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O. D. McGinnis

Publications and source records attributed to O. D. McGinnis.

2 recordsLinked to original sources

The influence of the binding energy on Compton-scattering-driven ionization

We present a comprehensive study of Compton scattering of 20 keV photons by bound electrons over a wide range of binding energies (Ne 2p, Ne 2s, C 1s, O 1s, and Ne 1s orbitals). In particular, we have measured fully differential cross sections, i.e., electron angular distributions with respect to the direction of the photon momentum transfer for fixed electron energy. Our data show strong deviations from the predictions of the ''quasi-free'' electron approximation. The binding energy and the shape of the Coulomb potential from which the electron escapes both play a significant role in its kinematics. We find that Compton electrons are scattered and even back-reflected by the ionic potential. The strength of this effect depends on the orbital from which the electron is ejected.

physics.atom-ph↗

Selective Bond Breaking in CO$_2^{2+}$ Induced by Photoelectron Recoil

After core-ionization of CO$_2$, typically an Auger-Meitner decay takes place, leading to the formation of a dicationic molecule that may dissociate into CO$^+$ and O$^+$. We demonstrate experimentally that the recoil momentum of the photoelectron steers, which of the two equivalent bonds breaks during the dissociation. At 20 keV photon energy, we observe an asymmetry of up to 25% for bond cleavage that depends on the emission direction of the photoelectron. Furthermore, we show that this effect leads to a significant nondipole effect in molecular dissociation in the laboratory frame: O$^+$ fragments are more likely to be emitted in the direction opposite to the light propagation than along it.

physics.atom-ph↗