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N. S. Rogado

Publications and source records attributed to N. S. Rogado.

2 recordsLinked to original sources

Fermi surface and quasiparticle dynamics of Na(x)CoO2 {x=0.7} investigated by Angle-Resolved Photoemission Spectroscopy

We present an angle-resolved photoemission study of Na0.7CoO2, the host cobaltate of the NaxCoO2.yH2O series. Our results show a large hexagonal-like hole-type Fermi surface, an extremely narrow strongly renormalized quasiparticle band and a small Fermi velocity. Along the Gamma to M high symmetry line, the quasiparticle band crosses the Fermi level from M toward Gamma consistent with a negative sign of effective single-particle hopping (t ): t is estimated to be about 8 meV which is on the order of exchange coupling J in this system. This suggests that t ~ J ~ 10 meV is an important energy scale in the system. Quasiparticles are well defined only in the T-linear resistivity regime. Small single particle hopping and unconventional quasiparticle dynamics may have implications for understanding the unusual behavior of this new class of compounds.

cond-mat.str-el

Chemical Instability of the Cobalt Oxyhydrate Superconductor under Ambient Conditions

The layered sodium cobalt oxyhydrate superconductor Na0.3CoO2*1.4H2O is shown through X-ray diffraction and thermogravimetric studies to be one of a series of hydrated phases of Na0.3CoO2. Further, it is shown that the material is exceptionally sensitive to both temperature and humidity near ambient conditions, easily dehydrating to a non-superconducting lower hydrate. The observation of this stable lower hydrate with c=13.8 angstroms implies that the superconductivity turns on in this system between CoO2 layer spacings of 6.9 and 9.9 angstroms at nominally constant chemical doping.

cond-mat.supr-con