arXiv subjects

Olli Siltanen

Publications and source records attributed to Olli Siltanen.

12 recordsLinked to original sources

arXiv2026

Group-theoretic treatment of strong light-matter coupling with an arbitrary number of excitations

Strong light-matter interactions in optical microcavities give rise to hybrid light-matter states known as polaritons. While actively used in modern technologies, theoretical descriptions of such systems are often restricted to the single-excitation case, limiting their ability to capture many-excitation physics and hindering further technological advancements. Here, by exploiting the combinatorial structure of quantum emitters, we investigate the Tavis-Cummings model with arbitrary number of excitations. We derive the structure and properties of its eigensystem and identify allowed radiative transitions in systems of realistic size scales. Our work reveals new behavior inaccessible to the few-excitation regime, while also providing a framework to reduce the computational complexity of similar systems with exponentially growing Hilbert spaces.

quant-ph↗

arXiv2026

Nanoparticle Arrays for Efficient Organic Light-Emitting Diode Emission Management

OLEDs are increasingly applied in illumination and displays because they offer excellent color quality, are mechanically flexible, and are self-emissive. However, their usage is limited by low external quantum efficiency (EQE) and efficiency roll-off at high driving voltages. These limitations, together with demands for smaller pixels and device sizes in emerging technologies, motivate innovations that increase efficiency and allow replacing external optical elements with embedded solutions. Here, we demonstrate enhanced outcoupling as well as directional and polarization control of OLED emission, based on collective surface lattice resonances of plasmonic nanoparticle arrays that are embedded in the active layers of four different state-of-the-art OLED structures. Both square arrays and more complex lattices producing flat bands are demonstrated to guide the light to directions and polarizations determined by their optical modes. We show that by the design of the array geometry and the OLED structure, spectral and angular enhancement of the electroluminescence (EL), up to 30 %, can be achieved. Our results verify that surface lattice resonances of nanoparticle arrays offer a robust and versatile embedded solution for tailoring the OLED emission, as well as exciting prospects for efficiency increase if combined with narrow-spectrum emitters.

physics.optics↗

arXiv2026

Non-Markovianity-based ultrasensitive parameter estimation

Accurate parameter estimation is a central task in quantum metrology and sensing, where quantum resources can provide precision beyond classical limits. In realistic settings, however, system-environment interactions lead to decoherence, reducing these strategies to their classical counterparts. Noise is typically classified as Markovian or non-Markovian, with the latter often preserving quantum coherence longer and thus supporting better metrological performance. Still, the absence of noise is generally considered ideal. In this work, we uncover a striking reversal: certain non-Markovian environments not only outperform Markovian ones - including their quantum Cramér-Rao bounds - but can also surpass the entirely noiseless case. We demonstrate these findings numerically for an all-optical setup, which is experimentally feasible and can be extended to other physical platforms. In general, our results open new avenues for noise-assisted quantum metrology beyond conventional limits.

quant-ph↗

arXiv2026

Impact of light-matter coupling strength on the efficiency of microcavity OLEDs: A unified quantum master equation approach

Controlling light-matter interactions is emerging as a powerful strategy to enhance the performance of organic light-emitting diodes (OLEDs). By embedding the emissive layer in planar microcavities or other modified optical environments, excitons can couple to photonic modes, enabling new regimes of device operation. In the weak-coupling regime, the Purcell effect can accelerate radiative decay, while in the strong-coupling regime, excitons and photons hybridize to form entirely new energy eigenstates with altered dynamics. These effects offer potential solutions to key challenges in OLEDs, such as triplet accumulation and efficiency roll-off, yet demonstrations in the strong-coupling case remain sparse and modest. To systematically understand and optimize photodynamics across the different coupling regimes, we develop a unified quantum master equation model for microcavity OLEDs. The model is then applied to estimate device performance in the different coupling regimes to determine which one is the best.

cond-mat.mtrl-sci↗

arXiv2024

Giant Rabi splitting and polariton photoluminescence in an all solution-deposited dielectric microcavity

Planar microcavity polaritons have recently emerged as a promising technology for improving several performance characteristics of organic light-emitting diodes, photodiodes and photovoltaics. To form polaritons and achieve enhanced performance, traditional microcavities with high reflectivity mirrors are fabricated by energy-intensive physical vapor deposition methods, which restrict their use in applications requiring flexibility and low cost. Here, for the first time, we demonstrate a dielectric all-solution-processed polariton microcavity consisting of Rhodamine 6G films in a poly(vinyl alcohol) matrix, exhibiting more than 400 meV Rabi-splitting and photoluminescence with uniform dispersion along the lower polariton mode. Our fully automated deposition and annealing fabrication protocol played a key role in preventing interlayer mixing and producing high optical-quality polariton microcavities, enabling us to observe enhanced scattering of reservoir excitons to the lower polariton and to explore the effects of strong coupling on bimolecular interactions. Notably, we found that polariton microcavities exhibit a more than 10-fold increase in the critical excitation density for bimolecular annihilation compared to bare Rhodamine 6G films. This enhancement can only be partially attributed to the sub-3-fold measured enhancement in radiative lifetime, highlighting the critical role of strong coupling in the influence of molecular dynamics.

cond-mat.mtrl-sci↗

arXiv2024

Enhancing the efficiency of polariton OLEDs in and beyond the single-excitation subspace

Organic light-emitting diodes (OLEDs) have redefined lighting with their environment-friendliness and flexibility. However, only 25 % of the electronic states of organic molecules can emit light upon electrical excitation, limiting the overall efficiency of OLEDs. Strong light-matter coupling, achieved by confining light within OLEDs using mirrors, creates hybrid light-matter states known as polaritons, which could "activate" the remaining 75 % electronic triplet states. Here, we study triplet-to-polariton transition and derive rates for both reverse inter-system crossing and triplet-triplet annihilation. In addition, we explore how the harmful singlet-singlet annihilation could be reduced with strong coupling.

cond-mat.mtrl-sci↗

arXiv2024

Overcoming noise in quantum teleportation with multipartite hybrid entanglement

Quantum entanglement and decoherence are the two counterforces of many quantum technologies and protocols. For example, while quantum teleportation is fueled by a pair of maximally entangled resource qubits, it is vulnerable to decoherence. In this Article, we propose an efficient quantum teleportation protocol in the presence of pure decoherence and without entangled resource qubits entering the Bell-state measurement. Instead, we employ multipartite hybrid entanglement between the auxiliary qubits and their local environments within the open-quantum-system context. Interestingly, with a hybrid-entangled initial state, it is the decoherence that allows us to achieve high fidelities. We demonstrate our protocol in an all-optical experiment.

quant-ph↗

arXiv2023

Identifying the origin of delayed electroluminescence in a polariton organic light-emitting diode

Modifying the energy landscape of existing molecular emitters is an attractive challenge with favourable outcomes in chemistry and organic optoelectronic research. It has recently been explored through strong light-matter coupling studies where the organic emitters were placed in an optical cavity. Nonetheless, a debate revolves around whether the observed change in the material properties represents novel coupled system dynamics or the unmasking of pre-existing material properties induced by light-matter interactions. Here, for the first time, we examined the effect of strong coupling in polariton organic light-emitting diodes via time-resolved electroluminescence studies. We accompanied our experimental analysis with theoretical fits using a model of coupled rate equations accounting for all major mechanisms that can result in delayed electroluminescence in organic emitters. We found that in our devices the delayed electroluminescence was dominated by emission from trapped charges and this mechanism remained unmodified in the presence of strong coupling.

cond-mat.mtrl-sci↗

arXiv2021

Engineering of Hong-Ou-Mandel interference with effective noise

The Hong-Ou-Mandel effect lies at the heart of quantum interferometry, having multiple applications in the field of quantum information processing and no classical counterpart. Despite its popularity, only a few works have considered polarization-frequency interaction within the interferometer. In this paper, we fill this gap. Our system of interest is a general biphoton polarization state that experiences effective dephasing noise by becoming entangled with the same photons' frequency state, as the photons propagate through birefringent media. The photons then meet at a beam splitter, where either coincidence or bunching occurs, after which the polarization-frequency interaction continues on the output paths. Alongside performing extensive theoretical analysis on the coincidence probability and different polarization states, we outline multiple interesting applications that range from constructing Bell states to an alternative delayed choice quantum eraser.

quant-ph↗

arXiv2021

Experimental Snapshot Verification of non-Markovianity with Unknown System-Probe Coupling

We apply the recently proposed quantum probing protocols with an unknown system-probe coupling to probe the convex coefficients in mixtures of commuting states. By using two reference states instead of one as originally suggested, we are able to probe both lower and upper bounds for the convex coefficient. We perform extensive analysis for the roles of the parameters characterizing the double peaked Gaussian frequency spectrum in the Markovian-to-non-Markovian transition of the polarization dynamics of a single photon. We apply the probing of the convex coefficient to the transition-inducing frequency parameter and show that the non-Markovianity of the polarization dynamics can be confirmed with a single snapshot measurement of the polarization qubit performed at unknown time and even with unknown coupling. We also show how the protocol can identify Markovian and non-Markovian time intervals in the dynamics. The results are validated with single photon experiments.

quant-ph↗

arXiv2020

Experimental Quantum Probing Measurements With No Knowledge on the System-Probe Interaction

In any natural science, measurements are the essential link between theory and observable reality. Is it possible to obtain accurate and relevant information via measurement whose action on the probed system is unknown? In other words, can one be convinced to know something about the nature without knowing in detail how the information was obtained? In this paper, we show that the answer is surprisingly, yes. We construct and experimentally implement a quantum optical probing measurement where measurements on the probes, the photons' polarization states, are used to extract information on the systems, the frequency spectra of the same photons. Unlike the pre-existing probing protocols, our measurement does not require any knowledge of the interaction between the probe and the system.

quant-ph↗

arXiv2018

Entanglement Protection via Periodic Environment Resetting in Continuous Time Quantum Dynamical Processes

The temporal evolution of entanglement between a noisy system and an ancillary system is analyzed in the context of continuous time open quantum system dynamics. Focusing on a couple of analytically solvable models for qubit systems, we study how Markovian and non-Markovian characteristics influence the problem, discussing in particular their associated entanglement-breaking regimes. These performances are compared with those one could achieve when the environment of the system is forced to return to its input configuration via periodic instantaneous resetting procedures.

quant-ph↗