arXiv subjects

Nicole Yunger Halpern

Publications and source records attributed to Nicole Yunger Halpern.

At least 55 records · Page 3Linked to original sources

arXiv2020

Fundamental limitations on photoisomerization from thermodynamic resource theories

Small, out-of-equilibrium, and quantum systems defy simple thermodynamic expressions. Such systems are exemplified by molecular switches, which exchange heat with a bath. These molecules can photoisomerize, or change conformation, or switch, upon absorbing light. The photoisomerization probability depends on kinetic details that couple the molecule's energetics to its dissipation. Therefore, a simple, general, thermodynamic-style bound on the photoisomerization probability seems out of reach. We derive such a bound using a resource theory. The resource-theory framework is a set of mathematical tools, developed in quantum information theory, used to generalize thermodynamics to small and quantum settings. From this toolkit has been derived a generalization of the second law, the thermomajorization preorder. We use thermomajorization to upper-bound the photoisomerization probability. Then, we compare the bound with an equilibrium prediction and with a Lindbladian model. We identify a realistic parameter regime in which the Lindbladian evolution saturates the thermomajorization bound. We also quantify the energy coherence in the electronic degree of freedom, and we argue that this coherence cannot promote photoisomerization. This work illustrates how quantum-information-theoretic thermodynamics can elucidate complex quantum processes in nature, experiments, and synthetics.

quant-ph↗

arXiv2020

Noncommuting conserved quantities in quantum many-body thermalization

In statistical mechanics, a small system exchanges conserved quantities---heat, particles, electric charge, etc.---with a bath. The small system thermalizes to the canonical ensemble, or the grand canonical ensemble, etc., depending on the conserved quantities. The conserved quantities are represented by operators usually assumed to commute with each other. This assumption was removed within quantum-information-theoretic (QI-theoretic) thermodynamics recently. The small system's long-time state was dubbed ``the non-Abelian thermal state (NATS).'' We propose an experimental protocol for observing a system thermalize to the NATS. We illustrate with a chain of spins, a subset of which form the system of interest. The conserved quantities manifest as spin components. Heisenberg interactions push the conserved quantities between the system and the effective bath, the rest of the chain. We predict long-time expectation values, extending the NATS theory from abstract idealization to finite systems that thermalize with finite couplings for finite times. Numerical simulations support the analytics: The system thermalizes to the NATS, rather than to the canonical prediction. Our proposal can be implemented with ultracold atoms, nitrogen-vacancy centers, trapped ions, quantum dots, and perhaps nuclear magnetic resonance. This work introduces noncommuting conserved quantities from QI-theoretic thermodynamics into quantum many-body physics: atomic, molecular, and optical physics and condensed matter.

quant-ph↗

arXiv2020

Quantifying many-body learning far from equilibrium with representation learning

Far-from-equilibrium many-body systems, from soap bubbles to suspensions to polymers, learn the drives that push them. This learning has been observed via thermodynamic properties, such as work absorption and strain. We move beyond these macroscopic properties that were first defined for equilibrium contexts: We quantify statistical mechanical learning with machine learning. Our toolkit relies on a structural parallel that we identify between far-from-equilibrium statistical mechanics and representation learning, which is undergone by neural networks that contain bottlenecks, including variational autoencoders. We train a variational autoencoder, via unsupervised learning, on configurations assumed by a many-body system during strong driving. We analyze the neural network's bottleneck to measure the many-body system's classification ability, memory capacity, discrimination ability, and novelty detection. Numerical simulations of a spin glass illustrate our technique. This toolkit exposes self-organization that eludes detection by thermodynamic measures, more reliably and more precisely identifying and quantifying learning by matter.

cond-mat.stat-mech↗

arXiv2019

Entropic uncertainty relations for quantum information scrambling

How violently do two quantum operators disagree? Different fields of physics feature different measures of incompatibility: (i) In quantum information theory, entropic uncertainty relations constrain measurement outcomes. (ii) In condensed matter and high-energy physics, the out-of-time-ordered correlator (OTOC) signals scrambling, the spread of information through many-body entanglement. We unite these measures, proving entropic uncertainty relations for scrambling. The entropies are of distributions over weak and strong measurements' possible outcomes. The weak measurements ensure that the OTOC quasiprobability (a nonclassical generalization of a probability, which coarse-grains to the OTOC) governs terms in the uncertainty bound. The quasiprobability causes scrambling to strengthen the bound in numerical simulations of a spin chain. This strengthening shows that entropic uncertainty relations can reflect the type of operator disagreement behind scrambling. Generalizing beyond scrambling, we prove entropic uncertainty relations satisfied by commonly performed weak-measurement experiments. We unveil a physical significance of weak values (conditioned expectation values): as governing terms in entropic uncertainty bounds.

quant-ph↗

arXiv2019

Quantum information in the Posner model of quantum cognition

Matthew Fisher recently postulated a mechanism by which quantum phenomena could influence cognition: Phosphorus nuclear spins may resist decoherence for long times, especially when in Posner molecules. The spins would serve as biological qubits. We imagine that Fisher postulates correctly. How adroitly could biological systems process quantum information (QI)? We establish a framework for answering. Additionally, we construct applications of biological qubits to quantum error correction, quantum communication, and quantum computation. First, we posit how the QI encoded by the spins transforms as Posner molecules form. The transformation points to a natural computational basis for qubits in Posner molecules. From the basis, we construct a quantum code that detects arbitrary single-qubit errors. Each molecule encodes one qutrit. Shifting from information storage to computation, we define the model of Posner quantum computation. To illustrate the model's quantum-communication ability, we show how it can teleport information incoherently: A state's weights are teleported. Dephasing results from the entangling operation's simulation of a coarse-grained Bell measurement. Whether Posner quantum computation is universal remains an open question. However, the model's operations can efficiently prepare a Posner state usable as a resource in universal measurement-based quantum computation. The state results from deforming the Affleck-Kennedy-Lieb-Tasaki (AKLT) state and is a projected entangled-pair state (PEPS). Finally, we show that entanglement can affect molecular-binding rates, boosting a binding probability from 33.6% to 100% in an example. This work opens the door for the QI-theoretic analysis of biological qubits and Posner molecules.

quant-ph↗

arXiv2019

MBL-mobile: Quantum engine based on many-body localization

Many-body-localized (MBL) systems do not thermalize under their intrinsic dynamics. The athermality of MBL, we propose, can be harnessed for thermodynamic tasks. We illustrate this ability by formulating an Otto engine cycle for a quantum many-body system. The system is ramped between a strongly localized MBL regime and a thermal (or weakly localized) regime. The difference between the energy-level correlations of MBL systems and of thermal systems enables mesoscale engines to run in parallel in the thermodynamic limit, enhances the engine's reliability, and suppresses worst-case trials. We estimate analytically and calculate numerically the engine's efficiency and per-cycle power. The efficiency mirrors the efficiency of the conventional thermodynamic Otto engine. The per-cycle power scales linearly with the system size and inverse-exponentially with a localization length. This work introduces a thermodynamic lens onto MBL, which, having been studied much recently, can now be considered for use in thermodynamic tasks.

quant-ph↗

arXiv2019

Out-of-Time-Ordered-Correlator Quasiprobabilities Robustly Witness Scrambling

Out-of-time-ordered correlators (OTOCs) have received considerable recent attention as qualitative witnesses of information scrambling in many-body quantum systems. Theoretical discussions of OTOCs typically focus on closed systems, raising the question of their suitability as scrambling witnesses in realistic open systems. We demonstrate empirically that the nonclassical negativity of the quasiprobability distribution (QPD) behind the OTOC is a more sensitive witness for scrambling than the OTOC itself. Nonclassical features of the QPD evolve with timescales that are robust with respect to decoherence and are immune to false positives caused by decoherence. To reach this conclusion, we numerically simulate spin-chain dynamics and three measurement protocols (the interferometric, quantum-clock, and weak-measurement schemes) for measuring OTOCs. We target experiments based on quantum-computing hardware such as superconducting qubits and trapped ions.

quant-ph↗

arXiv2018

Strengthening weak measurements of qubit out-of-time-order correlators

For systems of controllable qubits, we provide a method for experimentally obtaining a useful class of multitime correlators using sequential generalized measurements of arbitrary strength. Specifically, if a correlator can be expressed as an average of nested (anti)commutators of operators that square to the identity, then that correlator can be determined exactly from the average of a measurement sequence. As a relevant example, we provide quantum circuits for measuring multiqubit out-of-time-order correlators using optimized control-Z or ZX-90 two-qubit gates common in superconducting transmon implementations.

quant-ph↗

arXiv2018

Quantum steampunk: Quantum information, thermodynamics, their intersection, and applications thereof across physics

Combining quantum information theory with thermodynamics unites 21st-century technology with 19th-century principles. The union elucidates the spread of information, the flow of time, and the leveraging of energy. This thesis contributes to the theory of quantum thermodynamics, particularly to quantum-information-theoretic thermodynamics. The thesis also contains applications of the theory, wielded as a toolkit, across physics. Fields touched on include atomic, molecular, and optical physics; nonequilibrium statistical mechanics; condensed matter; high-energy physics; and chemistry. I propose the name "quantum steampunk" for this program. The term derives from the steampunk genre of literature, art, and cinema that juxtaposes futuristic technologies with 19th-century settings.

quant-ph↗

arXiv2018

Resilience of scrambling measurements

Most experimental protocols for measuring scrambling require time evolution with a Hamiltonian and with the Hamiltonian's negative counterpart (backwards time evolution). Engineering controllable quantum many-body systems for which such forward and backward evolution is possible is a significant experimental challenge. Furthermore, if the system of interest is quantum-chaotic, one might worry that any small errors in the time reversal will be rapidly amplified, obscuring the physics of scrambling. This paper undermines this expectation: We exhibit a renormalization protocol that extracts nearly ideal out-of-time-ordered-correlator measurements from imperfect experimental measurements. We analytically and numerically demonstrate the protocol's effectiveness, up to the scrambling time, in a variety of models and for sizable imperfections. The scheme extends to errors from decoherence by an environment.

quant-ph↗

arXiv2018

Maximum one-shot dissipated work from Renyi divergences

Thermodynamics describes large-scale, slowly evolving systems. Two modern approaches generalize thermodynamics: fluctuation theorems, which concern finite-time nonequilibrium processes, and one-shot statistical mechanics, which concerns small scales and finite numbers of trials. Combining these approaches, we calculate a one-shot analog of the average dissipated work defined in fluctuation contexts: the cost of performing a protocol in finite time instead of quasistatically. The average dissipated work has been shown to be proportional to a relative entropy between phase-space densities, to a relative entropy between quantum states, and to a relative entropy between probability distributions over possible values of work. We derive one-shot analogs of all three equations, demonstrating that the order-infinity Renyi divergence is proportional to the maximum possible dissipated work in each case. These one-shot analogs of fluctuation-theorem results contribute to the unification of these two toolkits for small-scale, nonequilibrium statistical physics.

cond-mat.stat-mech↗

arXiv2018

The quasiprobability behind the out-of-time-ordered correlator

Two topics, evolving rapidly in separate fields, were combined recently: The out-of-time-ordered correlator (OTOC) signals quantum-information scrambling in many-body systems. The Kirkwood-Dirac (KD) quasiprobability represents operators in quantum optics. The OTOC has been shown to equal a moment of a summed quasiprobability. That quasiprobability, we argue, is an extension of the KD distribution. We explore the quasiprobability's structure from experimental, numerical, and theoretical perspectives. First, we simplify and analyze the weak-measurement and interference protocols for measuring the OTOC and its quasiprobability. We decrease, exponentially in system size, the number of trials required to infer the OTOC from weak measurements. We also construct a circuit for implementing the weak-measurement scheme. Next, we calculate the quasiprobability (after coarse-graining) numerically and analytically: We simulate a transverse-field Ising model first. Then, we calculate the quasiprobability averaged over random circuits, which model chaotic dynamics. The quasiprobability, we find, distinguishes chaotic from integrable regimes. We observe nonclassical behaviors: The quasiprobability typically has negative components. It becomes nonreal in some regimes. The onset of scrambling breaks a symmetry that bifurcates the quasiprobability, as in classical-chaos pitchforks. Finally, we present mathematical properties. The quasiprobability obeys a Bayes-type theorem, for example, that exponentially decreases the memory required to calculate weak values, in certain cases. A time-ordered correlator analogous to the OTOC, insensitive to quantum-information scrambling, depends on a quasiprobability closer to a classical probability. This work not only illuminates the OTOC's underpinnings, but also generalizes quasiprobability theory and motivates immediate-future weak-measurement challenges.

quant-ph↗

arXiv2018

Beyond heat baths II: Framework for generalized thermodynamic resource theories

Thermodynamics, which describes vast systems, has been reconciled with small scales, relevant to single-molecule experiments, in resource theories. Resource theories have been used to model exchanges of energy and information. Recently, particle exchanges were modeled; and an umbrella family of thermodynamic resource theories was proposed to model diverse baths, interactions, and free energies. This paper motivates and details the family's structure and prospective applications. How to model electrochemical, gravitational, magnetic, and other thermodynamic systems is explained. Szilard's engine and Landauer's Principle are generalized, as resourcefulness is shown to be convertible not only between information and gravitational energy, but also among diverse degrees of freedom. Extensive variables are associated with quantum operators that might fail to commute, introducing extra nonclassicality into thermodynamic resource theories. An early version of this paper partially motivated the later development of noncommutative thermalization. This generalization expands the theories' potential for modeling realistic systems with which small-scale statistical mechanics might be tested experimentally.

quant-ph↗

arXiv2017

Quantum voting and violation of Arrow's Impossibility Theorem

We propose a quantum voting system, in the spirit of quantum games such as the quantum Prisoner's Dilemma. Our scheme enables a constitution to violate a quantum analog of Arrow's Impossibility Theorem. Arrow's Theorem is a claim proved deductively in economics: Every (classical) constitution endowed with three innocuous-seeming properties is a dictatorship. We construct quantum analogs of constitutions, of the properties, and of Arrow's Theorem. A quantum version of majority rule, we show, violates this Quantum Arrow Conjecture. Our voting system allows for tactical-voting strategies reliant on entanglement, interference, and superpositions. This contribution to quantum game theory helps elucidate how quantum phenomena can be harnessed for strategic advantage.

quant-ph↗

arXiv2017

Entropic equality for worst-case work at any protocol speed

We derive an equality for non-equilibrium statistical mechanics in finite-dimensional quantum systems. The equality concerns the worst-case work output of a time-dependent Hamiltonian protocol in the presence of a Markovian heat bath. It has has the form "worst-case work = penalty - optimum". The equality holds for all rates of changing the Hamiltonian and can be used to derive the optimum by setting the penalty to 0. The optimum term contains the max entropy of the initial state, rather than the von Neumann entropy, thus recovering recent results from single-shot statistical mechanics. Energy coherences can arise during the protocol but are assumed not to be present initially. We apply the equality to an electron box.

quant-ph↗

arXiv2017

Jarzynski-like equality for the out-of-time-ordered correlator

The out-of-time-ordered correlator (OTOC) diagnoses quantum chaos and the scrambling of quantum information via the spread of entanglement. The OTOC encodes forward and reverse evolutions and has deep connections with the flow of time. So do fluctuation relations such as Jarzynski's Equality, derived in nonequilibrium statistical mechanics. I unite these two powerful, seemingly disparate tools by deriving a Jarzynski-like equality for the OTOC. The equality's left-hand side equals the OTOC. The right-hand side suggests a protocol for measuring the OTOC indirectly. The protocol is platform-nonspecific and can be performed with weak measurement or with interference. Time evolution need not be reversed in any interference trial. The equality opens holography, condensed matter, and quantum information to new insights from fluctuation relations and vice versa.

quant-ph↗

arXiv2017

Toward physical realizations of thermodynamic resource theories

Conventional statistical mechanics describes large systems and averages over many particles or over many trials. But work, heat, and entropy impact the small scales that experimentalists can increasingly control, e.g., in single-molecule experiments. The statistical mechanics of small scales has been quantified with two toolkits developed in quantum information theory: resource theories and one-shot information theory. The field has boomed recently, but the theorems amassed have hardly impacted experiments. Can thermodynamic resource theories be realized experimentally? Via what steps can we shift the theory toward physical realizations? Should we care? I present eleven opportunities in physically realizing thermodynamic resource theories.

quant-ph↗

arXiv2016

Microcanonical and resource-theoretic derivations of the thermal state of a quantum system with noncommuting charges

The grand canonical ensemble lies at the core of quantum and classical statistical mechanics. A small system thermalizes to this ensemble while exchanging heat and particles with a bath. A quantum system may exchange quantities represented by operators that fail to commute. Whether such a system thermalizes and what form the thermal state has are questions about truly quantum thermodynamics. Here we investigate this thermal state from three perspectives. First, we introduce an approximate microcanonical ensemble. If this ensemble characterizes the system-and-bath composite, tracing out the bath yields the system's thermal state. This state is expected to be the equilibrium point, we argue, of typical dynamics. Finally, we define a resource-theory model for thermodynamic exchanges of noncommuting observables. Complete passivity---the inability to extract work from equilibrium states---implies the thermal state's form, too. Our work opens new avenues into equilibrium in the presence of quantum noncommutation.

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