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N. Ysard

Publications and source records attributed to N. Ysard.

At least 37 records · Page 2Linked to original sources

Low-temperature optical constants of amorphous silicate dust analogues

Cosmic dust models are key ingredients in advancing our understanding of astronomical environments as diverse as interstellar clouds in galaxies, circumstellar envelopes around evolved and young stars, and protoplanetary disks. Such models consist of several dust populations, each with different compositions and size distributions. They may also consider different grain shapes, although most models assume spherical grains. All include a component of silicate dust. The absorption and emission properties of these dust components are calculated from the optical constants of each dust material which have various experimental, phenomenological, and theoretical origins depending on the model. We aim to provide the community with new sets of optical constants for amorphous silicate dust analogues at low temperatures. The analogues consist of four Mg-rich silicate samples of stoichiometry ranging from enstatite to olivine, and of eight samples of Mg and Fe rich silicates with a pyroxene stoichiometry and differing magnesium and iron content. We calculated the optical constants from transmission measurements using the Kramers-Kronig relations, assuming that the grains are small compared to the wavelength and prolate in shape with axis ratios of 1.5 and 2 for the Mg and Fe rich samples, respectively. New optical constants for silicate dust analogues were calculated over the wavelength range from 5 to 800-1000 microns, depending on the sample, and at temperatures of 10, 30, 100, 200, and 300 K.We determined the uncertainties on the derived optical constants based on the assumptions used to calculate them. To facilitate the use of these data in cosmic dust models, we provide optical constants extrapolated outside the measured spectral range into the UV-NIR and mm-cm wavelength ranges, as well as formulae that can be used to interpolate them at any temperature in the range 10 - 300 K.

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Nano-grain depletion in photon-dominated regions

Context. Carbonaceous nano-grains play a fundamental role in the physico-chemistry of the interstellar medium (ISM) and especially of photon-dominated regions (PDRs). Their properties vary with the local physical conditions and affect the local chemistry and dynamics. Aims. We aim to highlight the evolution of carbonaceous nano-grains in three different PDRs and propose a scenario of dust evolution as a response to the physical conditions. Methods. We used Spitzer/IRAC (3.6, 4.5, 5.8, and 8 $μ$m) and Spitzer/MIPS (24 $μ$m) together with Herschel/PACS (70 $μ$m) to map dust emission in IC63 and the Orion Bar. To assess the dust properties, we modelled the dust emission in these regions using the radiative transfer code SOC together with the THEMIS dust model. Results. Regardless of the PDR, we find that nano-grains are depleted and that their minimum size is larger than in the diffuse ISM (DISM), which suggests that the mechanisms that lead nano-grains to be photo-destroyed are very efficient below a given critical size limit. The evolution of the nano-grain dust-to-gas mass ratio with both G0 and the effective temperature of the illuminating star indicates a competition between the nano-grain formation through the fragmentation of larger grains and nano-grain photo-destruction. We modelled dust collisions driven by radiative pressure with a classical 1D approach to show that this is a viable scenario for explaining nano-grain formation through fragmentation and, thus, the variations observed in nano-grain dust-to-gas mass ratios from one PDR to another. Conclusions. We find a broad variation in the nano-grain dust properties from one PDR to another, along with a general trend of nano-grain depletion in these regions. We propose a viable scenario of nano-grain formation through fragmentation of large grains due to radiative pressure-induced collisions.

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Dust emissivity in resolved spiral galaxies

Context: The far-infrared (FIR) and sub-millimeter (submm) emissivity of the Milky Way (MW) cirrus is an important benchmark for dust grain models. Dust masses in other galaxies are generally derived from the FIR/submm using the emission properties of these MW-calibrated models. Aims: We seek to derive the FIR/submm emissivity in nine nearby spiral galaxies to check its compatibility with MW cirrus measurements. Methods: We obtained values of the emissivity at 70 to 500 um, using maps of dust emission from the Herschel satellite and of gas surface density from the THINGS and HERACLES surveys on a scale generally corresponding to 440 pc. We studied the variation of the emissivity with the surface brightness ratio I(250um)/I(500um), a proxy for the intensity of the interstellar radiation field heating the dust. Results: We find that the average value of the emissivity agrees with MW estimates for pixels sharing the same color as the cirrus, namely, for I(250um)/I(500um) = 4.5. For I(250um)/I(500um) > 5, the measured emissivity is instead up to a factor ~2 lower than predicted from MW dust models heated by stronger radiation fields. Regions with higher I(250um)/I(500um) are preferentially closer to the galactic center and have a higher overall (stellar+gas) surface density and molecular fraction. The results do not depend strongly on the adopted CO-to-molecular conversion factor and do not appear to be affected by the mixing of heating conditions. Conclusions: Our results confirm the validity of MW dust models at low density, but are at odds with predictions for grain evolution in higher density environments. If the lower-than-expected emissivity at high I(250um)/I(500um) is the result of intrinsic variations in the dust properties, it would imply an underestimation of the dust mass surface density of up to a factor ~2 when using current dust models.

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Performance of the polarization leakage correction in the PILOT data

The Polarized Instrument for Long-wavelength Observation of the Tenuous interstellar medium (PILOT) is a balloon-borne experiment that aims to measure the polarized emission of thermal dust at a wavelength of 240 um (1.2 THz). The PILOT experiment flew from Timmins, Ontario, Canada in 2015 and 2019 and from Alice Springs, Australia in April 2017. The in-flight performance of the instrument during the second flight was described in Mangilli et al. 2019. In this paper, we present data processing steps that were not presented in Mangilli et al. 2019 and that we have recently implemented to correct for several remaining instrumental effects. The additional data processing concerns corrections related to detector cross-talk and readout circuit memory effects, and leakage from total intensity to polarization. We illustrate the above effects and the performance of our corrections using data obtained during the third flight of PILOT, but the methods used to assess the impact of these effects on the final science-ready data, and our strategies for correcting them will be applied to all PILOT data. We show that the above corrections, and in particular that for the intensity to polarization leakage, which is most critical for accurate polarization measurements with PILOT, are accurate to better than 0.4 % as measured on Jupiter during flight#3.

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Searching for Anomalous Microwave Emission in nearby galaxies. K-band observations with the Sardinia Radio Telescope

We observed four nearby spiral galaxies (NGC 3627, NGC 4254, NGC 4736 and NGC 5055) in the K band with the 64-m Sardinia Radio Telescope, with the aim of detecting the Anomalous Microwave Emission (AME), a radiation component presumably due to spinning dust grains, observed so far in the Milky Way and in a handful of other galaxies only (most notably, M 31). We mapped the galaxies at 18.6 and 24.6 GHz and studied their global photometry together with other radio-continuum data from the literature, in order to find AME as emission in excess of the synchrotron and thermal components. We only find upper limits for AME. These non-detections, and other upper limits in the literature, are nevertheless consistent with the average AME emissivity from the few detections: it is $ε^\mathrm{AME}_{\mathrm{30~GHz}} = 2.4\pm0.4 \times 10^{-2}$ MJy sr$^{-1}$ (M$_\odot$ pc$^{-2}$)$^{-1}$ in units of dust surface density (equivalently, $1.4\pm0.2 \times 10^{-18}$ Jy sr$^{-1}$ (H cm$^{-2}$)$^{-1}$ in units of H column density). We finally suggest to search for AME in quiescent spirals with relatively low radio luminosity, such as M~31.

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The mm-to-cm SED of spiral galaxies. Synergies between NIKA2 and SRT instruments

The mm-to-cm range of the Spectral Energy Distribution of spiral galaxies remains largely unexplored. Its coverage is required to disentangle the contribution of dust emission, free-free and synchrotron radiation and can provide constraints on dust models, star-formation rates and ISM properties. We present the case for a synergy between NIKA2 observations of nearby spirals and those from planned and current instrumentation at the Sardinia Radio Telescope, and report on a pilot K-band program to search for Anomalous Microwave Emission, an elusive emission component which is presumably related to dust.

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First MATISSE L-band observations of HD 179218. Is the inner 10 au region rich in carbon dust particles?

Carbon is one of the most abundant components in the Universe. While silicates have been the main focus of solid phase studies in protoplanetary discs (PPDs), little is known about the solid carbon content especially in the planet-forming regions ($\sim $0.1 to 10 au). Fortunately, several refractory carbonaceous species present C-H bonds (such as hydrogenated nano-diamond and amorphous carbon as well as polycyclic aromatic hydrocarbons (PAHs)), which generate infrared (IR) features that can be used to trace the solid carbon reservoirs. The new mid-IR instrument MATISSE, installed at the Very Large Telescope Interferometer (VLTI), can spatially resolve the inner regions ($\sim$ 1 to 10 au) of PPDs and locate, down to the au-scale, the emission coming from carbon grains. Our aim is to provide a consistent view on the radial structure, down to the au-scale, as well as basic physical properties and the nature of the material responsible for the IR continuum emission in the inner disk region around HD 179218. We implemented a temperature-gradient model to interpret the disk IR continuum emission, based on a multiwavelength dataset comprising a broadband spectral energy distribution (SED) and VLTI H-, L-, and N-bands interferometric data obtained in low spectral resolution. Then, we added a ring-like component, representing the carbonaceous L-band features-emitting region, to assess its detectability in future higher spectral resolution observations employing mid-IR interferometry.

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The formation of planetary systems with SPICA

In this era of spatially resolved observations of planet forming disks with ALMA and large ground-based telescopes such as the VLT, Keck and Subaru, we still lack statistically relevant information on the quantity and composition of the material that is building the planets, such as the total disk gas mass, the ice content of dust, and the state of water in planetesimals. SPICA is an infrared space mission concept developed jointly by JAXA and ESA to address these questions. The key unique capabilities of SPICA that enable this research are (1) the wide spectral coverage 10-220 micron, (2) the high line detection sensitivity of (1-2) 10-19 W m-2 with R~2000-5000 in the far-IR (SAFARI) and 10-20 W m-2 with R~29000 in the mid-IR (SMI, spectrally resolving line profiles), (3) the high far-IR continuum sensitivity of 0.45 mJy (SAFARI), and (4) the observing efficiency for point source surveys. This paper details how mid- to far-IR infrared spectra will be unique in measuring the gas masses and water/ice content of disks and how these quantities evolve during the planet forming period. These observations will clarify the crucial transition when disks exhaust their primordial gas and further planet formation requires secondary gas produced from planetesimals. The high spectral resolution mid-IR is also unique for determining the location of the snowline dividing the rocky and icy mass reservoirs within the disk and how the divide evolves during the build-up of planetary systems. Infrared spectroscopy (mid- to far-IR) of key solid state bands is crucial for assessing whether extensive radial mixing, which is part of our Solar System history, is a general process occurring in most planetary systems and whether extrasolar planetesimals are similar to our Solar System comets/asteroids. ... (abbreviated)

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Influence of the nano-grain depletion in photon-dominated regions: Application to the gas physics and chemistry in the Horsehead

The large disparity in physical conditions from the diffuse interstellar medium (ISM) to denser clouds such as photon-dominated regions (PDRs) triggers an evolution of the dust properties (i.e. composition, size, and shape). The gas physics and chemistry are tightly connected to these dust properties and are therefore affected by dust evolution and especially the nano-grain depletion in the outer irradiated part of PDRs. We highlight the influence of nano-grain depletion on the gas physics and chemistry in the Horsehead nebula, a prototypical PDR. We used a model for atomic and molecular gas in PDRs, the Meudon PDR code, using diffuse ISM-like dust and Horsehead-like dust to study the influence of nano-grain depletion on the gas physics and chemistry, focusing on the impact on photoelectric heating and H2 formation and, therefore, on the H2 gas lines. We find that nano-grain depletion in the Horsehead strongly affects gas heating through the photoelectric effect and thus the gas temperature and the H2 formation, hence the H -> H2 position. Consequently, the first four pure rotational lines of H2 (e.g. 0-0 S(0), S(1), S(2), and S(3)) vary by a factor of 2 to 14. The 0-0 S(3) line that is often underestimated in models is underestimated even more when taking nano-grain depletion into account due to the decrease in gas heating through the photoelectric effect. This strongly suggests that our understanding of the excitation of H2 and/or of heating processes in the Horsehead, and more generally in PDRs, is still incomplete. Nano-grain depletion in the outer part of the Horsehead has a strong influence on several gas tracers that will be prominent in JWST observations of irradiated clouds. We therefore need to take this depletion into account in order to improve our understanding of the Horsehead, and more generally PDRs, and to contribute to the optimal scientific return of the mission.

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Multi-wavelength observations and modelling of a quiescent cloud LDN1512

Light scattering at near-infrared wavelengths has been used to study the optical properties of the interstellar dust grains, but these studies are limited by the assumptions on the strength of the radiation field. On the other hand, thermal dust emission can be used to constrain the properties of the radiation field, although this is hampered by uncertainty about the dust emissivity. We test if current dust models allow us to model a molecular cloud simultaneously in the near infrared (NIR) and far infrared (FIR) wavelengths and compare the results with observations. Our aim is to place constraints on the properties of the dust grains and the strength of the radiation field. We present computations of dust emission and scattered light of a quiescent molecular cloud LDN1512. We construct radiative transfer models for LDN1512 that include an anisotropic radiation field and a three-dimensional cloud model. We are able to reproduce the observed FIR observations, with a radiation field derived from the DIRBE observations, with all of the tested dust models. However, with the same density distribution and the assumed radiation field, the models fail to reproduce the observed NIR scattering in all cases except for models that take into account dust evolution via coagulation and mantle formation. We find that the column densities derived from our radiative transfer modelling can differ by a factor of up to two, compared to the column densities derived from the observations with modified blackbody fits. The discrepancy in the column densities is likely caused because of temperature difference between a modified blackbody fit and the real spectra. We show that the observed dust emission can be reproduced with several different assumptions about the properties of the dust grains. However, in order to reproduce the observed scattered surface brightness dust evolution must be taken into account.

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High-resolution, 3D radiative transfer modelling IV. AGN-powered dust heating in NGC 1068

Dust emission, an important diagnostic of star formation and ISM mass throughout the Universe, can be powered by sources unrelated to ongoing star formation. In the framework of the DustPedia project we have set out to disentangle the radiation of the ongoing star formation from that of the older stellar populations. This is done through detailed, 3D radiative transfer simulations of face-on spiral galaxies. In this particular study, we focus on NGC 1068, which contains an active galactic nucleus (AGN). The effect of diffuse dust heating by AGN (beyond the torus) was so far only investigated for quasars. This additional dust heating source further contaminates the broadband fluxes on which classic galaxy modelling tools rely to derive physical properties. We aim to fit a realistic model to the observations of NGC 1068 and quantify the contribution of the several dust heating sources. Our model is able to reproduce the global spectral energy distribution of the galaxy. It matches the resolved optical and infrared images fairly well, but deviates in the UV and the submm. We find a strong wavelength dependency of AGN contamination to the broadband fluxes. It peaks in the MIR, drops in the FIR, but rises again at submm wavelengths. We quantify the contribution of the dust heating sources in each 3D dust cell and find a median value of 83% for the star formation component. The AGN contribution is measurable at the percentage level in the disc, but quickly increases in the inner few 100 pc, peaking above 90%. This is the first time the phenomenon of an AGN heating the diffuse dust beyond its torus is quantified in a nearby star-forming galaxy. NGC 1068 only contains a weak AGN, meaning this effect can be stronger in galaxies with a more luminous AGN. This could significantly impact the derived star formation rates and ISM masses for such systems.

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Dust evolution across the Horsehead Nebula

Micro-physical processes on interstellar dust surfaces are tightly connected to dust properties (i.e. dust composition, size and shape) and play a key role in numerous phenomena in the interstellar medium (ISM). The large disparity in physical conditions (i.e. density, gas temperature) in the ISM triggers an evolution of dust properties. The analysis of how dust evolves with the physical conditions is a stepping-stone towards a more thorough understanding of interstellar dust. The aim of this paper is to highlight dust evolution in the Horsehead Nebula PDR region. We use Spitzer/IRAC (3.6, 4.5, 5.8 and 8 μm), Spitzer/MIPS (24 μm) together with Herschel/PACS (70 and 160 μm) and Herschel/SPIRE (250, 350 and 500 μm) to map the spatial distribution of dust in the Horsehead over the entire emission spectral range. We model dust emission and scattering using the THEMIS interstellar dust model together with the 3D radiative transfer code SOC. We find that the nano-grains dust-to-gas ratio in the irradiated outer part of the Horsehead is 6 to 10 times lower than in the diffuse ISM. Their minimum size is 2 to 2.25 times larger than in the diffuse ISM and the power-law exponent of their size distribution, 1.1 to 1.4 times lower than in the diffuse ISM. Regarding the denser part of the Horsehead, it is necessary to use evolved grains (i.e. aggregates, with or without an ice mantle). It is not possible to explain the observations using grains from the diffuse medium. We therefore propose the following scenario to explain our results. In the outer part of the Horsehead, all the nano-grains have not yet had time to re-form completely through photo-fragmentation of aggregates and the smallest of the nano-grains that are sensitive to the radiation field are photo-destroyed. In the inner part of the Horsehead, grains most likely consist of multi-compositional, mantled aggregates.

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From grains to pebbles: the influence of size distribution and chemical composition on dust emission properties

The size and composition of dust grains are critical in setting the dynamical, physical and chemical evolution of the media in which they are present. Thanks to facilities such as ALMA and in the future the SKA, their thermal emission in the (sub)mm to cm has become a convenient way to trace grain properties. Our aim is to understand the influence of the grain composition and size distribution on the shape of their SED in dense ISM regions such as molecular clouds, prestellar cores, YSOs and protoplanetary discs. Starting from the optical constants defined in the THEMIS model for amorphous hydrogenated carbon and silicate grains in addition to water ice, we define 6 material mixtures representative of the expected dust composition in dense ISM regions. The optical properties of 0.01 micron to 10 cm grains are then calculated with effective medium and Mie theories. The corresponding SEDs are calculated for isolated clouds either externally heated by the ISRF alone or in addition to an internal source. The 3 main outcomes of this study are as follows. First, the dust mass absorption coefficient strongly depends on both its composition and size distribution potentially leading to errors in dust mass estimates by factors up to 3 and 20, respectively. Second, it appears almost impossible to retrieve the grain composition from the (sub)mm to cm SED shape alone as its spectral index for lambda > 3 mm does not depend on composition. Third, using the true dust opacity spectral index to estimate grain sizes may lead to erroneous findings as the observed spectral index can be highly modified by the dust temperature distribution along the line-of-sight, which depends on the specific heating source and on the geometry of the studied region. Based on the interpretation of only the spectral shape of (sub)mm to cm SEDs, the determination of the dust masses, compositions and sizes are highly uncertain.

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A systematic metallicity study of DustPedia galaxies reveals evolution in the dust-to-metal ratios

Observations of evolution in the dust-to-metal ratio allow us to constrain the dominant dust processing mechanisms. In this work, we present a study of the dust-to-metal and dust-to-gas ratios in a sub-sample of ~500 DustPedia galaxies. Using literature and MUSE emission line fluxes, we derived gas-phase metallicities (oxygen abundances) for over 10000 individual regions and determine characteristic metallicities for each galaxy. We study how the relative dust, gas, and metal contents of galaxies evolve by using metallicity and gas fraction as proxies for evolutionary state. The global oxygen abundance and nitrogen-to-oxygen ratio are found to increase monotonically as galaxies evolve. Additionally, unevolved galaxies (gas fraction > 60%, metallicity 12 + log(O/H) < 8.2) have dust-to-metal ratios that are about a factor of 2.1 lower (a factor of six lower for galaxies with gas fraction > 80%) than the typical dust-to-metal ratio (Md/MZ ~ 0.214) for more evolved sources. However, for high gas fractions, the scatter is larger due to larger observational uncertainties as well as a potential dependence of the dust grain growth timescale and supernova dust yield on local conditions and star formation histories. We find chemical evolution models with a strong contribution from dust grain growth describe these observations reasonably well. The dust-to-metal ratio is also found to be lower for low stellar masses and high specific star formation rates (with the exception of some sources undergoing a starburst). Finally, the metallicity gradient correlates weakly with the HI-to-stellar mass ratio, the effective radius and the dust-to-stellar mass ratio, but not with stellar mass.

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Dust emissivity and absorption cross section in DustPedia late-type galaxies

Aims: We compare the far-infrared to sub-millimetre dust emission properties measured in high Galactic latitude cirrus with those determined in a sample of 204 late-type DustPedia galaxies. The aim is to verify if it is appropriate to use Milky Way dust properties to derive dust masses in external galaxies. Methods: We used Herschel observations and atomic and molecular gas masses to estimate the disc-averaged dust emissivity at 250 micrometres, and from this, the absorption cross section per H atom and per dust mass. The emissivity requires one assumption, which is the CO-to-H_2 conversion factor, and the dust temperature is additionally required for the absorption cross section per H atom; yet another constraint on the dust-to-hydrogen ratio D/H, depending on metallicity, is required for the absorption cross section dust mass. Results: We find epsilon(250) = 0.82 +/- 0.07 MJy sr^-1 (1E20 H cm^-2)^-1 for galaxies with 4 < F(250)/F(500) < 5. This depends only weakly on the adopted CO-to-H_2 conversion factor. The value is almost the same as that for the Milky Way at the same colour ratio. Instead, for F(250)/F(500) > 6, epsilon(250) is lower than predicted by its dependence on the heating conditions. The reduction suggests a variation in dust emission properties for spirals of earlier type, higher metallicity, and with a higher fraction of molecular gas. When the standard emission properties of Galactic cirrus are used for these galaxies, their dust masses might be underestimated by up to a factor of two. Values for the absorption cross sections at the Milky Way metallicity are also close to those of the cirrus. Mild trends of the absorption cross sections with metallicity are found, although the results depend on the assumptions made.

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Probing the cold magnetized Universe with SPICA-POL (B-BOP)

SPICA, the cryogenic infrared space telescope recently pre-selected for a `Phase A' concept study as one of the three remaining candidates for ESA's fifth medium class (M5) mission, is foreseen to include a far-infrared polarimetric imager (SPICA-POL, now called B-BOP), which would offer a unique opportunity to resolve major issues in our understanding of the nearby, cold magnetized Universe. This paper presents an overview of the main science drivers for B-BOP, including high dynamic range polarimetric imaging of the cold interstellar medium (ISM) in both our Milky Way and nearby galaxies. Thanks to a cooled telescope, B-BOP will deliver wide-field 100-350 micron images of linearly polarized dust emission in Stokes Q and U with a resolution, signal-to-noise ratio, and both intensity and spatial dynamic ranges comparable to those achieved by Herschel images of the cold ISM in total intensity (Stokes I). The B-BOP 200 micron images will also have a factor ~30 higher resolution than Planck polarization data. This will make B-BOP a unique tool for characterizing the statistical properties of the magnetized interstellar medium and probing the role of magnetic fields in the formation and evolution of the interstellar web of dusty molecular filaments giving birth to most stars in our Galaxy. B-BOP will also be a powerful instrument for studying the magnetism of nearby galaxies and testing galactic dynamo models, constraining the physics of dust grain alignment, informing the problem of the interaction of cosmic rays with molecular clouds, tracing magnetic fields in the inner layers of protoplanetary disks, and monitoring accretion bursts in embedded protostars.

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DustPedia - the relationships between stars, gas and dust for galaxies residing in different environments

We use a sub-set of the DustPedia galaxy sample (461 galaxies) to investigate the effect the environment has had on galaxies. We consider Virgo cluster and field samples and also assign a density contrast parameter to each galaxy, as defined by the local density of SDSS galaxies. We consider their chemical evolution (using M_{Dust}/M_{Baryon} and M_{Gas}/M_{Baryon}), their specific star formation rate (SFR/M_{Stars}), star formation efficiency (SFR/M_{Gas}), stars-to-dust mass ratio (M_{Stars}/M_{Dust}), gas-to-dust mass ratio (M_{Gas}/M_{Dust}) and the relationship between star formation rate per unit mass of dust and dust temperature (SFR/M_{Dust} and T_{Dust}). Late type galaxies (later than Sc) in all of the environments can be modelled using simple closed box chemical evolution and a simple star formation history (SFR(t) \propto t\exp{-t/τ}). For earlier type galaxies the physical mechanisms that give rise to their properties are clearly much more varied and require a more complicated model (mergers, gas in or outflow). However, we find little or no difference in the properties of galaxies of the same morphological type within the cluster, field or with different density contrasts. It appears that it is morphology, how and whenever this is laid down, and consistent internal physical processes that primarily determine the derived properties of galaxies in the DustPedia sample and not processes related to differences in the local environment.

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Nano carbon dust emission in proto-planetary disks: the aliphatic-aromatic components

In the interstellar medium, carbon (nano-)grains are a major component of interstellar dust. This solid phase is more vulnerable to processing and destruction than its silicate counterpart. It exhibits a complex, size-dependent evolution due to interactions within different radiative and dynamical environments. Infrared signatures of these nanocarbon grains are seen in a large number of disks around Herbig HAeBe stars. We probe the composition and evolution of carbon nano-grains at the surface of (pre-)transitional protoplanetary disks around Herbig stars. We present spatially resolved infrared emission spectra obtained with NAOS CONICA at the VLT in the 3-4 $μ$m range with a spatial resolution of 0.1", which allow us to trace aromatic, olefinic and aliphatic bands which are attributed to sub-nanometer hydrocarbon grains. We apply a gaussian fitting to analyse the observed spectral signatures. Finally, we propose an interpretation in the framework of the The Heterogeneous dust Evolution Model of Interstellar Solids (THEMIS). We show the presence of several spatially extended spectral features, related to aromatic and aliphatic hydrocarbon material in disks around Herbig stars, from ~ 10 to 50-100 au, and even in inner gaps devoided of large grains. The correlation and constant intensity ratios between aliphatic and aromatic CH stretching bands suggest a common nature of the carriers. Given their expected high destruction rates due to UV photons, our observations suggest that they are continuously replenished at the disk surfaces.

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