Searcharxiv⌕ Search

arXiv subjects

Onofre Rojas

Publications and source records attributed to Onofre Rojas.

At least 19 recordsLinked to original sources
arXiv2026

Weak irreducibility as a spectral criterion for phase coexistence

Conventional finite-size theories describe first-order coexistence through free-energy competition and interfacial tunneling, but the distinct spectral roles of sector balance and inter-sector connectivity are not usually explicit. We show that pseudo-transitions and thermodynamic phase coexistence are governed by two spectral coordinates: sector imbalance locates balance, while connectivity determines whether that balance remains avoided. At balance, finite connectivity produces a unique dominant state with equal spectral weights in the symmetrized two-sector representation. For short-range systems with positive interface tension, interfacial costs suppress the connectivity exponentially, close the coexistence splitting, and asymptotically restore reducibility. Thus, genuine phase coexistence emerges as the singular limit of finite-size avoided coexistence, whereas one-dimensional pseudo-transitions retain finite connectivity. In a decorated bilayer Ising model, the coexistence gap at independently est

cond-mat.stat-mech↗
arXiv2026

Magnetoelastic control of quantum correlations and field sensitivity in a spin-1/2 Heisenberg dimer

We investigate the thermodynamic and quantum properties of a magnetoelastic spin-1/2 Heisenberg dimer, where the exchange interaction depends on the dimer displacement. By combining an exact treatment of the spin sector with a harmonic description of the vibrational degree of freedom, we obtain an effective model in which each spin configuration is associated with a distinct vibrational mode, leading to a non-factorizable partition function. We analyze the thermal behavior and identify regimes corresponding to entangled and fully polarized states. Quantum correlations are analyzed through concurrence and local quantum uncertainty, showing that while entanglement is rapidly suppressed by temperature, nonclassical correlations persist over a broader range due to the competition between spin sectors. We further examine the magnetic Fisher information, which provides a measure of the sensitivity of the system to the external magnetic field. Its behavior reveals enhanced response in crossover regions where magnetoelastic effects induce strong redistribution of the level populations. Our results demonstrate that magnetoelastic coupling plays a central role in controlling both quantum correlations and magnetic response, establishing a direct link between entanglement, nonclassical correlations, and thermodynamic sensitivity in coupled spin-dimer systems.

cond-mat.mes-hall↗
arXiv2026

Thermal pseudo-transitions in a frustrated spin-pseudospin sawtooth chain

We present an exact analysis of a spin--pseudospin X sawtooth chain that incorporates three distinct valence states of copper ions and serves as a minimal model for one-dimensional cuprates composed of corner-sharing copper triangles. The model includes magnetic exchange and electrostatic coupling constants both along the base sites and between base and apex sites capturing the competition between spin and charge degrees of freedom. Using the transfer-matrix method, we derive exact expressions for the free energy and obtain an analytical condition defining the pseudo-critical line associated with pronounced thermodynamic anomalies. The ground-state analysis reveals, besides an antiferromagnetic phase, three frustrated phases characterized by distinct residual entropies. At finite temperatures, these zero-temperature phase boundaries evolve into narrow entropy ridges signaling pseudo-transitions between the corresponding quasi-phases. The specific heat and the avoided-crossing scale exhibit sharp but continuous peaks at the pseudo-critical temperature, whereas the physical correlation length may be controlled by a different subleading eigenvalue. Local correlation functions uncover a cooperative rearrangement from charge-dominated to magnetically correlated regimes. Our results demonstrate that the sawtooth geometry promotes frustration and short-range coherence leading to pronounced pseudo-transition behavior.

cond-mat.stat-mech↗
arXiv2026

Thermodynamic and magnetocaloric properties of a triangular spin-1/2 cluster with Dzyaloshinskii-Moriya interaction

We present a theoretical investigation of the magnetic and thermodynamic properties of the triangular spin-1/2 cluster with Dzyaloshinskii-Moriya (DM) interaction, described by a spin-1/2 Heisenberg Hamiltonian with antisymmetric exchange interactions. The energy spectrum and ground-state phase diagram reveal the presence of ferromagnetic (FM), ferrimagnetic (FI), and frustrated (FR) phases, strongly influenced by the total spin and the DM interaction. We analyze magnetization and susceptibility, showing that at low temperatures the system exhibits a characteristic 1/3 magnetization plateau, while thermal fluctuations suppress magnetic order at higher temperatures. The entropy and specific heat display residual entropies due to ground-state degeneracies, Schottky-type anomalies at intermediate temperatures, and additional low-temperature features related to phase transitions. Particular attention is given to the magnetocaloric effect (MCE), characterized by both direct and inverse regimes depending on the magnetic field variation. We find that the DM interaction enhances the complexity of the MCE, leading to nontrivial entropy variations as a function of the magnetic field. These results provide insights into the role of frustration and anisotropy in tuning the MCE of properties triangular spin clusters, with relevance to \mathrm{Cu}_{3}-based molecular magnets.

cond-mat.mes-hall↗
arXiv2026

Dual thermal pseudocritical features in a spin-1/2 Ising chain with twin-diamond geometry

We study the coupled twin-diamond chain, a decorated one-dimensional Ising model motivated by the magnetic structure of $\mathrm{Cu}_{2}(\mathrm{TeO}_{3})_{2}\mathrm{Br}_{2}$. By applying an exact mapping to an effective Ising chain, we obtain the full thermodynamic description of the system through a compact transfer-matrix formulation. The ground-state analysis reveals five distinct phases, including two frustrated sectors with extensive degeneracy. These frustrated regions give rise to characteristic entropy plateaus and separate the ordered phases in the zero-temperature diagram. At low temperatures the model exhibits peculiar sharp yet continuous variations of entropy, magnetization, and response functions, reflecting clear signatures of pseudotransition behavior. The coupled twin-diamond chain thus provides an exactly solvable setting in which competing local configurations and internal frustration lead to pronounced dual pseudocritical features in one dimension.

cond-mat.stat-mech↗
arXiv2026

Spectral mechanism and nearly reducible transfer matrices for pseudotransitions in one-dimensional systems

While true phase transitions are forbidden in one-dimensional systems with short-range interactions, several models have recently been shown to exhibit sharp yet analytic thermodynamic anomalies that mimic thermal phase transitions. We show that this behavior arises from transfer matrices that are mathematically irreducible but possess a nearly block-diagonal structure due to the weak contribution of off-diagonal Boltzmann weights in the low-temperature regime. This results in weakly coupled competing sectors whose eigenvalue competition produces abrupt crossovers without nonanalyticity, a mechanism we term nearly block-diagonal irreducible. A key thermodynamic signature of such pseudotransitions is that the residual entropy at the interface remains bounded between the residual entropies of the competing sectors. We develop a general spectral framework to describe this behavior and apply it to two representative models: the Ising chain with internal degeneracy (Doniach model) and a hexagonal nanowire chain with mixed spin-1/2 and spin-1 components. In the first case, we derive exact expressions for the pseudo-critical temperature and residual entropy. In the second, we reduce the full $1458\times1458$ transfer matrix via symmetry decomposition and construct a low-rank effective matrix that accurately captures the crossover between quasi-ferromagnetic and quasi-core-ferromagnetic regimes. Our results demonstrate that pseudotransitions can be understood as spectral phenomena emerging from irreducible but functionally decoupled structures within the transfer matrix.

cond-mat.stat-mech↗
arXiv2026

Operational modes of a Raman-coupled two-qubit quantum thermal machine

We investigate a quantum thermal machine composed of two qubits coupled through a Raman-induced exchange interaction and driven by inhomogeneous transition frequencies. The system is analyzed within Carnot, Otto, and Stirling thermodynamic cycles, including the Stirling cycle with and without regeneration. We identify the conditions under which the device operates as a heat engine, refrigerator, thermal accelerator, or heater. Efficiency maps and operational-mode diagrams reveal well-defined boundaries in parameter space, governed by the frequency ratio $r=\barω/ω$, the coupling strength $g$, and the thermal gradient between reservoirs. The Carnot cycle exhibits sharp transitions between engine and refrigerator regimes, while the Otto cycle displays a richer structure with the coexistence of all operational modes. The Stirling cycle shows enhanced versatility and performance, particularly when assisted by a regenerator, where near-ideal efficiencies are achieved. Overall, the Raman-type interaction introduces a controllable left-right asymmetry that enables nontrivial manipulation of thermodynamic behavior through frequency tuning.

quant-ph↗
arXiv2025

Thermodynamic constraints and pseudotransition behavior in a one-dimensional water-like system

We investigate a one-dimensional water-like lattice model with Van der Waals and hydrogen-bond interactions, allowing for particle number fluctuations through a chemical potential. The model, defined on a chain with periodic boundary conditions, exhibits three ground-state phases: gas, bonded liquid, and dense liquid, separated by sharp phase boundaries in the chemical potential and temperature plane. Using the transfer matrix method, we derive exact analytical results within the grand-canonical ensemble and examine the finite-temperature behavior. The system exhibits clear pseudotransition features, including sharp but analytic changes in entropy, density, and internal energy, along with finite peaks in specific heat and correlation length. To assess the role of thermodynamic constraints, we consider the behavior under fixed density through a Legendre transformation. This constrained analysis reveals smoother anomalies, such as entropy kinks and finite jumps in specific heat, contrasting with the sharper grand-canonical signatures. These results underscore the ensemble dependence of pseudotransitions and show how statistical constraints modulate critical-like behavior. We also verify that the residual entropy continuity criterion holds in the grand-canonical ensemble but is violated when the system is constrained. Our findings illustrate how even a simple one-dimensional model can mimic water-like thermodynamic anomalies.

cond-mat.stat-mech↗
arXiv2025

Quantum Otto engine mimicking Carnot near pseudotransitions in the one-dimensional extended Hubbard model in the atomic limit

The one-dimensional extended Hubbard model (EHM) in the atomic limit has recently been found to exhibit a curious thermal pseudo-transition behavior, which closely resembles first and second-order thermal phase transitions. This phenomenon, occurring at half-filling, is influenced by the quantum phase transition between the alternating pair (AP) and paramagnetic (PM) phases at zero temperature. In this study, we leverage this anomalous behavior to investigate the performance of quantum many-body machines, using the EHM as the working substance. Our analysis reveals that the quantum Otto engine, when operating in the anomalous region, closely mimics the ideal Carnot engine. In this region, both the work output and thermal efficiency of the Otto engine increase, approaching the performance of a Carnot engine. This highlights the potential of many-body systems, such as the EHM, in enhancing quantum thermodynamic performance. Our findings demonstrate that, although the second law of thermodynamics prevents engines from surpassing Carnot efficiency, the Otto engine can operate remarkably close to this limit in the anomalous region, offering insights into new directions for future research on quantum thermodynamic cycles and working substances.

cond-mat.str-el↗
arXiv2024

Thermal quantum correlations of a single electron in a double quantum dot with transverse magnetic field

In this paper, we investigate the thermal quantum correlations in a semiconductor double quantum dot system. The device comprises a single electron in a double quantum dot subjected to a longitudinal magnetic field and a transverse magnetic field gradient. The thermal entanglement of the single electron is driven by the charge and spin qubits. Utilizing the density matrix formalism, we derive analytical expressions for thermal concurrence and correlated coherence. The main goal of this work is to provide a good understanding of the effects of temperature and various parameters on quantum coherence. Additionally, our findings indicate that the transverse magnetic field can be employed to adjust the thermal entanglement and quantum coherence of the system. We also highlight the roles of thermal entanglement and correlated coherence in generating quantum correlations, noting that thermal correlated coherence is consistently more robust than thermal entanglement. This suggests that quantum algorithms based solely on correlated coherence might be more resilient than those relying on entanglement.

quant-ph↗
arXiv2024

Quantum machines using $\rm{Cu}_{3}$-like compounds modeled by Heisenberg antiferromagnetic in a triangular ring

A theoretical study of an antiferromagnetically coupled spin system, specifically $\rm{Cu}_{3}-\rm{X}$ $(\rm{X=As, Sb})$, characterized by a slightly distorted equilateral triangle configuration is presented. Using the Heisenberg model with exchange and Dzyaloshinskii-Moriya interactions, g-factors, and an external magnetic field, three quantum machines are investigated using this system as the working substance, assuming reversible processes. For ${\rm{Cu}_{3}-\rm{X}}$ he magnetocaloric effect (MCE) is significant at low temperatures (around 1K) under a perpendicular magnetic field ($\sim5$T). Although only the $\rm{Cu}_{3}-\rm{As}$ compound is considered, since the $\rm{Cu}_{3}-\rm{Sb}$ compound behaves quite similarly. How MCE influences the Carnot machine, which operates as a heat engine or refrigerator when varying the external magnetic field is analyzed. In contrast, the Otto and Stirling machines can operate as heat engines, refrigerators, heaters, or thermal accelerators, depending on the magnetic field intensity. The results indicate that enhanced MCE broadens the operating regions for these machines, with the Otto and Stirling machines primarily functioning as refrigerators and accelerators. The corresponding thermal efficiencies are also discussed for all operating modes.

quant-ph↗
arXiv2024

Unusual low-temperature behavior in the half-filled band of the one-dimensional extended Hubbard model in atomic limit

Recently, a kind of finite-temperature pseudo-transition was observed in several quasi-one-dimensional models. In this work, we consider a genuine one-dimensional extended Hubbard model in the atomic limit, influenced by an external magnetic field and with the arbitrary number of particles controlled by the chemical potential. The one-dimensional extended Hubbard model in the atomic limit was initially studied in the seventies and has been investigated over the past decades, but it still surprises us today with its fascinating properties. We rigorously analyze its low-temperature behavior using the transfer matrix technique and provide accurate numerical results. Our analysis confirms that there is an anomalous behavior in the half-filled band, specifically occurring between the alternating pair (AP) and paramagnetic (PM) phases at zero temperature. Previous investigations did not deeply identify this anomalous behavior, maybe due to the numerical simplicity of the model, but from analytical point of view this is not so easy to manipulate algebraically because one needs to solve an algebraic cubic equation. In this study, we explore this behavior and clearly distinguish the pseudo-transition, which could easily be mistaken with a real phase transition. This anomalous behavior mimics features of both first- and second-order phase transitions. However, due to its nature, we cannot expect a finite-temperature phase transition in this model.

cond-mat.str-el↗
arXiv2024

Decoherence effects on local quantum Fisher information and quantum coherence in a spin-1/2 Ising-XYZ chain

This research explores the effects of decoherence on local quantum Fisher information and quantum coherence dynamics in a spin-1/2 Ising-XYZ chain model with independent reservoirs at zero temperature. Contrasting these effects with those in the spin-1/2 Heisenberg XYZ model reveals intricate interactions among quantum coherence, entanglement, and environmental decoherence in spin systems. Analysis of coherence dynamics highlights differences between the original and hybrid models, showcasing increased entanglement due to Ising interactions alongside reduced coherence from environmental redistribution. The local quantum Fisher information proves more resilient than coherence in specific scenarios, emphasizing decoherence is varying impacts on quantum correlations. This research underscores the complexity of quantum coherence dynamics and the crucial role of environmental factors in shaping quantum correlations, providing insights into entanglement and coherence behavior under environmental influences and guiding future studies in quantum information processing and correlation dynamics.

quant-ph↗
arXiv2023

Magnetocaloric effect in $\mathrm{Cu}_{3}$-type compounds using the Heisenberg antiferromagnetic model in a triangular ring

In this work we present a theoretical investigation into an antiferromagnetically coupled spin system, specifically ${\rm Cu}_{3}-X$ ($\mathrm{X=As,Sb}$), which exhibits an isosceles triangular configuration or slightly distorted equilateral triangular configuration, as previously identified in reference {[}Phys. Rev. Lett. \textbf{96}, 107202 (2006){]}. This system can be effectively represented by the Heisenberg model on a triangular structure, taking into account the exchange interaction, the Dzyaloshinskii-Moriya interaction, g-factors and external magnetic field, as delineated in the aforementioned reference. By using numerical approach we explore both zero-temperature and finite-temperature behaviors of a ${\rm Cu}_{3}$-like antiferromagnetically coupled spin system. At zero temperature, the system displays a 1/3 quasi-plateau magnetization, when the magnetic field is varied. Moreover, we place particular emphasis on magnetic properties including magnetization, magnetic susceptibility, entropy, and specific heat at finite temperatures. Furthermore, we investigate the magnetocaloric effect as a function of an externally imposed magnetic field, oriented both parallel and perpendicular to the plane of the triangular structure. Interestingly, these configurations demonstrate remarkably similar behavior for both orientations of the magnetic field. Our investigation also includes an analysis of the adiabatic curve, the Grüneisen parameter, and the variation in entropy when applied or removed the magnetic field. The magnetocaloric effect is found to be more prominent in low the temperature region, typically at $T\sim1$K, for both parallel and perpendicular magnetic fields at $\sim4.5$T and $\sim5$T, respectively.

cond-mat.str-el↗
arXiv2023

Zero temperature phase transitions and their anomalous influence on thermodynamic behavior in the q-state Potts model on a diamond chain

The q-state Potts model on a diamond chain has mathematical significance in analyzing phase transitions and critical behaviors in diverse fields, including statistical physics, condensed matter physics, and materials science. By focusing on the 3-state Potts model on a diamond chain, we reveal rich and analytically solvable behaviors without phase transitions at finite temperatures. Upon investigating thermodynamic properties such as internal energy, entropy, specific heat, and correlation length, we observe sharp changes near zero temperature. Magnetic properties, including magnetization and magnetic susceptibility, display distinct behaviors that provide insights into spin configurations in different phases. However, the Potts model lacks genuine phase transitions at finite temperatures, in line with the Peierls argument for one-dimensional systems. Nonetheless, in the general case of an arbitrary $q$-state, magnetic properties such as correlation length, magnetization, and magnetic susceptibility exhibit intriguing remnants of a zero-temperature phase transition at finite temperatures. Furthermore, residual entropy uncovers unusual frustrated regions at zero-temperature phase transitions. This feature leads to the peculiar thermodynamic properties of phase boundaries, including a sharp entropy change resembling a first-order discontinuity without an entropy jump, and pronounced peaks in second-order derivatives of free energy, suggestive of a second-order phase transition divergence, but without singularities. This unusual behavior is also observed in the correlation length at the pseudo-critical temperature, which could potentially be misleading as a divergence.

cond-mat.stat-mech↗
arXiv2023

Thermal entanglement and quantum coherence of a single electron in a double quantum dot with Rashba Interaction

In this work, we study the thermal quantum coherence and fidelity in a semiconductor double quantum dot. The device consists of a single electron in a double quantum dot with Rashba spin-orbit coupling in the presence of an external magnetic field. In our scenario, the thermal entanglement of the single electron is driven by the charge and spin qubits, the latter controlled by Rashba coupling. Analytical expressions are obtained for thermal concurrence and correlated coherence using the density matrix formalism. The main goal of this work is to provide a good understanding of the effects of temperature and several parameters in quantum coherence. In addition, our findings show that we can use the Rashba coupling to tune in the thermal entanglement, quantum coherence, as well as, the thermal fidelity behavior of the system. Moreover, we focus on the role played by thermal entanglement and correlated coherence responsible for quantum correlations. We observe that the correlated coherence is more robust than the thermal entanglement in all cases, so quantum algorithms based only on correlated coherence may be stronger than those based on entanglement.

cond-mat.mes-hall↗
arXiv2023

Towards a quasiphase transition in the single-file chain of water molecules: Simple lattice model

Recently, X.Ma et al. [Phys. Rev. Lett. 118, 027402 (2017)] have suggested that water molecules encapsulated in (6,5) single-wall carbon nanotube experience a temperature-induced quasiphase transition around 150 K interpreted as changes in the water dipoles orientation. We discuss further this temperature-driven quasiphase transition performing quantum chemical calculations and molecular dynamics simulations and, most importantly, suggesting a simple lattice model to reproduce the properties of the one-dimensionally confined finite arrays of water molecules. The lattice model takes into account not only the short-range and long-range interactions but also the rotations in a narrow tube and the both ingredients provide an explanation for a temperature-driven orientational ordering of the water molecules, which persists within a relatively wide temperature range.

cond-mat.stat-mech↗
arXiv2022

Emergence of quantum spin frustration in spin-1/2 Ising-Heisenberg model on a decorated honeycomb lattice

We study the spin-1/2 Ising-XXZ model on a decorated honeycomb lattice composed of five spins per unit cell, one Ising spin, and four Heisenberg spins. This model involving the Heisenberg exchange interaction is one of the few models that can be exactly solvable through the generalized star-triangle transformation. The significance of this model is its close relationship to the fully decorated quantum Heisenberg honeycomb lattice since 4/5 of the particles are Heisenberg spins. We investigate the phase diagram at zero temperature and identify a relevant quantum spin frustrated phase resulting from the contribution of quantum Heisenberg exchange interaction. We obtain an exact residual entropy for the quantum spin frustrated phase, which coincides with the residual entropy of the antiferromagnetic spin-1/2 Ising model on a triangular lattice. We also thoroughly explore its thermodynamic properties, focusing mainly on the frustrated region such as entropy, specific heat, spontaneous magnetization, and critical temperature under several conditions.

cond-mat.stat-mech↗