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Natalia B. Perkins

Publications and source records attributed to Natalia B. Perkins.

At least 55 records · Page 3Linked to original sources

Quantum-classical crossover in the spin-1/2 Heisenberg-Kitaev kagome magnet

The spin-1/2 Heisenberg kagome antiferromagnet is one of the paradigmatic playgrounds for frustrated quantum magnetism, with an extensive number of competing resonating valence bond (RVB) states emerging at low energies, including gapped and gapless spin liquids and valence bond crystals. Here we revisit the crossover from this quantum RVB phase to a semiclassical regime brought about by anisotropic Kitaev interactions, and focus on the precise mechanisms underpinning this crossover. To this end, we introduce a simple parametrization of the classical ground states (GSs) in terms of emergent Ising-like variables, and use this parametrizaton: i) to construct an effective low-energy description of the order-by-disorder mechanism operating in a large part of the phase diagram, and ii) to contrast, side by side, exact diagonalization data obtained from the full basis with that obtained from the restricted (orthonormalized) basis of classical GSs. The results reveal that fluctuation corrections from states outside the restricted basis are strongly quenched inside the semiclassical regime (due to the large anisotropy spin gaps), and that the RVB phase survives up to a relatively large value of Kitaev anisotropy $K$. We further find that the pure Kitaev model admits a subextensive number of one-dimensional symmetries, which explains naturally the absence of classical and quantum order by disorder reported previously.

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Reentrant incommensurate order and anomalous magnetic torque in the Kitaev magnet $β$-$\text{Li}_2\text{IrO}_3$

We present a theoretical study of the response of $β$-$\text{Li}_2\text{IrO}_3$ under external magnetic fields in the $ab$, $bc$ and $ac$ crystallographic planes. The results are based on the minimal nearest-neighbor $J$-$K$-$Γ$ model and reveal a rich intertwining of field-induced phases and magnetic phase transitions with distinctive signatures that can be probed directly via torque magnetometry. Most saliently, we observe: i) an unusual reentrance of the incommensurate counter-rotating order for fields in the $ab$-plane, and ii) a set of abrupt torque discontinuities which are particularly large for fields rotating in the $bc$ plane, and whose characteristic shape resembles closely the ones observed in the 3D Kitaev magnet $γ$-$\text{Li}_2\text{IrO}_3$. An experimental confirmation of these predictions will pave the way for an accurate determination of all relevant microscopic parameters of this 3D Kitaev magnet.

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Unconventional magnetic field response of the hyperhoneycomb Kitaev magnet $β-\textbf{Li}_2\textbf{IrO}_3$

We present a unified description of the response of the hyperhoneycomb Kitaev magnet $β$-$\text{Li}_2\text{IrO}_3$ to applied magnetic fields along the orthorhombic directions ${\bf a}$, ${\bf b}$ and ${\bf c}$. This description is based on the minimal nearest-neighbor $J$-$K$-$Γ$ model and builds on the idea that the incommensurate counter-rotating order observed experimentally at zero field can be treated as a long-distance twisting of a nearby commensurate order with six spin sublattices. The results reveal that the behavior of the system for ${\bf H}\parallel{\bf a}$, ${\bf H}\parallel{\bf b}$ and ${\bf H}\parallel{\bf c}$ share a number of qualitative features, including: i) a strong intertwining of the modulated, counter-rotating order with a set of uniform orders; ii) the disappearance of the modulated order at a critical field $H^\ast$, whose value is strongly anisotropic with $H_{\bf b}^\ast\!<\!H_{\bf c}^\ast\!\ll\!H_{\bf a}^\ast$; iii) the presence of a robust zigzag phase above $H^\ast$; and iv) the fulfillment of the Bragg peak intensity sum rule. It is noteworthy that the disappearance of the modulated order for ${\bf H}\parallel{\bf c}$ proceeds via a `metamagnetic' first-order transition which does not restore all broken symmetries. This implies the existence of a second finite-$T$ phase transition at higher magnetic fields. We also demonstrate that quantum fluctuations give rise to a significant reduction of the local moments for all directions of the field. The results for the total magnetization for ${\bf H}\parallel{\bf b}$ are consistent with available data and confirm a previous assertion that the system is very close to the highly-frustrated $K$-$Γ$ line in parameter space. Our predictions for the magnetic response for fields along ${\bf a}$ and ${\bf c}$ await experimental verification.

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Collective spin dynamics of Z2 vortex crystals in triangular Kitaev-Heisenberg antiferromagnets

We show that the mesoscopic incommensurate $\mathbb{Z}_2$ vortex crystals proposed for layered triangular anisotropic magnets can be most saliently identified by two distinctive signatures in dynamical spin response experiments: The presence of pseudo-Goldstone `phonon' modes at low frequencies $ω$, associated with the collective vibrations of the vortex cores, and a characteristic multi-scattered intensity profile at higher $ω$, arising from a large number of Bragg reflections and magnon bandgaps. These are direct fingerprints of the large vortex sizes and magnetic unit cells and the solitonic spin profile around the vortex cores.

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Observing spin fractionalization in the Kitaev spin liquid via temperature evolution of indirect resonant inelastic x-ray scattering

Motivated by the ongoing effort to search for high-resolution signatures of quantum spin liquids, we investigate the temperature dependence of the indirect resonant inelastic x-ray scattering (RIXS) response for the Kitaev honeycomb model. We find that, as a result of spin fractionalization, the RIXS response changes qualitatively at two well-separated temperature scales, $T_L$ and $T_H$, which correspond to the characteristic energies of the two kinds of fractionalized excitations, $\mathbb{Z}_2$ gauge fluxes and Majorana fermions, respectively. While thermally excited $\mathbb{Z}_2$ gauge fluxes at temperature $T_L$ lead to a general broadening and softening of the response, the thermal proliferation of Majorana fermions at temperature $T_H \sim 10 \, T_L$ results in a significant shift of the spectral weight, both in terms of energy and momentum. Due to its exclusively indirect nature, the RIXS process we consider gives rise to a universal magnetic response and, from an experimental perspective, it directly corresponds to the $K$-edge of Ru$^{3+}$ in the Kitaev candidate material $α$-RuCl$_3$.

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Bond disordered spin liquid and the honeycomb iridate H$_3$LiIr$_2$O$_6$ $-$ abundant low energy density of states from random Majorana hopping

The 5d-electron honeycomb compound H$_3$LiIr$_2$O$_3$ [K. Kitagawa $et$ $al.$, Nature 554, 341-345 (2018)] exhibits an apparent quantum spin liquid (QSL) state. In this intercalated spin-orbital compound, a remarkable pile up of low-energy states was experimentally observed in specific heat and nuclear magnetic (NMR) spin relaxation. We show that a bond disordered Kitaev model can naturally account for this phenomenon, suggesting that disorder plays an essential role in its theoretical description. In the exactly soluble Kitaev model, we obtain, via spin fractionalization, a random bipartite hopping problem of Majorana fermions in a random flux background. This has a divergent low-energy density of states (DOS) of the required power-law form $N(E)\propto E^{-ν}$ with a drifting exponent which takes on the value $ν\approx 1/2$ for relatively strong bond disorder. Breaking time reversal symmetry (TRS) removes the divergence of the DOS, as does applying a magnetic field in experiment. We discuss the implication of our scenario for future experiments and its broader implications.

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Magnetic structure and excitation spectrum of the hyperhoneycomb Kitaev magnet $β$-Li$_2$IrO$_3$

We present a theoretical study of the static and dynamical properties of the Kitaev magnet $β$-Li$_2$IrO$_3$ based on the minimal $J$-$K$-$Γ$ model. We argue that the incommensurate magnetic order of $β$-Li$_2$IrO$_3$ can be qualitatively understood in terms of a long-wavelength twisting of a nearby commensurate, period-3 state, that shares the same symmetry, propagation vector, counter-rotation of the two spin sublattices, and non-coplanarity. This period-3 state shows very different structure when either the Kitaev interaction $K$ or the off-diagonal exchange anisotropy $Γ$ is dominant, featuring in particular ferromagnetic or antiferromagnetic spin dimers, respectively. We compute the magnon excitation spectra and the dynamical spin structure factor for both structures. The results for the momentum and energy dependence of the neutron-scattering intensity provide distinctive qualitative and quantitative fingerprints of the $K$-dominant or $Γ$-dominant states and thus gives additional information on the relative strength of these interactions in $β$-Li$_2$IrO$_3$.

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Magnetic field-induced evolution of intertwined orders in the Kitaev magnet $β$-Li$_2$IrO$_3$

Recent scattering experiments in the 3D Kitaev magnet $β$-Li$_2$IrO$_3$ have shown that a relatively weak magnetic field along the crystallographic ${\bf b}$-axis drives the system from its incommensurate counter-rotating order to a correlated paramagnet, with a significant uniform `zigzag' component superimposing the magnetization along the field. Here it is shown that the zigzag order is not emerging from its linear coupling to the field (via a staggered, off-diagonal element of the ${\bf g}$-tensor), but from its intertwining with the incommensurate order and the longitudinal magnetization. The emerging picture explains all qualitative experimental findings at zero and finite fields, including the rapid decline of the incommensurate order with field and the so-called intensity sum rule. The latter are shown to be independent signatures of the smallness of the Heisenberg exchange $J$, compared to the Kitaev coupling $K$ and the off-diagonal anisotropy $Γ$. Remarkably, in the regime of interest, the field $H^\ast$ at which the incommensurate component vanishes, depends essentially only on $J$, which allows to extract an estimate of $J\!\simeq\!4K$ from reported measurements of $H^\ast$. We also comment on recent experiments in pressurized $β$-Li$_2$IrO$_3$ and conclude that $J$ decreases with pressure.

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Majorana representations of spin and an alternative solution of the Kitaev honeycomb model

Based on the Dirac spinor representation of the SO(4) group, we discuss the relationship between three types of representation of spin in terms of Majorana fermions, namely the Kitaev representation, the SO(3) representation and the SO(4) chiral representation. Comparing the three types, we show that the Hilbert space of the SO(3) representation is different from the other two by requiring pairing of sites, but it has the advantage over the other two in that no unphysical states are involved. As an example of its application, we present a new alternative solution of the Kitaev honeycomb model. Our new solution involves no unphysical states which enables a systematic calculation of physical observables. Finally, we discuss an extension of the model to a more general exactly soluble $Z_{2}$ gauge theory interacting with complex fermions.

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Quantum spin liquid in the semiclassical regime

Quantum spin liquids have been at the forefront of correlated electron research ever since their original proposal in 1973, and the realization that they belong to the broader class of intrinsic topological orders, along with the fractional quantum Hall states. According to received wisdom, quantum spin liquids can arise in frustrated magnets with low spin $S$, where strong quantum fluctuations act to destabilize conventional, magnetically ordered states. Here we present a magnet that has a $Z_2$ quantum spin liquid ground state already in the semiclassical, large-$S$ limit. The state has both topological and symmetry related ground state degeneracy, and two types of gaps, a `magnetic flux' gap that scales linearly with $S$ and an `electric charge' gap that drops exponentially in $S$. The magnet is described by the spin-$S$ version of the spin-1/2 Kitaev honeycomb model, which has been the subject of intense studies in correlated electron systems with strong spin-orbit coupling, and in optical lattice realizations with ultracold atoms. The results apply to both integer and half-integer spins.

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Probing spinon nodal structures in three-dimensional Kitaev spin liquids

We propose that resonant inelastic X-ray scattering (RIXS) is an effective probe of the fractionalized excitations in three-dimensional (3D) Kitaev spin liquids. While the non-spin-conserving RIXS responses are dominated by the gauge-flux excitations and reproduce the inelastic-neutron-scattering response, the spin-conserving (SC) RIXS response picks up the Majorana-fermion excitations and detects whether they are gapless at Weyl points, nodal lines, or Fermi surfaces. As a signature of symmetry fractionalization, the SC RIXS response is suppressed around the $Γ$ point. On a technical level, we calculate the exact SC RIXS responses of the Kitaev models on the hyperhoneycomb, stripyhoneycomb, hyperhexagon, and hyperoctagon lattices, arguing that our main results also apply to generic 3D Kitaev spin liquids beyond these exactly solvable models.

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Fingerprints of quantum spin ice in Raman scattering

We develop a theory of the dynamical response of a minimal model of quantum spin ice (QSI) by means of inelastic light scattering. In particular, we are interested in the Raman response of the fractionalized U(1) spin liquid realized in the XXZ QSI. We show that the low-energy Raman intensity is dominated by spinon and gauge fluctuations. We find that the Raman response in the QSI state of that model appears only in the $T_{2g}$ polarization channel. We show that the Raman intensity profile displays a broad continuum from the spinons and coupled spinon and gauge fluctuations, and a low-energy peak arising entirely from gauge fluctuations. Both features originate from the exotic interaction between photon and the fractionalized excitations of QSI. Our theoretical results suggest that inelastic Raman scattering can in principle serve as a promising experimental probe of the nature of a U(1) spin liquid in QSI.

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Selection of direction of the ordered moments in Na$_2$IrO$_3$ and $α-$RuCl$_3$

The magnetic orders in Na$_2$IrO$_3$ and $α-$RuCl$_3$, honeycomb systems with strong spin-orbit coupling and correlations, have been recently described by models with the dominant Kitaev interactions. In this work we discuss how the orientation of magnetic order parameter is selected in this class of models. We show that while the order-by-disorder mechanism in the models with solely Kitaev anisotropies always select cubic axes as easy axes for magnetic ordering, the additional effect of other small bond-dependent anisotropies, such as, e.g., $Γ$-terms, lead to a deviation of the order parameter from the cubic directions. We show that both the zigzag ground state and the face-diagonal orientation of magnetic moments in Na$_2$IrO$_3$ can be obtained within the $J_1-K_1-J_2-K_2-J_3$ model in the presence of perturbatively small $Γ$-terms. We also show that the zigzag phase found in the nearest neighbor Kitaev-Heisenberg model, relevant for $α-$RuCl$_3$, has some stability against the $Γ$-term.

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Kitaev-Heisenberg model in a magnetic field: order-by-disorder and commensurate-incommensurate transitions

We present a theoretical study of field-induced magnetic phases in the honeycomb Kitaev-Heisenberg model, which is believed to describe the essential physics of Mott insulators with strong spin-orbit coupling such as $A_2$IrO$_3$ and $α$-RuCl$_3$. We obtain a finite temperature phase diagram based on extensive Monte Carlo simulations and analytical calculations. We show that, while Zeeman coupling favors a symmetric non-coplanar magnetic order, thermal fluctuations enhances the stability of a collinear zigzag phase that breaks the rotational symmetry of the lattice. Our large-scale simulations also uncover intriguing commensurate-incommensurate transitions and multiple-$\mathbf Q$ incommensurate phases at high field. Experimental implications are also discussed.

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Resonant inelastic X-ray scattering response of the Kitaev honeycomb model

We calculate the resonant inelastic X-ray scattering (RIXS) response of the Kitaev honeycomb model, an exactly solvable quantum-spin-liquid model with fractionalized Majorana and flux excitations. We find that the fundamental RIXS channels, the spin-conserving (SC) and the non-spin-conserving (NSC) ones, do not interfere and give completely different responses. SC-RIXS picks up exclusively the Majorana sector with a pronounced momentum dispersion, whereas NSC-RIXS also creates immobile fluxes, thereby rendering the response only weakly momentum dependent, as in the spin structure factor measured by inelastic neutron scattering. RIXS can therefore pick up the fractionalized excitations of the Kitaev spin liquid separately, making it a sensitive probe to detect spin-liquid character in potential material incarnations of the Kitaev honeycomb model.

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Resonant Raman scattering theory for Kitaev models and their Majorana fermion boundary modes

We study the inelastic light scattering response in two- (2D) and three-dimensional (3D) Kitaev spin-liquid models with \ms band structures in the symmetry classes BDI and D leading to protected gapless surface modes. We present a detailed calculation of the resonant Raman/Brillouin scattering vertex relevant to iridate and ruthenate compounds whose low-energy physics is believed to be proximate to these spin-liquid phases. In the symmetry class BDI, we find that while the resonant scattering on thin films can detect the gapless boundary modes of spin liquids, the non-resonant processes do not couple to them. For the symmetry class D, however, we find that the coupling between both types of light-scattering processes and the low-energy surface states is strongly suppressed. Additionally, we describe the effect of weak time-reversal symmetry breaking perturbations on the bulk Raman response of these systems.

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Lifting mean-field degeneracies in anisotropic classical spin systems

In this work, we propose a method for calculating the free energy of anisotropic classical spin systems. We use a Hubbard-Stratonovich transformation to express the partition function of a generic bilinear super-exchange Hamiltonian in terms of a functional integral over classical time-independent fields. As an example, we consider an anisotropic spin-exchange Hamiltonian on the cubic lattice as is found for compounds with strongly correlated electrons in multiorbital bands and subject to strong spin-orbit interaction. We calculate the contribution of Gaussian spin fluctuations to the free energy. While the mean-field solution of ordered states for such systems usually has full rotational symmetry, we show here that the fluctuations lead to a pinning of the spontaneous magnetization along some preferred direction of the lattice.

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Raman scattering in correlated thin films as a probe of chargeless surface states

Several powerful techniques exist to detect topologically protected surface states of weakly-interacting electronic systems. In contrast, surface modes of strongly interacting systems which do not carry electric charge are much harder to detect. We propose resonant light scattering as a means of probing the chargeless surface modes of interacting quantum spin systems, and illustrate its efficacy by a concrete calculation for the 3D hyperhoneycomb Kitaev quantum spin liquid phase. We show that resonant scattering is required to efficiently couple to this model's sublattice polarized surface modes, comprised of emergent Majorana fermions that result from spin fractionalization. We demonstrate that the low-energy response is dominated by the surface contribution for thin films, allowing identification and characterization of emergent topological band structures.

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