arXiv subjects

Nicola Melchioni

Publications and source records attributed to Nicola Melchioni.

6 recordsLinked to original sources

arXiv2026

Ultrafast Control of Lifetime in High Q Anisotropic Plasmon Polaritons

Losses are a major roadblock in the technological implementation of surface plasmons at optical frequencies. The recent emergence of MoOCl2, a correlated van-der-Waals material with strongly anisotropic optical properties, offers new avenues to circumvent this limit. We report the far-field observation of high-Q surface plasmon polaritons in this material, arising from the anisotropic hybridisation of surface plasmons and dielectric modes. We then explore nonlinear pumping of intraband electrons to the conduction band in these structures, leading, contrary to intuition, to an abrupt increase in the lifetime of the polariton resonance, despite the injection of hot electrons. This counterintuitive phenomenon stems from the competition between photon and plasmon excitations in a lenticular polariton resonance, yielding a largely tuneable lifetime at ultrafast speeds.

physics.optics↗

arXiv2026

Anisotropic electron gas in a hyperbolic van der Waals material

Electron gases in low dimensional materials exhibit unconventional transport and optical phenomena due to reduced phase space, enhanced interactions, and strong sensitivity to lattice symmetry. While commonly realized in quantum confined systems and engineered heterostructures, such states are rare in naturally occurring materials. Hyperbolic materials provide a compelling alternative, as extreme lattice anisotropy can host unconventional electronic states and novel electron-phonon interactions. Here, we investigate the angle resolved polarized Raman (ARPR) response of MoOCl2, the first naturally occurring hyperbolic material whose hyperbolicity originates from a highly anisotropic electron gas. We observe pronounced polarization dependent Fano line shapes, revealing coherent coupling between phonons and an anisotropic electronic continuum. We characterize the directional response of this continuum, incorporating it into effective Raman tensors that quantitatively reproduce the ARPR measurements and capture the distinct Raman fingerprint of MoOCl2. Excitation energy and thickness dependent ARPR measurements further demonstrate a tunable quasi 1D electronic continuum with weak interlayer coupling, establishing MoOCl2 as a model system for Raman studies of electron-phonon coupling in hyperbolic materials

cond-mat.mes-hall↗

arXiv2024

Tailoring coherent charge transport in graphene by deterministic defect generation

Harnessing the wave-nature of charge carriers in solid state devices, electron optics investigates and exploits coherent phenomena, in analogy with optics and photonics. Typically, this requires complex electronic devices leveraging macroscopically coherent charge transport in two-dimensional electron gases and superconductors. Here, collective coherent effects are induced in a simple counterintuitive architecture by defect engineering. Deterministically introduced lattice defects in graphene enable the phase coherent charge transport by playing the role of potential barriers, instead of scattering centres as conventionally considered. Thus, graphene preserves its quasi-ballistic quantum transport and can support phase-matched charge carrier waves. Based on this approach, multiple electronic Fabry-Pèrot cavities are formed by creating periodically alternating defective and pristine nano-stripes through low energy electron-beam irradiation. Indeed, defective stripes behave as partially reflecting mirrors and resonantly confine the charge carrier waves within the pristine areas, giving rise to Fabry-Pèrot resonant modes. These modes experimentally manifest as sheet resistance oscillations, as also confirmed by Landauer-Büttiker simulations. Moreover, these coherent phenomena survive up to 30 K for both polarities of charge carriers, contrarily to traditional monopolar electrostatically created Fabry-Pèrot interferometers. Our study positions defective graphene as an innovative platform for coherent electronic devices, with potential applications in nano and quantum technologies.

cond-mat.mes-hall↗

arXiv2024

Visible-frequency hyperbolic plasmon polaritons in a natural van der Waals crystal

Controlling light at subwavelength scales is one of the main challenges of nanophotonics. Leveraging hyperbolic polaritons supporting arbitrarily large wavevectors can lead to extreme light confinement, effectively overcoming the diffraction limit. Hyperbolicity was initially realized in artificial metamaterials, but their performances are limited by high losses in the metallic components. While recently discovered natural low-loss hyperbolic phonon polaritons initiated a revival in the interest for hyperbolic materials, they are confined to the mid-infrared frequency range, limiting their use for several applications. Some hyperbolic materials at visible frequencies have been studied, but they are either very lossy or only feature out-of-plane hyperbolicity. Here, we demonstrate the presence of low-loss, in-plane hyperbolic plasmon polaritons in the visible and near-infrared in thin films of $\mathrm{MoOCl}_2$, a natural van der Waals crystal. The polariton dispersion is predicted based on the framework of light propagation in biaxial media, and experimentally confirmed by real space nano imaging on exfoliated flakes. $\mathrm{MoOCl}_2$ constitutes a novel material platform for visible-range applications leveraging the unboundedness of hyperbolic modes, such as hyperlensing, Purcell factor enhancement and super-resolution imaging, without the drawbacks of metamaterials.

physics.optics↗

arXiv2023

Operability timescale of defect-engineered graphene

Defects in the lattice are of primal importance to tune graphene chemical, thermal and electronic properties. Electron-beam irradiation is an easy method to induce defects in graphene following pre-designed patterns, but no systematic study of the time evolution of the resulting defects is available. In this paper, the change over time of defected sites created in graphene with low-energy ($\leq 20$ keV) electron irradiation is studied both experimentally via micro-Raman spectroscopy for a period of $6\times 10^3$ hours and through molecular dynamics simulations. During the first 10 h, the structural defects are stable at the highest density value. Subsequently, the crystal partially reconstructs, eventually reaching a stable, less defected condition after more than one month. The simulations allow the rationalization of the processes at the atomic level and confirm that the irradiation induces composite clusters of defects of different nature rather than well-defined nanoholes as in the case of high-energy electrons. The presented results identify the timescale of the defects stability, thus establishing the operability timespan of engineerable defect-rich graphene devices with applications in nanoelectronics. Moreover, long-lasting chemical reactivity of the defective graphene is pointed out. This property can be exploited to functionalize graphene for sensing and energy storage applications.

cond-mat.mtrl-sci↗

arXiv2023

Optical grade bromide-based thin film electrolytes

Controlling the charge density in low-dimensional materials with an electrostatic potential is a powerful tool to explore and influence their electronic and optical properties. Conventional solid gates impose strict geometrical constraints to the devices and often absorb electromagnetic radiation in the infrared (IR) region. A powerful alternative is ionic liquid (IL) gating. This technique only needs a metallic electrode in contact with the IL and the highest achievable electric field is limited by the electrochemical interactions of the IL with the environment. Despite the excellent gating properties, a large number of ILs is hardly exploitable for optical experiments in the mid-IR region, because they typically suffer from low optical transparency and degradation in ambient conditions. Here, we report the realization of two electrolytes based on bromide ILs dissolved in polymethyl methacrylate (PMMA). We demonstrate that such electrolytes can induce state-of-the-art charge densities as high as $20\times10^{15}\ \mathrm{cm^{-2}}$. Thanks to the low water absorption of PMMA, they work both in vacuum and in ambient atmosphere after a simple vacuum curing. Furthermore, our electrolytes can be spin coated into flat thin films with optical transparency in the range from 600 cm$^{-1}$ to 4000 cm$^{-1}$. Thanks to these properties, the electrolytes are excellent candidates to fill the gap as versatile gating layers for electronic and mid-IR optoelectronic devices.

cond-mat.mes-hall↗