arXiv subjects

Oleg Gendelman

Publications and source records attributed to Oleg Gendelman.

28 records · Page 2Linked to original sources

arXiv2015

A Generalized Electrowetting Equation: Its Derivation and Consequences

The thermodynamics of electrowetting is treated. A general equation of electrowetting is derived from the first principles. It is demonstrated that the well-known Lippmann Equation describes a particular case of electrowetting when the radial derivative of the capacitance of the double layer is constant. The apparent contact angle of electrowetting depends on the gradient of capacity of a double layer in the vicinity of the triple line. The role of the area adjacent to the triple line in constituting the equilibrium apparent contact angle of electrowetting is emphasized.

physics.chem-ph↗

arXiv2015

Elastic Properties of Liquid Surfaces Coated with Colloidal Particles

The physical mechanism of elasticity of liquid surfaces coated with colloidal particles is proposed. It is suggested that particles are separated by water clearings and the capillary interaction between them is negligible. The case is treated when the colloidal layer is deformed normally to its surface. The elasticity arises as an interfacial effect. The effective Young modulus of a surface depends on the interfacial tension, equilibrium contact angle, radius of colloidal particles and their surface density. For the nanometrically scaled particles the line tension becomes essential and has an influence on the effective Young modulus.

cond-mat.soft↗

arXiv2014

Shear Transformation Zones: State Determined or Protocol Dependent?

The concept of a Shear Transformation Zone (STZ) refers to a region in an amorphous solid that undergoes a plastic event when the material is put under an external mechanical load. An important question that had accompanied the development of the theory of plasticity in amorphous solids for many years now is whether an STZ is a {\em region} existing in the material (which can be predicted by analyzing the unloaded material), or is it an {\em event} that depends on the loading protocol (i.e., the event cannot be predicted without following the protocol itself). In this Letter we present strong evidence that the latter is the case. Infinitesimal changes of protocol result in macroscopically big jumps in the positions of plastic events, meaning that these can never be predicted from considering the unloaded material.

cond-mat.soft↗

arXiv2014

Elasticity and Plasticity in Stiff and Flexible Oligomeric Glasses

In this paper we focus on the mechanical properties of oligomeric glasses (waxes), employing a microscopic model that provides, via numerical simulations, information about the shear modulus of such materials, the failure mechanism via plastic instabilities and about the geometric responses of the oligomers themselves to a mechanical load. We present a microscopic theory that explains the numerically observed phenomena, including an exact theory of the shear modulus and of the plastic instabilities, both local and system spanning. In addition we present a model to explain the geometric changes in the oligomeric chains under increasing strains.

cond-mat.soft↗

arXiv2014

Low Voltage Reversible Electrowetting Exploiting Lubricated Polymer Honeycomb Substrates

Low-voltage electrowetting-on-dielectric scheme realized with lubricated honeycomb polymer surfaces is reported. Polycarbonate honeycomb reliefs manufactured with the breath-figures self-assembly were impregnated with silicone and castor oils. The onset of the reversible electrowetting for silicone oil impregnated substrates occurred at 35 V, whereas for castor oil impregnated ones it took place at 80 V. The semi-quantitative analysis of electrowetting of impregnated surfaces is proposed.

cond-mat.soft↗

arXiv2013

Percolating Plastic Failure as a Mechanism for Shear Softening in Amorphous Solids

``Shear softening" refers to the observed reduction in shear modulus when the stress on an amorphous solid is increased beyond the initial linear region. Careful numerical quasi-static simulations reveal an intimate relation between plastic failure and shear softening. The attaintment of the steady-state value of the shear modulus associated with plastic flow is identified with a percolation of the regions that underwent a plastic event. We present an elementary ``two-state" model that interpolates between failed and virgin regions and provides a simple and effective characterization of the shear softening.

cond-mat.soft↗

arXiv2013

On the Effect of Micro-alloying on the Mechanical Properties of Metallic Glasses

"Micro-alloying", referring to the addition of small concentration of a foreign metal to a given metallic glass, was used extensively in recent years to attempt to improve the mechanical properties of the latter. The results are haphazard and nonsystematic. In this paper we provide a microscopic theory of the effect of micro-alloying, exposing the delicate consequences of this procedure and the large parameter space which needs to be controlled. In particular we consider two very similar models which exhibit opposite trends for the change of the shear modulus, and explain the origins of the difference as displayed in the different microscopic structure and properties.

cond-mat.mtrl-sci↗

arXiv2013

Shear localization in 3-Dimensional Amorphous Solids

In this paper we extend the recent theory of shear-localization in 2-dimensional amorphous solids to 3-D. In 2-D the fundamental instability of shear-localization is related to the appearance of a line of displacement quadrupoles, that makes an angle of 45 degrees with the principal stress axis. In 3-D the fundamental plastic instability is also explained by the formation of a lattice of anisotropic elastic inclusions. In the case of pure external shear stress, we demonstrate that this is a 2-dimensional triangular lattice of similar elementary events. It is shown that this lattice is arranged on a plane, that, similarly to the 2-D case, makes an angle of 45 degrees with respect to the principal stress axis. This solution is energetically favorable only if the external strain exceeds a yield-strain value, which is determined by the strain parameters of the elementary events and the Poisson ratio. The predictions of the theory are compared to numerical simulations and very good agreement is observed.

cond-mat.soft↗

arXiv2013

The Yield-Strain and Shear-Band Direction in Amorphous Solids Under General Loading

It is well known experimentally that well-quenched amorphous solids exhibit a plastic instability in the form of a catastrophic shear localization at a well defined value of the external strain. The instability may develop to a shear-band that in some cases is followed by a fracture. It is also known that the values of the yield-strain (and yield-stress), as well as the direction of the shear band with respect to the principal stress axis, vary considerably with variations in the external loading conditions. In this paper we present a microscopic theory of these phenomena for 2-dimensional athermal amorphous solids that are strained quasi-statically. We present analytic formulae for the yield-strains for different loading conditions, and well as for the angles of the shear bands. We explain that the external loading conditions determine the eigenvalues of the quadrupolar Eshelby inclusions which model the non-affine displacement field. These inclusions model elementary plastic events and determine both the yield-strain and the direction of the shear-band. We show that the angles of the shear bands with respect to the principal stress axis are limited theoretically between $30^o$ and $60^o$. Available experimental data conform to this prediction.

cond-mat.soft↗

arXiv2013

Atomistic theory of the shear band direction in amorphous solids

One of the major theoretical riddles in shear banding instabilities is the angle that the shear band chooses spontaneously with respect to the principal stress axis. Here we employ our recent atomistic theory to compute analytically the angle in terms of the characteristics of the Eshelby inclusion that models faithfully the eigenfunction of the Hessian matrix that goes soft at the plastic instability. We show that loading protocols that do not conserve volume result in shear bands at angles different from 45$^o$ to the strain axis; only when the external strains preserve volume like in pure shear, the shear bands align precisely at 45$^o$ to the strain axis. We compute an analytic formula for the angle of the shear band in terms of the characteristics of the loading protocol; quantitative agreement with computer simulations is demonstrated.

cond-mat.mtrl-sci↗