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Ngoc-Tram D. Hoang

Publications and source records attributed to Ngoc-Tram D. Hoang.

5 recordsLinked to original sources

A Direct Algebraic Approach to Normal Ordering of Exponential Bosonic Operators with Applications to Two-Dimensional Excitonic Form Factors

We develop a systematic algebraic approach, based on the Wei--Norman factorization method, to the normal ordering of exponential bosonic operators and apply it to derive analytical excitonic form factors in two-dimensional semiconducting materials. By introducing an auxiliary parameter, the normal-ordering problem is reduced to a system of ordinary differential equations determined by the commutation relations of the underlying closed Lie algebra. The approach is first illustrated for exponential operators associated with the Heisenberg--Weyl and $su(1,1)$ algebras, and is then extended to two-mode bosonic operators involving $su(2)$ and a six-generator closed algebra that contains two coupled $su(1,1)$ subalgebras. For the excitonic application, the Levi--Civita transformation maps the two-dimensional exciton problem onto an oscillator representation, providing a natural formulation in terms of bosonic creation and annihilation operators. Combined with the Laplace and Fourier representations of the Rytova--Keldysh potential, this formulation reduces the interaction matrix elements to the evaluation of exponential bosonic form factors. The isotropic problem is governed by a three-generator $su(1,1)$ algebra, whereas the anisotropic case requires the full six-generator algebra together with an additional $su(2)$ factorization. Explicit analytical expressions for both form factors, $\langle e^{-rt}\rangle$ and $\langle e^{i\mathbf q\cdot\mathbf r}\rangle$, are obtained, providing useful building blocks for matrix-element calculations in two-dimensional excitonic systems and potentially in other quantum problems involving exponential bosonic operators.

cond-mat.mtrl-sci↗

Analytical Retrieval of Material Parameters in Monolayer Transition-Metal Dichalcogenides Based on a Solvable Exciton Model

We develop an analytical procedure to retrieve fundamental material parameters of monolayer transition-metal dichalcogenides from optical and magneto-optical exciton spectra, based on the solvable modified Kratzer model. The proposed retrieval procedure naturally consists of two complementary stages. In the first stage, explicit inversion formulas determine the quasiparticle bandgap, effective screening parameter, and energy scaling factor directly from the experimentally measured energies of the three lowest excitonic states, from which the screening length is subsequently obtained. In the second stage, an analytical expression for the magnetic-field dependence of the exciton energies independently yields the reduced exciton mass, from which the surrounding dielectric constant is then calculated. Once the complete set of material parameters has been retrieved, the framework analytically predicts the diamagnetic coefficients, exciton radii, and complete magnetoexciton spectra without introducing additional fitting parameters or matrix diagonalization. The method is applied to a broad range of experimental samples for WSe$_2$, WS$_2$, MoS$_2$, MoSe$_2$, and MoTe$_2$ monolayers embedded in different dielectric environments. The retrieved material parameters are in good agreement with independent experimental measurements and previous Rytova--Keldysh (RK) calculations, while the predicted excitonic properties accurately reproduce available magneto-optical observations. The proposed analytical theory provides an efficient, physically transparent alternative to conventional numerical fitting procedures and offers an effective tool for the rapid characterization of two-dimensional semiconductors via excitonic spectroscopy.

cond-mat.mtrl-sci↗

Anisotropic two-dimensional magnetoexciton with exact center-of-mass separation

Excitons in anisotropic two-dimensional (2D) materials, defined by direction-dependent effective masses, are of pronounced interest for their roles in excitonic and magneto-optical phenomena. A perpendicular magnetic field complicates the separation of center-of-mass (c.m.) and relative motions, especially when electron and hole masses are comparable. Conventional theories often employ an approximate c.m. separation using factorized wave functions, modifying magnetic Hamiltonian terms and possibly introducing inaccuracies in magnetoexciton energy predictions. This work develops an exact analytical framework for c.m. and relative motion separation in anisotropic 2D magnetoexcitons, without resorting to the stationary-c.m. approximation. Starting from the full electron-hole Hamiltonian in a homogeneous magnetic field, the formalism uses the conserved pseudomomentum to derive a relative-motion Hamiltonian, revealing new anisotropy-dependent couplings and magnetic coefficients absent in approximate models. The resulting Schrödinger equation is treated via the Feranchuk-Komarov operator method and Levi-Civita transformation, allowing non-perturbative, systematically convergent solutions. Application to monolayer black phosphorus and titanium trisulfide, both freestanding and encapsulated in hexagonal boron nitride, yields magnetoexciton energies, diamagnetic coefficients, and probability densities for the ten lowest states across considerable magnetic-field ranges. The results demonstrate the significant influence of anisotropy-dependent coupling on magnetic response in systems with strong mass anisotropy. This formalism is generalizable to other anisotropic 2D semiconductors, establishing a foundation for advanced magneto-optical studies.

cond-mat.mes-hall↗

Analytical exciton energies in monolayer transition-metal dichalcogenides

We derive an analytical expression for $s$-state exciton energies in monolayer transition-metal dichalcogenides (TMDCs): $E_{\text{ns}}=-{\text{Ry}}^*\times P_n/{(n-1/2+0.479\, r^*_0/κ)^2}$, $n=1,2,...$, where $r^*_0$ and $κ$ are the dimensionless screening length and dielectric constant of the surrounding medium; $\text{Ry}^*$ is an effective Rydberg energy scaled by the dielectric constant and exciton reduced mass; $P_n(r^*_0/κ)$ is a function of variables $n$ and $r^*_0/κ$. Its values are around 1.0 so we consider it a term that corrects the Rydberg energy. Despite the simple form, the suggested formula gives exciton energies with high precision compared to the exact numerical solutions that accurately describe recent experimental data for a large class of TMDC materials, including WSe$_2$, WS$_2$, MoSe$_2$, MoS$_2$, and MoTe$_2$. To achieve these results, we have developed a so-called regulated perturbation theory by combining the conventional perturbation method with several elements of the Feranchuk-Komarov operator method, including the Levi-Civita transformation, the algebraic calculation technique via the annihilation and creation operators, and the introduction of a free parameter to optimize the convergence rate of the perturbation series. This universal form of exciton energies could be helpful in various physical analyses, including retrieval of the material parameters such as reduced exciton mass and screening length from the available measured exciton energies.

cond-mat.mtrl-sci↗

Retrieval of material properties of monolayer transition-metal dichalcogenides from magnetoexciton energy spectra

Reduced exciton mass, polarizability, and dielectric constant of the surrounding medium are essential properties for semiconducting materials, and they have been extracted recently from the magnetoexciton energies. However, the acceptable accuracy of the suggested method requires very high magnetic intensity. Therefore, in the present paper, we propose an alternative method of extracting these material properties from recently available experimental magnetoexciton s-state energies in monolayer transition-metal dichalcogenides (TMDCs). The method is based on the high sensitivity of exciton energies to the material parameters in the Rytova-Keldysh model. It allows us to vary the considered material parameters to get the best fit of the theoretical calculation to the experimental exciton energies for the $1s$, $2s$, and $3s$ states. This procedure gives values of the exciton reduced mass and $2D$ polarizability. Then, the experimental magnetoexciton spectra compared to the theoretical calculation also determine the average dielectric constant. Concrete applications are presented only for monolayers WSe$_2$ and WS$_2$ from the recently available experimental data; however, the presented approach is universal and can be applied to other monolayer TMDCs. The mentioned fitting procedure requires a fast and effective method of solving the Schrödinger equation of an exciton in monolayer TMDCs with a magnetic field. Therefore, we also develop such a method in this paper for highly accurate magnetoexciton energies.

cond-mat.mes-hall↗