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Ortwin Hess

Publications and source records attributed to Ortwin Hess.

At least 37 records · Page 2Linked to original sources
arXiv2019

Quantum Plasmonic Immunoassay Sensing

Plasmon-polaritons are among the most promising candidates for next generation optical sensors due to their ability to support extremely confined electromagnetic fields and empower strong coupling of light and matter. Here we propose quantum plasmonic immunoassay sensing as an innovative scheme, which embeds immunoassay sensing with recently demonstrated room temperature strong coupling in nanoplasmonic cavities. In our protocol, the antibody-antigen-antibody complex is chemically linked with a quantum emitter label. Placing the quantum-emitter enhanced antibody-antigen-antibody complexes inside or close to a nanoplasmonic (hemisphere dimer) cavity facilitates strong coupling between the plasmon-polaritons and the emitter label resulting in signature Rabi splitting. Through rigorous statistical analysis of multiple analytes randomly distributed on the substrate in extensive realistic computational experiments, we demonstrate a drastic enhancement of the sensitivity up to nearly 1500% compared to conventional shifting-type plasmonic sensors. Most importantly and in stark contrast to classical sensing, we achieve in the strong-coupling (quantum) sensing regime an enhanced sensitivity that is no longer dependent on the concentration of antibody-antigen-antibody complexes -- down to the single-analyte limit. The quantum plasmonic immunoassay scheme thus not only leads to the development of plasmonic bio-sensing for single molecules but also opens up new pathways towards room-temperature quantum sensing enabled by biomolecular inspired protocols linked with quantum nanoplasmonics.

physics.optics↗
arXiv2019

Single plasmon hot carrier generation in metallic nanoparticles

Hot carriers produced from the decay of localized surface plasmons in metallic nanoparticles are intensely studied because of their optoelectronic, photovoltaic and photocatalytic applications. From a classical perspective, plasmons are coherent oscillations of the electrons in the nanoparticle, but their quantized nature comes to the fore in the novel field of quantum plasmonics. In this work, we introduce a quantum-mechanical material-specific approach for describing the decay of single quantized plasmons into hot electrons and holes. We find that hot carrier generation rates differ significantly from semiclassical predictions. We also investigate the decay of excitations without plasmonic character and show that their hot carrier rates are comparable to those from the decay of plasmonic excitations for small nanoparticles. Our study provides a rigorous and general foundation for further development of plasmonic hot carrier studies in the plasmonic regime required for the design of ultrasmall devices.

cond-mat.mes-hall↗
arXiv2018

Non-local quantum gain facilitates loss compensation and plasmon amplification in graphene hyperbolic metamaterials

Graphene-based hyperbolic metamaterials have been predicted to transport evanescent fields with extraordinarily large vacuum wave-vectors. It is particularly at much higher wave vector values that the commonly employed descriptional models involving structure homogenization and assumptions of an approximatively local graphene conductivity start breaking down. Here, we combine a non-local quantum conductivity model of graphene with an exact mathematical treatment of the periodic structure in order to develop a tool-set for determining the hyperbolic behavior of these graphene-based hyperbolic metamaterials. The quantum conductivity model of graphene facilitates us to predict the plasmonic amplification in graphene sheets of the considered structures. This allows us to reverse the problem of Ohmic and temperature losses, making this simple yet powerful arrangement practically applicable. We analyze the electric field distribution inside of the finite structures, concluding that Bloch boundary solutions can be used to predict their behavior. With the transfer matrix method we show that at finite temperature and collision loss we can compensate for losses, restoring imaging qualities of the finite structure via an introduction of chemical imbalance.

physics.app-ph↗
arXiv2018

Coulomb effects on the photo-excited quantum dynamics of electrons in a plasmonic nanosphere

With recent experiments investigating the optical properties of progressively smaller plasmonic particles, quantum effects become increasingly more relevant, requiring a microscopic description. Using the density matrix formalism we analyze the photo-excited few-electron dynamics of a small nanosphere. Following the standard derivation of the bulk plasmon we particularly aim on elucidating the role of the Coulomb interaction. Calculating the dielectric susceptibility spectrum in the linear optical response we find discrete resonances resulting from a collective response mediated by the Coulomb interaction between the electrons. In the nonlinear regime, the occupations of the system exhibit oscillations between the interacting eigenstates. Our approach provides an ideal platform to study and explain nonlinear and quantum plasmonics, revealing that the photo-excited dynamics of plasmonic nano spheres has similarities with and combines characteristics of both, the well-known two-level Rabi dynamics, and the collective many-electron behavior typical of plasmons.

cond-mat.mes-hall↗
arXiv2018

Suppressing spatio-temporal lasing instabilities with wave-chaotic microcavities

Spatio-temporal instabilities are widespread phenomena resulting from complexity and nonlinearity. In broad-area edge-emitting semiconductor lasers, the nonlinear interactions of multiple spatial modes with the active medium can result in filamentation and spatio-temporal chaos. These instabilities degrade the laser performance and are extremely challenging to control. We demonstrate a powerful approach to suppress spatio-temporal instabilities using wave-chaotic or disordered cavities. The interference of many propagating waves with random phases in such cavities disrupts the formation of self-organized structures like filaments, resulting in stable lasing dynamics. Our method provides a general and robust scheme to prevent the formation and growth of nonlinear instabilities for a large variety of high-power lasers.

physics.optics↗
arXiv2018

Coherent phonon lasing in a thermal quantum nanomachine

The notion of nanomachines has recently emerged to engage and use collective action of ensembles of nanoscale components or systems. Here we present a heat-gradient driven nanomachine concept which through appropriate coupling between quantum nanosystems is capable of realising and maintaining an inversion. Based on a Lindblad form of the Quantum Master Equation with a semiclassical coupling to the lattice displacement phonon field we show that this positive inversion can be harnessed to generate coherent optomechanical oscillations and phonon lasing.

cond-mat.mes-hall↗
arXiv2018

Polarization and plasmons in hot photoexcited graphene

We present a robust and exact method for calculating the polarization function and plasmon dispersion of graphene, for an arbitrary (isotropic) non-equilibrium carrier distribution, within random phase approximation (RPA). This is demonstrated for a range of carrier distributions, including hot carrier distributions which occur within the femtoseconds following photoexcitation. We show that qualitatively different behaviour from the equilibrium case can occur. As the polarization function determines dynamic screening, its calculation shall be essential to quantifying carrier-carrier scattering channels for graphene far from equilibrium.

cond-mat.mes-hall↗
arXiv2017

Mapping nanoscale hotspots with single-molecule emitters assembled into plasmonic nanocavities using DNA origami

Fabricating nanocavities in which optically-active single quantum emitters are precisely positioned, is crucial for building nanophotonic devices. Here we show that self-assembly based on robust DNA-origami constructs can precisely position single molecules laterally within sub-5nm gaps between plasmonic substrates that support intense optical confinement. By placing single-molecules at the center of a nanocavity, we show modification of the plasmon cavity resonance before and after bleaching the chromophore, and obtain enhancements of $\geq4\times10^3$ with high quantum yield ($\geq50$%). By varying the lateral position of the molecule in the gap, we directly map the spatial profile of the local density of optical states with a resolution of $\pm1.5$ nm. Our approach introduces a straightforward non-invasive way to measure and quantify confined optical modes on the nanoscale.

physics.optics↗
arXiv2017

A group theoretical route to deterministic Weyl points in chiral photonic lattices

Classical topological phases derived from point degeneracies in photonic bandstructures show intriguing and unique behaviour. Previously identified exceptional points are based on accidental degeneracies and subject to engineering on a case-by-case basis. Here we show that symmetry induced (deterministic) pseudo Weyl points with non-trivial topology and hyper-conic dispersion exist at the centre of the Brillouin zone of chiral cubic systems. We establish the physical implications by means of a $P2_13$ sphere packing, realised as a nano plasmonic system and a photonic crystal.

physics.optics↗
arXiv2017

Suppressed Quenching and Strong Coupling of Purcell-Enhanced Single-Molecule Emission in Plasmonic Nanocavities

An emitter in the vicinity of a metal nanostructure is quenched by its decay through non-radiative channels, leading to the belief in a zone of inactivity for emitters placed within $<$10nm of a plasmonic nanostructure. Here we demonstrate that in tightly-coupled plasmonic resonators forming nanocavities "quenching is quenched" due to plasmon mixing. Unlike isolated nanoparticles, plasmonic nanocavities show mode hybridization which massively enhances emitter excitation and decay via radiative channels. This creates ideal conditions for realizing single-molecule strong-coupling with plasmons, evident in dynamic Rabi-oscillations and experimentally confirmed by laterally dependent emitter placement through DNA-origami.

physics.optics↗
arXiv2016

Dynamical calculation of third harmonic generation in a semiconductor quantum well

Non-linear phenomena in optically excited semiconductor structures are of high interest. We here develop a model capable of studying the dynamics of the photoexcited carriers, including Coulomb interaction on a Hartree-Fock level, on the same footing as the dynamics of the light field impinging on an arbitrary photonic structure. Applying this method to calculate the third harmonic generation in a semiconductor quantum well embedded in a Bragg mirror structure, we find that the power-law exponent of the intensity dependence of the third harmonic generation depends on the frequency of the exciting pulse. Off-resonant pulses follow the expected cubic dependence, while the exponent is smaller for resonant pulses due to saturation effects in the induced carrier density. Our study provides a detailed understanding of the carrier and light field dynamics during non-linear processes.

cond-mat.mes-hall↗
arXiv2015

Nonequilibrium plasmons with gain in graphene

Graphene supports strongly confined transverse-magnetic sheet plasmons whose spectral characteristics depend on the energetic distribution of Dirac particles. The question arises whether plasmons can become amplified when graphene is pumped into a state of inversion. In establishing a theory for the dynamic non-equilibrium polarizability, we are able to determine the exact complex-frequency plasmon dispersion of photo-inverted graphene and study the impact of doping, collision loss, and temperature on the plasmon gain. We calculate the spontaneous emission spectra and carrier recombination rates self-consistently and compare the results with approximations based on Fermi's golden rule. Our results show that amplification of plasmons is possible under realistic conditions but inevitably competes with ultrafast spontaneous emission, which for intrinsic graphene, is a factor 5 faster than previously estimated. This work casts new light on the nature of non-equilibrium plasmons and may aid the experimental realization of active plasmonic devices based on graphene.

cond-mat.mes-hall↗
arXiv2013

Dispersive Media Subcell Averaging in the FDTD Method using Corrective Surface Currents

We present a corrective subcell averaging technique that improves on the accuracy of the volume-averaged finite-difference time-domain (FDTD) method in the presence of dispersive material interfaces. The method is based on an alternative effective-medium formulation that captures field discontinuities at interfaces as electric and magnetic surface currents. In calculating the spectra of strongly dispersive Mie scatterers we demonstrate that the derived FDTD algorithm is both highly efficient and able to approximately restore second order accuracy.

physics.comp-ph↗
arXiv2013

Plasmonic Nano-Gap Tilings: Light-Concentrating Surfaces for Low-Loss Photonic Integration

Owing to their ability to concentrate light on nanometer scales, plasmonic surface structures are ideally suited for on-chip functionalization with nonlinear or gain materials. However, achieving a high effective quantum yield across a surface not only requires strong light localization but also control over losses. Here, we report on a particular class of tunable low-loss metasurfaces featuring dense arrangements of nanometer sized focal points on a photonic chip with an underlying waveguide channel. Guided within the plane, the photonic wave evanescently couples to the nano-gaps, concentrating light in a lattice of hot-spots. In studying the energy transfer between photonic and plasmonic channels of single trimer molecules and triangular nano-gap tilings in dependence on element size, we identify different regimes of operation. We show that the product of field enhancement, propagation length and element size is close-to-constant in both the radiative and subwavelength regimes, opening pathways for device designs that combine high field enhancements with large propagation lengths.

physics.optics↗
arXiv2013

Dirac-like plasmons in honeycomb lattices of metallic nanoparticles

We consider a two-dimensional honeycomb lattice of metallic nanoparticles, each supporting a localized surface plasmon, and study the quantum properties of the collective plasmons resulting from the near field dipolar interaction between the nanoparticles. We analytically investigate the dispersion, the effective Hamiltonian and the eigenstates of the collective plasmons for an arbitrary orientation of the individual dipole moments. When the polarization points close to the normal to the plane the spectrum presents Dirac cones, similar to those present in the electronic band structure of graphene. We derive the effective Dirac Hamiltonian for the collective plasmons and show that the corresponding spinor eigenstates represent Dirac-like massless bosonic excitations that present similar effects to electrons in graphene, such as a non-trivial Berry phase and the absence of backscattering off smooth inhomogeneities. We further discuss how one can manipulate the Dirac points in the Brillouin zone and open a gap in the collective plasmon dispersion by modifying the polarization of the localized surface plasmons, paving the way for a fully tunable plasmonic analogue of graphene.

cond-mat.mes-hall↗
arXiv2013

Analytic theory of optical nano-plasmonic metamaterials

Recent advances in nano-fabrication techniques allow for the manufacture of optical metamaterials, bringing their unique and extra-ordinary properties to the visible regime and beyond. However, an analytical description of optical nano-plasmonic metamaterials is challenging due to the characteristic optical behaviour of metals. Here we present an analytical theory that allows to bring established microwave metamaterials models to optical wavelengths. This method is implemented for nano-scaled plasmonic wire-mesh and tri-helical metamaterials, and we obtain an accurate prediction for their dispersive behaviour at optical and near-IR wavelengths.

physics.optics↗
arXiv2013

Linear coupling between lightwaves in metamaterials enables lossless artificial magnetism

A well-known principle in optical physics states that power can never be exchanged between two light waves propagating inside a homogeneous medium when the medium response is strictly linear. Power exchange between light waves usually occurs with the aid of nonlinearity. A typical example is nonlinear optical parametric amplification where net energy can flow from a high-frequency (high-energy) light wave (pump) to a lower-frequency signal wave, leading to amplification of the signal wave. Here, we show that this limitation of ordinary media can be overcome using suitably engineered metamaterials, which in the recent past have enabled a variety of extraordinary applications, unattainable using conventional materials, such as perfect lenses, invisibility cloaks and trapped rainbows. We introduce a blueprint for magnetic metamaterials that enables, in a totally linear fashion, coherent and constructive active power flow from one light wave to another (second) light wave.

physics.optics↗