the heavily-reddened B0 star BD63\,1964 reaches an unprecedented S/N for this instrument ($\sim600-800$), allowing the detection of the diffuse interstellar band (DIB) at 9577 Å attributed to C60+ as well as new DIBs in the near-IR. Unfortunately, the presence of overlapping stellar lines, and the unexpected weakness of the C60+ bands in this sightline, prevents conclusive detection of the weaker C60+ bands. A probable correlation between the 9577 Å DIB strength and interstellar radiation field is identified, which suggests that more strongly-irradiated interstellar sightlines will provide the optimal targets for future C60+ searches.

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