arXiv subjects

O. Sipilä

Publications and source records attributed to O. Sipilä.

At least 19 recordsLinked to original sources

arXiv2026

Corona Australis 151: an extremely young protostar

Context. Prestellar cores are the birthplace of stars and planetary systems, but they are short-lived objects, since the initial stages of dense core evolution, collapse, and the formation of a protostellar seed are fast. In an effort to build a catalogue of bona-fide prestellar cores in the Solar neighbourhood, we used APEX observations to identify dynamically evolved cores among dense cores observed with Herschel. One of them, Corona Australis 151, stood out because of its centrally peaked structure, with densities above 1e7cm-3 in the central 500-1000 au, and high deuteration levels (N2D+/N2H+~0.5), suggestive of an evolved, prestellar stage. Aims. Corona Australis 151 appears to be an evolved prestellar core, but the presence of broad wings in some of the detected lines and a tentative 70micron detection with Herschel partially challenges its prestellar stage. We intend to assess its evolutionary stage. Methods. We analyse new ALMA data of the continuum emission and of several line tracers (including typical outflow tracers) at a resolution of~150-200au, tracing the envelope. Results. We unveil the presence of a compact and young outflow (projected dynamical age:~500yr), traced by SiO, CO, and H2CO emission. The continuum emission traces an envelope structure of size~1000 au and mass 0.33M_sun(assuming Tdust=20 K). Conclusions. Corona Australis 151 is an extremely young protostar, possibly one of the youngest known in the Solar neighbourhood, and hence a new laboratory to study the chemical and dynamical evolution at the dawn of star formation.

astro-ph.GA↗

arXiv2026

High $^{12}$C/$^{13}$C isotopic ratios toward G+0.693-0.027: evidence for gas inflow to the Central Molecular Zone

Isotopic ratios are key tracers of Galactic chemical evolution because different isotopes are synthesized through distinct stellar nucleosynthesis processes. While the $^{12}$C/$^{13}$C ratio increases with galactocentric distance across the Galactic disc, measurements in the Central Molecular Zone (CMZ) have historically yielded low values ($\sim$3-30), often affected by high optical depths. We aim to determine the initial $^{12}$C/$^{13}$C ratio of the parent material of the CMZ molecular cloud G+0.693$-$0.027 using optically thin molecular tracers and correcting for isotopic fractionation. We analyzed an ultra-high-sensitivity spectral survey obtained with the IRAM 30m and Yebes 40m telescopes, detecting single and double $^{13}$C isotopologues of HC$_3$N and HC$_5$N. Column densities and isotopic ratios were derived and compared with astrochemical models including $^{13}$C- and $^{15}$N-isotopologues to quantify isotopic fractionation. We derive $^{12}$C/$^{13}$C ratios of $36.7\pm1.0$ for HC$_3$N (using double $^{13}$C isotopologues) and $38.8\pm1.5$ for HC$_5$N, significantly higher than previous CMZ estimates based on simpler molecules. The models indicate low to intermediate isotopic fractionation at early times ($<3\times10^4$ yr), implying an initial $^{12}$C/$^{13}$C ratio of $\sim$48 for the gas from which present-day CMZ molecular clouds formed. The inferred range (37-48) is consistent with values observed at Galactocentric distances of 3-5 kpc, supporting a scenario in which the CMZ is replenished by gas inflows from the Galactic disc driven by the Galactic bar, with a possible contribution from less chemically processed material accreted from external systems such as dwarf galaxies.

astro-ph.GA↗

arXiv2026

Tracing the sulfur depletion in starless and pre-stellar cores

Sulfur is one of the most abundant elements in the Universe, yet the sulfur budget inferred from the observed sulfur-bearing molecules in dense cores is significantly lower than expected. Starless and pre-stellar cores represent the earliest stages of star formation and provide a laboratory for studying the physical and chemical processes that cause sulfur depletion. We aim to constrain sulfur chemistry in dense cores by measuring abundances of sulfur-bearing molecules and how they reflect core evolution and environmental effects. We observed nine cores in the Taurus Molecular Cloud, targeting 13 sulfur-bearing molecules, including CS, CCS, C$_3$S, OCS, SO, SO$_2$, H$_2$CS, and isotopologs. Molecular abundances and six abundance ratios were compared to three evolutionary tracers: H$_2$ column density, N$_2$D$^+$/N$_2$H$^+$, and the CO depletion factor. We also compared observations with 0D chemical models with different initial sulfur abundances. We find variations in abundances across cores. L1517B exhibits low abundances and a high depletion factor, whereas L1495B shows enhanced levels in oxygen-bearing species within the L1495 filament. Ratios tracing carbon- and oxygen-bearing species (CCS/$^{34}$SO and C$^{34}$S/$^{34}$SO) decrease with increasing H$_2$ column density and N$_2$D$^+$/N$_2$H$^+$ ratio. Other species and ratios show weak or no correlation with tracers. Models reproduce OCS, H$_2$CS, and HDCS reasonably well, but not all species simultaneously, especially between carbon- and oxygen-bearing molecules. The variations and lack of consistent correlations suggest that a single evolutionary parameter cannot describe sulfur chemistry and that the local environmental conditions strongly influence the observed abundances. Reproducing the full sample of sulfur-bearing molecules would require improved chemical networks and models that account for the core's physical structure.

astro-ph.GA↗

arXiv2026

Modeling the UV-photon irradiation of CS$_2$-bearing ices in the laboratory with the pyRate gas-grain astrochemical code. New insights into the missing sulfur problem

Observations indicate that the total abundance of S-bearing species in dense clouds is orders of magnitude lower than the cosmic sulfur abundance. Addressing this "missing sulfur problem" requires a combination of astronomical observations, laboratory experiments, and theoretical models. In this work, we use the pyRate astrochemical model to simulate the VUV photon irradiation of a CO$_2$:CS$_2$ ice mixture at 10 K in the laboratory, with the goal of supporting the interpretation of the experimental results and testing our current understanding of the sulfur evolution in interstellar ices. For this purpose, the astrochemical model was adapted to the experimental conditions, and the chemical network was compiled from several sources to ensure that all known reactions involving sulfur species were included. The results indicate that nondiffusive chemistry is necessary to reproduce the formation of S-bearing species observed in the experiment. However, some discrepancies were found in the major S-bearing ice chemistry products predicted by the model and the experiment. The compounds OCS, CS, and SO are overpredicted by the model, while it falls short in accounting for $\rm SO_2$ and sulfur allotropes. These discrepancies are likely due to a combination of an incomplete knowledge of the chemical reactions at play (either because of missing reactions and/or because of unconstrained reaction barriers), and uncertainties in the experimental analysis. This work represents the first effort to model the chemistry of a multicomponent ice analog with a rate-equation based code, and highlights the complementary nature of theoretical and experimental astrochemistry to disentangle the chemical evolution of sulfur in the interstellar medium.

astro-ph.GA↗

arXiv2026

A 3D physico-chemical model of a pre-stellar core. II. Dynamic chemical evolution in a pre-stellar core model using tracer particles

This work explores the differences between static and dynamically evolving physico-chemical models of pre-stellar cores. A 3D MHD model of a pre-stellar core embedded in a dynamic star-forming cloud is post-processed using sequentially dust radiative transfer, a gas-grain chemical model, and a non-LTE line-radiative transfer model. The chemical evolution is modeled along $\sim$20,000 tracer particle trajectories to capture the impact of a realistic dynamical evolution as the core is formed. The emission morphology of CH$_3$OH and $c$-C$_3$H$_2$ and the intensities of CH$_3$OH, $c$-C$_3$H$_2$, CS, SO, HCN, HCO$^+$ and N$_2$H$^+$ are compared with observations of L1544. Our results show a distinct difference in chemical morphology between the dynamical and static models. The dynamical model reproduces the observed spatial distribution of CH$_3$OH and $c$-C$_3$H$_2$ toward L1544, whereas the static model fails to reproduce this morphology. In contrast, when comparing modeled and observed intensities across a broad range of molecules, the static model shows good agreement with observations for L1544. The dynamical model systematically predicts lower abundances and modeled intensities for six of the seven species presented here. For sulphur-bearing species, the intensities are in better agreement with observations when the initial abundances are undepleted in heavier elements. This study reveals distinct differences between dynamical and static physico-chemical models. The static model predicts higher abundances and intensities for the majority of the molecules studied here, compared with the dynamical model. This discrepancy may stem from the specific choices of initial conditions, which could limit the dynamical models ability to fully capture the physical and chemical history. The intensities predicted by the static model are comparable to those observed toward L1544.

astro-ph.SR↗

arXiv2026

Deuteration of HC3N and CH3CCH in the pre-stellar core L1544

Deuterated molecules are a useful diagnostic tool to probe the evolution and the kinematics in the earliest stages of star formation. Due to the low temperatures and high densities in the centre of pre-stellar cores, the deuterium fraction is enhanced by several orders of magnitude. We study the distribution of the emission and the deuteration of the two carbon chains HC3N and CH3CCH throughout the pre-stellar core L1544. We analyse emission maps of CH3CCH, CH2DCCH, CH3CCD, HC3N, HCC13CN, and DC3N, observed with the IRAM 30m single-dish radio telescope. We use non-LTE radiative transfer calculations, combined with chemical modelling of the molecular abundances, to constrain physical parameters of the observed species. Following this, we derive the column density and deuteration maps. We find D-fractions of N(DC3N)/N(HC3N)=0.04-0.07, N(CH2DCCH)/N(CH3CCH)=0.09-0.15, and N(CH3CCD)/N(CH3CCH)=0.07-0.09. The deuteration of HC3N appears homogeneous across the core, with widespread D-fraction values above 0.06, tracing intermediate-density gas in the outer layers of the core. CH3CCD is most efficiently formed in the higher-density regions towards the core centre, while the D-fraction of CH2DCCH traces a local density enhancement in the north-east of the core, coinciding with the CH3OH emission peak. The results suggest that gas-phase reactions dominate the formation and deuteration of both HC3N and CH3CCH in L1544, with spatial variations driven by physical structure, density and external radiation. The significantly higher D-fraction of CH2DCCH compared to CH3CCD and a tentative gradient with higher values in the north suggest different deuteration mechanisms for the two functional groups. Similarities between the CH2DCCH emission and CH2DOH might indicate an additional deuteration pathway of CH3CCH on the surfaces of dust grains, as observed for H2CO.

astro-ph.GA↗

arXiv2026

New Estimate for the Cosmic Ray-Induced $\rm H_2$ Photodissociation Rate in the Interstellar Medium

In the interstellar medium, cosmic rays (CRs) generate a field of ultraviolet (UV) photons via the excitation and subsequent radiative decay of $\rm H_2$ molecules. This UV field is a major agent of ionization and dissociation in the inner regions of molecular clouds that are shielded from the effects of the interstellar radiation field. In particular, the dissociation of $\rm H_2$, by far the most abundant molecule in interstellar clouds, leads to the production of atomic hydrogen which then takes part in the production of a multitude of molecules, in particular complex organics on the surfaces of interstellar dust grains. Precise knowledge of the rates of CR-induced dissociation processes is thus crucial for constructing reliable chemical models. For the present paper, we have derived a new value of $k_{\rm diss, CR}(\mbox{$\rm H_2$})=0.831ζ$ for the rate of $\rm H_2$ dissociation, where $ζ$ is the CR ionization rate of $\rm H_2$. This prediction contrasts a previous value from the Leiden database which overestimated the rate due to an inconsistent treatment of the $\rm H_2$ abundances and photodissociation cross sections. By running a series of chemical models, we show that the overestimated dissociation rate has a large effect on the results of chemical simulations, with the abundance of methanol being overestimated by over one order of magnitude. Hence, we strongly recommend the adoption of our new estimate $k_{\rm diss, CR}(\mbox{$\rm H_2$})=0.831ζ$ in all chemical models that include this process. Our newly derived value corresponds to $\rm H_2$ being purely in the para form ($J^{\prime\prime} = 0$). However, in the interiors of molecular clouds the $\rm H_2$ ortho-to-para ratio is low and using the rate for para-$\rm H_2$ is an adequate approximation.

astro-ph.GA↗

arXiv2025

High deuteration of methanol in L1544

Isotopic fractionation is a very powerful tool to follow the evolution of material from one stage to the next in the star-formation process. Pre-stellar cores exhibit some of the highest levels of deuteration because their physical conditions greatly favor deuteration processes. Deuteration maps are a measure of the effectiveness of the deuteration across the core, and they are useful to study both the deuteration as well as the formation mechanism of the main species. Methanol is the simplest O-bearing complex organic molecule (COM) detected in the interstellar medium (ISM). It represents the beginning of molecular complexity in star-forming regions, thus a complete understanding of its formation and deuteration is a necessary step to understand the development of further chemical complexity. In this paper, we use single-dish observations with the IRAM 30 m telescope and state-of-the-art chemical models to investigate the deuteration of methanol towards the prototypical pre-stellar core L1544. We also compare the results of the chemical models with previous observations of deuterated methanol towards the pre-stellar cores HMM1 and L694-2. The spectra extracted from the CHD$_2$OH map show that the emission is concentrated in the center and towards the north-west of the core. Using deep observations towards the dust and the methanol peaks of the core, we derive a very large deuterium fraction for methanol ($\sim20\%$) towards both peaks. The comparison of our observational results with chemical models has highlighted the importance of H-abstraction processes in the formation and deuteration of methanol. Deep observations combined with state-of-the-art chemical models are of fundamental importance in understanding the development of molecular complexity in the ISM. Our analysis also shows the importance of non-LTE effects when measuring the D/H ratios in methanol.

astro-ph.GA↗

arXiv2025

Hunting pre-stellar cores with APEX: overview

[Abridged] $Context.$ Pre-stellar cores are centrally concentrated starless cores on the verge of star formation and they represent the initial conditions for star and planet formation. Pre-stellar cores host an active organic chemistry and isotopic fractionation, kept stored into thick icy mantles, which can be inherited by the future protoplanetary disks and planetesimals. So far, only a few have been studied in detail, with special attention being paid to L1544 in the Taurus Molecular Cloud. $Aims.$ The aim is to identify nearby ($<$200 pc) pre-stellar cores in an unbiased way, to build a sample that can then be studied in detail. $Methods.$ We first used the Herschel Gould Belt Survey archival data, selecting all those starless cores with central H$_2$ number densities higher than or equal to 3$\times$10$^5$ cm$^{-3}$, the density of L1544 within the Herschel beam. The selected 40 (out of 1746) cores have then been observed in N$_2$H$^+$(3-2) and N$_2$D$^+$(4-3) using the APEX antenna. $Results.$ A total of 17 bona-fide (i.e., with a deuterium fraction larger than 10%) pre-stellar cores have been identified. Other 16 objects can also be considered pre-stellar, as they are dynamically evolved starless cores, but their deuterium fraction is relatively low ($<$10%). The remaining 7 objects have been found associated with very young stellar objects. $Conclusions.$ Dust continuum emission, together with spectroscopic observations of N$_2$H$^+$(3-2) and N$_2$D$^+$(4-3), is a powerful tool to identify pre-stellar cores in molecular clouds. Detailed modeling of the physical structure of the objects is now required for reconstructing the chemical composition as a function of radius. This work has provided a statistically significant sample of 33 pre-stellar cores, a crucial step in the understanding of the process of star and planet formation.

astro-ph.GA↗

arXiv2025

High sensitivity molecular line observations towards the L1544 pre-stellar core challenge current models

The increased sensitivity and spectral resolution of observed spectra towards the pre-stellar core L1544 are challenging the current physical and chemical models. With the aim of further constraining the structure of L1544 as well as assessing the completeness of chemical networks, we turn to radiative transfer modelling of observed molecular lines towards this source. We obtained high-sensitivity and high-spectral resolution observations of HCO+ (J = 1 - 0), CS (J = 2 - 1), C34S (J = 2 - 1), H2CO (J ,Ka,Kc = 2,1,2 - 1,1,1), c-C3H2 (J,Ka,Kc = 2,1,2 - 1,0,1), SO (N,J = 2,3 - 1,2) and 34SO (N,J = 2,3 - 1,2) with the IRAM 30m telescope towards the dust peak of L1544. A non-Local Thermodynamic Equilibrium radiative transfer code is coupled to the Markov Chain Monte Carlo method to model the observations. We find that with just one transition for each isotope, the modelling cannot find a global minimum that fits the observations. The derived fractional abundance profiles are compared to those computed with chemical models. The observed transitions trace gas components with distinct dynamics at different distances along the radius of the core. Moreover, the results evidence a poor reproduction of sulphur chemistry by chemical modelling and stresses the need to include a more consistent S-depletion process to accurately reproduce the S-chemistry towards dense cores.

astro-ph.GA↗

arXiv2025

Chemical segregation analysed with unsupervised clustering

Molecular emission is a powerful tool for studying the physical and chemical structures of dense cores. The distribution and abundance of different molecules provide information on the chemical composition and physical properties in these cores. We study the chemical segregation of three molecules (c-C$_3$H$_2$, CH$_3$OH, CH$_3$CCH) in the starless cores B68 and L1521E, and the prestellar core L1544. We applied the density-based clustering algorithms DBSCAN and HDBSCAN to identify chemical and physical structures within these cores. To enable cross-core comparisons, the input samples were characterised based on their physical environment, discarding the 2D spatial information. The clustering analysis showed significant chemical differentiation across the cores, successfully reproducing the known molecular segregation of c-C$_3$H$_2$ and CH$_3$OH in all three cores. Furthermore, it identifies a segregation between c-C$_3$H$_2$ and CH$_3$CCH, which is not apparent from the emission maps. Key features driving the clustering are integrated intensity, velocity offset, H$_2$ column density, and H$_2$ column density gradient. Different environmental conditions are reflected in the variations in the feature relevance across the cores. This study shows that density-based clustering provides valuable insights into chemical and physical structures of starless cores. It demonstrates that already small datasets of two or three molecules can yield meaningful results. This new approach revealed similarities in the clustering patterns of CH$_3$OH and CH$_3$CCH relative to c-C$_3$H$_2$, suggesting that c-C$_3$H$_2$ traces regions of lower density than to the other two molecules. This allowed for insight into the CH$_3$CCH peak in L1544, which appears to trace a landing point of chemically fresh gas that is accreted to the core, highlighting the impact of accretion processes on molecular distributions.

astro-ph.GA↗

arXiv2025

The Effect of Weak Cosmic Ray Heating Events on the Desorption of $\rm H_2$

The typical amount of molecular hydrogen (${\rm H_2}$) in interstellar ices is not known, but significant freeze-out of ${\rm H_2}$ on dust grains is not expected. However, chemical models ubiquitously predict large amounts of $\rm H_2$ freeze-out in dense cloud conditions, and specialized treatments are needed to control the $\rm H_2$ population on grains. Here we present a numerical desorption model where the effect of weak heating events induced by cosmic rays (CRs) that heat grains to temperatures of a few tens of Kelvin at high frequencies is included, improving upon earlier desorption models that only consider strong heating events (maximum grain temperature close to 100 K) that occur at a low frequency. A temperature of a few tens of Kelvin is high enough to induce efficient desorption of $\rm H_2$, but we find that even the weak heating events do not occur often enough to lead to significant $\rm H_2$ desorption. Taking the weak heating events into account does affect the predicted abundances of other lightly-bound species, but the effect is restricted to low column densities. We make here the canonical assumption that the grains are spherical with a radius of 0.1 $μ$m. It is conceivable that in the case of a grain size distribution, weak heating events could provide a boost to $\rm H_2$ desorption coming off small grains, which are the most numerous. Further studies are still required to better quantify the role of CRs in the desorption of $\rm H_2$ and other weakly bound species.

astro-ph.GA↗

arXiv2025

PRODIGE - envelope to disk with NOEMA: V. Low 12C/13C ratios for CH3OH and CH3CN in hot corinos

The 12C/13C isotope ratio has been derived towards numerous cold clouds (20-50 K) and a couple protoplanetary disks and exoplanet atmospheres. However, direct measurements of this ratio in the warm gas (>100 K) around young low-mass protostars remain scarce, but are required to study its evolution during star and planet formation. We derived 12C/13C ratios from the isotopologues of the complex organic molecules (COMs) CH3OH and CH3CN in the warm gas towards seven Class 0/I protostellar systems to improve our understanding of the evolution of the 12C/13C ratios during star and planet formation. We used the data that were taken as part of the PRODIGE large program with the NOEMA at 1mm. The emission of CH3OH and CH3CN is spatially unresolved in the PRODIGE data (300au scale). Derived rotational temperatures exceed 100K, telling us that they trace the gas of the hot corino, where CH3CN probes hotter regions than CH3OH on average (290 K versus 180 K). The column density ratios between the 12C and 13C isotopologues, derived from LTE analysis, range from 4 to 30, thus, are significantly lower than the expected local ISM isotope ratio of about 68. Assuming that CH3CN and CH3OH may inherit the 12C/13C ratio from their precursor species, astrochemical models were conducted for the latter and compared with our observational results. We conclude that an enrichment in 13C in COMs at the earliest protostellar stages is likely inherited from the COMs' precursor species, whose 12C/13C ratios are set during the prestellar stage via isotopic exchange reactions. This also implies that low 12C/13C ratios observed at later evolutionary stages could at least partially be inherited. A final conclusion on 12C/13C ratios in protostellar environments requires improved observations to tackle current observational limitations and additional modelling efforts.

astro-ph.GA↗

arXiv2025

Hunting pre-stellar cores with APEX: Corona Australis 151, the densest pre-stellar core or the youngest protostar?

Context. Pre-stellar cores are the birthplaces of Sun-like stars and represent the initial conditions for the assembly of protoplanetary systems. Due to their short lifespans, they are rare. In recent efforts to increase the number of such sources identified in the Solar neighbourhood, we have selected a sample of 40 starless cores from the publicly available core catalogs of the Herschel Gould Belt survey. In this work, we focus on one of the sources that stands out for its high central density: Corona Australis 151. Aims. We use molecular lines that trace dense gas (n>=10^6 cm-3) to confirm the exceptionally high density of this object, to study its physical structure, and to understand its evolutionary stage. Methods. We detected the N2H+ 3-2 and 5-4 transitions, and the N2D+ 3-2, 4-3, and 6-5 lines with the APEX telescope. We use the Herschel continuum data to infer a spherically symmetric model of the core's density and temperature. This is used as input to perform non-local-thermodynamic-equilibrium radiative transfer to fit the observed five lines. Results. Our analysis confirms that this core is characterised by very high densities (a few x 10^7 cm-3 at the centre) and cold temperatures. We infer a high deuteration level of N2D+/N2H+=0.50, indicative of an advanced evolutionary stage. In the large bandwidth covered by the APEX data, we detect several other deuterated species, including CHD2OH, D2CO, and ND3. We also detect multiple sulphurated species that present broader lines with signs of high-velocity wings. Conclusions. The observation of high-velocity wings and the fact that the linewidths of N2H+ and N2D+ become larger with increasing frequency can be interpreted either as an indication of supersonic infall motions developing in the central parts of a very evolved pre-stellar core or as the signature of outflows from a very low luminosity object (VeLLO). *SHORTENED*

astro-ph.SR↗

arXiv2024

Hunting pre-stellar cores with APEX: IRAS16293E (Oph464)

Pre-stellar cores are the first steps in the process of star and planet formation. However, the dynamical and chemical evolution of pre-stellar cores is still not well understood. We aim at estimating the central density of the pre-stellar core IRAS16293E and at carrying out an inventory of molecular species towards the density peak of the core. We observed high-$J$ rotational transitions of N$_2$H$^+$ and N$_2$D$^+$, and several other molecular lines towards the dust emission peak using the Atacama Pathfinder EXperiment (APEX) telescope, and derived the density and temperature profiles of the core using far-infrared surface brightness maps from $Herschel$. The N$_2$H$^+$ and N$_2$D$^+$ lines were analysed by non-LTE radiative transfer modelling. Our best-fit core model consists in a static inner region, embedded in an infalling envelope with an inner radius of approximately 3000 au (21" at 141 pc). The observed high-J lines of N$_2$H$^+$ and N$_2$D$^+$ (with critical densities greater than 10$^6$ cm$^{-3}$) turn out to be very sensitive to depletion; the present single-dish observations are best explained with no depletion of N$_2$H$^+$ and N$_2$D$^+$ in the inner core. The N$_2$D$^+$/N$_2$H$^+$ ratio that best reproduces our observations is 0.44, one of the largest observed to date in pre-stellar cores. Additionally, half of the molecules that we observed are deuterated isotopologues, confirming the high-level of deuteration towards this source. Non-LTE radiative transfer modelling of N$_2$H$^+$ and N$_2$D$^+$ lines proved to be an excellent diagnostic of the chemical structure and dynamics of a pre-stellar core. Probing the physical conditions immediately before the protostellar collapse is a necessary reference for theoretical studies and simulations with the aim of understanding the earliest stages of star and planet formation and the time scale of this process.

astro-ph.GA↗

arXiv2024

Impact of ice growth on the physical and chemical properties of dense cloud cores

We investigated the effect of time-dependent ice growth on dust grains on the opacity and hence on the dust temperature in a collapsing molecular cloud core, with the aim of quantifying the effect of the dust temperature variations on ice abundances as well as the evolution of the collapse. We employed a one-dimensional collapse model that self-consistently and time-dependently combines hydrodynamics with chemical and radiative transfer simulations. The dust opacity was updated on-the-fly based on the ice growth as a function of location in the core. The results of the fully dynamical model were compared against simulations assuming fixed ice thickness. We found that the ice thickness increases fast and reaches a saturation value of approximately 90 monolayers in the central core (volume density $\sim$$10^4\,\rm cm^{-3}$), and several tens of monolayers at a volume density of $\sim$$10^3\,\rm cm^{-3}$, after only a few $10^5\,\rm yr$ of evolution. The results thus exclude the adoption of thin ($\sim$10 monolayer) ices in molecular cloud simulations except at very short timescales. The differences in abundances and dust temperature between the fully dynamic simulation and those with fixed dust opacity are small; abundances change between the solutions generally within a factor of two. The assumptions on the dust opacity do have an effect on the collapse dynamics through the influence of the photoelectric effect on the gas temperature, and the simulations take a different time to reach a common central density. In conclusion, carrying out chemical simulations using a dust temperature corresponding to a fixed opacity seems to be a good approximation. Still, although at least in the present case its effect on the overall results is limited - as long as the grains are monodisperse - ice growth should be considered to obtain the most accurate representation of the collapse dynamics.

astro-ph.GA↗

arXiv2024

Fractionation in young cores: Direct determinations of nitrogen and carbon fractionation in HCN

We aim to determine the $^{14}$N/$^{15}$N and $^{12}$C/$^{13}$C ratios for HCN in six starless and prestellar cores and compare the results between the direct method using radiative transfer modeling and the indirect double isotope method assuming a fixed $^{12}$C/$^{13}$C ratio. We present IRAM 30m observations of the HCN 1-0, HCN 3-2, HC15N 1-0 and H13CN 1-0 transitions toward six embedded cores. The ${}^{14}$N/${}^{15}$N ratio was derived using both the indirect double isotope method and directly through non-local thermodynamic equilibrium (NLTE) 1D radiative transfer modeling of the HCN emission. The latter also provides the ${}^{12}$C/${}^{13}$C ratio, which we compared to the local interstellar value. The derived ${}^{14}$N/${}^{15}$N ratios using the indirect method are generally in the range of 300-550. This result could suggest an evolutionary trend in the nitrogen fractionation of HCN between starless cores and later stages of the star formation process. However, the direct method reveals lower fractionation ratios of around $\sim$250, mainly resulting from a lower ${}^{12}$C/${}^{13}$C ratio in the range $\sim$20-40, as compared to the local interstellar medium value of 68. This study reveals a significant difference between the nitrogen fractionation ratio in HCN derived using direct and indirect methods. This can influence the interpretation of the chemical evolution and reveal the pitfalls of the indirect double isotope method for fractionation studies. However, the direct method is challenging, as it requires well-constrained source models to produce accurate results. No trend in the nitrogen fractionation of HCN between earlier and later stages of the star formation process is evident when the results of the direct method are considered.

astro-ph.GA↗

arXiv2024

Deuterium fractionation in cold dense cores in the low-mass star forming region L1688

In this work, we study deuterium fractionation in four starless cores in the low-mass star-forming region L1688 in the Ophiuchus molecular cloud. We study how the deuterium fraction ($R_D$) changes with environment, compare deuteration of ions and neutrals, core centre and its envelope, and attempt to reproduce the observed results with a gas-grain chemical model. We chose high and low gas density tracers to study both core centre and the envelope. With the IRAM 30m antenna, we mapped N$_2$H$^+$(1-0), N$_2$D$^+$(1-0), H$^{13}$CO$^+$ (1-0) and (2-1), DCO$^+$(2-1), and $p$-NH$_2$D(1$_{11}$-1$_{01}$) towards the chosen cores. The missing $p$-NH$_3$ and N$_2$H$^+$(1-0) data were taken from the literature. To measure the molecular hydrogen column density, dust and gas temperature within the cores, we used the Herschel/SPIRE dust continuum emission data, the GAS survey data (ammonia), and the COMPLETE survey data to estimate the upper limit on CO depletion. We present the deuterium fraction maps for three species towards four starless cores. Deuterium fraction of the core envelopes traced by DCO$^+$/H$^{13}$CO$^+$ is one order of magnitude lower ($\sim$0.08) than that of the core central parts traced by the nitrogen-bearing species ($\sim$0.5). Deuterium fraction increases with the gas density as indicated by high deuterium fraction of high gas density tracers and low deuterium fraction of lower gas density tracers and by the decrease of $R_D$ with core radii, consistent with the predictions of the chemical model. Our model results show a good agreement with observations for $R_D$(N$_2$D$^+$/N$_2$H$^+$) and R$_D$(DCO$^+$/HCO$^+$) and underestimate the $R_D$(NH$_2$D/NH$_3$).

astro-ph.GA↗