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Olga Movilla Miangolarra

Publications and source records attributed to Olga Movilla Miangolarra.

At least 19 recordsLinked to original sources

Quo vadis, stochastic thermodynamics?

Stochastic thermodynamics is a framework for describing non-equilibrium processes at the level of fluctuating trajectories, where the state of a system evolves as a stochastic time series, allowing thermodynamic quantities such as work, heat, and entropy production to be defined along individual realizations rather than at the ensemble level only. Over the past three decades, the field has yielded fundamental results, including fluctuation theorems and several universal bounds, such as thermodynamic uncertainty relations, speed limit theorems, and many others. Many of them have been tested on a range of experimental platforms. This Perspective reviews recent developments in stochastic thermodynamics that extend its scope beyond its traditional domains, including systems with memory and hidden degrees of freedom, microscopic approaches to interacting and active matter, and geometric formulations based on optimal transport. Next, the Perspective surveys the challenges that arise when applying these ideas to macroscopic and complex systems, where the link between statistical irreversibility and thermodynamic dissipation becomes less direct. Finally, emerging applications in non-physical contexts are highlighted, including computation, biological systems, and social dynamics. Transcending the traditional boundaries of physics, these developments catalyze an unorthodox framework to tackle the thermodynamics of complex systems.

cond-mat.stat-mech↗

Wasserstein-2 gradient flows and the geometry of entropy production in classical and quantum stochastic thermodynamics

The second law does more than set the direction of thermodynamic evolution: it endows nonequilibrium transformations with an underlying geometry. In this work, we provide a unified geometric description of entropy production in classical and quantum thermodynamics based on Wasserstein-2 structures arising from gradient flows of free energy. We review how relaxation to equilibrium, in overdamped diffusions, discrete detailed-balanced Markov chains, and dissipative Lindblad dynamics, can be formulated as a gradient flow on the space of states. The associated Wasserstein-2 distance bounds entropy production, yielding a finite-time refinement of the second law. We extend this framework beyond purely dissipative dynamics by introducing generalized Wasserstein-2 metrics that incorporate conservative (Hamiltonian) dynamics in both classical inertial systems and open quantum systems, yielding intrinsic distances that exactly characterize minimal entropy production under fixed dissipative mobilities. We establish equivalence bounds between purely dissipative and Hamiltonian-dissipative geometries, explicitly quantifying how inertial or coherent dynamics can reduce dissipation. Finally, when restricted to equilibrium distributions, we recover the thermodynamic length of linear response-including the quantum thermodynamic length-thereby linking optimal transport, thermodynamic length, and counterdiabatic protocols within a single geometric framework. All in all, our results extend the Riemannian program of thermodynamics further from equilibrium and provide a geometric foundation for optimal protocols beyond the overdamped setting.

cond-mat.stat-mech↗

On a time-resolved interpretation of the Husimi function

In this Letter, we interpret the Husimi function as the conditional probability density of continuously measuring a stream of constant position and momentum outcomes, indefinitely. This gives rise to an alternative definition that naturally extends to an arbitrary collection of self-adjoint operators without reference to coherent states. This definition recovers the Husimi distribution for a spin-half particle when monitoring the three Pauli matrices, as well as Born's rule for quantum measurement when monitoring commuting quantum observables. Ultimately, the proposed paradigm generates positive representations of quantum states as conditional densities, on both finite and infinite time classical experiments, as expectations of a fundamental operator, the Gaussian semigroup.

quant-ph↗

Regulation of a continuously monitored quantum harmonic oscillator with inefficient detectors

We study the control problem of regulating the purity of a quantum harmonic oscillator in a Gaussian state via weak measurements. Specifically, we assume time-invariant Hamiltonian dynamics and that control is exerted via the back-action induced from monitoring the oscillator's position and momentum observables; the manipulation of the detector measurement strengths regulates the purity of the target Gaussian quantum state. After briefly drawing connections between Gaussian quantum dynamics and stochastic control, we focus on the effect of inefficient detectors and derive closed-form expressions for the transient and steady-state dynamics of the state covariance. We highlight the degradation of attainable purity that is due to inefficient detectors, as compared to that dictated by the Robertson-Schrödinger uncertainty relation. Our results suggest that quantum correlations can enhance the purity at steady-state. The quantum harmonic oscillator represents a basic system where analytic formulae may provide insights into the role of inefficient measurements in quantum control; the gained insights are pertinent to measurement-based quantum engines and cooling experiments.

quant-ph↗

Quantum Schrodinger bridges: large deviations and time-symmetric ensembles

Quantum counterparts of Schrodinger's classical bridge problem have been around for the better part of half a century. During that time, several quantum approaches to this multifaceted classical problem have been introduced. In the present work, we unify, extend, and interpret several such approaches through a classical large deviations perspective. To this end, we consider time-symmetric ensembles that are pre- and post-selected before and after a Markovian experiment is performed. The Schrodinger bridge problem is that of finding the most likely joint distribution of initial and final outcomes that is consistent with obtained endpoint results. The derived distribution provides quantum Markovian dynamics that bridge the observed endpoint states in the form of density matrices. The solution retains its classical structure in that density matrices can be expressed as the product of forward-evolving and backward-evolving matrices. In addition, the quantum Schrodinger bridge allows inference of the most likely distribution of outcomes of an intervening measurement with unknown results. This distribution may be written as a product of forward- and backward-evolving expressions, in close analogy to the classical setting, and in a time-symmetric way. The derived results are illustrated through a two-level amplitude damping example.

quant-ph↗

Maximum entropy inference of reaction-diffusion models

Reaction-diffusion equations are commonly used to model a diverse array of complex systems, including biological, chemical, and physical processes. Typically, these models are phenomenological, requiring the fitting of parameters to experimental data. In the present work, we introduce a novel formalism to construct reaction-diffusion models that is grounded in the principle of maximum entropy. This new formalism aims to incorporate various types of experimental data, including ensemble currents, distributions at different points in time, or moments of such. To this end, we expand the framework of Schrödinger bridges and Maximum Caliber problems to nonlinear interacting systems. We illustrate the usefulness of the proposed approach by modeling the evolution of (i) a morphogen across the fin of a zebrafish and (ii) the population of two varieties of toads in Poland, so as to match the experimental data.

cond-mat.stat-mech↗

Particle approximations of Wigner distributions for n arbitrary observables

A class of signed joint probability measures for n arbitrary quantum observables is derived and studied based on quasi-characteristic functions with symmetrized operator orderings of Margenau-Hill type. It is shown that the Wigner distribution associated with these observables can be rigorously approximated by such measures. These measures are given by affine combinations of Dirac delta distributions supported over the finite spectral range of the quantum observables and give the correct probability marginals when coarse-grained along any principal axis. We specialize to bivariate quasi-probability distributions for the spin measurements of spin-1/2 particles and derive their closed-form expressions. As a side result, we point out a connection between the convergence of these particle approximations and the Mehler-Heine theorem. Finally, we interpret the supports of these quasi-probability distributions in terms of repeated thought experiments.

quant-ph↗

Wasserstein speed limits for Langevin systems

Physical systems transition between states with finite speed that is limited by energetic costs. In this work, we derive bounds on transition times for general Langevin systems that admit a decomposition into reversible and irreversible dynamics, in terms of the Wasserstein distance between states and the energetic costs associated with respective reversible and irreversible currents. For illustration we discuss Brownian particles subject to arbitrary forcing and an RLC circuit with time-varying inductor.

math-ph↗

Refined bounds on energy harvesting from anisotropic fluctuations

We consider overdamped Brownian particles with two degrees of freedom (DoF) that are confined in a time-varying quadratic potential and are in simultaneous contact with heat baths of different temperatures along the respective DoF. The anisotropy in thermal fluctuations can be used to extract work by suitably manipulating the confining potential. The question of what the maximal amount of work that can be extracted is has been raised in recent work, and has been computed under the simplifying assumption that the entropy of the distribution of particles (thermodynamic states) remains constant throughout a thermodynamic cycle. Indeed, it was shown that the maximal amount of work that can be extracted amounts to solving an isoperimetric problem, where the 2-Wasserstein length traversed by thermodynamic states quantifies dissipation that can be traded off against an area integral that quantifies work drawn out of the thermal anisotropy. Here, we remove the simplifying assumption on constancy of entropy. We show that the work drawn can be computed similarly to the case where the entropy is kept constant while the dissipation can be reduced by suitably tilting the thermodynamic cycle in a thermodynamic space with one additional dimension. Optimal cycles can be locally approximated by solutions to an isoperimetric problem in a tilted lower-dimensional subspace.

cond-mat.stat-mech↗

An excursion onto Schrödinger's bridges: Stochastic flows with spatio-temporal marginals

The purpose of the present work is to expand substantially the type of control and estimation problems that can be addressed following the paradigm of Schrödinger bridges, by incorporating termination (killing) of stochastic flows. Specifically, in the context of estimation, we seek the most likely evolution realizing measured spatio-temporal marginals of killed particles. In the context of control, we seek a suitable control action directing the killed process toward spatio-temporal probabilistic constraints. To this end, we derive a new Schrödinger system of coupled, in space and time, partial differential equations to construct the solution of the proposed problem. Further, we show that a Fortet-Sinkhorn type of algorithm is available to attain the associated bridge. A key feature of our framework is that the obtained bridge retains the Markovian structure in the prior process, and thereby, the corresponding controller takes the form of state feedback.

math.OC↗

Inferring potential landscapes: A Schrödinger bridge approach to Maximum Caliber

Schrödinger bridges have emerged as an enabling framework for unveiling the stochastic dynamics of systems based on marginal observations at different points in time. The terminology "bridge'' refers to a probability law that suitably interpolates such marginals. The theory plays a pivotal role in a variety of contemporary developments in machine learning, stochastic control, thermodynamics, and biology, to name a few, impacting disciplines such as single-cell genomics, meteorology, and robotics. In this work, we extend Schrödinger's paradigm of bridges to account for integral constraints along paths, in a way akin to Maximum Caliber - a Maximum Entropy principle applied in a dynamic context. The Maximum Caliber principle has proven useful to infer the dynamics of complex systems e.g., that model gene circuits and protein folding. We unify these two problems via a maximum likelihood formulation to reconcile stochastic dynamics with ensemble-path data. A variety of data types can be encompassed, ranging from distribution moments to average currents along paths. The framework enables inference of time-varying potential landscapes that drive the process. The resulting forces can be interpreted as the optimal control that drives the system in a way that abides by specified integral constraints. Analogous results are presented in a discrete-time, discrete-space setting and specialized to steady-state dynamics. We finish by illustrating the practical applicability of the framework through paradigmatic examples, such as that of bit erasure or protein folding. In doing so, we highlight the strengths of the proposed framework, namely, the generality of the theory, the ease of computation, and the ability to interpret results in terms of system dynamics. This is in contrast to Maximum-Caliber problems where the focus is typically on updating a probability law on paths.

cond-mat.stat-mech↗

A matching principle for power transfer in Stochastic Thermodynamics

Gradients in temperature and particle concentration fuel many processes in the physical and biological world. In the present work we study a thermodynamic engine powered by anisotropic thermal excitation (that may be due to e.g., a temperature gradient), and draw parallels with the well-known principle of impedance matching in circuit theory, where for maximal power transfer, the load voltage needs to be half of that of the supplying power source. We maximize power output of the thermodynamic engine at steady-state and show that the optimal reactive force is precise half of that supplied by the anisotropy.

eess.SY↗

Minimal entropy production in the presence of anisotropic fluctuations

Anisotropy in temperature, chemical potential, or ion concentration, provides the fuel that feeds dynamical processes that sustain life. At the same time, anisotropy is a root cause of incurred losses manifested as entropy production. In this work we consider a rudimentary model of an overdamped stochastic thermodynamic system in an anisotropic temperature heat bath, and study minimum entropy production when driving the system between thermodynamic states in finite time. While entropy production in isotropic temperature environments can be expressed in terms of the length (in the Wasserstein-2 metric) traversed by the thermodynamic state of the system, anisotropy complicates substantially the mechanism of entropy production since, besides dissipation, seepage of energy between ambient anisotropic heat sources by way of the system dynamics is often a major contributing factor. A key result of the paper is to show that in the presence of anisotropy, minimization of entropy production can once again be expressed via a modified Optimal Mass Transport (OMT) problem. However, in contrast to the isotropic situation that leads to a classical OMT problem and a Wasserstein length, entropy production may not be identically zero when the thermodynamic state remains unchanged (unless one has control over non-conservative forces); this is due to the fact that maintaining a Non-Equilibrium Steady-State (NESS) incurs an intrinsic entropic cost that can be traced back to a seepage of heat between heat baths. As alluded to, NESSs represent hallmarks of life, since living matter by necessity operates far from equilibrium. Therefore, the question studied herein, to characterize minimal entropy production in anisotropic environments, appears of central importance in biological processes and on how such processes may have evolved to optimize for available usage of resources.

cond-mat.stat-mech↗

Geometry of finite-time thermodynamic cycles with anisotropic thermal fluctuations

In contrast to the classical concept of a Carnot engine that alternates contact between heat baths of different temperatures, naturally occurring processes usually harvest energy from anisotropy, being exposed simultaneously to chemical and thermal fluctuations of different intensities. In these cases, the enabling mechanism responsible for transduction of energy is typically the presence of a non-equilibrium steady state (NESS). A suitable stochastic model for such a phenomenon is the Brownian gyrator -- a two-degree of freedom stochastically driven system that exchanges energy and heat with the environment. In the context of such a model we present, from a stochastic control perspective, a geometric view of the energy harvesting mechanism that entails a forced periodic trajectory of the system state on the thermodynamic manifold. Dissipation and work output are expressed accordingly as path integrals of a controlled process, and fundamental limitations on power and efficiency are expressed in geometric terms via a relationship to an isoperimetric problem. The theory is presented for high-order systems far from equilibrium and beyond the linear response regime.

eess.SY↗

Minimal entropy production in anisotropic temperature fields

Anisotropy of temperature fields, chemical potentials and ion concentration gradients provide the fuel that feeds dynamical processes that sustain life. Dynamical flows in respective environments incur losses manifested as entropy production. In this work we consider a rudimentary model of an overdamped stochastic thermodynamic system in an anisotropic temperature heat bath, and analyze the problem to minimize entropy production while driving the system between thermodynamic states in finite time. It is noted that entropy production in a fully isotropic temperature field, can be expressed as the Wasserstein-2 length of the path traversed by the thermodynamic state of the system. In the presence of an anisotropic temperature field, the mechanism of entropy production is substantially more complicated as, besides dissipation, it entails seepage of energy between the ambient heat sources by way of the system dynamics. We show that, in this case, the entropy production can be expressed as the solution of a suitably constrained and generalized Optimal Mass Transport (OMT) problem. In contrast to the situation in standard OMT, entropy production may not be identically zero, even when the thermodynamic state remains unchanged. Physically, this is due to the fact that maintaining a Non-Equilibrium Steady State (NESS), incurs an intrinsic entropic cost. As already noted, NESSs are the hallmark of life and living systems by necessity operate away from equilibrium. Thus our problem of minimizing entropy production appears of central importance in understanding biological processes, such as molecular motors and motor proteins, and on how such processes may have evolved to optimize for available usage of resources.

cond-mat.stat-mech↗

Inertialess Gyrating Engines

A typical model for a gyrating engine consists of an inertial wheel powered by an energy source that generates an angle-dependent torque. Examples of such engines include a pendulum with an externally applied torque, Stirling engines, and the Brownian gyrating engine. Variations in the torque are averaged out by the inertia of the system to produce limit cycle oscillations. While torque generating mechanisms are also ubiquitous in the biological world, where they typically feed on chemical gradients, inertia is not a property that one naturally associates with such processes. In the present work, seeking ways to dispense of the need for inertial effects, we study an inertia-less concept where the combined effect of coupled torque-producing components averages out variations in the ambient potential and helps overcome dissipative forces to allow sustained operation for vanishingly small inertia. We exemplify this inertia-less concept through analysis of two of the aforementioned engines, the Stirling engine and the Brownian gyrating engine. An analogous principle may be sought in biomolecular processes as well as in modern-day technological engines, where for the latter, the coupled torque-producing components reduce vibrations that stem from the variability of the generated torque.

cond-mat.stat-mech↗

Stochastic thermodynamic engines under time-varying temperature profile

In the present paper, we study the power output and efficiency of overdamped stochastic thermodynamic engines that are in contact with a heat bath having a temperature that varies periodically with time. This is in contrast to most of the existing literature that considers the Carnot paradigm of alternating contact with heat baths having different fixed temperatures, hot and cold. Specifically, we consider a periodic and bounded but otherwise arbitrary temperature profile and derive explicit bounds on the power and efficiency achievable by a suitable controlling potential that couples the thermodynamic engine to the external world. Standing assumptions in our analysis are bounds on the norm of the gradient of effective potentials -- in the absence of any such constraint, the physically questionable conclusion of arbitrarily large power can be drawn.

cond-mat.stat-mech↗

Underdamped stochastic thermodynamic engines in contact with a heat bath with arbitrary temperature profile

We study thermodynamic processes in contact with a heat bath that may have an arbitrary time-varying periodic temperature profile. Within the framework of stochastic thermodynamics, and for models of thermo-dynamic engines in the idealized case of underdamped particles in the low-friction regime, we derive explicit bounds as well as optimal control protocols that draw maximum power and achieve maximum efficiency at any specified level of power.

math.OC↗