Searcharxiv⌕ Search

arXiv subjects

Oleg V. Gendelman

Publications and source records attributed to Oleg V. Gendelman.

15 recordsLinked to original sources

Infinite Set of Resonances in the Linear Damped Oscillator Subject to Harmonic Forcing with Non-standard Frequency Modulation

It is shown that harmonic signals incorporating a type of weak non-standard frequency modulation (wNSFM) have interesting spectral properties, namely, time-dependent bandwidths that become increasingly broader with increasing time. As such, they represent a class of signals with frequency-time coupling in their spectra. Specifically, the weakly damped oscillator exhibits always two transient resonance captures involving two distinct harmonics possessing relatively high amplitudes over finite time intervals, while the overall response decays as $~t^{-1/2}$ as $t\rightarrow\infty$. Considering the undamped oscillator, it possesses two types of resonances, referred to as simple and non-simple resonances. Simple resonances correspond to finite-amplitude steady-state responses caused by two sustained resonance captures, in the form of two distinct modulated quasi-periodic responses, which, however are "activated" at different time instances. The necessary and sufficient conditions for non-simple resonances are given in the form of a theorem which predicts the existence of resonant harmonics and specifies the special phase conditions that the resonant harmonics must satisfy for constructive interference; the resulting undamped non-simple resonance grows unboundedly as $~t^{-1/2}$ as $t\rightarrow\infty$, in contrast to the classical resonance growth of the linear resonator with unmodulated harmonic excitation whose response grows as $~t$ as $t\rightarrow\infty$. These resonant responses are persistent to changes in the parameters of the wNSFM. Our results reveal interesting infinite sets of resonances in linear SDOF resonators under frequency-modulated excitations.

math.DS↗

The Trachenko-Zaccone equation: nonlinear relaxation from glasses to complex systems

The Trachenko-Zaccone equation provides a compact nonlinear dynamical framework for describing non-Debye relaxation in disordered condensed matter. Originally developed to rationalize stretched- and compressed-exponential relaxation in liquids and glasses from the dynamics of interacting local relaxation events, the same equation has subsequently appeared in broader contexts, including polymer relaxation and nonlinear models of global population dynamics. This review retraces the conceptual development of the equation, with particular emphasis on its physical origin in Kostya Trachenko's feed-forward interaction mechanism, its mathematical structure, and its possible generalizations. We also include personal recollections of the work with Kostya Trachenko at Queen Mary University of London in August 2019, during which the equation emerged in essentially its present form. After reviewing applications to stress relaxation, glassy materials, polymer relaxation and population dynamics, we discuss future directions including time-dependent feedback parameters, coupled order parameters, heterogeneous and spatially resolved formulations, flux terms, network versions and stochastic extensions. The central theme of the review is that the Trachenko-Zaccone equation should be viewed not only as a model of glassy relaxation, but as a general nonlinear feedback equation with potential applications across complex systems.

cond-mat.dis-nn↗

Critical damping in linear system with two degrees of freedom: surprises and pitfalls

In this Brief Communication, we establish the notion of critical damping for generic two-degree-of-freedom system. For given set of masses and stiffnesses, the critical damping corresponds to the real eigenvalue with maximal multiplicity, equal to minus geometrical mean of the eigenfrequencies. This case corresponds to the fastest possible asymptotic decay rate for generic initial conditions. The damping matrix for the critical case is unique up to reflection of one modal coordinate and, generically, non-diagonal. Quite surprisingly, for large difference of the eigenfrequencies, it is also not positive definite. Therefore, physical realization of the critical case will require active elements that provide negative effective damping.

physics.class-ph↗

Modeling the Fatigue Behavior of Amorphous Polymers

Prediction of material durability is both very important and very difficult. In many cases, material durability is measured by subjecting a sample to repeating oscillatory cycles (in shear or tension-compression) until it fails in either ductile or brittle fashion. Typically, the stress amplitude is denoted S, and the number of cycles N, so the resulting dependence is known as the SN-curve. For many materials, SN curve has been shown to obey the empirical Basquin's law, N = AS^(-m), where the prefactor A was a function of the temperature, load frequency, and sample history, and the power law m was a real number, usually between 3 and 12. Here, we derive the Basquin's law using a linearized version of the Long's plasticity model and demonstrate that within this framework, m = 3. We also derive the expression for the prefactor A. Finally, we show that our theory successfully describes experimental data for three amorphous polymers, PS, PMMA, and PVC.

cond-mat.mtrl-sci↗

Modeling the Slow Arrhenius Process (SAP) in Polymers

Amorphous glass-forming polymers exhibit multiple relaxation processes, including the structural α-relaxation associated with the glass transition and faster secondary relaxations that typically follow Arrhenius behavior. Recently, a distinct slow Arrhenius process (SAP) has been observed at frequencies well below the α-process. Although Arrhenian in its temperature dependence, the SAP involves much longer relaxation times and its microscopic origin remains unclear. Here, we extend the two-state, two-timescale (TS2) theory to describe both the α-relaxation and the SAP within a unified framework. We propose that the SAP represents the high-temperature limit of an α-like process in a coarse-grained fluid of dynamically correlated clusters. With renormalized interaction energies and coordination parameters, the same model quantitatively reproduces both α and SAP data across multiple polymers without additional adjustable parameters and explains the observed Meyer-Neldel compensation behavior. The theory further predicts that the SAP should deviate from Arrhenius behavior at sufficiently low temperatures, transitioning to Vogel-Fulcher-Tammann-Hesse-like dynamics, thereby offering a physically transparent interpretation of cluster-scale relaxation in glass-forming polymers.

cond-mat.soft↗

Universality of Dynamic and Thermodynamic Behavior of Polymers near their Glass Transition

Describing the dynamics and thermodynamics of amorphous materials near the glass transition is a major challenge in soft-matter physics and polymer engineering. Here, we show that the dependence of the dielectric alpha-relaxation time on temperature can be captured by a universal equation with only two independent parameters, Tg and fragility, m. This is similar in spirit to the ideas of van Krevelen and Bicerano, and can be related to the Boyer-Spencer and Simha-Boyer rules for the volumetric thermal expansion via a modified free-volume approach such as Sanchez-Lacombe "Two-state, two-(time)scale" (SL-TS2) theory. The model is compared to experimental data for nine amorphous polymers with varying values of Tg and m, and a good qualitative and quantitative agreement is found. We also derive the relationship between the experimental and computational (high-cooling-rate) Tg, and compare our model prediction for the Tg-shift between the two with the simulation results of Afzal et al., finding a good qualitative and semi-quantitative agreement. The results could serve as a guidance for future simulation studies.

cond-mat.soft↗

New Insights into the Dependence of Glass Transition Temperature and Dynamic Fragility on Molecular Weight in Oligomers and Polymers

In an earlier preprint (V. V. Ginzburg, O. V. Gendelman, R. Casalini, and A. Zaccone, arxiv:2409.17291), we demonstrated that the dynamic (relaxation time) and volume equations of state for many amorphous polymers are near-universal -- each material is characterized by two governing parameters -- the glass transition temperature, T_{g}, and the elementary relaxation time, /tau_{el}. The dynamic fragility, m, is uniquely related to /tau_{el}. The earlier analysis was based on the data for high polymers (degree of polymerization, N > 200, and molecular weight, Mw > 20,000 g/mol). Here, we investigate the dependence of T_{g} and /tau_{el} on N (or, equivalently, on the molecular weight, M). We consider the dielectric spectroscopy data for homologous series of four polymers: polystyrene (PS), poly-(2-vinylpyridine) (P2VP), poly(dimethylsiloxane) (PDMS), and polybutadiene (PB). It is shown that the relaxation time curves for various oligomers can be successfully collapsed onto the same master curve as the high polymers. The glass transition temperature and the dynamic fragility are found to be linear functions of 1/M, in agreement with the Fox-Flory equation. The scaling results are interpreted based on the SL-TS2 theory, ensuring that the model description is consistent with the Boyer rules for the coefficients of thermal expansion above and below T_{g}, as well as the thermodynamical scaling for the pressure dependence of the relaxation time.

cond-mat.soft↗

Unified physical framework for stretched-exponential, compressed-exponential, and logarithmic relaxation phenomena in glassy polymers

We develop a simple yet comprehensive nonlinear model to describe relaxation phenomena in amorphous glass-formers near the glass transition temperature. The model is based on the two-state, two-(time)scale (TS2) framework, and describes the isothermal relaxation of specific volume, enthalpy, or shear stress via a simple first-order nonlinear differential equation (the Trachenko-Zaccone [TZ] equation) for local cooperative events. These nonlinear dynamics of cooperatively rearranging regions (CRR) naturally arise from the TS2 framework. We demonstrate that the solutions of the TZ equation comprehensively encompass the Debye exponential relaxation, the Kohlrausch-Williams-Watts (KWW) stretched and compressed relaxations, and the Guiu-Pratt logarithmic relaxation. Furthermore, for the case of stress relaxation modeling, our model recovers, as one of its limits, the Eyring law for plastic flow, where the Eyring activation volume is related to thermodynamic parameters of the material. Using the example of polystyrene (PS), we demonstrate how our model successfully describes the Kovacs "asymmetry of approach" specific volume and enthalpy experiments, as well as the stress relaxation. Other potential applications of the model, including the dielectric relaxation, are also discussed. The presented approach disentangles the physical origins of different relaxation laws within a single general framework based on the underlying physics.

cond-mat.soft↗

Escape of a forced-damped particle from weakly nonlinear truncated potential well

Escape from a potential well is an extreme example of transient behavior. We consider the escape of the harmonically forced particle under viscous damping from the benchmark truncated weakly nonlinear potential well. Main attention is paid to most interesting case of primary 1:1 resonance. The treatment is based on multiple-scales analysis and exploration of the slow-flow dynamics. Contrary to Hamiltonian case described in earlier works, in the case with damping the slow-flow equations are not integrable. However, if the damping is small enough, it is possible to analyze the perturbed slow-flow equations. The effect of the damping on the escape threshold is evaluated in the explicit analytic form. Somewhat unexpectedly, the escape mechanisms in terms of the slow flow are substantially different for the linear and weakly nonlinear cases.

nlin.CD↗

Localization in Coupled Finite Vibro-Impact Chains: Discrete Breathers and Multibreathers

We examine the dynamics of strongly localized periodic solutions (discrete breathers) in two-dimensional array of coupled finite one-dimensional chains of oscillators. Localization patterns with both single and multiple localization sites (multibreathers) are considered. The model is scalar, i.e. each particle can move only parallel to the axis of the chain it belongs to. The model involves symmetric parabolic on-site potential with rigid constraints (the displacement domain of each particle is finite) and a linear nearest-neighbor coupling in the chain, and also between the neighbors in adjacent chains. When the particle approaches the constraint, it undergoes an elastic Newtonian impact. The rigid impact constraints are the only source of nonlinearity in the system. The model allows easy computation of highly accurate approximate solutions for the breathers and multibreathers with an arbitrary set of localization sites in conservative setting. The vibro-impact nonlinearity permits explicit derivation of a monodromy matrix for the breather and multi-breather solutions. Consequently, the stability of the derived breather and multibreather solutions can be studied in the framework of simple methods of linear algebra, without additional approximations. It is shown that due to the coupling of the chains, the breather solutions can undergo the symmetry breaking.

nlin.PS↗

Discrete Breathers and Multi-Breathers in Finite Vibro-Impact Chain

We explore dynamics of discrete breathers and multi-breathers in finite one-dimensional chain. The model involves parabolic on-site potential with rigid constraints and linear nearest-neighbor coupling. The rigid non-ideal impact constraints are the only source of nonlinearity and damping in the model. The model allows derivation of exact analytic solutions for the breathers and multi-breathers with arbitrary set of localization sites, both in conservative and forced-damped settings. We choose periodic boundary conditions; exact solutions for other types of the boundary conditions are also possible. Local character of the nonlinearity allows explicit derivation of a monodromy matrix for the breather solutions. Consequently, a stability of the derived breather and multi-breather solutions can be efficiently studied in the framework of simple methods of linear algebra, and with rather moderate computational efforts. We demonstrate that finitness of the chain fragment and proximity of the localization sites strongly effect existence and stability patterns of these localized solutions.

nlin.PS↗

Internal resonances and dynamic responses in equivalent mechanical model of partially liquid-filled vessel

The paper treats oscillations of a liquid in partially filled vessel under horizontal harmonic ground excitation. Such excitation may lead to hydraulic impacts. The liquid sloshing mass is modeled by equivalent pendulum, which can impact the vessel walls. We use parameters of the equivalent pendulum for well-explored case of cylindrical vessels. The hydraulic impacts are modeled by high-power potential function. Conditions for internal resonances are presented. A non-resonant behavior and dynamic response related to 3:1 internal resonance are explored. When the excitation amplitude exceeds a critical value, the system exhibits multiple steady state solutions. Quasi-periodic solutions appear in relatively narrow range of parameters. Numerical continuation links between resonant regimes found asymptotically for small excitation amplitude, and high-amplitude responses with intensive impacts.

physics.flu-dyn↗

Heat conduction in diatomic chains with correlated disorder

The paper considers heat transport in diatomic one-dimensional lattices, containing equal amounts of particles with different masses. Ordering of the particles in the chain is governed by single correlation parameter -- the probability for two neighboring particles to have the same mass. As this parameter grows from zero to unity, the structure of the chain varies from regular staggering chain to completely random configuration, and then -- to very long clusters of particles with equal masses. Therefore, this correlation parameter allows a control of typical cluster size in the chain. In order to explore different regimes of the heat transport, two interatomic potentials are considered. The first one is an infinite potential wall, corresponding to instantaneous elastic collisions between the neighboring particles. In homogeneous chains such interaction leads to an anomalous heat transport. The other one is classical Lennard-Jones interatomic potential, which leads to a normal heat transport. The simulations demonstrate that the correlated disorder of the particle arrangement does not change the convergence properties of the heat conduction coefficient, but essentially modifies its value. For the collision potential, one observes essential growth of the coefficient for fixed chain length as the limit of large homogeneous clusters is approached. The thermal transport in these models remains superdiffusive. In the Lennard-Jones chain the effect of correlation appears to be not monotonous in the limit of low temperatures. This behavior stems from the competition between formation of long clusters mentioned above, and Anderson localization close to the staggering ordered state.

cond-mat.stat-mech↗

Mechanical control of heat conductivity in microscopic models of dielectrics

We discuss a possibility to control a heat conductivity in simple one-dimensional models of dielectrics by means of external mechanical loads. To illustrate such possibilities we consider first a well-studied chain with degenerate double-well potential of the interparticle interaction. Contrary to previous studies, we consider varying length of the chain with fixed number of particles. Number of possible energetically degenerate ground states strongly depends on the overall length of the chain, or, in other terms, on average length of the link between neighboring particles. These degenerate states correspond to mechanical equilibrium, therefore one can say that the transition between them mimics to some extent a process of plastic deformation. We demonstrate that such modification of the chain length can lead to quite profound (almost five-fold) reduction of the heat conduction coefficient. Even more profound effect is revealed for a model with single-well non-convex potential. It is demonstrated that in certain range of constant external forcing this model becomes "effectively"\ double-well, and has a multitude of possible states of equilibrium for the same value of the external load. Thus, the heat conduction coefficient can be reduced by two orders of magnitude. We suggest a mechanical model of a chain with periodic double-well potential, which allows control over the heat conduction. The models considered may be useful for description of heat transport in biological macromolecules and for control of the heat transport in microsystems.

cond-mat.mes-hall↗

Non-stationary heat conduction in one-dimensional chains with conserved momentum

The Letter addresses the relationship between hyperbolic equations of heat conduction and microscopic models of dielectrics. Effects of the non-stationary heat conduction are investigated in two one-dimensional models with conserved momentum: Fermi-Pasta-Ulam (FPU) chain and chain of rotators (CR). These models belong to different universality classes with respect to stationary heat conduction. Direct numeric simulations reveal in both models a crossover from oscillatory decay of short-wave perturbations of the temperature field to smooth diffusive decay of the long-wave perturbations. Such behavior is inconsistent with parabolic Fourier equation of the heat conduction. The crossover wavelength decreases with increase of average temperature in both models. For the FPU model the lowest order hyperbolic Cattaneo-Vernotte equation for the non-stationary heat conduction is not applicable, since no unique relaxation time can be determined.

cond-mat.stat-mech↗