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Olivier Berné

Publications and source records attributed to Olivier Berné.

43 records · Page 3Linked to original sources

C$_{60}$ in Photodissociation Regions

Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation and excitation processes, and the connection between C$_{60}$ and other carbonaceous compounds in the interstellar medium, in particular polycyclic aromatic hydrocarbons (PAHs). In this paper we study several photodissociation regions (PDRs) where C$_{60}$ and PAHs are detected and the local physical conditions are reasonably well constrained, to provide observational insights into these questions. C$_{60}$ is found to emit in PDRs where the dust is cool ($T_d = 20-40$ K) and even in PDRs with cool stars. These results exclude the possibility for C$_{60}$ to be locked in grains at thermal equilibrium in these environments. We observe that PAH and C$_{60}$ emission are spatially uncorrelated and that C$_{60}$ is present in PDRs where the physical conditions (in terms of radiation field and hydrogen density) allow for full dehydrogenation of PAHs, with the exception of Ced 201. We also find trends indicative of an increase in C$_{60}$ abundance within individual PDRs, but these trends are not universal. These results support models where the dehydrogenation of carbonaceous species is the first step towards C$_{60}$ formation. However, this is not the only parameter involved and C$_{60}$ formation is likely affected by shocks and PDR age.

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Random mixtures of polycyclic aromatic hydrocarbon spectra match interstellar infrared emission

The mid-infrared (IR; 5-15~$μ$m) spectrum of a wide variety of astronomical objects exhibits a set of broad emission features at 6.2, 7.7, 8.6, 11.3 and 12.7 $μ$m. About 30 years ago it was proposed that these signatures are due to emission from a family of UV heated nanometer-sized carbonaceous molecules known as polycyclic aromatic hydrocarbons (PAHs), causing them to be referred to as aromatic IR bands (AIBs). Today, the acceptance of the PAH model is far from settled, as the identification of a single PAH in space has not yet been successful and physically relevant theoretical models involving ``true'' PAH cross sections do not reproduce the AIBs in detail. In this paper, we use the NASA Ames PAH IR Spectroscopic Database, which contains over 500 quantum-computed spectra, in conjunction with a simple emission model, to show that the spectrum produced by any random mixture of at least 30 PAHs converges to the same 'kernel'-spectrum. This kernel-spectrum captures the essence of the PAH emission spectrum and is highly correlated with observations of AIBs, strongly supporting PAHs as their source. Also, the fact that a large number of molecules are required implies that spectroscopic signatures of the individual PAHs contributing to the AIBs spanning the visible, near-infrared, and far infrared spectral regions are weak, explaining why they have not yet been detected. An improved effort, joining laboratory, theoretical, and observational studies of the PAH emission process, will support the use of PAH features as a probe of physical and chemical conditions in the nearby and distant Universe.

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CO rotational line emission from a dense knot in Cas A Evidence for active post-reverse-shock chemistry

We report a Herschel detection of high-J rotational CO lines from a dense knot in the supernova remnant Cas A. Based on a combined analysis of these rotational lines, and previously observed ro-vibrational CO lines, we find the gas to be warm (two components at 400 and 2000 K) and dense (1e6-7 cm-3), with a CO column density of 5e17 cm-2. This, along with the broad line widths (400 kms-1), suggests that the CO emission originates in the post-shock region of the reverse shock. As the passage of the reverse shock dissociates any existing molecules, the CO has most likely reformed in the last few years, in the post-shock gas. The CO cooling time is comparable to the CO formation time, so possible heating sources (UV photons from the shock front, X-rays, electron conduction) to maintain the large column density of warm CO are discussed.

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Detection of the buckminsterfullerene cation (C60+) in space

In the early 90s, C60+ was proposed as the carrier of two diffuse interstellar bands (DIBs) at 957.7 and 963.2 nm, but a firm identification still awaits gas-phase spectroscopic data. Neutral C60, on the other hand, was recently detected through its infrared emission bands in the interstellar medium and evolved stars. In this contribution, we present the detection of C60+ through its infrared vibrational bands in the NGC 7023 nebula, based on spectroscopic observations with the Spitzer space telescope, quantum chemistry calculation, and laboratory data from the literature. This detection supports the idea that C60+ could be a DIB carrier, and provides robust evidence that fullerenes exist in the gas-phase in the interstellar medium. Modeling efforts to design specific observations, combined with new gas-phase data, will be essential to confirm this proposal. A definitive attribution of the 957.7 and 963.2 nm DIBs to C60+ would represent a significant step forward in the field.

astro-ph.GA↗

Probing the role of polycyclic aromatic hydrocarbons in the photoelectric heating within photodissociation regions

We observationally investigate the relation between the photoelectric heating efficiency in PDRs and the charge of PAHs, which are considered to play a key role in photoelectric heating. Using PACS onboard Herschel, we observed six PDRs spanning a wide range of FUV radiation fields (G_0=100-10^5). To measure the photoelectric heating efficiency, we obtained the intensities of the main cooling lines, i.e., the [OI]63um, 145um, and [CII]158um, as well as the FIR continuum intensity. We used Spitzer/IRS spectroscopic mapping observations to investigate the MIR PAH features in the same regions. We decomposed the MIR PAH emission into that of neutral (PAH^0) and positively ionized (PAH^+) species to derive the fraction of the positively charged PAHs, and compare it to the photoelectric heating efficiency. The heating efficiency traced by ([OI]63um+[OI]145um+[CII]158um) / TIR, ranges between 0.1% and 0.9% in different sources, and the fraction of PAH^+ relative to (PAH^0 + PAH^+) spans from 0(+11)% to 87(+/-10)%. All positions with a high PAH^+ fraction show a low heating efficiency, and all positions with a high heating efficiency have a low PAH^+ fraction, supporting the scenario in which a positive grain charge results in a decreased heating efficiency. Theoretical estimates of the photoelectric heating efficiency show a stronger dependence on the charging parameter gamma=G_0 T^{1/2}/n_e than the observed efficiency reported in this study, and the discrepancy is significant at low gamma. The photoelectric heating efficiency on PAHs, traced by ([OI]63um+[OI]145um+[CII]158um) / (PAH+[OI]63um+[OI]145um+[CII]158um), shows a much better match between the observations and the theoretical estimates. The good agreement of the photoelectric heating efficiency on PAHs with a theoretical model indicates the dominant contribution of PAHs to the photoelectric heating. (abridged for arXiv)

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Formation of buckminsterfullerene (C60) in interstellar space

Buckminsterfullerene (C60) was recently confirmed to be the largest molecule identified in space. However, it remains unclear how, and where this molecule is formed. It is generally believed that C60 is formed from the build up of small carbonaceous compounds, in the hot and dense envelopes of evolved stars. Analyzing infrared observations, obtained by Spitzer and Herschel, we found that C60 is efficiently formed in the tenuous and cold environment of an interstellar cloud illuminated by strong ultraviolet (UV) radiation fields. This implies that another formation pathway, efficient at low densities, must exist. Based on recent laboratory and theoretical studies, we argue that Polycyclic Aromatic Hydrocarbons are converted into graphene, and subsequently C60, under UV irradiation from massive stars. This shows that alternative - top-down - routes are key to understanding the organic inventory in space.

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Waves on the surface of the Orion molecular cloud

Massive stars influence their parental molecular cloud, and it has long been suspected that the development of hydrodynamical instabilities can compress or fragment the cloud. Identifying such instabilities has proved difficult. It has been suggested that elongated structures (such as the `pillars of creation') and other shapes arise because of instabilities, but alternative explanations are available. One key signature of an instability is a wave-like structure in the gas, which has hitherto not been seen. Here we report the presence of `waves' at the surface of the Orion molecular cloud near where massive stars are forming. The waves seem to be a Kelvin-Helmholtz instability that arises during the expansion of the nebula as gas heated and ionized by massive stars is blown over pre-existing molecular gas.

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