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O. A. Dobush

Publications and source records attributed to O. A. Dobush.

23 records · Page 2Linked to original sources

A phase transition in a Curie-Weiss system with binary interactions

A single-sort continuum Curie-Weiss system of interacting particles is studied. The particles are placed in the space $\mathbb{R}^d$ divided into congruent cubic cells. For a region $V\subset \mathbb{R}^d$ consisting of $N\in \mathbb{N}$ cells, every two particles contained in $V$ attract each other with intensity $J_1/N$. The particles contained in the same cell are subjected to binary repulsion with intensity $J_2>J_1$. For fixed values of the temperature, the interaction intensities, and the chemical potential the thermodynamic phase is defined as a probability measure on the space of occupation numbers of cells, determined by a condition typical of Curie-Weiss theories. It is proved that the half-plane $J_1\,\times\,$\textit{chemical potential} contains phase coexistence points at which there exist two thermodynamic phases of the system. An equation of state for this system is obtained.

math-ph↗

Phase behavior of a cell fluid model with modified morse potential

The present manuscript gives a theoretical description of the first-order phase transition in a cell fluid model with a modified Morse potential and additional repulsive interaction. In the framework of the grand canonical ensemble, the equation of state of the system in terms of chemical potential-temperature and terms of density-temperature is calculated for a wide range of density and temperature. The behavior of the chemical potential as a function of temperature and density is investigated. The maximum and minimum admissible values of the chemical potential, which approach each other with decreasing temperature, are exhibited. The existence of a liquid-gas phase transition in a limited temperature range below the critical $T_c$ is established.

cond-mat.stat-mech↗

The equation of state of a cell fluid model in the supercritical region

The analytic method for deriving the equation of state of a cell fluid model in the region above the critical temperature ($T \geqslant T_\text{c}$) is elaborated using the renormalization group transformation in the collective variables set. Mathematical description with allowance for non-Gaussian fluctuations of the order parameter is performed in the vicinity of the critical point on the basis of the $ρ^4$ model. The proposed method of calculation of the grand partition function allows one to obtain the equation for the critical temperature of the fluid model in addition to universal quantities such as critical exponents of the correlation length. The isothermal compressibility is plotted as a function of density. The line of extrema of the compressibility in the supercritical region is also represented.

cond-mat.stat-mech↗

Using a fluid cell model for description of a phase transition in simple liquid alkali metals

This article embraces a theoretical description of the first order phase transition in liquid metals with application of a cell fluid model. The results are obtained through calculation of the grand partition function without usage of phenomenological parameters. The Morse potential is used for calculation of the equation of state and the coexistence curve. Specific results for sodium and potassium are obtained. Comparison of outcome of analytical expressions with data of computer simulations is presented.

cond-mat.stat-mech↗

Phase transition in a cell fluid model

We propose a method of describing a phase transition in a cell fluid model with pair interaction potential that includes repulsive and attractive parts. An exact representation of the grand partition function of this model is obtained in the collective variables set. The behavior of the system at temperatures below and above the critical one is explored in the approximation of a mean-field type. An explicit analytic form of the equation of state which is applicable in a wide range of temperatures is derived, taking into account an equation between chemical potential and density. The coexistence curve, the surface of the equation of state and the phase diagram of the cell Morse fluid are plotted.

cond-mat.stat-mech↗