arXiv subjects

Oliver Shorttle

Publications and source records attributed to Oliver Shorttle.

At least 37 records · Page 2Linked to original sources

arXiv2024

Impact sculpting of the early martian atmosphere

Intense bombardment of solar system planets in the immediate aftermath of protoplanetary disk dissipation has played a key role in their atmospheric evolution. During this epoch, energetic collisions will have removed significant masses of gas from rocky planet atmospheres. Noble gases are powerful tracers of this early atmospheric history, xenon in particular, which on Mars and Earth shows significant depletions and isotopic fractionations relative to the lighter noble gasses. To evaluate the effect of impacts on the loss and fractionation of xenon, we measure its ionization and recombination efficiency by laser shock and apply these constraints to model impact-driven atmospheric escape on Mars. We demonstrate that impact bombardment within the first $200$ to $300\,\text{Myr}$ of solar system history generates the observed Xe depletion and isotope fractionation of the modern martian atmosphere. This process may also explain the Xe depletion recorded in Earth's deep mantle and provides a latest date for the timing of giant planet instability.

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arXiv2024

White dwarf constraints on geological processes at the population level

White dwarf atmospheres are frequently polluted by material from their own planetary systems. Absorption features from Ca, Mg, Fe and other elements can provide unique insights into the provenance of this exoplanetary material, with their relative abundances being used to infer accretion of material with core- or mantle-like composition. Across the population of white dwarfs, the distribution of compositions reveals the prevalence of geological and collisional processing across exoplanetary systems. By predicting the distribution of compositions in three evolutionary scenarios, this work assesses whether they can explain current observations. We consider evolution in an asteroid belt analog, in which collisions between planetary bodies that formed an iron core lead to core- or mantle-rich fragments. We also consider layer-by-layer accretion of individual bodies, such that the apparent composition of atmospheric pollution changes during the accretion of a single body. Finally, we consider that compositional spread is due to random noise. We find that the distribution of Ca, Fe and Mg in a sample of 202 cool DZs is consistent with the random noise scenario, although 7 individual systems show strong evidence of core-mantle differentiation from additional elements and/or low noise levels. Future surveys which detect multiple elements in each of a few hundred white dwarfs, with well understood biases, have the potential to confidently distinguish between the three models.

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arXiv2024

From stars to diverse mantles, melts, crusts and atmospheres of rocky exoplanets

This review is focused on describing the logic by which we make predictions of exoplanetary compositions and mineralogies, and how these processes could lead to compositional diversity among rocky exoplanets. We use these predictions to determine the sensitivity of present-day and future observations to detecting compositional differences between rocky exoplanets and the four terrestrial planets. First, we review data on stellar abundances and infer how changes in composition may manifest themselves in the expected bulk compositions of rocky exoplanets (section 2). Converting this information in mass-radius relationships requires calculation of the stable mineral assemblages at a given temperature-pressure-composition (T-P-X), an exercise we describe in section 3. Should the planet be hot enough to engender partial melting of the mantle, then these liquids are likely to rise to the surface and erupt to form planetary crusts; the possible compositional and mineralogical variability of which we examine in section 4. Finally, the expected spectroscopic responses of such crusts are examined in section 5.

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arXiv2024

A Surface Hydrothermal Source of Nitriles and Isonitriles

Giant impacts can generate transient hydrogen-rich atmospheres, reducing atmospheric carbon. The reduced carbon will form hazes that rain out onto the surface and can become incorporated into the crust. Once heated, a large fraction of the carbon would be converted into graphite. The result is that local regions of the Hadean crust were plausibly saturated with graphite. We explore the consequences of such a crust for a prebiotic surface hydrothermal vent scenario. We model a surface vent fed by nitrogen-rich volcanic gas from high-temperature magmas passing through graphite-saturated crust. We consider this occurring at pressures of 1-1000 bar and temperatures of 1500-1700 degC. The equilibrium with graphite purifies the left-over gas, resulting in substantial quantities of nitriles (0.1% HCN and 1 ppm HC3N) and isonitriles (0.01% HNC) relevant for prebiotic chemistry. We use these results to predict gas-phase concentrations of methyl isonitrile of ~ 1 ppm. Methyl isocyanide can participate in the non-enzymatic activation and ligation of the monomeric building blocks of life, and surface, or shallow, hydrothermal environments provide its only known equilibrium geochemical source.

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arXiv2024

Distinguishing oceans of water from magma on mini-Neptune K2-18b

Mildly irradiated mini-Neptunes have densities potentially consistent with them hosting substantial liquid water oceans (`Hycean' planets). The presence of CO2 and simultaneous absence of ammonia (NH3) in their atmospheres has been proposed as a fingerprint of such worlds. JWST observations of K2-18b, the archetypal Hycean, have found the presence of CO2 and the depletion of NH3 to <100 ppm; hence, it has been inferred that this planet may host liquid water oceans. In contrast, climate modelling suggests that many of these mini-Neptunes, including K2-18b, may likely be too hot to host liquid water. We propose a solution to this discrepancy between observation and climate modelling by investigating the effect of a magma ocean on the atmospheric chemistry of mini-Neptunes. We demonstrate that atmospheric NH3 depletion is a natural consequence of the high solubility of nitrogen species in magma at reducing conditions; precisely the conditions prevailing where a thick hydrogen envelope is in communication with a molten planetary surface. The magma ocean model reproduces the present JWST spectrum of K2-18b to < 3 sigma, suggesting this is as credible an explanation for current observations as the planet hosting a liquid water ocean. Spectral areas that could be used to rule out the magma ocean model include the >4um region, where CO2 and CO features dominate: Magma ocean models suggest a systematically lower CO2/CO ratio than estimated from free chemistry retrieval, indicating that deeper observations of this spectral region may be able to distinguish between oceans of liquid water and magma on mini-Neptunes.

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arXiv2024

Cosmic dust fertilization of glacial prebiotic chemistry on early Earth

Earth's surface is deficient in available forms of many elements considered limiting for prebiotic chemistry. In contrast, many extraterrestrial rocky objects are rich in these same elements. Limiting prebiotic ingredients may, therefore, have been delivered by exogenous material; however, the mechanisms by which exogeneous material may be reliably and non-destructively supplied to a planetary surface remains unclear. Today, the flux of extraterrestrial matter to Earth is dominated by fine-grained cosmic dust. Although this material is rarely discussed in a prebiotic context due to its delivery over a large surface area, concentrated cosmic dust deposits are known to form on Earth today due to the action of sedimentary processes. Here we combine empirical constraints on dust sedimentation with dynamical simulations of dust formation and planetary accretion to show that localized sedimentary deposits of cosmic dust could have accumulated in arid environments on early Earth, in particular glacial settings that today produce cryoconite sediments. Our results challenge the widely held assumption that cosmic dust is incapable of fertilizing prebiotic chemistry. Cosmic dust deposits may have plausibly formed on early Earth and acted to fertilize prebiotic chemistry.

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arXiv2023

Spatially resolving the volatile sulfur abundance in the HD 100546 protoplanetary disk

Volatile elements play a crucial role in the formation of planetary systems. Their abundance and distribution in protoplanetary disks provide vital insights into the connection between formation processes and the atmospheric composition of individual planets. Sulfur, being one of the most abundant elements in planet-forming environments, is of great significance, and now observable in exoplanets with JWST. However, planetary formation models currently lack vital knowledge regarding sulfur chemistry in protoplanetary disks. Developing a deeper understanding of the major volatile sulfur carriers in disks is essential to building models that can meaningfully predict planetary atmospheric composition, and reconstruct planetary formation pathways. In this work, we combine archival observations with new data from ALMA and APEX, covering a range of sulfur-bearing species/isotopologs. We interpret this data using the DALI thermo-chemical code, for which our model is highly refined and disk-specific. We find that volatile sulfur is heavily depleted from the cosmic value by a factor of 1000, with a disk-averaged abundance of S/H = 1e-8. We show that the gas-phase sulfur abundance varies radially by 3 orders of magnitude, with the highest abundances inside the inner dust ring and coincident with the outer dust ring at 150 to 230 au. Extracting chemical abundances from our models, we find OCS, H2CS, and CS to be the dominant molecular carriers in the gas phase. We also infer the presence of a substantial OCS ice reservoir. We relate our results to the potential atmospheric composition of planets in HD 100546, and the wider exoplanet population

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arXiv2023

The distribution of impactor core material during large impacts on Earth-like planets

Large impacts onto young rocky planets may transform their compositions, creating highly reducing conditions at their surfaces and reintroducing highly siderophile metals to their mantles. Key to these processes is the availability of an impactor's chemically reduced core material (metallic iron). It is, therefore, important to constrain how much of an impactor's core remains accessible to a planet's mantle/surface, how much is sequestered to its core, and how much escapes. Here, we present 3D simulations of such impact scenarios using the shock physics code iSALE to determine the fate of impactor iron. iSALE's inclusion of material strength is vital in capturing the behavior of both solid and fluid components of the planet and thus characterizing iron sequestration to the core. We find that the mass fractions of impactor core material that accretes to the planet core ($f_{core}$) or escapes ($f_{esc}$) can be readily parameterized as a function of a modified specific impact energy, with $f_{core} > f_{esc}$ for a wide set of impacts. These results differ from previous works that do not incorporate material strength. Our work shows that large impacts can place substantial reducing impactor core material in the mantles of young rocky planets. Impact-generated reducing atmospheres may thus be common for such worlds. However, through escape and sequestration to a planet's core, large fractions of an impactor's core can be geochemically hidden from a planet's mantle. Consequently, geochemical estimates of late bombardments of planets based on mantle siderophile element abundances may be underestimates.

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arXiv2023

Atmospheres as a Window to Rocky Exoplanet Surfaces

As the characterization of exoplanet atmospheres proceeds, providing insights into atmospheric chemistry and composition, a key question is how much deeper into the planet we might be able to see from its atmospheric properties alone. For small planets with modest atmospheres and equilibrium temperatures, the first layer below the atmosphere will be their rocky surface. For such warm rocky planets, broadly Venus-like planets, the high temperatures and moderate pressures at the base of their atmospheres may enable thermochemical equilibrium between rock and gas. This links the composition of the surface to that of the observable atmosphere. Using an equilibrium chemistry code, we find a boundary in surface pressure-temperature space which simultaneously separates distinct mineralogical regimes and atmospheric regimes, potentially enabling inference of surface mineralogy from spectroscopic observations of the atmosphere. Weak constraints on the surface pressure and temperature also emerge. This regime boundary corresponds to conditions under which SO2 is oxidized and absorbed by calcium-bearing minerals in the crust, thus the two regimes reflect the sulphidation of the crust. The existence of these atmospheric regimes for Venus-like planets is robust to plausible changes in the elemental composition. Our results pave the way to the prospect of characterizing exoplanetary surfaces as new data for short period rocky planet atmospheres emerge.

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arXiv2023

Phanerozoic biological reworking of the continental carbonate rock reservoir

Understanding the co-evolution of complex life with Earth's geology is an enduring challenge. The rock record evidences remarkable correlations between changes in biology and the wider Earth system, yet cause and effect remain unclear. Here, we link the evolutionary history of eukaryotes with the rise and fall of carbonate rock fraction within continental crust - a key variable in controlling the efficiency of carbon drawdown during weathering, solid Earth degassing rates, and ultimately nutrient supply to life. We use geospatial database analyses to demonstrate a strongly non-linear growth and then collapse in Earth's continental crust carbonate reservoir. Biomineralisers reshaped Earth's surface in their image; armouring continental margins with carbonate platforms, such that the continental carbonate reservoir increased in size by 5-fold in under 100 Myr after the Cambrian Radiation of animal life. This Paleozoic carbonate revolution represents among the most dramatic crustal evolutionary events in Earth's history. The Permo-Triassic extinction event coupled to the rise of open ocean calcifiers initiated a steady decline in continental crustal carbonate content; one that still continues today, which unabated would produce Precambrian-style crustal carbonate distributions in around 500-1000 Myr. Our results demonstrate strongly non-linear crustal evolution after the rise of the complex Phanerozoic biosphere. This outcome suggests that complex life may generate unique biogeochemical trajectories on otherwise geologically similar worlds, posing a new challenge in the hunt for life beyond Earth.

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arXiv2023

Post-main sequence thermal evolution of planetesimals

White dwarfs that have accreted planetary materials provide a powerful tool to probe the interiors and formation of exoplanets. In particular, the high Fe/Si ratio of some white dwarf pollutants suggests that they are fragments of bodies that were heated enough to undergo large-scale melting and iron core formation. In the solar system, this phenomenon is associated with bodies that formed early and so had short-lived radionuclides to power their melting, and/or grew large. However, if the planetary bodies accreted by white dwarfs formed during the (pre)-main sequence lifetime of the host star, they will have potentially been exposed to a second era of heating during the star's giant branches. This work aims to quantify the effect of stellar irradiation during the giant branches on planetary bodies by coupling stellar evolution to thermal and orbital evolution of planetesimals. We find that large-scale melting, sufficient to form an iron core, can be induced by stellar irradiation, but only in close-in small bodies: planetesimals with radii $\lesssim$ 30 km originally within $\sim$ 2 AU orbiting a 1$-$3$\,M_{\odot}$ host star with solar metallicity. Most of the observed white dwarf pollutants are too massive to be explained by the accretion of these small planetesimals that are melted during the giant branches. Therefore, we conclude that those white dwarfs that have accreted large masses of materials with enhanced or reduced Fe/Si remain an indicator of planetesimal's differentiation shortly after formation, potentially linked to radiogenic heating.

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arXiv2023

Avoiding methane emission rate underestimates when using the divergence method

Methane is a powerful greenhouse gas, and a primary target for mitigating climate change in the short-term future due to its relatively short atmospheric lifetime and greater ability to trap heat in Earth's atmosphere compared to carbon dioxide. Top-down observations of atmospheric methane are possible via drone and aircraft surveys as well as satellites such as the TROPOspheric Monitoring Instrument (TROPOMI). Recent work has begun to apply the divergence method to produce regional methane emission rate estimates. Here we show that when the divergence method is applied to spatially incomplete observations of methane, it can result in negatively biased time-averaged regional emission rates. We show that this effect can be counteracted by adopting a procedure in which daily advective fluxes of methane are time-averaged before the divergence method is applied. Using such a procedure with TROPOMI methane observations, we calculate yearly Permian emission rates of 3.1, 2.4 and 2.7 million tonnes per year for the years 2019 through 2021. We also show that highly-resolved plumes of methane can have negatively biased estimated emission rates by the divergence method due to the presence of turbulent diffusion in the plume, but this is unlikely to affect regional methane emission budgets constructed from TROPOMI observations of methane. The results from this work are expected to provide useful guidance for future implementations of the divergence method for emission rate estimation from satellite data -- be it for methane or other gaseous species in the atmosphere.

physics.ao-ph↗

arXiv2023

Iceline Variations Driven by Protoplanetary Disc Gaps

The composition of forming planets is strongly affected by the protoplanetary disc's thermal structure. This thermal structure is predominantly set by dust radiative transfer and viscous (accretional) heating and can be impacted by gaps - regions of low dust and gas density that can occur when planets form. The effect of variations in dust surface density on disc temperature has been poorly understood until now. In this work, we use the radiative transfer code MCMax to model the 2D dust thermal structure with individual gaps corresponding to planets with masses of 0.1 M$_J$ - 5 M$_J$ and orbital radii of 3, 5, and 10 AU. Low dust opacity in the gap allows radiation to penetrate deeper into the disc and warm the midplane by up to 16 K, but only for gaps located in the region of the disc where stellar irradiation is the dominant source of heat (here, a$\gtrsim$4 AU). In viscously-heated regions (a$\lesssim$4 AU), the midplane of the gap is relatively cooler by up to 100 K. Outside of the gap, broad radial oscillations in heating and cooling are present due to changes in disc flaring. These thermal features affect local segregation of volatile elements (H$_2$O, CH$_4$, CO2, CO) between the dust and gas. We find that icelines experience dramatic shifts relative to gapless models: up to 6.5 AU towards the star and 4.3 AU towards the midplane. While quantitative predictions of iceline deviations will require more sophisticated models which include transport and sublimation/condensation kinetics, our results provide evidence that planet-induced iceline variations represent a potential feedback from the planet onto the composition of material it is accreting.

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arXiv2023

A mineralogical reason why all exoplanets cannot be equally oxidising

From core to atmosphere, the oxidation states of elements in a planet shape its character. Oxygen fugacity (fO$_2$) is one parameter indicating these likely oxidation states. The ongoing search for atmospheres on rocky exoplanets benefits from understanding the plausible variety of their compositions, which depends strongly on their oxidation states -- and if derived from interior outgassing, on the fO$_2$ at the top of their silicate mantles. This fO$_2$ must vary across compositionally-diverse exoplanets, but for a given planet its value is unconstrained insofar as it depends on how iron (the dominant multivalent element) is partitioned between its 2+ and 3+ oxidation states. Here we focus on another factor influencing how oxidising a mantle is -- a factor modulating fO$_2$ even at fixed Fe$^{3+}$/Fe$^{2+}$ -- the planet's mineralogy. Only certain minerals (e.g., pyroxenes) incorporate Fe$^{3+}$. Having such minerals in smaller mantle proportions concentrates Fe$^{3+}$, increasing fO$_2$. Mineral proportions change within planets according to pressure, and between planets according to bulk composition. Constrained by observed host star refractory abundances, we calculate a minimum fO$_2$ variability across exoplanet mantles, of at least two orders of magnitude, due to mineralogy alone. This variability is enough to alter by a hundredfold the mixing ratio of SO$_2$ directly outgassed from these mantles. We further predict that planets orbiting high-Mg/Si stars are more likely to outgas detectable amounts of SO$_2$ and H$_2$O; and for low-Mg/Si stars, detectable CH$_4$, all else equal. Even absent predictions of Fe$^{3+}$ budgets, general insights can be obtained into how oxidising an exoplanet's mantle is.

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arXiv2023

Prebiosignature Molecules Can Be Detected in Temperate Exoplanet Atmospheres with JWST

The search for biosignatures on exoplanets connects the fields of biology and biochemistry to astronomical observation, with the hope that we might detect evidence of active biological processes on worlds outside the solar system. Here we focus on a complementary aspect of exoplanet characterisation connecting astronomy to prebiotic chemistry: the search for molecules associated with the origin of life, prebiosignatures. Prebiosignature surveys in planetary atmospheres offer the potential to both constrain the ubiquity of life in the galaxy and provide important tests of current prebiotic syntheses outside of the laboratory setting. Here, we quantify the minimum abundance of identified prebiosignature molecules that would be required for detection by transmission spectroscopy using JWST. We consider prebiosignatures on five classes of terrestrial planet: an ocean planet, a volcanic planet, a post-impact planet, a super-Earth, and an early Earth analogue. Using a novel modelling and detection test pipeline, with simulated JWST noise, we find the detection thresholds of hydrogen cyanide (HCN), hydrogen sulfide (H2S), cyanoacetylene (HC3N), ammonia (NH3), methane (CH4), acetylene (C2H2), sulfur dioxide (SO2), nitric oxide (NO), formaldehyde (CH2O), and carbon monoxide (CO) in a variety of low mean molecular weight (<5) atmospheres. We test the dependence of these detection thresholds on M dwarf target star and the number of observed transits, finding that a modest number of transits (1-10) are required to detect prebiosignatures in numerous candidate planets, including TRAPPIST-1e with a high mean molecular weight atmosphere. We find that the NIRSpec G395M/H instrument is best suited for detecting most prebiosignatures.

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arXiv2023

Photochemically-produced SO$_2$ in the atmosphere of WASP-39b

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $μ$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $μ$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$σ$) and G395H (4.5$σ$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.

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arXiv2023

Azimuthal C/O Variations in a Planet-Forming Disk

The elemental carbon-to-oxygen ratio (C/O) in the atmosphere of a giant planet is a promising diagnostic of that planet's formation history in a protoplanetary disk. Alongside efforts in the exoplanet community to measure C/O in planetary atmospheres, observational and theoretical studies of disks are increasingly focused on understanding how the gas-phase C/O varies both with radial location and between disks. This is mostly tied to the icelines of major volatile carriers such as CO and H2O. Using ALMA observations of CS and SO, we have unearthed evidence for an entirely novel type of C/O variation in the protoplanetary disk around HD 100546: an azimuthal variation from a typical, oxygen-dominated ratio (C/O=0.5) to a carbon-dominated ratio (C/O>1.0). We show that the spatial distribution and peculiar line kinematics of both CS and SO molecules can be well-explained by azimuthal variations in the C/O ratio. We propose a shadowing mechanism that could lead to such a chemical dichotomy. Our results imply that tracing the formation history of giant exoplanets using their atmospheric C/O ratios will need to take into account time-dependent azimuthal C/O variations in a planet's accretion zone.

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arXiv2023

Growth and Evolution of Secondary Volcanic Atmospheres: II. The Importance of Kinetics

Volcanism is a major and long-term source of volatile elements such as C and H to Earth's atmosphere, likely has been to Venus's atmosphere, and may be for exoplanets. Models simulating volcanic growth of atmospheres often make one of two assumptions: either that atmospheric speciation is set by the high-temperature equilibrium of volcanism; or, that volcanic gases thermochemically re-equilibrate to the new, lower, temperature of the surface environment. In the latter case it has been suggested that volcanic atmospheres may create biosignature false positives. Here, we test the assumptions underlying such inferences by performing chemical kinetic calculations to estimate the relaxation timescale of volcanically-derived atmospheres to thermochemical equilibrium, in a simple 0D atmosphere neglecting photochemistry and reaction catalysis. We demonstrate that for planets with volcanic atmospheres, thermochemical equilibrium over geological timescales can only be assumed if the atmospheric temperature is above ~700K. Slow chemical kinetics at lower temperatures inhibit the relaxation of redox-sensitive species to low-temperature thermochemical equilibrium, precluding the production of two independent biosignatures through thermochemistry alone: 1. ammonia, and 2. the co-occurrence of CO$_2$ and CH$_4$ in an atmosphere in the absence of CO. This supports the use of both biosignatures for detecting life. Quenched at the high temperature of their degassing, volcanic gases also have speciations characteristic of those produced from a more oxidized mantle, if interpreted as being at thermochemical equilibrium. This therefore complicates linking atmospheres to the interiors of rocky exoplanets, even when their atmospheres are purely volcanic in origin.

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