arXiv subjects

Nanase Harada

Publications and source records attributed to Nanase Harada.

At least 19 recordsLinked to original sources

arXiv2026

A New Framework for Multi-Line Analysis Combined Kernel PCA and Kernel SHAP: A Case of NGC 1068 ALMA Band 3 Data

We present a new framework for multi-line analysis that combines kernel principal component analysis (Kernel PCA), an unsupervised machine-learning method, and Kernel SHapley Additive exPlanations (Kernel SHAP), an explainable artificial intelligence (XAI) technique. To enable a comparison with PCA-based studies, which have been widely used in multi-line analyses, we apply our framework to integrated intensity maps of 13 molecular lines from Atacama Large Millimeter/submillimeter Array (ALMA) Band 3 archival data of the nearby galaxy NGC 1068. Previous PCA-based studies of NGC 1068 reported that physically meaningful structures are mainly captured up to the second component. In contrast, our framework can interpret physically meaningful features up to the fourth component. Furthermore, by comparing the results obtained from our framework with molecular column densities derived from local thermodynamical equilibrium (LTE) analysis, we suggest that the abundance of HCO+ is relatively enhanced in the molecular outflow region extending to a radius of about 400 pc from the galactic center, likely due to the effects of ultraviolet radiation and highly dense gas. These results show that our framework can provide data-driven insights into physical and chemical features that have not been clearly identified in previous studies. It also provides an efficient tool for interpreting the rapidly increasing amount of multi-line observational data.

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arXiv2025

Clumpy, dense gas in the outflow of NGC 1266

Outflows are one of the most spectacular mechanisms through which active galactic nuclei (AGN) impact their host galaxy, though the role of AGN-driven outflows in global star formation regulation across the galaxy population is unclear. NGC 1266 is an excellent case study for investigating the outflows and star formation quenching because it is a nearby (D\sim30 Mpc) AGN host galaxy with an outflow driving shocks through the interstellar medium (ISM) and has recently quenched its star formation outside the nucleus. While previous works have studied the molecular outflow from its CO emission, to fully characterize the impact the outflow has on the ISM observations probing the dense, cold gas are necessary. Our ALMA cycle 0 observations do not detect a molecular outflow in 13CO(2-1) and yield a lower limit 12CO/13CO \geq 250, suggesting a highly optically thin CO outflow with low 13CO abundance. In contrast, we detect substantial HCN(1-0) emission in the outflow, with an HCN(1-0)/12CO(1-0) ratio of 0.09, consistent with global measurements of many star-forming galaxies and Luminous InfraRed Galaxies (LIRGs). We conclude that the CO emission traces a diffuse component of the molecular gas with a low optical depth, whereas the HCN(1-0) traces dense clumps of gas entrained in the outflow. We measure an upper limit molecular outflow rate of < 85 Msun/yr. Assuming the ongoing nuclear star formation and outflow continue at the same rates, NGC 1266 will deplete its gas reservoirs in 450 Myr or longer, indicating that relatively low-level AGN feedback is capable of gradually expelling the molecular gas reservoir after a rapid quenching event.

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arXiv2025

Detailed analysis of multi-line molecular distributions in the Seyfert galaxy NGC 1068: Possible effect of the AGN outflow to the starburst ring

We apply principal component analysis (PCA) to the integrated intensity maps of 13 molecular lines of the nearby type-2 Seyfert galaxy NGC 1068 obtained by Atacama Large Millimeter/sub-millimeter Array (ALMA) to objectively visualize the features of its center, (1) within a radius of about 2 kpc ($\sim$ 27".5; hereafter the "overall region") and (2) the ring shaped starburst region between 750 pc ($\sim$ 10") and 2 kpc ($\sim$ 27".5) of the galaxy (hereafter the "SB ring region"). PCA is a powerful unsupervised machine learning technique that extracts key information through dimensionality reduction. The PCA results for the overall region have a possibility to reconstruct a map representing the approximate H$_2$ column density and difference of volume density and/or chemical composition between the circumnuclear disk (CND) and the starburst ring (SB ring). Additionally, the PCA results for the SB ring region have a possibility to reconstruct a map representing the approximate H$_2$ column density and distinction between starburst dominated region and shock dominated region. Furthermore, the PCA results for the SB ring region indicate a possible interaction between the Active Galactic Nucleus (AGN) outflow and gas in the SB ring. Although further investigation is required, we suggest that the AGN outflow interacts with gas in the SB ring, as this feature is consistent with the direction of the AGN outflow and is contributed by CN, C$_2$H and HCN, which are known to be enhanced by the AGN outflow. These results demonstrate that PCA can effectively extract features even for galaxies with complex structures, such as AGN + SB ring. This study also implies that PCA has the potential to uncover previously unrecognized phenomena by visualizing latent structures in multi-line data.

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arXiv2024

Components of star formation in NGC 253 : Non-negative Matrix Factorization Analysis with the ALCHEMI integrated intensity images

It is essential to examine the physical or chemical properties of molecular gas in starburst galaxies to reveal the underlying mechanisms characterizing starbursts. We used non-negative matrix factorization (NMF) to extract individual molecular or physical components involved in the star formation process in NGC\,253. We used images of 148 transitions from 44 different species of the ALMA large program ALCHEMI. Additionally, we included the continuum images at ALMA Bands 3 and 7 from the same dataset. For the five NMF components (NF1--5), we obtained that their distributions correspond to various basic phenomena related to star formation: i) low-density gas extended through the galactic central molecular zone (NF2), ii) shocks (NF3), iii) starburst regions (NF4), and iv) young star-forming regions (NF5). The other component (NF1) is related to excitation; three components obtained by NMF (NF3, 1, and 5) show a strong dependence upon the upper state energies of transitions, and represent low-, intermediate-, and high-excitation, respectively. We also compared our results using principal component analysis (PCA) previously applied to the same dataset. Molecular components extracted from NMF are similar to the ones obtained from PCA. However, NMF is better at extracting components associated with a single physical component, while a single component in PCA usually contains information on multiple physical components. This is especially true for features with weak intensities like emission from outflows. Our results suggest that NMF can be one of promising methods interpreting molecular line survey data, especially in the upcoming era of wide-band receivers.

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arXiv2024

Whole-disk sampling of molecular clouds in M83

We present a catalog of clouds identified from the $^{12}$CO (1--0) data of M83, which was observed using Atacama Large Millimeter/submillimeter Array (ALMA) with a spatial resolution of $\sim$46 pc and a mass sensitivity of $\sim$10$^4$ $M_{\odot}$ (3 $\sigma$). The almost full-disk coverage and high sensitivity of the data allowed us to sample 5724 molecular clouds with a median mass of $\sim1.9$ $\times$ $10^5$ $M_{\odot}$, which is comparable to the most frequently sampled mass of Giant Molecular Clouds by surveys in the Milky Way. About 60 percent of the total CO luminosity in M83's disk arises from clouds more massive than 10$^6$ $M_{\odot}$. Such massive clouds comprise 16 percent of the total clouds in number and tend to concentrate toward the arm, bar, and center, while smaller clouds are more prevalent in inter-arm regions. Most $>10^6$ $M_{\odot}$ clouds have peak brightness temperatures $T_{\mathrm{peak}}$ above 2 K with the current resolution. Comparing the observed cloud properties with the scaling relations determined by Solomon et al. 1987 (S87), $T_{\mathrm{peak}}$$>2$ K clouds follow the relations, but $T_{\mathrm{peak}}$$<2$ K clouds, which are dominant in number, deviate significantly. Without considering the effect of beam dilution, the deviations would suggest modestly high virial parameters and low surface mass densities for the entire cloud samples, which are similar to values found for the Milky Way clouds by Rice et al. (2016) and Miville-Desch{\^e}nes et al. (2017). However, once beam dilution is taken into account, the observed $\alpha_{\mathrm{vir}}$ and $\Sigma$ for a majority of the clouds (mostly $T_{\mathrm{peak}}$ $<2$ K) can be potentially explained with intrinsic $\Sigma$ of $\sim$100 $M_{\mathrm{\odot}}\ \mathrm{pc}^{-2}$ and $\alpha_{\mathrm{vir}}$ of $\sim$1, which are similar to the clouds of S87.

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arXiv2024

Neural Network Constraints on the Cosmic-Ray Ionization Rate and Other Physical Conditions in NGC 253 with ALCHEMI Measurements of HCN and HNC

We use a neural network model and ALMA observations of HCN and HNC to constrain the physical conditions, most notably the cosmic-ray ionization rate (CRIR, zeta), in the Central Molecular Zone (CMZ) of the starburst galaxy NGC 253. Using output from the chemical code UCLCHEM, we train a neural network model to emulate UCLCHEM and derive HCN and HNC molecular abundances from a given set of physical conditions. We combine the neural network with radiative transfer modeling to generate modeled integrated intensities, which we compare to measurements of HCN and HNC from the ALMA Large Program ALCHEMI. Using a Bayesian nested sampling framework, we constrain the CRIR, molecular gas volume and column densities, kinetic temperature, and beam-filling factor across NGC 253's CMZ. The neural network model successfully recovers UCLCHEM molecular abundances with about 3 percent error and, when used with our Bayesian inference algorithm, increases the parameter inference speed tenfold. We create images of these physical parameters across NGC 253's CMZ at 50 pc resolution and find that the CRIR, in addition to the other gas parameters, is spatially variable with zeta a few times 10^{14} s^{-1} at greater than 100 pc from the nucleus, increasing to zeta greater than 10^{-13} s^{-1} at its center. These inferred CRIRs are consistent within 1 dex with theoretical predictions based on non-thermal emission. Additionally, the high CRIRs estimated in NGC 253's CMZ can be explained by the large number of cosmic-ray-producing sources as well as a potential suppression of cosmic-ray diffusion near their injection sites.

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arXiv2024

Parabolic-like Trend in SiO Ratios throughout the Central Molecular Zone: Possible Signature of a Past Nuclear Activity in the Galactic Center

We report the discovery of a characteristic trend in the intensity ratios of SiO emissions across the Central Molecular Zone (CMZ) of our Galaxy. Using the Nobeyama Radio Observatory 45-m telescope, we conducted large-scale, high-sensitivity imaging observations in molecular lines including SiO $J$=2$-$1 and CS $J$=2$-$1. By identifying SiO-emitting clouds and examining their intensity ratios relative to the other molecular lines, we unveiled a parabolic-like trend showing lower ratios near the Galactic nucleus, Sgr A$^*$, with gradual increases toward the edges of the CMZ. This pattern suggests a possible outburst of the nucleus within the last $\sim 10^5$ yr, which may have propagated through the entire CMZ with strong shocks. Alternatively, the observed trend may also be attributed to the destruction of small dust grains by high-energy photons. Our results can potentially lead to a new perspective on the history of nuclear activity and its impact on the surrounding molecular environment.

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arXiv2024

Measuring 60-pc-scale Star Formation Rate of the Nearby Seyfert Galaxy NGC 1068 with ALMA, HST, VLT/MUSE, and VLA

Star formation rate (SFR) is a fundamental parameter for describing galaxies and inferring their evolutionary course. HII regions yield the best measure of instantaneous SFR in galaxies, although the derived SFR can have large uncertainties depending on tracers and assumptions. We present an SFR calibration for the entire molecular gas disk of the nearby Seyfert galaxy NGC 1068, based on our new high-sensitivity ALMA 100GHz continuum data at 55pc (=0."8) resolution in combination with the HST Paα line data. In this calibration, we account for the spatial variations of dust extinction, electron temperature of HII regions, AGN contamination, and diffuse ionized gas (DIG) based on publicly available multi-wavelength data. Especially, given the extended nature and the possible non-negligible contribution to the total SFR, a careful consideration of DIG is essential. With a cross-calibration between two corrected ionized gas tracers (free-free continuum&Paα), the total SFR of the NGC 1068 disk is estimated to be 3.2\pm0.5 Msol/yr, one-third of the SFR without accounting for DIG (9.1\pm1.4 Msol/yr). We confirmed high SFR around the southern bar-end and the corotation radius, which is consistent with the previous SFR measurements. In addition, our total SFR exceeds the total SFR based on 8μm dust emission by a factor of 1.5. We attribute this discrepancy to the differences in the young stars at different stages of evolution traced by each tracer and their respective timescales. This study provides an example to address the various uncertainties in conventional SFR measurements and their potential to lead to significant SFR miscalculations.

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arXiv2024

A temperature or FUV tracer? The HNC/HCN ratio in M83 on the GMC scale

The HNC/HCN ratio is observationally known as a thermometer in Galactic interstellar molecular clouds. A recent study has alternatively suggested that the HNC/HCN ratio is affected by the ultraviolet (UV) field, not by the temperature. We aim to study this ratio on the scale of giant molecular clouds in the barred spiral galaxy M83 towards the southwestern bar end and the central region from ALMA observations, and if possible, distinguish the above scenarios. We compare the high (40-50 pc) resolution HNC/HCN ratios with the star formation rate from the 3-mm continuum intensity and the molecular mass inferred from the HCN intensities. Our results show that the HNC/HCN ratios do not vary with the star formation rates, star formation efficiencies, or column densities in the bar-end region. In the central region, the HNC/HCN ratios become higher with higher star formation rates, which tend to cause higher temperatures. This result is not consistent with the previously proposed scenario in which the HNC/HCN ratio decreases with increasing temperature. Spectral shapes suggest that this trend may be due to optically thick HCN and optically thin HNC. In addition, we compare the large-scale ($\sim 200$ pc) correlation between the dust temperature from the FIR ratio and the HNC/HCN ratio for the southwestern bar-end region. The HNC/HCN ratio is lower when the dust temperatures are higher. We suggest from the above results that the HNC/HCN ratio depends on the UV radiation field that affects the interstellar medium on the $\sim100\,$pc scale where the column densities are low.

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arXiv2024

Physical Properties of the Southwest Outflow Streamer in the Starburst Galaxy NGC 253 with ALCHEMI

The physical properties of galactic molecular outflows are important as they could constrain outflow formation mechanisms. We study the properties of the southwest (SW) outflow streamer including gas kinematics, optical depth, dense gas fraction, and shock strength in the central molecular zone of the starburst galaxy NGC 253. We image the molecular emission at a spatial resolution of $\sim$27 pc based on data from the ALCHEMI program. We trace the kinematics of molecular gas with CO(1-0) line. We constrain the optical depth of CO emission with CO/$^{13}$CO(1-0) ratio, the dense gas fraction with HCN/CO(1-0) ratio, as well as the shock strength with SiO(2-1)/$^{13}$CO(1-0) ratio. The CO/$^{13}$CO(1-0) integrated intensity ratio is $\sim$21 in the SW streamer region, which approximates the C/$^{13}$C isotopic abundance ratio. The higher integrated intensity ratio compared to the disk can be attributed to the optically thinner environment for CO(1-0) emission inside the SW streamer. The HCN/CO(1-0) and SiO(2-1)/$^{13}$CO(1-0) integrated intensity ratios both approach $\sim$0.2 in three giant molecular clouds (GMCs) at the base of the outflow streamers, which implies the higher dense gas fraction and enhanced strength of fast shocks in those GMCs than in the disk. The contours of those two integrated intensity ratios are extended towards the directions of outflow streamers, which connects the enhanced dense gas fraction and shock strength with molecular outflow. Moreover, the molecular gas with enhanced dense gas fraction and shock strength located at the base of the SW streamer shares the same velocity with the outflow. These phenomena suggest that the star formation inside the GMCs can trigger the shocks and further drive the molecular outflow.

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arXiv2024

The ALMaQUEST Survey XII: Dense Molecular Gas as traced by HCN and HCO$^{+}$ in Green Valley Galaxies

We present ALMA observations of two dense gas tracers, HCN(1-0) and HCO$^{+}$(1-0), for three galaxies in the green valley and two galaxies on the star-forming main sequence with comparable molecular gas fractions as traced by the CO(1-0) emissions, selected from the ALMaQUEST survey. We investigate whether the deficit of molecular gas star formation efficiency (SFE$_{\rm mol}$) that leads to the low specific star formation rate in these green valley galaxies is due to a lack of dense gas (characterized by the dense gas fraction $f_{\rm dense}$) or the low star formation efficiency of dense gas (SFE$_{\rm dense}$). We find that SFE$_{\rm mol}$ as traced by the CO emissions, when considering both star-forming and retired spaxels together, is tightly correlated with SFE$_{\rm dense}$ and depends only weakly on $f_{\rm dense}$. The specific star formation rate (sSFR) on kpc scales is primarily driven by SFE$_{\rm mol}$ and SFE$_{\rm dense}$, followed by the dependence on $f_{\rm mol}$, and is least correlated with $f_{\rm dense}$ or the dense-to-stellar mass ratio ($R_{\rm dense}$). When compared with other works in the literature, we find that our green valley sample shows lower global SFE$_{\rm mol}$ as well as lower SFE$_{\rm dense}$ while exhibiting similar dense gas fractions when compared to star-forming and starburst galaxies. We conclude that the star formation of the 3 green valley galaxies with a normal abundance of molecular gas is suppressed mainly due to the reduced SFE$_{\rm dense}$ rather than the lack of dense gas.

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arXiv2024

The ALCHEMI atlas: principal component analysis reveals starburst evolution in NGC 253

Molecular lines are powerful diagnostics of the physical and chemical properties of the interstellar medium (ISM). These ISM properties, which affect future star formation, are expected to differ in starburst galaxies from those of more quiescent galaxies. We investigate the ISM properties in the central molecular zone of the nearby starburst galaxy NGC 253 using the ultra-wide millimeter spectral scan survey from the ALMA Large Program ALCHEMI. We present an atlas of velocity-integrated images at a 1".6 resolution of 148 unblended transitions from 44 species, including the first extragalactic detection of HCNH$^+$ and the first interferometric images of C$_3$H$^+$, NO, HCS$^+$. We conduct a principal component analysis (PCA) on these images to extract correlated chemical species and to identify key groups of diagnostic transitions. To the best of our knowledge, our dataset is currently the largest astronomical set of molecular lines to which PCA has been applied. The PCA can categorize transitions coming from different physical components in NGC 253 such as i) young starburst tracers characterized by high-excitation transitions of HC$_3$N and complex organic molecules (COMs) versus tracers of on-going star formation (radio recombination lines) and high-excitation transitions of CCH and CN tracing PDRs, ii) tracers of cloud-collision-induced shocks (low-excitation transitions of CH$_3$OH, HNCO, HOCO$^+$, and OCS) versus shocks from star-formation-induced outflows (high-excitation transitions of SiO), as well as iii) outflows showing emission from HOC$^+$, CCH, H$_3$O$^+$, CO isotopologues, HCN, HCO$^+$, CS, and CN. Our findings show these intensities vary with galactic dynamics, star formation activities, and stellar feedback.

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arXiv2023

Volume density structure of the NGC253 CMZ through ALCHEMI excitation analysis

We present a spatially-resolved excitation analysis for the central molecular zone (CMZ) of the starburst galaxy NGC 253 using the data from the ALMA Large program ALCHEMI, whereby we explore parameters distinguishing NGC 253 from the quiescent Milky Way's Galactic Center (GC). Non-LTE analyses employing a hierarchical Bayesian framework are applied to Band 3-7 transitions from nine molecular species to delineate the position-position-velocity distributions of column density ($N_\mathrm{H_2}$), volume density ($n_\mathrm{H_2}$), and temperature ($T_\mathrm{kin}$) at 27 pc resolution. Two distinct components are detected: a low-density component with $(n_\mathrm{H_2},\ T_\mathrm{kin})\sim(10^{3.3}\ \mathrm{cm}^{-3}, 85 K)$ and a high-density component with $(n_\mathrm{H_2},\ T_\mathrm{kin})\sim (10^{4.4}\ \mathrm{cm}^{-3}, 110\ \mathrm{K})$, separated at $n_\mathrm{H_2}\sim10^{3.8}\ \mathrm{cm}^{-3}$. NGC 253 has $\sim10$ times the high-density gas mass and $\sim3$ times the dense-gas mass fraction of the GC. These properties are consistent with their HCN/CO ratio but cannot alone explain the factor of $\sim30$ difference in their star formation efficiencies (SFEs), contradicting the dense-gas mass to star formation rate scaling law. The $n_\mathrm{H_2}$ histogram toward NGC 253 exhibits a shallow declining slope up to $n_\mathrm{H_2}\sim10^6\ \mathrm{cm}^{-3}$, while that of the GC steeply drops in $n_\mathrm{H_2}\gtrsim10^{4.5}\ \mathrm{cm}^{-3}$ and vanishes at $10^5\ \mathrm{cm}^{-3}$. Their dense-gas mass fraction ratio becomes consistent with their SFEs when the threshold $n_\mathrm{H_2}$ for the dense gas is taken at $\sim 10^{4.2\mbox{-}4.6}\ \mathrm{cm}^{-3}$. The rich abundance of gas above this density range in the NGC 253 CMZ, or its scarcity in the GC, is likely to be the critical difference characterizing the contrasting star formation in the centers of the two galaxies.

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arXiv2023

Molecular Abundance of the Circumnuclear Region Surrounding an Active Galactic Nucleus in NGC 1068 based on Imaging Line Survey in the 3-mm Band with ALMA

We present an imaging molecular line survey in the 3-mm band (85-114 GHz) focused on one of the nearest galaxies with an active galactic nucleus (AGN), NGC 1068, based on observations taken with the Atacama Large Millimeter/submillimeter Array (ALMA). Distributions of 23 molecular transitions are obtained in the central ~3 kpc region, including both the circumnuclear disk (CND) and starburst ring (SBR) with 60 and 350 pc resolution. The column densities and relative abundances of all the detected molecules are estimated under the assumption of local thermodynamic equilibrium in the CND and SBR. Then, we discuss the physical and chemical effects of the AGN on molecular abundance corresponding to the observation scale. We found that H13CN, SiO, HCN, and H13CO+ are abundant in the CND relative to the SBR. In contrast, 13CO is more abundant in the SBR. Based on the calculated column density ratios of N(HCN)/N(HCO+), N(HCN)/N(CN), and other molecular distributions, we conclude that the enhancement of HCN in the CND may be due to high-temperature environments resulting from strong shocks, which are traced by the SiO emission. Moreover, the abundance of CN in the CND is significantly lower than the expected value of the model calculations in the region affected by strong radiation. The expected strong X-ray irradiation from the AGN has a relatively lower impact on the molecular abundance in the CND than mechanical feedback.

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arXiv2023

Diverse Molecular Structures Across The Whole Star-Forming Disk of M83: High fidelity Imaging at 40pc Resolution

We present high-fidelity CO(1-0) imaging of molecular gas across the full star-forming disk of M83, using ALMA's 12m, 7m, and TP arrays and the MIRIAD package. The data have a mass sensitivity and resolution of 10^4Msun and 40 pc. The full disk coverage shows that the characteristics of molecular gas change radially from the center to outer disk. The molecular gas distribution shows coherent large-scale structures in the inner part, including the central concentration, bar offset ridges, and prominent molecular spiral arms. In the outer disk, the spiral arms appear less spatially coherent, and even flocculent. Massive filamentary gas concentrations are abundant even in the interarm regions. Building up these structures in the interarm regions would require a very long time (~>100Myr). Instead, they must have formed within stellar spiral arms and been released into the interarm regions. For such structures to survive through the dynamical processes, the lifetimes of these structures and their constituent molecules and molecular clouds must be long (~>100Myr). These interarm structures host little or no star formation traced by Halpha. The new map also shows extended CO emission, which likely represents an ensemble of unresolved molecular clouds.

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arXiv2022

Tracing Interstellar Heating: An ALCHEMI Measurement of the HCN Isomers in NGC 253

We analyze HCN and HNC emission in the nearby starburst galaxy NGC 253 to investigate its effectiveness in tracing heating processes associated with star formation. This study uses multiple HCN and HNC rotational transitions observed using ALMA via the ALCHEMI Large Program. To understand the conditions and associated heating mechanisms within NGC 253's dense gas, we employ Bayesian nested sampling techniques applied to chemical and radiative transfer models which are constrained using our HCN and HNC measurements. We find that the volume density $n_{\text{H}_{2}}$ and cosmic ray ionization rate (CRIR) $ζ$ are enhanced by about an order of magnitude in the galaxy's central regions as compared to those further from the nucleus. In NGC 253's central GMCs, where observed HCN/HNC abundance ratios are lowest, $n \sim 10^{5.5}$ cm$^{-3}$ and $ζ\sim 10^{-12}$ s$^{-1}$ (greater than $10^4$ times the average Galactic rate). We find a positive correlation in the association of both density and CRIR with the number of star formation-related heating sources (supernova remnants, HII regions, and super hot cores) located in each GMC, as well as a correlation between CRIRs and supernova rates. Additionally, we see an anticorrelation between the HCN/HNC ratio and CRIR, indicating that this ratio will be lower in regions where $ζ$ is higher. Though previous studies suggested HCN and HNC may reveal strong mechanical heating processes in NGC 253's CMZ, we find cosmic ray heating dominates the heating budget, and mechanical heating does not play a significant role in the HCN and HNC chemistry.

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arXiv2022

ALCHEMI finds a "shocking" carbon footprint in the starburst galaxy NGC~253

Centers of starburst galaxies may be characterized by a specific gas and ice chemistry due to their gas dynamics and the presence of various ice desorption mechanisms. This may result in a peculiar observable composition. We analyze abundances of $CO_2$, a reliable tracer of ice chemistry, from data collected as part of the ALMA large program ALCHEMI, a wide-frequency spectral scan toward the starburst galaxy NGC~253 with an angular resolution of 1.6$''$. We constrain the $CO_2$ abundances in the gas phase using its protonated form $HOCO^+$. The distribution of $HOCO^+$ is similar to that of methanol, which suggests that $HOCO^+$ is indeed produced from the protonation of $CO_2$ sublimated from ice. The $HOCO^+$ fractional abundances are found to be $(1-2)\times10^{-9}$ at the outer part of the central molecular zone (CMZ), while they are lower ($\sim10^{-10}$) near the kinematic center. This peak fractional abundance at the outer CMZ is comparable to that in the Milky Way CMZ, and orders of magnitude higher than that in Galactic disk star-forming regions. From the range of $HOCO^+/CO_2$ ratios suggested from chemical models, the gas-phase $CO_2$ fractional abundance is estimated to be $(1-20)\times10^{-7}$ at the outer CMZ, and orders of magnitude lower near the center. We estimate the $CO_2$ ice fractional abundances at the outer CMZ to be $(2-5)\times10^{-6}$ from the literature. A comparison between the ice and gas $CO_2$ abundances suggests an efficient sublimation mechanism. This sublimation is attributed to large-scale shocks at the orbital intersections of the bar and CMZ.

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arXiv2022

AGN-driven Cold Gas Outflow of NGC 1068 Characterized by Dissociation-Sensitive Molecules

Recent developments in (sub-)millimeter facilities have drastically changed the amount of information obtained from extragalactic spectral scans. In this paper, we present a feature extraction technique using principal component analysis (PCA) applied to arcsecond-resolution (1.0-2.0 arcsec = 72-144 pc) spectral scan datasets for the nearby type-2 Seyfert galaxy, NGC 1068, using Band 3 of the Atacama Large Millimeter/submillimeter Array. We apply PCA to 16 well-detected molecular line intensity maps convolved to a common 150 pc resolution. In addition, we include the [SIII]/[SII] line ratio and [CI] $^3P_1$-$^3P_0$ maps in the literature, both of whose distributions show remarkable resemblance with that of a kpc-scale biconical outflow from the central AGN. We identify two prominent features: (1) central concentration at the circumnuclear disk (CND) and (2) two peaks across the center that coincide with the biconical outflow peaks. The concentrated molecular lines in the CND are mostly high-dipole molecules (e.g., H$^{13}$CN, HC$_3$N, and HCN). Line emissions from molecules known to be enhanced in irradiated interstellar medium, CN, C$_2$H, and HNC, show similar concentrations and extended components along the bicone, suggesting that molecule dissociation is a dominant chemical effect of the cold molecular outflow of this galaxy. Although further investigation should be made, this scenario is consistent with the faintness or absence of the emission lines from CO isotopologues, CH$_3$OH, and N$_2$H$^+$, in the outflow, which are easily destroyed by dissociating photons and electrons.

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