Searcharxiv⌕ Search

arXiv subjects

Nelly H. Y. Ng

Publications and source records attributed to Nelly H. Y. Ng.

26 records · Page 2Linked to original sources

Entanglement generation from athermality

We investigate the thermodynamic constraints on the pivotal task of entanglement generation using out-of-equilibrium states through a model-independent framework with minimal assumptions. We establish a necessary and sufficient condition for a thermal process to generate bipartite qubit entanglement, starting from an initially separable state. Consequently, we identify the set of system states that cannot be entangled, when no external work is invested. In the regime of infinite temperature, we analytically construct this set; while for finite temperature, we provide a simple criterion to verify whether any given initial state is or is not entanglable. Furthermore, we provide an explicit construction of the future thermal cone of entanglement - the set of entangled states that a given separable state can thermodynamically evolve to. We offer a detailed discussion on the properties of this cone, focusing on the interplay between entanglement and its volumetric properties. We conclude with several key remarks on the generation of entanglement beyond two-qubit systems, and discuss its dynamics in the presence of dissipation.

quant-ph↗

A hierarchy of thermal processes collapses under catalysis

Thermal operations are a generic description for allowed state transitions under thermodynamic restrictions. However, the quest for simpler methods to encompass all these processes remains unfulfilled. We resolve this challenge through the catalytic use of thermal baths, which are assumed to be easily accessible. We select two sets of simplified operations: elementary thermal operations and Markovian thermal operations. They are known for their experimental feasibility, but fail to capture the full extent of thermal operations due to their innate Markovianity. We nevertheless demonstrate that this limitation can be overcome when the operations are enhanced by ambient-temperature Gibbs state catalysts. In essence, our result indicates that free states within thermal operations can act as catalysts that provide the necessary non-Markovianity for simpler operations. Furthermore, we prove that when any catalyst can be employed, different thermal processes (thermal operations, elementary thermal operations, and Markovian thermal operations) converge. Notably, our results extend to scenarios involving initial states with coherence in the energy eigenbasis, a notoriously difficult process to characterise.

quant-ph↗

Uniqueness of quantum state over time function

A fundamental A fundamental asymmetry exists within the conventional framework of quantum theory between space and time, in terms of representing causal relations via quantum channels and acausal relations via multipartite quantum states. Such a distinction does not exist in classical probability theory. In effort to introduce this symmetry to quantum theory, a new framework has recently been proposed, such that dynamical description of a quantum system can be encapsulated by a static quantum state over time. In particular, Fullwood and Parzygnat recently proposed the state over time function based on the Jordan product as a promising candidate for such a quantum state over time function, by showing that it satisfies all the axioms required in the no-go result by Horsman et al. However, it was unclear if the axioms induce a unique state over time function. In this work, we demonstrate that the previously proposed axioms cannot yield a unique state over time function. In response, we therefore propose an alternative set of axioms that is operationally motivated, and better suited to describe quantum states over any spacetime regions beyond two points. By doing so, we establish the Fullwood-Parzygnat state over time function as the essentially unique function satisfying all these operational axioms.

quant-ph↗

Catalysis in Action via Elementary Thermal Operations

We investigate catalysis in the framework of elementary thermal operations, leveraging the distinct features of such operations to illuminate catalytic dynamics. As groundwork, we establish new technical tools that enhance the computability of state transition rules for elementary thermal operations. Specifically, we provide a complete characterisation of state transitions for a qutrit system and special classes of initial states of arbitrary dimension. By employing these tools in conjunction with numerical methods, we find that by adopting a small catalyst, including just a qubit catalyst, one can significantly enlarge the set of state transitions for a qutrit system. This advancement notably narrows the gap of reachable states between elementary thermal operations and generic thermal operations. Furthermore, we decompose catalytic transitions into time-resolved evolution, which critically enables the tracking of nonequilibrium free energy exchanges between the system and bath. Our results provide evidence for the existence of simple and practicable catalytic advantage in thermodynamics while offering insight into analysing the mechanism of catalytic processes.

quant-ph↗

Catalysis always degrades external quantum correlations

Catalysts used in quantum resource theories need not be in isolation and therefore are possibly correlated with external systems, which the agent does not have access to. Do such correlations help or hinder catalysis, and does the classicality or quantumness of such correlations matter? To answer this question, we first focus on the existence of a non-invasively measurable observable that yields the same outcomes for repeated measurements, since this signifies macro-realism, a key property distinguishing classical systems from quantum systems. We show that a system quantumly correlated with an external system so that the joint state is necessarily perturbed by any repeatable quantum measurement, also has the same property against general quantum channels. Our full characterization of such systems called totally quantum systems, solves the open problem of characterizing tomographically sensitive systems raised in [Lie and Jeong, Phys. Rev. Lett. 130, 020802 (2023)]. An immediate consequence is that a totally quantum system cannot catalyze any quantum process, even when a measure of correlation with its environment is arbitrarily low. It generalizes to a stronger result, that the mutual information of totally quantum systems cannot be used as a catalyst either. These results culminate in the conclusion that, out of the correlations that a generic quantum catalyst has with its environment, only classical correlations allow for catalysis, and therefore using a correlated catalyst is equivalent to using an ensemble of uncorrelated catalysts.

quant-ph↗

The variance of relative surprisal as single-shot quantifier

The variance of (relative) surprisal, also known as varentropy, so far mostly plays a role in information theory as quantifying the leading order corrections to asymptotic i.i.d.~limits. Here, we comprehensively study the use of it to derive single-shot results in (quantum) information theory. We show that it gives genuine sufficient and necessary conditions for approximate state-transitions between pairs of quantum states in the single-shot setting, without the need for further optimization. We also clarify its relation to smoothed min- and max-entropies, and construct a monotone for resource theories using only the standard (relative) entropy and variance of (relative) surprisal. This immediately gives rise to enhanced lower bounds for entropy production in random processes. We establish certain properties of the variance of relative surprisal which will be useful for further investigations, such as uniform continuity and upper bounds on the violation of sub-additivity. Motivated by our results, we further derive a simple and physically appealing axiomatic single-shot characterization of (relative) entropy which we believe to be of independent interest. We illustrate our results with several applications, ranging from interconvertibility of ergodic states, over Landauer erasure to a bound on the necessary dimension of the catalyst for catalytic state transitions and Boltzmann's H-theorem.

quant-ph↗

By-passing fluctuation theorems

Fluctuation theorems impose constraints on possible work extraction probabilities in thermodynamical processes. These constraints are stronger than the usual second law, which is concerned only with average values. Here, we show that such constraints, expressed in the form of the Jarzysnki equality, can be bypassed if one allows for the use of catalysts - additional degrees of freedom that may become correlated with the system from which work is extracted, but whose reduced state remains unchanged so that they can be re-used. This violation can be achieved both for small systems but also for macroscopic many-body systems and leads to positive work extraction per particle with finite probability from macroscopic states in equilibrium. In addition to studying such violations for a single system, we also discuss the scenario in which many parties use the same catalyst to induce local transitions. We show that there exist catalytic processes that lead to highly correlated work distributions, expected to have implications for stochastic and quantum thermodynamics.

quant-ph↗