arXiv subjects

Nicolas Iro

Publications and source records attributed to Nicolas Iro.

At least 19 recordsLinked to original sources

arXiv2026

Phase-dependent chemistry of WASP-43 b revealed with a suite of one-, two-, and three-dimensional models

Our goal is to investigate the chemistry of the hot Jupiter WASP-43 b in detail using theoretical models, considering the constraints of the James Webb Space Telescope MIRI phase curve. With a suite of pseudo-two-dimensional and three-dimensional photochemical models, we simulate the composition of WASP-43 b in various configurations, and compare them with atmospheric retrieval models. We confirm that disequilibrium chemistry in our theoretical models reduces the methane concentration on the planet night side for wind jet speeds > 500 m/s. Varying the metallicity in the models induces large changes in the CO$_2$ and SO$_2$ concentrations, with SO$_2$ producing mid-infrared absorption features in synthetic emission spectra of the night side at atmospheric metallicities > 10x solar. Our models provide evidence for pole-to-equator circulation enhancing the CH$_4$, NH$_3$, and HCN abundances, which is nonetheless insufficient for detectable spectral features. Finally, we show that H$_2$O, CO, and CO$_2$ are robustly modeled, but species affected by photochemistry are more sensitive to model-specific assumptions and pathways. We conclude that horizontal quenching is the prime mechanism that explains the non-detection of methane in the MIRI phase-curve of WASP-43 b. This mechanism requires only moderate wind speeds and is operative at various thermal structures and atmospheric metallicities. Furthermore, coupled carbon-sulfur chemistry leads to an additional decrease in methane compared to previous models in the literature that did not contain sulfur chemistry. We do not favor a high metallicity as it would have led to observable SO$_2$ features in the MIRI spectra. Our study shows that phase-dependent photochemistry models are essential tools in the interpretation of hot-Jupiter phase curves, but benchmarking is needed to improve the accuracy of photochemical models in the future.

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arXiv2025

Horizontal and vertical exoplanet thermal structure from a JWST spectroscopic eclipse map

Highly-irradiated giant exoplanets known as "ultra-hot Jupiters" are anticipated to exhibit large variations of atmospheric temperature and chemistry as a function of longitude, latitude, and altitude. Previous observations have hinted at these variations, but the existing data have been fundamentally restricted to probing hemisphere-integrated spectra, thereby providing only coarse information on atmospheric gradients. Here we present a spectroscopic eclipse map of an extrasolar planet, resolving the atmosphere in multiple dimensions simultaneously. We analyze a secondary eclipse of the ultra-hot Jupiter WASP-18b observed with the NIRISS instrument on JWST. The mapping reveals weaker longitudinal temperature gradients than were predicted by theoretical models, indicating the importance of hydrogen dissociation and/or nightside clouds in shaping global thermal emission. Additionally, we identify two thermally distinct regions of the planet's atmosphere: a "hotspot" surrounding the substellar point and a "ring" near the dayside limbs. The hotspot region shows a strongly inverted thermal structure due to the presence of optical absorbers and a water abundance marginally lower than the hemispheric average, in accordance with theoretical predictions. The ring region shows colder temperatures and poorly constrained chemical abundances. Similar future analyses will reveal three-dimensional thermal, chemical, and dynamical properties of a broad range of exoplanet atmospheres.

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arXiv2025

Limb Asymmetries on WASP-39b: A Multi-GCM Comparison of Chemistry, Clouds, and Hazes

With JWST, observing separate spectra of the morning and evening limbs of hot Jupiters has finally become a reality. The first such observation was reported for WASP-39b, where the evening terminator was observed to have a larger transit radius by about 400 ppm and a stronger 4.3 $\mu$m CO$_2$ feature than the morning terminator. Multiple factors, including temperature differences, photo/thermochemistry, clouds and hazes, could cause such limb asymmetries. To interpret these new limb asymmetry observations, a detailed understanding of how the relevant processes affect morning and evening spectra grounded in forward models is needed. Focusing on WASP-39b, we compare simulations from five different general circulation models (GCMs), including one simulating disequilibrium thermochemistry and one with cloud radiative feedback, to the recent WASP-39b limb asymmetry observations. We also post-process the temperature structures of all simulations with a 2D photochemical model and one simulation with a cloud microphysics model. Although the temperatures predicted by the different models vary considerably, the models are remarkably consistent in their predicted morning--evening temperature differences. Several equilibrium-chemistry simulations predict strong methane features in the morning spectrum, not seen in the observations. When including disequilibrium processes, horizontal transport homogenizes methane, and these methane features disappear. However, even after including photochemistry and clouds, our models still cannot reproduce the observed ${\sim}2000$ ppm asymmetry in the CO$_2$ feature. A combination of factors, such as varying metallicity and unexplored parameters in cloud models, may explain the discrepancy, emphasizing the need for future models integrating cloud microphysics and feedback across a broader parameter space.

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arXiv2025

First JWST thermal phase curves of temperate terrestrial exoplanets reveal no thick atmosphere around TRAPPIST-1 b and c

We report JWST/MIRI 15 $\mu$m phase curves of TRAPPIST-1 b and c, revealing thermal emission consistent with their irradiation levels, assuming no efficient heat redistribution. We find that TRAPPIST-1 b shows a high dayside brightness temperature (490 $\pm$ 17 K), no significantly detectable nightside emission ($F_{\rm b, Night, max}$ = $39_{-27}^{+55}$ ppm), and no phase offset -- features consistent with a low-albedo, airless ultramafic rocky surface. TRAPPIST-1 c exhibits a lower dayside brightness temperature (369 $\pm$ 23 K), and a nightside flux statistically indistinguishable from that of TRAPPIST-1 b ($F_{\rm c, Night, max}$ = $62_{-43}^{+60}$ ppm). Atmosphere models with surface pressures $\geq$1 bar and efficient greenhouse effects are strongly disfavoured for both planets. TRAPPIST-1 b is unlikely to possess any substantial atmosphere, while TRAPPIST-1 c may retain a tenuous, greenhouse-poor O$_2$-dominated atmosphere or be similarly airless with a more reflective surface. These results suggest divergent evolutionary pathways or atmospheric loss processes, despite similar compositions. These measurements tightly constrain atmosphere retention in the inner TRAPPIST-1 system.

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arXiv2024

The effect of a biosphere on the habitable timespan of stagnant-lid planets and implications for the atmospheric spectrum

Temperature-dependent biological productivity controls silicate weathering and thereby extends the potential habitable timespan of Earth. Models and theoretical considerations indicate that the runaway greenhouse on Earth-like exoplanets is generally accompanied by a dramatic increase in atmospheric H$_2$O and CO$_2$, which might be observed with the upcoming generation of space telescopes. If an active biosphere extends the habitable timespan of exoplanets similarly to Earth, observing the atmospheric spectra of exoplanets near the inner edge of the habitable zone could then give insights into whether the planet is inhabited. Here, we explore this idea for Earth-like stagnant-lid planets. We find that while for a reduced mantle, a surface biosphere extends the habitable timespan of the planet by about 1 Gyr, for more oxidising conditions, the biologically enhanced rate of weathering becomes increasingly compensated for by an increased supply rate of CO$_2$ to the atmosphere. Observationally, the resulting difference in atmospheric CO$_2$ near the inner edge of the habitable zone is clearly distinguishable between biotic planets with active weathering and abiotic planets that have experienced a runaway greenhouse. For an efficient hydrological cycle, the increased bioproductivity also leads to a CH$_4$ biosignature observable with JWST. As the planet becomes uninhabitable, the H$_2$O infrared absorption bands dominate, but the 4.3-micron CO$_2$ band remains a clear window into the CO$_2$ abundances. In summary, while the effect of life on the carbonate-silicate cycle leaves a record in the atmospheric spectrum of Earth-like stagnant-lid planets, future work is needed especially to determine the tectonic state and composition of exoplanets and to push forward the development of the next generation of space telescopes.

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arXiv2024

Sulphur dioxide in the mid-infrared transmission spectrum of WASP-39b

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $\mu$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $\mu$m in the 5-12 $\mu$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$\sigma$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $\mu$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.

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arXiv2024

The CUISINES Framework for Conducting Exoplanet Model Intercomparison Projects, Version 1.0

As JWST begins to return observations, it is more important than ever that exoplanet climate models can consistently and correctly predict the observability of exoplanets, retrieval of their data, and interpretation of planetary environments from that data. Model intercomparisons play a crucial role in this context, especially now when few data are available to validate model predictions. The CUISINES Working Group of NASA's Nexus for Exoplanet System Science (NExSS) supports a systematic approach to evaluating the performance of exoplanet models, and provides here a framework for conducting community-organized exoplanet Model Intercomparison Projects (exoMIPs). The CUISINES framework adapts Earth climate community practices specifically for the needs of exoplanet researchers, encompassing a range of model types, planetary targets, and parameter space studies. It is intended to help researchers to work collectively, equitably, and openly toward common goals. The CUISINES framework rests on five principles: 1) Define in advance what research question(s) the exoMIP is intended to address. 2) Create an experimental design that maximizes community participation, and advertise it widely. 3) Plan a project timeline that allows all exoMIP members to participate fully. 4) Generate data products from model output for direct comparison to observations. 5) Create a data management plan that is workable in the present and scalable for the future. Within the first years of its existence, CUISINES is already providing logistical support to 10 exoMIPs, and will continue to host annual workshops for further community feedback and presentation of new exoMIP ideas.

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arXiv2024

Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $\mu$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$\sigma$ upper limit of 1-6 parts per million, depending on model assumptions).

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arXiv2023

Impact of Cosmic Rays on Atmospheric Ion Chemistry and Spectral Transmission Features of TRAPPIST-1e

Ongoing observing projects like the James Webb Space Telescope (JWST) and future missions offer the chance to characterize Earth-like exoplanetary atmospheres. Thereby, M-dwarfs are preferred targets for transit observations, for example, due to their favorable planet-star contrast ratio. However, the radiation and particle environment of these cool stars could be far more extreme than what we know from the Sun. Thus, knowing the stellar radiation and particle environment and its possible influence on detectable biosignatures - particularly signs of life like ozone and methane - is crucial to understanding upcoming transit spectra. In this study, with the help of our unique model suite INCREASE, we investigate the impact of a strong stellar energetic particle event on the atmospheric ionization, neutral and ion chemistry, and atmospheric biosignatures of TRAPPIST-1e. Therefore, transit spectra for six scenarios are simulated. We find that a Carrington-like event drastically increases atmospheric ionization and induces substantial changes in ion chemistry and spectral transmission features: all scenarios show high event-induced amounts of nitrogen dioxide (i.e., at 6.2 $\mu$m), a reduction of the atmospheric transit depth in all water bands (i.e., at 5.5 -- 7.0 $\mu$m), a decrease of the methane bands (i.e., at 3.0 -- 3.5 $\mu$m), and depletion of ozone (i.e., at $\sim$ 9.6 $\mu$m). Therefore, it is essential to include high-energy particle effects to correctly assign biosignature signals from, e.g., ozone and methane. We further show that the nitric acid feature at 11.0 - 12.0 $\mu$m, discussed as a proxy for stellar particle contamination, is absent in wet-dead atmospheres.

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arXiv2023

A roadmap for the atmospheric characterization of terrestrial exoplanets with JWST

Ultra-cool dwarf stars are abundant, long-lived, and uniquely suited to enable the atmospheric study of transiting terrestrial companions with JWST. Amongst them, the most prominent is the M8.5V star TRAPPIST-1 and its seven planets. While JWST Cycle 1 observations have started to yield preliminary insights into the planets, they have also revealed that their atmospheric exploration requires a better understanding of their host star. Here, we propose a roadmap to characterize the TRAPPIST-1 system -- and others like it -- in an efficient and robust manner. We notably recommend that -- although more challenging to schedule -- multi-transit windows be prioritized to mitigate the effects of stellar activity and gather up to twice more transits per JWST hour spent. We conclude that, for such systems, planets cannot be studied in isolation by small programs, but rather need large-scale, jointly space- and ground-based initiatives to fully exploit the capabilities of JWST for the exploration of terrestrial planets.

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arXiv2023

Detection of carbon monoxide's 4.6 micron fundamental band structure in WASP-39b's atmosphere with JWST NIRSpec G395H

Carbon monoxide (CO) is predicted to be the dominant carbon-bearing molecule in giant planet atmospheres, and, along with water, is important for discerning the oxygen and therefore carbon-to-oxygen ratio of these planets. The fundamental absorption mode of CO has a broad double-branched structure composed of many individual absorption lines from 4.3 to 5.1 $\mathrm{\mu}$m, which can now be spectroscopically measured with JWST. Here we present a technique for detecting the rotational sub-band structure of CO at medium resolution with the NIRSpec G395H instrument. We use a single transit observation of the hot Jupiter WASP-39b from the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) program at the native resolution of the instrument ($R \,{\sim} 2700$) to resolve the CO absorption structure. We robustly detect absorption by CO, with an increase in transit depth of 264 $\pm$ 68 ppm, in agreement with the predicted CO contribution from the best-fit model at low resolution. This detection confirms our theoretical expectations that CO is the dominant carbon-bearing molecule in WASP-39b's atmosphere, and further supports the conclusions of low C/O and super-solar metallicities presented in the JTEC ERS papers for WASP-39b.

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arXiv2023

A broadband thermal emission spectrum of the ultra-hot Jupiter WASP-18b

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $\mu$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$\sigma$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$\sigma$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators.

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arXiv2022

Early Release Science of the exoplanet WASP-39b with JWST NIRCam

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $\mu$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $\mu$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere.

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arXiv2022

Early Release Science of the Exoplanet WASP-39b with JWST NIRSpec G395H

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $\mu$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$\sigma$) and H$_2$O (21.5$\sigma$), and identify SO$_2$ as the source of absorption at 4.1 $\mu$m (4.8$\sigma$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range.

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arXiv2022

Early Release Science of the exoplanet WASP-39b with JWST NIRISS

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 \mu$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator.

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arXiv2022

Identification of carbon dioxide in an exoplanet atmosphere

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called "metallicity"), and thus formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2 but have not yielded definitive detections due to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science Program (ERS). The data used in this study span 3.0 to 5.5 {\mu}m in wavelength and show a prominent CO2 absorption feature at 4.3 {\mu}m (26{\sigma} significance). The overall spectrum is well matched by one-dimensional, 10x solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide, and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 {\mu}m that is not reproduced by these models.

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arXiv2020

Understanding the atmospheric properties and chemical composition of the ultra-hot Jupiter HAT-P-7b II. Mapping the effects of gas kinetics

The atmospheres of ultra-hot Jupiters are commonly considered to be at thermochemical equilibrium. We aim to provide disequilibrium chemistry maps for a global understanding of the chemistry in HAT-P-7b's atmosphere and assess the importance of disequilibrium chemistry on UHJs. We apply a hierarchical modelling approach utilising 97 1D atmospheric profiles from 3D GCM of HAT-P-7b. For each 1D profile, we evaluate our kinetic cloud formation model consistently with the local gas-phase composition in chemical equilibrium. We then evaluate quenching results from a zeroth-order approximation in comparison to a kinetic gas-phase approach. We find that the zeroth-order approach of estimating quenching points agrees well with the full gas-kinetic modeling results. Chemical disequilibrium has the greatest effect on the nightside and morning abundance of species such as H, H$_2$O, CH$_4$, CO$_2$, HCN, and all C$_n$H$_m$ molecules; heavier C$_n$H$_m$ molecules are more affected by disequilibrium processes. CO abundance, however, is affected only marginally. While dayside abundances also notably change, those around the evening terminator of HAT-P-7b are the least affected by disequilibrium processes. The latter finding may partially explain the consistency of observed transmission spectra of UHJs with atmospheres in thermochemical equilibrium. Photochemistry only negligibly affects molecular abundances and quenching levels. In general, the quenching points of HAT-P-7b's atmosphere are at much lower pressures in comparison to the cooler hot-jupiters. We propose several avenues to look for the effect of disequilibrium processes on UHJs that are, in general, based on abundance and opacity measurements at different local times. It remains a challenge to completely disentangle this from the chemical effects of clouds and that of a primordial non-solar abundance.

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arXiv2019

The Need for Laboratory Measurements and Ab Initio Studies to Aid Understanding of Exoplanetary Atmospheres

We are now on a clear trajectory for improvements in exoplanet observations that will revolutionize our ability to characterize their atmospheric structure, composition, and circulation, from gas giants to rocky planets. However, exoplanet atmospheric models capable of interpreting the upcoming observations are often limited by insufficiencies in the laboratory and theoretical data that serve as critical inputs to atmospheric physical and chemical tools. Here we provide an up-to-date and condensed description of areas where laboratory and/or ab initio investigations could fill critical gaps in our ability to model exoplanet atmospheric opacities, clouds, and chemistry, building off a larger 2016 white paper, and endorsed by the NAS Exoplanet Science Strategy report. Now is the ideal time for progress in these areas, but this progress requires better access to, understanding of, and training in the production of spectroscopic data as well as a better insight into chemical reaction kinetics both thermal and radiation-induced at a broad range of temperatures. Given that most published efforts have emphasized relatively Earth-like conditions, we can expect significant and enlightening discoveries as emphasis moves to the exotic atmospheres of exoplanets.

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