arXiv subjects

Nathan X. Roth

Publications and source records attributed to Nathan X. Roth.

At least 19 recordsLinked to original sources

arXiv2026

JWST Spatial-Spectral Mapping of Green Comet C/2022 E3 (ZTF)

We report a survey of molecular emission from cometary volatiles using the James Webb Space Telescope (JWST) toward Oort cloud comet C/2022 E3 (ZTF) carried out on UT 2023 February 28 and March 1 at a heliocentric distance (rH) of 1.33 au. These measurements of H2O, HCN, CH3OH, C2H6, CH4, CO, CO2, 13CO2, and OCS sampled post-perihelion molecular chemistry in C/2022 E3. A suite of near to mid-infrared OH (prompt emission) transitions were also detected. This work presents nucleus-centered spectra for all detected species, spatial-spectral maps of column density and rotational temperature as a function of distance from the nucleus for all except C2H6, HCN, and OH, and maps of co-measured continuum. The spatial distributions of both quantities were anisotropic for all mapped molecules; however, H2O showed distributions distinct from the remaining species. Coma-averaged values of the ortho-to-para ratio (OPR) for H2O and the 12CO2/13CO2 ratio derived from these maps were consistent with the statistical equilibrium value of 3 and the terrestrial value of 89, respectively. The modeled mass fraction of the sub-micron dust grains is dominated by amorphous carbon (56%) followed by amorphous Mg:Fe pyroxene (28%), crystalline olivine (10%), and amorphous Mg:Fe olivine (5%) with a crystalline mass fraction of 0.2385(0.0008). We compare the volatile and dust composition of C/2022 E3 (ZTF) against comets measured to date, including those surveyed by JWST.

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arXiv2026

A JWST Study of Stardust. I. Infrared Spectroscopy of Comet 81P/Wild 2 and Overall Composition

We report observations of comet 81P/Wild 2, target of the Stardust sample return mission, on UT 2023 March 20 and 24 at a heliocentric distance ($r_H$) of 1.85 au using the NIRSpec and MIRI integral field unit spectrographs on board the James Webb Space Telescope (JWST). This study is the first compositional comparison between JWST remote-sensing spectroscopy of a solar system object against terrestrial analysis of its returned samples. We securely detected molecular emission from H$_2$O, CH$_4$, C$_2$H$_6$, CH$_3$OH, CO, CO$_2$, $^{13}$CO$_2$, OCS, HCN, and CN and find molecular abundances consistent within $2\sigma$ with those reported during previous perihelion passages. The water ortho-to-para ratio was $2.76\pm0.05$, and the $^{12}$CO$_2$/$^{13}$CO$_2$ ratio was $85\pm4$. Thermal emission from the nucleus and dust was detected and modeled, providing an effective nucleus radius of $1.77\pm0.04$ km and a dust composition (relative mass fraction of the submicron grains) of $\sim36\%$ amorphous carbon, $\sim25\%$ amorphous Mg:Fe olivine, $\sim23\%$ Mg-rich crystalline olivine, and $\sim15\%$ amorphous Mg:Fe pyroxene. The crystalline mass fraction of the sub-micron grains in the coma was $0.362\pm0.003$. Comparison of the JWST-derived thermal model against the fine-grained materials in Stardust returned samples demonstrates complementarity between the missions, with each most sensitive to a different population of the coma dust grains.

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arXiv2026

Monitoring Volatile Evolution in Disrupting Comet D/2021 A1 (Leonard) with NOEMA and APEX

We report a pre-perihelion survey of volatile emissions from comet D/2021 A1 (Leonard) with the Northern Extended Millimeter Array (NOEMA; UT 2021 Nov. 5, 21, and Dec. 1) and the Atacama Pathfinder Experiment (APEX; UT 2021 Dec. 9-10), spanning heliocentric distances ($r_H$) from 1.3 to 0.80 au. We securely detected HCN and CS and place 3$\sigma$ upper limits on CH$_3$OH, H$_2$CO, and CO abundances. Line kinematics and NOEMA spatial constraints indicate that HCN was released at or near the nucleus (parent scale length $<300$ km), while CS showed higher gas expansion velocities and mixing ratios that increased with decreasing $r_H$ $-$ consistent with production from a distributed source. Across our campaign, CS mixing ratios relative to H$_2$O increased by a factor of $\sim$5, from $0.02 \pm 0.01\%$ at $r_H$ = 1.3 au to $0.10\pm0.02\%$ by $r_H$ = 0.80 au. HCN mixing ratios in our data rose modestly, from $0.04 \pm 0.02\%$ at $r_H$ = 1.3 au to $0.07 \pm 0.02\%$ by $r_H$ = 0.81 au. However, contemporaneous measurements from other facilities placed HCN consistently at a higher absolute level ($\sim\!0.08\%$) with additional variability. Once cross-facility measurements were included, the HCN abundance showed no statistically robust monotonic dependence on $r_H$. Variability in both species during the mid-December outbursts and fragmentation suggests that D/2021 A1's volatile evolution reflected not only solar insolation but also disruption processes, underscoring the value of multi-epoch, multi-instrument monitoring to capture rapid, species-dependent changes.

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arXiv2026

Observations of Exocomets

Active small bodies in extrasolar systems, the extrasolar analogues of Solar System comets, provide insights into the orbital evolution and physical processes shaping planetary systems. Since the discovery of exocomets around $\beta$ Pictoris, these small, icy bodies have shown the potential to become key probes for understanding planetary formation and migration. This review presents an overview of current observational techniques used to detect exocomets, focusing on individual systems and large-scale searches. We discuss photometric methods that identify exocomet transits through asymmetric light curves and spectroscopic techniques revealing cometary gases via time-variable absorption lines. Despite progress, significant open questions remain regarding the physical properties, occurrence rates, and similarities between exocomets and their Solar System counterparts. This review explores future opportunities in observational exocomet research, highlighting advancements required to further our understanding of these active small bodies and their role in the context of planetary system evolution.

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arXiv2026

An Enriched Methane D/H Ratio in the Interstellar Object 3I/ATLAS

Interstellar objects are interlopers from other planetary systems, and their volatile compositions provide a glimpse into planet formation around their host star. We present near-infrared spectra of the coma of interstellar object 3I/ATLAS measured with the James Webb Space Telescope. Our results demonstrate an unexpectedly high D/H = $(3.33\pm0.31)\%$ for methane and represent an exceedingly rare detection of deuterated organic molecules in an interstellar object. This D/H ratio exceeds any other value for methane measured in the solar system, and is a factor of $14\pm2$ higher than that measured in comet 67P/Churyumov-Gerasimenko by the Rosetta spacecraft, the only other comet for which CH$_3$D has been detected. Both 3I/ATLAS and 67P/Churyumov-Gerasimenko show a higher degree of methane dueteration compared to water, consistent with trends seen in other solar system bodies and the nearby interstellar medium, where deuteration in organics exceeds that of water by up to an order of magnitude. The D/H ratio in methane itself is observationally unconstrained in extrasolar sources to date, but the enriched ratio in 3I/ATLAS is similar to those measured in methanol and formaldehyde toward primitive environments. The elevated D/H ratio for methane in 3I/ATLAS is consistent with the hypothesis that its ices formed in a cold, low metallicity interstellar or protostellar environment under a high cosmic ray irradiation rate (Cordiner et al. 2026).

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arXiv2026

Coma Physics of an Interstellar Object: JWST Spatial-Spectral Mapping of 3I/ATLAS

We report a survey of molecular emission from cometary volatiles using the James Webb Space Telescope (JWST) toward interstellar object 3I/ATLAS carried out on UT 2025 December 22 and 23 at a heliocentric distance ($r_H$) of $2.37-2.41$ au. These measurements of CO, CO$_2$, H$_2$O, CH$_3$OH, and CH$_4$ sampled molecular chemistry in 3I/ATLAS as it receded from its encounter with our Sun and entered the vicinity of the H$_2$O ice line -- the region between $r_H$ = $2-3$ au where the temperature becomes too low for H$_2$O to vigorously sublime and CO and CO$_2$ begin to control the overall activity. CO was the most abundant molecule, followed by H$_2$O and CO$_2$, whose molecular abundances with respect to CO were $(40.5\pm3.1)\%$ and ($41.6\pm0.3)\%$, respectively. This work presents spatial-spectral maps of column density and rotational temperature as a function of distance from the nucleus for all detected species. The spatial distributions of both quantities were highly anisotropic for the apolar species in the coma of 3I/ATLAS, yet were more nearly symmetric for the polar molecules. These results demonstrate how volatiles were segregated in the nucleus ices of 3I/ATLAS and reveal heating and cooling mechanisms in its coma. Derived maps of the ortho-to-para ratio (OPR) for H$_2$O were flat with increasing distance from the nucleus and consistent with a coma-averaged value $\mathrm{OPR}=2.7\pm0.2$, slightly less than the expected equilibrium value of three.

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arXiv2026

Water D/H in 3I/ATLAS as a Probe of Formation Conditions in Another Planetary System

Water reservoirs in the Solar System exhibit a deuterium enrichment that links back to the physical environment at the time of stellar birth. Gas-phase and ice-grain deuterium enrichments occur through chemical processes that operate at low temperatures ($<$~30~K) pointing towards an origin in the prestellar molecular cloud or in the outer parts of the protoplanetary disk. However, not all stars are born in environments similar to our Sun, nor do their subsequent evolutionary histories follow the same path. These environmental differences can be traced by the water deuterium-to-hydrogen (D/H) ratio. Here we use ALMA observations of the interstellar comet 3I/ATLAS to constrain the water D/H ratio in extrasolar cometary material. With a water D/H value of [D/H]$_{\mathrm{H_2O}} > 6.6\times10^{-3}$, 3I/ATLAS shows a deuterium enrichment exceeding Earth's ocean value by more than a factor of $\gtrsim40$ and typical Solar System cometary values by more than a factor of $\gtrsim30$. The elevated deuterium enrichment points to water that formed under colder, less irradiated conditions and from less thermally processed material, consistent with an origin in a planetary system that formed under different physical and chemical conditions than our own.

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arXiv2026

Isotopic Evidence for a Cold and Distant Origin of the Interstellar Object 3I/ATLAS

Interstellar objects provide the only directly observable samples of icy planetesimals formed around other stars, and can therefore provide insight into the diversity of physical and chemical conditions occurring during exoplanet formation. Here we report isotopic measurements of the interstellar comet 3I/ATLAS, which reveal an elemental composition unlike any Solar System body. The water in 3I/ATLAS is enriched in deuterium, at a level of D/H = (0.95 +- 0.06)%, which is more than an order of magnitude higher than in known comets, while its range of 12C/13C ratios (141-191 for CO2 and 123-172 for CO) exceeds typical values found in the Solar System, as well as nearby interstellar clouds and protoplanetary disks. Such extreme isotopic signatures indicate formation at temperatures $\lesssim30$ K in a relatively metal-poor environment, early in the history of the Galaxy. When interpreted with respect to models for Galactic chemical evolution, the carbon isotopic composition implies that 3I/ATLAS accreted roughly 10-12 billion years ago, following an early period of intense star formation. 3I/ATLAS thus represents a preserved fragment of an ancient planetary system, and provides direct evidence for active ice chemistry and volatile-rich planetesimal formation in the young Milky Way.

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arXiv2026

Coma Volatile Composition and Thermal Physics in Comet C/2022 E3 (ZTF) Measured Near Closest Approach to Earth with NASA-IRTF

The 2023 perihelion passage of comet C/2022 E3 (ZTF) afforded an opportunity to measure the abundances and spatial distributions of coma volatiles in an Oort cloud comet at high spatial resolution near its close approach to Earth ($\Delta_\mathrm{min}\sim 0.28$ au on UT February 1). We conducted near-infrared spectroscopic observations of C/2022 E3 (ZTF) using iSHELL at the NASA Infrared Telescope Facility on UT 2023 February 9. Our measurements securely detected fluorescent emission from H$_2$O, CO, OCS, CH$_3$OH, CH$_4$, C$_2$H$_6$, C$_2$H$_2$, and HCN. For each instrumental setting we took exposures with the slit oriented parallel and also perpendicular to the projected Sun-comet vector, thereby enabling a test of the spatial distributions of these molecules. We report rotational temperatures, production rates, and abundance ratios (i.e., mixing ratios) for all sampled species. Our measurements found that molecular abundances in C/2022 E3 were depleted compared to their average values in Oort cloud comets with the exception of OCS, which was consistent. The H$_2$O production rate varied significantly and was likely tied to nucleus rotation effects. Measurements at the two slit orientations showed distinct column density and rotational temperature profiles for H$_2$O. Peak temperatures occurred off-nucleus and slower cooling was present in the anti-sunward hemisphere, consistent with the presence of icy grain sublimation in the coma.

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arXiv2026

A Multi-Wavelength Study of Comet C/2022 E3 (ZTF): Complementary ALMA and JWST Investigations of Water and Methanol in Cometary Comae

Long-period comets, which are often considered to be representative of material in the protoplanetary disk that formed the Solar System, are ideal to investigate the question of chemical inheritance in astronomy. Determining the chemistry of comets, both individually and as a population, has become of great importance in comparative studies against sources representative of evolutionary precursors to planetary systems. Contemporaneous observations of long-period comet C/2022 E3 (ZTF) were obtained with the JWST and the Atacama Large Millimeter/submillimeter Array (ALMA) in early 2023 March. This work focuses on \ce{CH3OH} measurements from both ALMA and JWST as well as \ce{H2O} measurements from JWST. Radiative transfer modeling of \ce{CH3OH} and \ce{H2O} was performed to investigate spatial variations in rotational temperature, column density, and production rates, as well as a comparison of derived values between the two telescopes. Most of the spatial distributions of the modeled values are centrally peaked, and the modeled values from JWST are all within the error bars of the average values from ALMA. C/2022 E3 (ZTF) also displays an enhancement in modeled rotational temperature in the anti-Sunward direction that is shown to be statistically significant. Based on non-LTE radiative transfer modeling, the declining \ce{H2O} rotational temperatures as a function of nucleocentric distance observed by JWST can be explained primarily as a result of rotational line cooling. The values derived in this work are in general agreement with single-dish millimeter-wave observations.

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arXiv2025

CH$_3$OH and HCN in Interstellar Comet 3I/ATLAS Mapped with the ALMA Atacama Compact Array: Distinct Outgassing Behaviors and a Remarkably High CH$_3$OH/HCN Production Rate Ratio

We report the detection of methanol (CH$_3$OH) toward interstellar comet 3I/ATLAS using the Atacama Compact Array of the Atacama Large Millimeter/Submillimeter Array (ALMA) on UT 2025 August 28, September 18 and 22, and October 1, and of hydrogen cyanide (HCN) on September 12 and 15. These observations spanned pre-perihelion heliocentric distances ($r_H$) of 2.6 -- 1.7 au. The molecules showed outgassing patterns distinct from one another, with HCN production being depleted in the sunward hemisphere of the coma, whereas CH$_3$OH was enhanced in that direction. Statistical analysis of molecular scale lengths in 3I/ATLAS indicated that CH$_3$OH included production from coma sources at $L_p>258$ km at 99% confidence. However low signal-to-noise on long baselines, which sample emission on small spatial scales closest to the nucleus, prevented definitively ruling out CH$_3$OH as purely a parent species. In contrast, HCN production was indistinguishable from direct nucleus sublimation. The CH$_3$OH production rate increased sharply from August through October, including an uptick near the inner edge of the H$_2$O sublimation zone at $r_H$ = 2 au. Compared to comets measured to date at radio wavelengths, the derived CH$_3$OH/HCN ratios in 3I/ATLAS of $124^{+30}_{-34}$ and $79^{+11}_{-14}$ on September 12 and 15, respectively, are among the most enriched values measured in any comet, surpassed only by anomalous solar system comet C/2016 R2 (PanSTARRS).

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arXiv2025

The Evolution in Coma Molecular Composition of Comet C/2017 K2 (PanSTARRS) Across the H$_2$O Sublimation Zone: ALMA Imaging of an H$_2$O-Dominated Coma

We report a survey of molecular emission from cometary volatiles using the Atacama Large Millimeter/Submillimeter Array (ALMA) toward comet C/2017 K2 (PanSTARRS) carried out on UT 2022 September 21, 22, and 23 at a heliocentric distance ($r_H$) of 2.1 au. These measurements of HCN, CS, CO, CH$_3$OH, and H$_2$CO (along with continuum emission from dust) sampled molecular chemistry in C/2017 K2 at the inner edge of the H$_2$O sublimation zone, the region from $r_H$ = 2-3 au where H$_2$O begins vigorously subliming and increasingly dominating comet activity, discerning parent from daughter or extended source species. This work presents spectrally integrated flux maps, production rates, and parent scale lengths for each molecule. CH$_3$OH, CO, and HCN were produced within $\sim$250 km of the nucleus, potentially including contributions from sublimation of icy grains. CS was consistent with production from CS$_2$ photolysis, and H$_2$CO required production from extended sources in the coma. An ortho-to-para ratio OPR=$2.9\pm0.4$ for H$_2$CO was derived from simultaneously measured transitions of each spin species. The continuum was extended and spatially resolved, consistent with thermal emission from dust in the coma. Analysis of the continuum visibilities provided an upper limit on the nucleus diameter $d<6.6$ km and coma dust masses of $1.2-2.4\times10^{11}$ kg.

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arXiv2025

JCMT detection of HCN emission from 3I/ATLAS at 2.1 AU

We report the detection of HCN ($J=3-2$) rotational emission from comet 3I/ATLAS at a heliocentric distance of 2.13 AU with the James Clerk Maxwell Telescope (JCMT). Observations were conducted from 07 August 2025 and 14 September 2025 (UT) using the $^{\prime}\overline U^{\prime}\overline u$ heterodyne receiver and ACSIS spectroscopic backend. The HCN line was detected at $>6\sigma$ on 14 Sep 2025 (UT) and a production rate of $Q({\rm HCN})=(4.0\pm1.7)\times10^{25}\ {\rm s}^{-1}$ was derived by non-LTE radiative transfer modelling. Preliminary estimates of the HCN/H$_2$O and CN/HCN abundance ratios suggest values similar to Solar System comets.

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arXiv2025

Volatiles

Small bodies are the remnant building blocks from the time when the planets formed and migrated to their current positions. Their volatile composition and relative abundances serve as time capsules for the formation conditions in the protosolar nebula. By constraining the volatile composition of Centaurs, we can fill in important gaps in understanding the history of our solar system. We review here the state of knowledge for volatiles in small bodies, processes that influence volatile composition and activity in small bodies, and future capabilities that can be leveraged to advance our understanding of volatiles in Centaurs.

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arXiv2025

First Detection of Molecular Activity in the Largest Known Oort Cloud Comet: ALMA Imaging of C/2014 UN271 (Bernardinelli-Bernstein) at 16.6 au from the Sun

We report observations of comet C/2014 UN271 (Bernardinelli-Bernstein) carried out on UT 2024 March 8 and 17 at a heliocentric distance ($r_{\mathrm{H}}$) of 16.6 au using the Atacama Large Millimeter/Submillimeter Array (ALMA). The CO ($J$=2-1) line at 230 GHz was detected along with continuum emission from its dust coma and large ($\sim$140 km) nucleus, revealing the nature of the activity drivers and outgassing kinematics of the largest Oort cloud comet discovered to date. This work presents spectrally integrated flux maps, autocorrelation spectra, production rates, and parent scale lengths for CO and a stringent upper limit for the H$_2$CO production rate. CO outgassing displayed multiple active jets which evolved from one epoch to the next. The continuum emission was compact and spatially unresolved, and is consistent with thermal emission from the large nucleus and a tentative detection of a dust coma. Complementary optical observations provided activity context for the ALMA epochs, indicating that UN271 underwent an outburst in late February before returning to a quiescent brightness in mid--late March. These results represent the first secure detection of molecular activity reported in the literature for C/2014 UN271 and highlight the dynamic nature of this distantly active small world.

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arXiv2025

A JWST Study of the Remarkable Oort Cloud Comet C/2017 K2 (PanSTARRS)

Comets, during their journeys into the inner solar system, deliver volatile gases, organics, and particulates into their comae that provide crucial information for assessing the physico-chemical conditions in the outer disk from which they formed. Here we present observational and modeling results of a JWST NIRSpec and MIRI MRS integral-field-unit (IFU) spatial-spectral study of the inner coma of the Oort Cloud comet C/2017 K2 (PanSTARRS) at a heliocentric distance of 2.35 au. We find the comet is hyperactive (water ice active fraction greater than or equal to 86%), with a nucleus radius of $<$4.2 km, exhibiting strong emission from H$_{2}$O, $^{12}$CO, $^{13}$CO, and CO$_{2}$ as well as CN, H$_2$CO, CH$_3$OH, CH$_4$, C$_2$H$_6$, HCN, NH$_2$, and OH prompt emission. The water ortho-to-para ratio is greater than or equal to 2.75. The modeled dust composition (relative mass fraction of the sub-micron grains) in the coma is dominated by amorphous carbon ($\simeq 25$%), amorphous Mg:Fe olivine ($\simeq 19$%), amorphous Mg:Fe pyroxene ($\simeq 16$%), and Mg-rich crystalline olivine ($\simeq 39$%) and the crystalline mass fraction of the sub-micron grains in the coma is, $f_{cryst} \simeq 0.384 \pm 0.065$. Analysis of residuals in 3 to 8 $\mu$m region of the spectral energy distribution strongly suggests the presence of polycyclic aromatic hydrocarbon (PAHs) species in the coma.

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arXiv2024

Single Aperture Large Telescope for Universe Studies (SALTUS): Science Overview

The SALTUS Probe mission will provide a powerful far-infrared (far-IR) pointed space observatory to explore our cosmic origins and the possibility of life elsewhere. The observatory employs an innovative deployable 14-m aperture, with a sunshield that will radiatively cool the off-axis primary to <45K. This cooled primary reflector works in tandem with cryogenic coherent and incoherent instruments that span the 34 to 660 micron far-IR range at both high and moderate spectral resolutions.

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arXiv2023

ALMA Observations of the DART Impact: Characterizing the Ejecta at Sub-Millimeter Wavelengths

We report observations of the Didymos-Dimorphos binary asteroid system using the Atacama Large Millimeter/Submillimeter Array (ALMA) and the Atacama Compact Array (ACA) in support of the Double Asteroid Redirection Test (DART) mission. Our observations on UT 2022 September 15 provided a pre-impact baseline and the first measure of Didymos-Dimorphos' spectral emissivity at $λ=0.87$ mm, which was consistent with the handful of siliceous and carbonaceous asteroids measured at millimeter wavelengths. Our post-impact observations were conducted using four consecutive executions each of ALMA and the ACA spanning from T$+$3.52 to T$+$8.60 hours post-impact, sampling thermal emission from the asteroids and the impact ejecta. We scaled our pre-impact baseline measurement and subtracted it from the post-impact observations to isolate the flux density of mm-sized grains in the ejecta. Ejecta dust masses were calculated for a range of materials that may be representative of Dimorphos' S-type asteroid material. The average ejecta mass over our observations is consistent with 1.3--6.4$\times10^7$ kg, with the lower and higher values calculated for amorphous silicates and for crystalline silicates, respectively. Owing to the likely crystalline nature of S-type asteroid material, the higher value is favored. These ejecta masses represent 0.3--1.5\% of Dimorphos' total mass and are in agreement with lower limits on the ejecta mass based on measurements at optical wavelengths. Our results provide the most sensitive measure of mm-sized material in the ejecta and demonstrate the power of ALMA for providing supporting observations to spaceflight missions.

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