arXiv subjects

Nathaniel Hoffman

Publications and source records attributed to Nathaniel Hoffman.

2 recordsLinked to original sources

arXiv2022

Fano Resonant Optical coatings platform for Full Gamut and High Purity Structural Colors

Structural coloring is a photostable and environmentally friendly coloring approach that harnesses optical interference and nanophotonic resonances to obtain colors with a range of applications including steganography, d\'ecor, data storage, and anticounterfeiting measures. We show that optical coatings exhibiting the photonic Fano Resonance is an ideal platform for structural coloring -- it provides full color access, high color purity, high brightness, controlled iridescence, and scalable manufacturability. We show that an additional oxide film deposited on Fano resonant optical coatings (FROCs) increases the color purity (up to 97%) and color gamut coverage range (> 99% coverage of the sRGB and Adobe color spaces). For coloring applications that do not require high spatial resolution, FROCs provide a significant advantage over existing structural coloring schemes.

physics.optics↗

arXiv2020

Cluster variation method analysis of correlations and entropy in BCC solid solutions

Solid solutions occur when multiple chemical species share sites of a common crystal lattice. Although the single site occupation is random, chemical interaction preferences bias the occupation probabilities of neighboring sites, and this bias reduced the entropy of mixing below its ideal value. Sufficiently strong bias leads to symmetry-breaking phase transitions. We apply the cluster variation method to explore solid solutions on body centered cubic lattices in the context of two specific compounds that exhibit opposite ordering trends. Employing density functional theory to model the energetics, we show that CuZn exhibits an order-disorder transition to the CsCl prototype structure, while AlLi instead takes the NaTl prototype structure, and we evaluate their temperature-dependent order parameters, correlations and entropies.

cond-mat.mtrl-sci↗