arXiv subjects

N. Lorente

Publications and source records attributed to N. Lorente.

At least 19 recordsLinked to original sources

arXiv2024

Molecular spin-probe sensing of H-mediated changes in Co nanomagnets

The influence of hydrogen on magnetization is of significant interest to spintronics. Understanding and controlling this phenomenon at the atomic scale, particularly in nanoscale systems, is crucial. In this study, we utilized scanning tunneling microscopy (STM) combined with a nickelocene molecule to sense the spin of a hydrogen-loaded nanoscale Co island grown on Cu(111). Magnetic exchange maps obtained from the molecular tip revealed the presence of a hydrogen superstructure and a 90$^{\circ}$ rotation of the magnetization compared to the pristine island. \textit{Ab initio} calculations corroborate these observations, indicating that hydrogen hybridization with Co atoms on the island surface drives the spin reorientation of the island. This reorientation is further reinforced by hydrogen penetration into the island that locates at the Co/Cu interface. However, the subsurface sensitivity of the magnetic exchange maps indicate that this effect is limited. Our study provides valuable microscopic insights into the chemical control of magnetism at the nanoscale.

cond-mat.mtrl-sci↗

arXiv2023

Single-spin quantum sensing: A molecule-on-tip approach

Quantum sensing is a key component of quantum technology, enabling highly sensitive magnetometry. We combined a nickelocene molecule with scanning tunneling microscopy to perform versatile spin sensing of magnetic surfaces, namely of model Co islands on Cu(111) of different thickness. We demonstrate that atomic-scale sensitivity to spin polarization and orientation is possible due to direct exchange coupling between the Nc-tip and the Co surfaces. We find that magnetic exchange maps lead to unique signatures, which are well described by computed spin density maps. These advancements improve our ability to probe magnetic properties at the atomic level.

cond-mat.mes-hall↗

arXiv2023

A Nanocar and Rotor in One Molecule

Depending on its adsorption conformation on the Au(111) surface, a zwitterionic single-molecule machine works in two different ways under bias voltage pulses. It is a unidirectional rotor while anchored on the surface. It is a fast-drivable molecule-vehicle (nanocar) while physisorbed. By tuning the surface coverage, the conformation of the molecule can be selected to be either rotor or nanocar. The inelastic tunneling excitation producing the movement is investigated in the same experimental conditions for both the unidirectional rotation of the rotor and the directed movement of the nanocar.

physics.chem-ph↗

arXiv2021

The SAMI Galaxy Survey: the drivers of gas and stellar metallicity differences in galaxies

The combination of gas-phase oxygen abundances and stellar metallicities can provide us with unique insights into the metal enrichment histories of galaxies. In this work, we compare the stellar and gas-phase metallicities measured within a 1$R_{e}$ aperture for a representative sample of 472 star-forming galaxies extracted from the SAMI Galaxy Survey. We confirm that the stellar and interstellar medium (ISM) metallicities are strongly correlated, with scatter $\sim$3 times smaller than that found in previous works, and that integrated stellar populations are generally more metal-poor than the ISM, especially in low-mass galaxies. The ratio between the two metallicities strongly correlates with several integrated galaxy properties including stellar mass, specific star formation rate, and a gravitational potential proxy. However, we show that these trends are primarily a consequence of: (a) the different star formation and metal enrichment histories of the galaxies, and (b) the fact that while stellar metallicities trace primarily iron enrichment, gas-phase metallicity indicators are calibrated to the enrichment of oxygen in the ISM. Indeed, once both metallicities are converted to the same `element base' all of our trends become significantly weaker. Interestingly, the ratio of gas to stellar metallicity is always below the value expected for a simple closed-box model, which requires that outflows and inflows play an important role in the enrichment history across our entire stellar mass range. This work highlights the complex interplay between stellar and gas-phase metallicities and shows how care must be taken in comparing them to constrain models of galaxy formation and evolution.

astro-ph.GA↗

arXiv2021

A SAMI and MaNGA view on the stellar kinematics of galaxies on the star-forming main sequence

Galaxy internal structure growth has long been accused of inhibiting star formation in disc galaxies. We investigate the potential physical connection between the growth of dispersion-supported stellar structures (e.g. classical bulges) and the position of galaxies on the star-forming main sequence at $z\sim0$. Combining the might of the SAMI and MaNGA galaxy surveys, we measure the $λ_{Re}$ spin parameter for 3781 galaxies over $9.5 < \log M_{\star} [\rm{M}_{\odot}] < 12$. At all stellar masses, galaxies at the locus of the main sequence possess $λ_{Re}$ values indicative of intrinsically flattened discs. However, above $\log M_{\star}[\rm{M}_{\odot}]\sim10.5$ where the main sequence starts bending, we find tantalising evidence for an increase in the number of galaxies with dispersion-supported structures, perhaps suggesting a connection between bulges and the bending of the main sequence. Moving above the main sequence, we see no evidence of any change in the typical spin parameter in galaxies once gravitationally-interacting systems are excluded from the sample. Similarly, up to 1 dex below the main sequence, $λ_{Re}$ remains roughly constant and only at very high stellar masses ($\log M_{\star}[\rm{M}_{\odot}]>11$), do we see a rapid decrease in $λ_{Re}$ once galaxies decline in star formation activity. If this trend is confirmed, it would be indicative of different quenching mechanisms acting on high- and low-mass galaxies. The results suggest that while a population of galaxies possessing some dispersion-supported structure is already present on the star-forming main sequence, further growth would be required after the galaxy has quenched to match the kinematic properties observed in passive galaxies at $z\sim0$.

astro-ph.GA↗

arXiv2020

Directionality in van der Waals Interactions: the Case of 4-Acetylbiphenyl Adsorbed on Au(111)

We report on a theoretical study of adsorption of 4-Acetylbiphenyl molecule and its diffusion properties in the main directions of the Au(111) surface. Structural changes of the molecule, which are induced by adsorption lead to stronger conjugation of the $π$-system. The molecule is adsorbed in a flat configuration on the surface with roughly the same binding energy along the [110] and [112] directions, in good agreement with experiments. Furthermore, the diffusion barriers imply an important directionality of the molecule-surface interactions. This is somewhat surprising because our calculations show that the prevailing interaction is the long-range molecule-surface van der Waals interaction. Despite of its weakness, the van der Waals interaction discriminates the preferential adsorption sites as well as imposes a molecular geometry that needs to be considered when rationalizing the diffusion barriers.

cond-mat.mtrl-sci↗

arXiv2019

Efficient Ab-initio Multiplet Calculations for Magnetic Adatoms on MgO

Scanning probe microscopy and spectroscopy, and more recently in combination with electron spin resonance, have allowed the direct observation of electron dynamics on the single-atom limit. The interpretation of data is strongly depending on model Hamiltonians. However, fitting effective spin Hamiltonians to experimental data lacks the ability to explore a vast number of potential systems of interest. By using plane-wave density functional theory (DFT) as starting point, we build a multiplet Hamiltonian making use of maximally-localized Wannier functions. The Hamiltonian contains spin-orbit and electron-electron interactions needed to obtain the relevant spin dynamics. The resulting reduced Hamiltonian is solved by exact diagonalization. We compare three prototypical cases of 3d transition metals Mn (total spin $S=5/2$), Fe ($S=2$) and Co ($S=3/2$) on MgO with experimental data and find that our calculations can accurately predict the spin orientation and anisotropy of the magnetic adatom. Our method does not rely on experimental input and permits us to explore and predict the fundamental magnetic properties of adatoms on surfaces.

cond-mat.mes-hall↗

arXiv2019

Vibron-assisted spin excitation in a magnetically anisotropic nickelocene complex

The ability to electrically-drive spin excitations in molecules with magnetic anisotropy is key for high-density storage and quantum-information technology. Electrons, however, also tunnel via the vibrational excitations unique to a molecule. The interplay of spin and vibrational excitations offers novel routes to study and, ultimately, electrically manipulate molecular magnetism. Here we use a scanning tunneling microscope to electrically induce spin and vibrational excitations in a single molecule consisting of a nickelocene magnetically coupled to a Ni atom. We evidence a vibron-assisted spin excitation at an energy one order of magnitude higher compared to the usual spin excitations of nickelocene and explain it using first-principles calculations that include electron correlations. Furthermore, we observe that spin excitations can be quenched by modifying the Ni-nickelocene coupling. Our study suggests that nickelocene-based complexes constitute a model playground for exploring the interaction of spin and vibrations in the electron transport through single magnetic molecules.

cond-mat.mes-hall↗

arXiv2019

Atomic-scale spin sensing with a single-molecule at the apex of a scanning tunneling microscope

Recent advances in scanning probe techniques rely on the chemical functionalization of the probe-tip termination by a single molecule. The success of this approach opens the tantalizing prospect of introducing spin sensitivity through the functionalization by a magnetic molecule. Here, we use a nickelocene-terminated tip (Nc-tip), which offers the possibility of producing spin excitations on the tip apex of a scanning tunneling microscope (STM). We show that when the Nc-tip is a hundred pm away from point contact with a surface-supported object, magnetic effects may be probed through changes in the spin excitation spectrum of nickelocene. We use this detection scheme to simultaneously determine the exchange field and the spin polarization of the sample with atomic-scale resolution. Our findings demonstrate that the Nc-tip is a powerful probe for investigating surface magnetism with STM, from single magnetic atoms to surfaces.

cond-mat.mes-hall↗

arXiv2019

A cotunneling mechanism for all-electrical Electron Spin Resonance of single adsorbed atoms

The recent development of all-electrical electron spin resonance (ESR) in a scanning tunneling microscope (STM) setup has opened the door to vast applications. Despite the fast growing number of experimental works on STM-ESR, the fundamental principles remains unclear. By using a cotunneling picture, we show that the spin resonance signal can be explained as a time-dependent variation of the tunnel barrier induced by the alternating electric driving field. We demonstrate how this variation translates into the resonant frequency response of the direct current. Our cotunneling theory explains the main experimental findings. Namely, the linear dependence of the Rabi flop rate with the alternating bias amplitude, the absence of resonant response for spin-unpolarized currents, and the weak dependence on the actual atomic species.

cond-mat.mes-hall↗

arXiv2018

The SAMI Galaxy Survey: embedded discs and radial trends in outer dynamical support across the Hubble sequence

We study the balance in dynamical support of 384 galaxies with stellar kinematics out to >1.5R_e in the Sydney AAO Multi-object Integral Field (SAMI) Galaxy Survey. We present radial dynamical profiles of the local rotation dominance parameter, V/sigma, and local spin, lambda_loc. Although there is a broad range in amplitude, most kinematic profiles monotonically increase across the probed radial range. We do not find many galaxies with kinematic transitions such as those expected between the inner in-situ and outer accreted stars within the radial range probed. We compare the V/sigma gradient and maximum values to the visual morphologies of the galaxies to better understand the link between visual and kinematic morphologies. We find that the radial distribution of dynamical support in galaxies is linked to their visual morphology. Late-type systems have higher rotational support at all radii and steeper V/sigma gradients compared to early-type galaxies. We perform a search for embedded discs, which are rotationally supported discy structures embedded within large scale slowly or non-rotating structures. Visual inspection of the kinematics reveals at most three galaxies (out of 384) harbouring embedded discs. This is more than an order of magnitude fewer than the observed fraction in some local studies. Our tests suggest that this tension can be attributed to differences in the sample selection, spatial sampling and beam smearing due to seeing.

astro-ph.GA↗

arXiv2018

The SAMI Galaxy Survey: gas content and interaction as the drivers of kinematic asymmetry

In order to determine the causes of kinematic asymmetry in the H$α$ gas in the SAMI Galaxy Survey sample, we investigate the comparative influences of environment and intrinsic properties of galaxies on perturbation. We use spatially resolved H$α$ velocity fields from the SAMI Galaxy Survey to quantify kinematic asymmetry ($\overline{v_{asym}}$) in nearby galaxies and environmental and stellar mass data from the GAMA survey. {We find that local environment, measured as distance to nearest neighbour, is inversely correlated with kinematic asymmetry for galaxies with $\mathrm{\log(M_*/M_\odot)}>10.0$, but there is no significant correlation for galaxies with $\mathrm{\log(M_*/M_\odot)}<10.0$. Moreover, low mass galaxies ($\mathrm{\log(M_*/M_\odot)}<9.0$) have greater kinematic asymmetry at all separations, suggesting a different physical source of asymmetry is important in low mass galaxies.} We propose that secular effects derived from gas fraction and gas mass may be the primary causes of asymmetry in low mass galaxies. High gas fraction is linked to high $\frac{σ_{m}}{V}$ (where $σ_m$ is H$α$ velocity dispersion and $V$ the rotation velocity), which is strongly correlated with $\overline{v_{asym}}$, and galaxies with $\log(M_*/M_\odot)<9.0$ have offset $\overline{\frac{σ_{m}}{V}}$ from the rest of the sample. Further, asymmetry as a fraction of dispersion decreases for galaxies with $\log(M_*/M_\odot)<9.0$. Gas mass and asymmetry are also inversely correlated in our sample. We propose that low gas masses in dwarf galaxies may lead to asymmetric distribution of gas clouds, leading to increased relative turbulence.

astro-ph.GA↗

arXiv2017

The SAMI Galaxy Survey: The Low-Redshift Stellar Mass Tully-Fisher Relation

We investigate the Tully-Fisher Relation (TFR) for a morphologically and kine- matically diverse sample of galaxies from the SAMI Galaxy Survey using 2 dimensional spatially resolved Halpha velocity maps and find a well defined relation across the stellar mass range of 8.0 < log(M*) < 11.5. We use an adaptation of kinemetry to parametrise the kinematic Halpha asymmetry of all galaxies in the sample, and find a correlation between scatter (i.e. residuals off the TFR) and asymmetry. This effect is pronounced at low stellar mass, corresponding to the inverse relationship between stellar mass and kinematic asymmetry found in previous work. For galaxies with log(M*) < 9.5, 25 +/- 3% are scattered below the root mean square (RMS) of the TFR, whereas for galaxies with log(M*) > 9.5 the fraction is 10 +/- 1% We use 'simulated slits' to directly compare our results with those from long slit spectroscopy and find that aligning slits with the photometric, rather than the kinematic, position angle, increases global scatter below the TFR. Further, kinematic asymmetry is correlated with misalignment between the photometric and kinematic position angles. This work demonstrates the value of 2D spatially resolved kinematics for accurate TFR studies; integral field spectroscopy reduces the underestimation of rotation velocity that can occur from slit positioning off the kinematic axis.

astro-ph.GA↗

arXiv2017

Transport properties of Co in Cu(100) from first principles

The electronic transport properties of a point-contact system formed by a single Co atom adsorbed on Cu (100) and contacted by a copper tip is evaluated in the presence of intra-atomic Coulomb interactions and spin-orbit coupling. The calculations are performed using equilibrium Green's functions evaluated within density functional theory completed with a Hubbard $U$ term and spin-orbit interaction, as implemented in the Gollum package. We show that the contribution to the transmission between electrodes of spin-flip components is negative and scaling as $λ^2/Γ^2$ where $λ$ is the SOC and $Γ$ the Co atom-electrode coupling. Hence, due to this unfavorable ratio, SOC effects in transport in this system are small. However, we show that the spin-flip transmission component can increase by two orders of magnitude depending on the value of the Hubbard $U$ term. These effects are particularly important in the contact regime because of the prevalence of $d$-electron transport, while in the tunneling regime, transport is controlled by the $sp$-electron transmission and results are less dependent on the values of $U$ and SOC. Using our electronic structure and the elastic transmission calculations, we discuss the effect of $U$ and SOC on the well-known Kondo effect of this system.

cond-mat.mes-hall↗

arXiv2017

Spin-flip scattering selection in a controlled molecular junction

A simple double-decker molecule with magnetic anisotropy, nickelocene, is attached to the metallic tip of a low-temperature scanning tunneling microscope. In the presence of a Cu(100) surface, the conductance around the Fermi energy is governed by spin-flip scattering, the nature of which is determined by the tunneling barrier thickness. The molecular tip exhibits inelastic spin-flip scattering in the tunneling regime, while in the contact regime a Kondo ground state is stabilized causing an order of magnitude change in the zero-bias conductance. First principle calculations show that nickelocene reversibly switches from a spin 1 to 1/2 between the two transport regimes.

cond-mat.str-el↗

arXiv2016

Single-molecule enhanced spin-flip detection

We studied the spin-flip excitations of a double-decker nickelocene molecule (Nc) adsorbed on Cu(100) by means of inelastic tunneling spectroscopy (IETS), X-ray magnetic circular dichroism (XMCD) and density functional theory calculations (DFT). The results show that the molecule preserves its magnetic moment and magnetic anisotropy not only on Cu(100), but also in different metallic environments including the tip apex. Taking advantage of the efficient spin-flip excitation of this molecule, we show how such a molecular functionalized tip boosts the inelastic signal of a surface supported Nc by almost one order of magnitude thanks to a double spin-excitation process.

cond-mat.mes-hall↗

arXiv2016

The SAMI Galaxy Survey: Asymmetry in Gas Kinematics and its links to Stellar Mass and Star Formation

We study the properties of kinematically disturbed galaxies in the SAMI Galaxy Survey using a quantitative criterion, based on kinemetry (Krajnovic et al.). The approach, similar to the application of kinemetry by Shapiro et al. uses ionised gas kinematics, probed by Hα emission. By this method 23+/-7% of our 360-galaxy sub-sample of the SAMI Galaxy Survey are kinematically asymmetric. Visual classifications agree with our kinemetric results for 90% of asymmetric and 95% of normal galaxies. We find stellar mass and kinematic asymmetry are inversely correlated and that kinematic asymmetry is both more frequent and stronger in low-mass galaxies. This builds on previous studies that found high fractions of kinematic asymmetry in low mass galaxies using a variety of different methods. Concentration of star forma- tion and kinematic disturbance are found to be correlated, confirming results found in previous work. This effect is stronger for high mass galaxies (log(M*) > 10) and indicates that kinematic disturbance is linked to centrally concentrated star formation. Comparison of the inner (within 0.5Re) and outer Hα equivalent widths of asymmetric and normal galaxies shows a small but significant increase in inner equivalent width for asymmetric galaxies.

astro-ph.GA↗

arXiv2016

Extremely long-lived magnetic excitations in supported Fe chains

We report on a theoretical study of the lifetime of the first excited state of spin chains made of an odd number of Fe atoms on Cu2N/Cu(100). Yan et al (Nat. Nanotech. 10, 40 (2015)) recently observed very long lifetimes in the case of Fe3 chains. We consider the decay of the first excited state induced by electron-hole pair creation in the substrate. For a finite magnetic field, the two lowest-lying states in the chain have a quasi-Néel state structure. Decay from one state to the other strongly depends on the degree of entanglement of the local spins in the chain. The entanglement in the chain accounts for the long lifetimes that increase exponentially with chain length. Despite their apparently very different properties, the behaviour of odd and even chains is governed by the same kind of phenomena, in particular entanglement effects. The present results account quite well for the lifetimes recently measured by Yan et al on Fe3

cond-mat.mes-hall↗