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Norbert Christlieb

Publications and source records attributed to Norbert Christlieb.

At least 19 recordsLinked to original sources

Detailed Abundance Determination of Metal-Poor Stars with X-Shooter II. - Chemically Disentangling the Halo, Disk and GSE

We present a detailed chemical analysis of seven extremely metal-poor (EMP) star candidates observed with X-Shooter, combining them with 16 EMP candidates from Paper I. We measured abundances for 16 elements, showing excellent agreement with previously published results. The sample was further extended using high-resolution literature data for 315 metal-poor stars. The full sample was then kinematically separated into prograde disk, retrograde disk, Gaia-Sausage Enceladus (GSE) and halo classifications. Combining dynamics with chemistry, we demonstrate that the prograde disk exhibits a distinct negative linear trend in [Sc/Mg] with increasing metallicity, with a slope of -0.6 dex per dex. This contrasts with the halo trend at -0.04 dex per dex, a difference significant at the 3.95$\sigma$ level. Within the metallicity range -4.2 $\leq$ [Fe/H] $\leq$ -1.9, the prograde disk trend is driven by low [Mg/Fe] at lower metallicities, along with low [Sc/Fe] at higher metallicities. This could be due to reduced early Mg enrichment in the progenitor prograde disk, followed by subsequent Mg enrichment, possibly associated with a later gas accretion event. However, the physical origin of the higher-metallicity Sc depletion remains unexplained by current nucleosynthesis models. The result remains significant at the >3$\sigma$ level across kinematic classifications derived from a different Galactic potential. Additionally, we also identified an r-I star with enhanced Ti, moderately-enhanced Sc, and depleted in C (unrelated to its evolutionary state). These abundances suggest a massive jet-induced hypernova progenitor, though a measurement of Zn is needed to verify this.

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HE0144-4657: A Carbon-Enhanced Ultra Metal-Poor Star ([Fe/H] ~ -4.1) from the Helmi Stream Disrupted Dwarf Galaxy

We present the discovery of HE0144-4657, an ultra metal-poor, CNO-enhanced star dynamically associated with the Helmi Stream disrupted dwarf-galaxy remnant. This star was first identified as a carbon-enhanced, metal-poor star candidate from the Hamburg/ESO objective-prism survey, then followed up with medium- and high-resolution spectroscopy. At [Fe/H]=-4.11, HE0144-4657 is the lowest metallicity star found in a stellar stream to date. Its chemistry is consistent with field halo stars in the same metallicity regime, and the light-element (atomic number Z<=30) chemical abundance pattern suggests that HE0144-4657 is a bona-fide second-generation star with a possible Population III progenitor in the 50Msun mass range with low explosion energy. One possible scenario for the origin of HE0144-4657 is that it was formed in an ultra-faint dwarf galaxy accreted by the Helmi Stream progenitor system before merging with the Milky Way. This discovery provides further evidence for the extragalactic origin of carbon-enhanced ultra metal-poor stars in the Milky Way and for the specific environments conducive to their formation.

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Detailed Abundance Determination of Metal-Poor Stars with X-Shooter I. Unusual Chemistry in Halo Stars

We present a detailed chemical analysis study of 16 candidate metal-poor stars, previously identified with 2dF + AAOmega, using X-Shooter spectra and the Korg 1D local thermodynamic equilibrium spectral synthesis code. We confirm the earlier metallicity estimates and reveal six extremely metal-poor ([Fe/H] $< -3$) stars in the current sample. Two of these stars, including the most metal poor at [Fe/H] = $-3.89 \pm 0.07$, are kinematically associated with the Gaia-Sausage-Enceladus (GSE) accretion event, increasing the number of known GSE stars with [Fe/H] $< -3.5$ to eight. From the X-Shooter spectra we determine abundances for 16 elements, with the element-to-iron abundance ratios generally consistent with high-resolution studies of Galactic halo stars. Within the sample, we identify three peculiar stars: the first is a GSE nitrogen enhanced metal-poor ([N/Fe] $= 1.60 \pm 0.10$ and [C/Fe] $= 0.23 \pm 0.08$) star with unusually high Na ([Na/Fe] $= 2.26 \pm 0.07$) and Li (A(Li)$_{\rm 3DNLTE} = 1.90 \pm 0.08$) abundances, but lacking enhancements in [Al/Fe] or [Mg/Fe]. The second is a halo r-II star significantly enhanced in Sr ([Sr/Ba] $= 0.39 \pm 0.08$), suggesting mixture of r-process and s-process enrichment, uncommon for r-II stars. Whilst the third is a halo star very depleted in N ([N/Fe] $< -1.11$), with low C ([C/Fe] $= -0.33 \pm 0.08$) and otherwise 'normal' [X/Fe] abundances, suggesting enrichment with Type II supernova that proceeds enrichment from massive asymptotic giant branch stars. This study reveals the substantial degree of chemical diversity in the stellar populations which assembled the early Milky Way.

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Metal-poor stars observed with the Magellan Telescope. IV. Neutron-capture element signatures in 27 main-sequence stars

Based on high-resolution spectra obtained with Magellan/MIKE, we present a chemo-dynamical analysis for 27 near main-sequence turnoff metal-poor stars, including 20 stars analyzed for the first time. The sample spans a range in [Fe/H] from -2.5 to -3.6, with 44% having [Fe/H] <-2.9. We derived chemical abundances for 17 elements, including strontium and barium. We derive Li abundances for the sample, which are in good agreement with the ``Spite Plateau'' value. A dozen of stars are carbon-enhanced. The lighter elements (Z<30) generally agree well with those of other low-metallicity halo stars. This broadly indicates chemically homogeneous gas at the earliest times. Of the neutron-capture elements, we only detected strontium and barium. We used the [Sr/Ba] vs. [Ba/Fe] diagram to classify metal-poor stars into five populations based on their observed ratios. We find HE0232-3755 to be a likely main r-process star, and HE2214-6127 and HE2332-3039 to be limited-r stars. CS30302-145, HE2045-5057, and CD-24 17504 plausibly originated in long-disrupted early dwarf galaxies as evidenced by their [Sr/Ba] and [Ba/Fe] ratios. We also find that the derived [Sr/H] and [Ba/H] values for CD-24 17504 are not inconsistent with the predicted yields of the s-process in massive rotating low-metallicity stars models. Further theoretical explorations will be helpful to better understand the earliest mechanisms and time scales of heavy element production for comparison with these and other observational abundance data. Finally, we investigate the orbital histories of our sample stars. Most display halo-like kinematics although three stars (CS29504-018, HE0223-2814, and HE2133-0421) appear to be disk-like in nature. This confirms the extragalactic origin for CS30302-145, HE2045-5057, and, in particular, CD-24 17504 which likely originated from a small accreted stellar system as one of the oldest stars.

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Understanding the early stages of galaxy formation using very metal-poor stars from the Hamburg/ESO survey

We explore the chemo-dynamical properties of a sample of very metal-poor (VMP) stars selected from the Hamburg/ESO survey, matched with Gaia EDR3, in the phase-space identified by the three integrals of motion ($L_z$, $E$, $I_3$). Disk and halo orbits are separated by using the criteria defined in Carollo et al. (2021). We found 26 stars with $[Fe/H] \leq -2.5$ possessing disk kinematics, of which 14 are extremely metal-poor. At these metallicities, the number of stars with disk kinematics is three times its retrograde counterpart. In the same range of metallicity we also identified 37 halo stars most tightly bound to the gravitational potential of the progenitor halo. The origin of these stars are investigated by comparing the observational results with simulated galaxies from the Aquarius Project and the IllustrisTNG simulations. We found two mechanisms of formation of VMP stars with disk kinematics: accretion from early satellites (which is dominant), and {\it in-situ} formation. These stars are very old, with ages > 12.5 Gyr ($z$ > 5), and they are $\alpha$-enriched. Accretion and {\it in-situ} formation are also found for the retrograde counterparts with being accretion also the dominant mode. Contributing accreted satellites have stellar masses in the range $[10^{6}-10^9]$ M_sun, and are very gas-rich. The most bound halo stars are the oldest detected with a median age of ~ 13.3 Gyr ($z$ ~ 11), and $\alpha$-enriched. Our finding clearly show that very old, very metal-poor stars store important information on the first stages of assembly of our Galaxy and its halo.

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A method for identifying metal-poor stars with Gaia BP/RP spectra

Context. The study of the oldest and most metal-poor stars in our Galaxy promotes our understanding of the Galactic chemical evolution and the beginning of Galaxy and star formation. However, they are notoriously difficult to find, with only five stars at $\mathrm{[Fe/H]<-5.0}$ having been detected to date. Thus, the spectrophotometric data of 219 million sources which became available in the third Gaia Data Release comprise a very promising dataset for the identification of metal-poor stars. Aims. We want to use the low-resolution Gaia Blue Photometer / Red Photometer (BP/RP) spectra to identify metal-poor stars. Our primary aspiration is to help populate the poorly constrained tail of the metallicity distribution function of the stellar halo of the Galaxy. Methods. We developed a metal-poor candidate selection method based on flux ratios from the BP/RP Gaia spectra, using simulated synthetic spectra. Results. We found a relation between the relative iron abundance and the flux ratio of the Ca H \& K region to that of the $\mathrm{H\beta}$ line. This relation is temperature and surface gravity dependent, and it holds for stars with $\mathrm{4800\,K \leq T_{eff}\leq6300\,K}$. We applied it to noisy simulated synthetic spectra and inferred $\mathrm{[Fe/H]}$ with an uncertainty of $\sigma_{\mathrm{[Fe/H]}}\lessapprox0.65$ dex for $\mathrm{-3\leq[Fe/H]}\leq 0.5$ and G=15-17mag, which is sufficient to identify stars at $\mathrm{[Fe/H]<-2.0 }$ reliably. We predict that by selecting stars with inferred $\mathrm{[Fe/H]}\leq-2.5$ dex, we can retrieve 80% of the stars with $\mathrm{[Fe/H]}\leq-3$ and have a success rate of about 50%, that is one in two stars we select would have $\mathrm{[Fe/H]}\leq-3$. We do not take into account the effect of reddening, so our method should only be applied to stars which are located in regions of low extinction.

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The CUBES Science Case

We introduce the scientific motivations for the development of the Cassegrain U-Band Efficient Spectrograph (CUBES) that is now in construction for the Very Large Telescope. The assembled cases span a broad range of contemporary topics across Solar System, Galactic and extragalactic astronomy, where observations are limited by the performance of current ground-based spectrographs shortwards of 400nm. A brief background to each case is presented and specific technical requirements on the instrument design that flow-down from each case are identified. These were used as inputs to the CUBES design, that will provide a factor of ten gain in efficiency for astronomical spectroscopy over 300-405nm, at resolving powers of R~24,000 and ~7,000. We include performance estimates that demonstrate the ability of CUBES to observe sources that are up to three magnitudes fainter than currently possible at ground-ultraviolet wavelengths, and we place its predicted performance in the context of existing facillities.

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Four-hundred Very Metal-poor Stars studied with LAMOST and Subaru. I. Survey Design, Follow-up Program, and Binary Frequency

The chemical abundances of very metal-poor stars provide important constraints on the nucleosynthesis of the first generation of stars and early chemical evolution of the Galaxy. We have obtained high-resolution spectra with the Subaru Telescope for candidates of very metal-poor stars selected with a large survey of Galactic stars carried out with LAMOST. In this series of papers, we report on the elemental abundances of about 400 very metal-poor stars and discuss the kinematics of the sample obtained by combining the radial velocities measured in this study and recent astrometry obtained with Gaia. This paper provides an overview of our survey and follow-up program, and reports radial velocities for the whole sample. We identify seven double-lined spectroscopic binaries from our high-resolution spectra, for which radial velocities of the components are reported. We discuss the frequency of such relatively short-period binaries at very low metallicity.

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Dynamically Tagged Groups of Very Metal-poor Halo Stars from the HK and Hamburg/ESO Surveys

We analyze the dynamical properties of $\sim$1500 very metal-poor (VMP; [Fe/H] $\lesssim -2.0$) halo stars, based primarily on medium-resolution spectroscopic data from the HK and Hamburg/ESO surveys. These data, collected over the past thirty years, are supplemented by a number of calibration stars and other small samples, along with astrometric information from $Gaia$ DR2. We apply a clustering algorithm to the 4-D energy-action space of the sample, and identify a set of 38 Dynamically Tagged Groups (DTGs), containing between 5 and 30 member stars. Many of these DTGs can be associated with previously known prominent substructures such as $Gaia$-Sausage/Enceladus (GSE), Sequoia, the Helmi Stream (HStr), and Thamnos. Others are associated with previously identified smaller dynamical groups of stars and streams. We identify 10 new DTGs as well, many of which have strongly retrograde orbits. We also investigate possible connections between our DTGs and $\sim$300 individual $r$-process-enhanced (RPE) stars from a recent literature compilation. We find that several of these objects have similar dynamical properties to GSE (5), the HStr (4), Sequoia (1), and Rg5 (1), indicating that their progenitors might have been important sources of RPE stars in the Galaxy. Additionally, a number of our newly identified DTGs are shown to be associated with at least two RPE stars each (DTG-2: 3, DTG-7: 2; DTG-27: 2). Taken as a whole, these results are consistent with ultra-faint and/or dwarf spheroidal galaxies as birth environments in which $r$-process nucleosynthesis took place, and then were disrupted by the Milky Way.

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Observational Constraints on First-Star Nucleosynthesis. II. Spectroscopy of an Ultra Metal-Poor CEMP-no Star

We report on the first high-resolution spectroscopic analysis of HE0020-1741, a bright (V=12.9), ultra metal-poor ([Fe/H] = -4.1), carbon-enhanced ([C/Fe] = +1.7) star selected from the Hamburg/ESO Survey. This star exhibits low abundances of neutron-capture elements ([Ba/Fe] = -1.1), and an absolute carbon abundance A(C) = 6.1; based on either criterion, HE0020-1741 is sub-classified as a CEMP-no star. We show that the light-element abundance pattern of HE0020-1741 is consistent with predicted yields from a massive (M = 21.5 Mo), primordial composition, supernova (SN) progenitor. We also compare the abundance patterns of other ultra metal-poor stars from the literature with available measures of C, N, Na, Mg, and Fe abundances with an extensive grid of SN models (covering the mass range 10 Mo - 100 Mo), in order to probe the nature of their likely stellar progenitors. Our results suggest that at least two classes of progenitors are required at [Fe/H] < -4.0, as the abundance patterns for more than half of the sample studied in this work (7 out of 12 stars) cannot be easily reproduced by the predicted yields.

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The Chemical Abundances of Stars in the Halo (CASH) Project. III. A New Classification Scheme for Carbon-Enhanced Metal-poor Stars with S-process Element Enhancement

We present a detailed abundance analysis of 23 elements for a newly discovered carbon-enhanced metal-poor (CEMP) star, HE 0414-0343, from the Chemical Abundances of Stars in the Halo (CASH) Project. Its spectroscopic stellar parameters are Teff = 4863 K, log g = 1.25, vmic = 2.20 km/s, and [Fe/H] = -2.24. Radial velocity measurements covering seven years indicate HE 0414-0343 to be a binary. HE 0414-0343 has [C/Fe] = 1.44 and is strongly enhanced in neutron-capture elements but its abundances cannot be reproduced by a solar-type s-process pattern alone. Traditionally, it could be classified as "CEMP-r/s" star. Based on abundance comparisons with AGB star nucleosynthesis models, we suggest a new physically-motivated origin and classification scheme for CEMP-s stars and the still poorly-understood CEMP-r/s. The new scheme describes a continuous transition between these two so-far distinctly treated subgroups: CEMP-sA, CEMP-sB, and CEMP-sC. Possible causes for a continuous transition include the number of thermal pulses the AGB companion underwent, the effect of different AGB star masses on their nucleosynthetic yields, and physics that is not well approximated in 1-D stellar models such as proton ingestion episodes and rotation. Based on a set of detailed AGB models, we suggest the abundance signature of HE 0414-0343 to have arisen from a >1.3 Msun mass AGB star and a late-time mass transfer, that transformed HE 0414-0343 into a CEMP-sC star. We also find the [Y/Ba] ratio well parametrizes the classification and can thus be used to easily classify any future such stars.

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High-resolution spectroscopic studies of ultra metal-poor stars found in LAMOST survey

We report on the observations of two ultra metal-poor (UMP) stars with [Fe/H]~-4.0 including one new discovery. The two stars are studied in the on-going and quite efficient project to search for extremely metal-poor (EMP) stars with LAMOST and Subaru. Detailed abundances or upper limits of abundances have been derived for 15 elements from Li to Eu based on high-resolution spectra obtained with Subaru/HDS. The abundance patterns of both UMP stars are consistent with the "normal-population" among the low-metallicity stars. Both of the two program stars show carbon-enhancement without any excess of heavy neutron-capture elements, indicating that they belong to the subclass of CEMP-no stars, as is the case of most UMP stars previously studied. The [Sr/Ba] ratios of both CEMP-no UMP stars are above [Sr/Ba]~-0.4, suggesting the origin of the carbon-excess is not compatible with the mass transfer from an AGB companion where the s-process has operated. Lithium abundance is measured in the newly discovered UMP star LAMOST J125346.09+075343.1, making it the second UMP turnoff star with Li detection. The Li abundance of LAMOST J125346.09+075343.1 is slightly lower than the values obtained for less metal-poor stars with similar temperature, and provides a unique data point at [Fe/H]~-4.2 to support the "meltdown" of the Li Spite-plateau at extremely low metallicity. Comparison with the other two UMP and HMP (hyper metal-poor with [Fe/H]<-5.0) turnoff stars suggests that the difference in lighter elements such as CNO and Na might cause notable difference in lithium abundances among CEMP-no stars.

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Discovery of a strongly r-process enhanced extremely metal-poor star LAMOST J110901.22+075441.8

We report the discovery of an extremely metal-poor (EMP) giant, LAMOST J110901.22+075441.8, which exhibits large excess of r-process elements with [Eu/Fe] ~ +1.16. The star is one of the newly discovered EMP stars identified from LAMOST low-resolution spectroscopic survey and the high-resolution follow-up observation with the Subaru Telescope. Stellar parameters and elemental abundances have been determined from the Subaru spectrum. Accurate abundances for a total of 23 elements including 11 neutron-capture elements from Sr through Dy have been derived for LAMOST J110901.22+075441.8. The abundance pattern of LAMOST J110901.22+075441.8 in the range of C through Zn is in line with the "normal" population of EMP halo stars, except that it shows a notable underabundance in carbon. The heavy element abundance pattern of LAMOST J110901.22+075441.8 is in agreement with other well studied cool r-II metal-poor giants such as CS 22892-052 and CS 31082-001. The abundances of elements in the range from Ba through Dy well match the scaled Solar r-process pattern. LAMOST J110901.22+075441.8 provides the first detailed measurements of neutron-capture elements among r-II stars at such low metallicity with [Fe/H]<-3.4, and exhibits similar behavior in the abundance ratio of Zr/Eu as well as Sr/Eu and Ba/Eu as other r-II stars.

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Spectroscopic analysis of metal-poor stars from LAMOST: early results

We report on early results from a pilot program searching for metal-poor stars with LAMOST and follow-up high-resolution observation acquired with the MIKE spectrograph attached to the Magellan~II telescope. We performed detailed abundance analysis for eight objects with iron abundances [Fe/H] < -2.0, including five extremely metal-poor (EMP; [Fe/H] < -3.0) stars with two having [Fe/H] < -3.5. Among these objects, three are newly discovered EMP stars, one of which is confirmed for the first time with high-resolution spectral observations. Three program stars are regarded as carbon-enhanced metal-poor (CEMP) stars, including two stars with no enhancement in their neutron-capture elements, which thus possibly belong to the class of CEMP-no stars; one of these objects also exhibits significant enhancement in nitrogen, and is thus a potential carbon and nitrogen-enhanced metal-poor star. The [X/Fe] ratios of the sample stars generally agree with those reported in the literature for other metal-poor stars in the same [Fe/H] range. We also compared the abundance patterns of individual program stars with the average abundance pattern of metal-poor stars, and find only one chemically peculiar object with abundances of at least two elements (other than C and N) showing deviations larger than 0.5dex. The distribution of [Sr/Ba] versus [Ba/H] agrees that an additional nucleosynthesis mechanism is needed aside from a single r-process. Two program stars with extremely low abundances of Sr and Ba support the prospect that both main and weak r-process may have operated during the early phase of Galactic chemical evolution. The distribution of [C/N] shows that there are two groups of carbon-normal giants with different degrees of mixing. However, it is difficult to explain the observed behavior of the [C/N] of the nitrogen-enhanced unevolved stars based on current data.

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Stellar abundances and presolar grains trace the nucleosynthetic origin of molybdenum and ruthenium

This work presents a large consistent study of molybdenum (Mo) and ruthenium (Ru) abundances in the Milky Way. These two elements are important nucleosynthetic diagnostics. In our sample of 71 Galactic metal-poor field stars, we detect Ru and/or Mo in 51 of these (59 including upper limits). The sample consists of high-resolution, high signal-to-noise spectra covering both dwarfs and giants from [Fe/H]=-0.63 down to -3.16. Thus we provide information on the behaviour of Mo I and Ru I at higher and lower metallicity than is currently known. We find a wide spread in the Mo and Ru abundances, which is typical of heavy elements. This indicates that several formation processes, in addition to high entropy winds, can be responsible for the formation of Mo and Ru. The formation processes are traced by comparing Mo and Ru to elements (Sr, Zr, Pd, Ag, Ba, and Eu) with known formation processes. We find contributions from different formation channels, namely p-, slow (s-), and rapid (r-) neutron-capture processes. Molybdenum is a highly convolved element that receives contributions from several processes, whereas Ru is mainly formed by the weak r-process as is silver. We also compare our absolute elemental stellar abundances to relative isotopic abundances of presolar grains extracted from meteorites. Their isotopic abundances can be directly linked to the formation process (e.g. r-only isotopes) providing a unique comparison between observationally derived abundances and the nuclear formation process. The comparison to abundances in presolar grains shows that the r-/s-process ratios from the presolar grains match the total elemental chemical composition derived from metal-poor halo stars with [Fe/H]~ -1.5 to -1.1 dex. This indicates that both grains and stars around and above [Fe/H]=-1.5 are equally (well) mixed and therefore do not support a heterogeneous presolar nebula... Abridged.

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The Hamburg/ESO R-process Enhanced Star survey (HERES) IX. Constraining pure r-process Ba/Eu abundance ratio from observations of r-II stars

The oldest stars born before the onset of the main s-process are expected to reveal a pure r-process Ba/Eu abundance ratio. We revised barium and europium abundances of selected very metal-poor (VMP) and strongly r-process enhanced (r-II) stars to evaluate an empirical r-process Ba/Eu ratio. Our calculations were based on non-local thermodynamic equilibrium (NLTE) line formation for Ba II and Eu II in the classical 1D MARCS model atmospheres. Homogeneous stellar abundances were determined from the Ba II subordinate and resonance lines by applying a common Ba isotope mixture. We used high-quality VLT/UVES spectra and observational material from the literature. For most investigated stars, NLTE leads to a lower Ba, but a higher Eu abundance. The resulting elemental ratio of the NLTE abundances amounts, on average, log(Ba/Eu) = 0.78+-0.06. This is a new constraint to pure r-process production of Ba and Eu. The obtained Ba/Eu abundance ratio of the r-II stars supports the corresponding Solar System r-process ratio as predicted by recent Galactic chemical evolution calculations of Bisterzo, Travaglio, Gallino, Wiescher, and Kappeler. We present the NLTE abundance corrections for lines of Ba II and Eu II in the grid of VMP model atmospheres.

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Metal-Poor Stars Observed with the Magellan Telescope II. Discovery of Four Stars with [Fe/H] < -3.5

We report on the discovery of seven low-metallicity stars selected from the Hamburg/ESO Survey, six of which are extremely metal-poor ([Fe/H]<-3.0), with four having [Fe/H]<-3.5. Chemical abundances or upper limits are derived for these stars based on high-resolution (R~35,000) Magellan/MIKE spectroscopy, and are in general agreement with those of other very and extremely metal-poor stars reported in the literature. Accurate metallicities and abundance patterns for stars in this metallicity range are of particular importance for studies of the shape of the metallicity distribution function of the Milky Way's halo system, in particular for probing the nature of its low-metallicity tail. In addition, taking into account suggested evolutionary mixing effects, we find that six of the program stars (with [Fe/H]<-3.35) possess atmospheres that were likely originally enriched in carbon, relative to iron, during their main-sequence phases. These stars do not exhibit over-abundances of their s-process elements, and hence may be additional examples of the so-called CEMP-no class of objects.

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Normal and Outlying Populations of the Milky Way Stellar Halo at [Fe/H] < -2

From detailed abundance analysis of >100 Hamburg/ESO candidate extremely metal-poor (EMP) stars we find 45 with [Fe/H] < -3.0 dex. We identify a heretofore unidentified group: Ca-deficient stars, with sub-solar [Ca/Fe] ratios and the lowest neutron-capture abundances; the Ca-deficient group comprises ~ 10% of the sample, excluding Carbon stars. Our radial velocity distribution shows that the carbon-enhanced stars with no s-process enhancements, CEMP-no, and which do not show C2 bands are not preferentially binary systems. Ignoring Carbon stars, approximately 15% of our sample are strong (> 5 sigma) outliers in one, or more, elements between Mg and Ni; this rises to ~19% if very strong (>10 sigma) outliers for Sr and Ba are included. Examples include: HE0305-0554 with the lowest [Ba/H] known; HE1012-1540 and HE2323-0256, two (non-velocity variable) C-rich stars with very strong [Mg,Al/Fe] enhancements; and HE1226-1149 an extremely r-process rich star.

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