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N. Manini

Publications and source records attributed to N. Manini.

At least 19 recordsLinked to original sources

Experimental observation of the Aubry transition in two-dimensional colloidal monolayers

The possibility to achieve entirely frictionless, i.e. superlubric, sliding between solids, holds enormous potential for the operation of mechanical devices. At small length scales, where mechanical contacts are well-defined, Aubry predicted a transition from a superlubric to a pinned state when the mechanical load is increased. Evidence for this intriguing Aubry transition (AT), which should occur in one dimension (1D) and at zero temperature, was recently obtained in few-atom chains. Here, we experimentally and theoretically demonstrate the occurrence of the AT in an extended two-dimensional (2D) system at room temperature using a colloidal monolayer on an optical lattice. Unlike the continuous nature of the AT in 1D, we observe a first-order transition in 2D leading to a coexistence regime of pinned and unpinned areas. Our data demonstrate that the original concept of Aubry does not only survive in 2D but is relevant for the design of nanoscopic machines and devices at ambient temperature.

cond-mat.soft

Current trends in the physics of nanoscale friction

Tribology, which studies surfaces in contact and relative motion, includes friction, wear, and lubrication, straddling across different fields: mechanical engineering, materials science, chemistry, nanoscience, physics. This short review restricts to the last two disciplines, with a qualitative survey of a small number of recent progress areas in the physics of nanofriction.

cond-mat.mtrl-sci

Friction and Nonlinear Dynamics

The nonlinear dynamics associated with sliding friction forms a broad interdisciplinary research field that involves complex dynamical processes and patterns covering a broad range of time and length scales. Progress in experimental techniques and computational resources has stimulated the development of more refined and accurate mathematical and numerical models, capable of capturing many of the essentially nonlinear phenomena involved in friction.

cond-mat.soft

Thermal formation of carbynes

We simulate the formation of $sp$ carbon chains (carbynes) by thermal decomposition of $sp^2$ carbon heated by a hot discharge plasma, by means of tight-binding molecular dynamics. We obtain and analyze the total quantity of carbynes and their length distribution as a function of temperature and density.

cond-mat.mtrl-sci

Soliton dynamics in a solid lubricant during sliding friction

Recent highly idealized model studies of lubricated nanofriction for two crystalline sliding surfaces with an interposed thin solid crystalline lubricant layer showed that the overall relative velocity of the lubricant $v_{\rm lub} / v_{\rm slider}$ depends only on the ratio of the lattice spacings, and retains a strictly constant value even when system parameters are varied within a wide range. This peculiar "quantized" dynamical locking was understood as due to the sliding-induced motion of misfit dislocations, or soliton structures. So far, the practical relevance of this concept to realistic sliding three dimensional crystals has not been demonstrated. In this work, by means of classical molecular dynamics simulations and theoretical considerations, we realize a realistic three-dimensional crystal-lubricant-crystal geometry. Results show that the flux of lubricant particles associated to the advancing soliton lines gives rise here too to a quantized velocity ratio. Moreover, depending on the interface lattice spacing mismatch, both forward and backward quantized motion of the lubricant is predicted. The persistence under realistic conditions of the dynamically pinned state and quantized sliding is further investigated by varying sliding speed, temperature, load, and lubricant film thickness. The possibilities of experimental observation of quantized sliding are also discussed.

cond-mat.soft

Hydrostatic strain enhancement in laterally confined SiGe nanostripes

Strain-engineering in SiGe nanostructures is fundamental for the design of optoelectronic devices at the nanoscale. Here we explore a new strategy, where SiGe structures are laterally confined by the Si substrate, to obtain high tensile strain avoiding the use of external stressors, and thus improving the scalability. Spectro-microscopy techniques, finite element method simulations and ab initio calculations are used to investigate the strain state of laterally confined Ge-rich SiGe nano-stripes. Strain information is obtained by tip enhanced Raman spectroscopy with an unprecedented lateral resolution of ~ 30 nm. The nano-stripes exhibit a large tensile hydrostatic strain component, which is maximum at the center of the top free surface, and becomes very small at the edges. The maximum lattice deformation is larger than the typical values of thermally relaxed Ge/Si(001) layers. This strain enhancement originates from a frustrated relaxation in the out-of-plane direction, resulting from the combination of the lateral confinement induced by the substrate side walls and the plastic relaxation of the misfit strain in the (001) plane at the SiGe/Si interface. The effect of this tensile lattice deformation at the stripe surface is probed by work function mapping, performed with a spatial resolution better than 100 nm using X-ray photoelectron emission microscopy. The nano-stripes exhibit a positive work function shift with respect to a bulk SiGe alloy, quantitatively confirmed by electronic structure calculations of tensile strained configurations. The present results have a potential impact on the design of optoelectronic devices at a nanometer length scale.

cond-mat.mes-hall

Nano-indentation of a room-temperature ionic liquid film on silica: a computational experiment

We investigate the structure of the [bmim][Tf2N]/silica interface by simulating the indentation of a thin (4 nm) [bmim][Tf2N] film by a hard nanometric tip. The ionic liquid/silica interface is represented in atomistic detail, while the tip is modelled by a spherical mesoscopic particle interacting via an effective short-range potential. Plots of the normal force (Fz) on the tip as a function of its distance from the silica surface highlight the effect of weak layering in the ionic liquid structure, as well as the progressive loss of fluidity in approaching the silica surface. The simulation results for Fz are in near-quantitative agreement with new AFM data measured on the same [bmim][Tf2N]/silica interface at comparable thermodynamic conditions.

cond-mat.mes-hall

Low-energy scales and temperature-dependent photoemission of heavy fermions

We solve the $S=1/2$ Kondo lattice model within the dynamical mean field theory. Detailed predictions are made for the dependence of the lattice Kondo resonance and the conduction electron spectral density on temperature and band filling $n_{c}$. Two low-energy scales are identified in the spectra: a renormalized hybridization pseudogap scale $T^{*}$, which correlates with the single-ion Kondo scale, and a lattice Kondo scale $T_{0} < T^{*}$, which acts as the Fermi-liquid coherence scale. The lattice Kondo resonance is split into a main branch, which is pinned at the Fermi level, and whose width is set by $T_{0}$, and an upper branch at $ω\approx T^{*}$. The weight of the upper branch decreases rapidly away from $n_{c}=1$ and vanishes for $n_{c}\lesssim 0.7$. In contrast, the pseudogap in the conduction electron spectral density persists for all $n_{c}$. On increasing temperature, the lattice Kondo resonance at the Fermi level vanishes on a temperature scale of order $10 T_{0}$, as in impurity model calculations. In contrast to impurity model spectra, however, the position of the lattice Kondo resonance depends strongly on temperature, particularly close to the Kondo insulating state. The results are used to make predictions on the temperature dependence of the low-energy photoemission and inverse photoemission spectra of metallic heavy fermions and doped Kondo insulators. We compare our results with available high-resolution measurements on YbInCu$_4$ and YbAgCu$_4$. The loss in intensity with increasing temperature, and the asymmetric lineshape of the low-energy spectra are well accounted for by our model. More detailed agreement with experiment would require including the $f$-orbital degeneracy and crystal-field excited states.

cond-mat.str-el

Mesophases in Nearly 2D Room-Temperature Ionic Liquids

Computer simulations of (i) a [C12mim][Tf2N] film of nanometric thickness squeezed at kbar pressure by a piecewise parabolic confining potential reveal a mesoscopic in-plane density and composition modulation reminiscent of mesophases seen in 3D samples of the same room-temperature ionic liquid (RTIL). Near 2D confinement, enforced by a high normal load, relatively long aliphatic chains are strictly required for the mesophase formation, as confirmed by computations for two related systems made of (ii) the same [C12mim][Tf2N] adsorbed at a neutral solid surface and (iii) a shorter-chain RTIL ([C4mim][Tf2N]) trapped in the potential well of part i. No in-plane modulation is seen for ii and iii. In case ii, the optimal arrangement of charge and neutral tails is achieved by layering parallel to the surface, while, in case iii, weaker dispersion and packing interactions are unable to bring aliphatic tails together into mesoscopic islands, against overwhelming entropy and Coulomb forces. The onset of in-plane mesophases could greatly affect the properties of long-chain RTILs used as lubricants.

cond-mat.mtrl-sci

DC and AC Josephson effects with superfluid Fermi atoms across a Feshbach resonance

We show that both DC and AC Josephson effects with superfluid Fermi atoms in the BCS-BEC crossover can be described at zero temperature by a nonlinear Schrodinger equation (NLSE). By comparing our NLSE with mean-field extended BCS calculations, we find that the NLSE is reliable in the BEC side of the crossover up to the unitarity limit. The NLSE can be used for weakly-linked atomic superfluids also in the BCS side of the crossover by taking the tunneling energy as a phenomenological parameter.

cond-mat.other

Nonlinear hysteretic behavior of a confined sliding layer

A nonlinear model representing the tribological problem of a thin solid lubricant layer between two sliding periodic surfaces is used to analyze the phenomenon of hysteresis at pinning/depinning around a moving state rather than around a statically pinned state. The cycling of an external driving force F_ext is used as a simple means to destroy and then to recover the dynamically pinned state previously discovered for the lubricant center-of-mass velocity. De-pinning to a quasi-freely sliding state occurs either directly, with a single jump, or through a sequence of discontinuous transitions. The intermediate sliding steps are reminiscent of phase-locked states and stick-slip motion in static friction, and can be interpreted in terms of the appearance of travelling density defects in an otherwise regular arrangement of kinks. Re-pinning occurs more smoothly, through the successive disappearance of different travelling defects. The resulting bistability and multistability regions may also be explored by varying mechanical parameters other than F_ext, e.g. the sliding velocity or the corrugation amplitude of the sliders.

cond-mat.mtrl-sci

Macroscopic Periodic Tunneling of Fermi Atoms in the BCS-BEC Crossover

We study the macroscopic quantum tunneling of two weakly-linked superfluids made of interacting fermionic atoms. We derive atomic Josephson junction equations and find that zero-mode and pi-mode frequencies of coherent atomic oscillations depend on the tunneling coefficient and the sound velocity of the superfluid. By considering a superfluid of ^40K atoms, we calculate these oscillation frequencies in the crossover from the Bardeen-Cooper-Schrieffer state of weakly-bound Cooper pairs to the Bose-Einstein Condensate of strongly-bound molecular dimers.

cond-mat.stat-mech

Static friction on the fly: velocity depinning transitions of lubricants in motion

The dragging velocity of a model solid lubricant confined between sliding periodic substrates exhibits a phase transition between two regimes, respectively with quantized and with continuous lubricant center-of-mass velocity. The transition, occurring for increasing external driving force F_ext acting on the lubricant, displays a large hysteresis, and has the features of depinning transitions in static friction, only taking place on the fly. Although different in nature, this phenomenon appears isomorphic to a static Aubry depinning transition in a Frenkel-Kontorova model, the role of particles now taken by the moving kinks of the lubricant-substrate interface. We suggest a possible realization in 2D optical lattice experiments.

cond-mat.mtrl-sci

Self-induced density modulations in the free expansion of Bose-Einstein condensates

We simulate numerically the free expansion of a repulsive Bose-Einstein condensate with an initially Gaussian density profile. We find a self-similar expansion only for weak inter-atomic repulsion. In contrast, for strong repulsion we observe the spontaneous formation of a shock wave at the surface followed by a significant depletion inside the cloud. In the expansion, contrary to the case of a classical viscous gas, the quantum fluid can generate radial rarefaction density waves with several minima and maxima. These intriguing nonlinear effects, never observed yet in free-expansion experiments with ultra-cold alkali-metal atoms, can be detected with the available setups.

cond-mat.other

Bulk and Collective Properties of a Dilute Fermi Gas in the BCS-BEC Crossover

We investigate the zero-temperature properties of a dilute two-component Fermi gas with attractive interspecies interaction in the BCS-BEC crossover. We build an efficient parametrization of the energy per particle based on Monte Carlo data and asymptotic behavior. This parametrization provides, in turn, analytical expressions for several bulk properties of the system such as the chemical potential, the pressure and the sound velocity. In addition, on the basis of a local polytropic equation of state, we determine the collective modes of the Fermi gas under harmonic confinement in the framework of the hydrodynamic theory. The calculated collective frequencies are compared to experimental data on confined vapors of $^6$Li atoms and with other theoretical predictions.

cond-mat.soft

Observation of off-diagonal geometric phase in polarized neutron interferometer experiments

Off-diagonal geometric phases acquired in the evolution of a spin-1/2 system have been investigated by means of a polarized neutron interferometer. Final counts with and without polarization analysis enable us to observe simultaneously the off-diagonal and diagonal geometric phases in two detectors. We have quantitatively measured the off-diagonal geometric phase for noncyclic evolutions, confirming the theoretical predictions. We discuss the significance of our experiment in terms of geometric phases (both diagonal and off-diagonal) and in terms of the quantum erasing phenomenon.

quant-ph

Dynamical Jahn-Teller Effect and Berry Phase in Positively Charged Fullerene I. Basic Considerations

We study the Jahn-Teller effect of positive fullerene ions $^2$C$_{60}^{+}$ and $^1$C$_{60}^{2+}$. The aim is to discover if this case, in analogy with the negative ion, possesses a Berry phase or not, and what are the consequences on dynamical Jahn-Teller quantization. Working in the linear and spherical approximation, we find no Berry phase in $^1$C$_{60}^{2+}$, and presence/absence of Berry phase for coupling of one $L=2$ hole to an $L=4$/$L=2$ vibration. We study in particular the special equal-coupling case ($g_2=g_4$), which is reduced to the motion of a particle on a 5-dimensional sphere. In the icosahedral molecule, the final outcome assesses the presence/absence of a Berry phase of $π$ for the $h_u$ hole coupled to $G_g$/$H_h$ vibrations. Some qualitative consequences on ground-state symmetry, low-lying excitations, and electron emission from C$_{60}$ are spelled out.

cond-mat