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P. Caselli

Publications and source records attributed to P. Caselli.

At least 217 records · Page 12Linked to original sources

Chemical tracers in proto-brown dwarfs: CO, ortho-H$_{2}$CO, para-H$_{2}$CO, HCO$^{+}$, CS observations

We present a study of the CO isotopologues and the high-density tracers H$_{2}$CO, HCO$^{+}$, and CS in Class 0/I proto-brown dwarfs (proto-BDs). We have used the IRAM 30m telescope to observe the $^{12}$CO (2-1), $^{13}$CO (2-1), C$^{18}$O (2-1), C$^{17}$O (2-1), H$_{2}$CO (3-2), HCO$^{+}$ (3-2), and CS (5-4) lines in 7 proto-BDs. The hydrogen column density for the proto-BDs derived from the CO gas emission is $\sim$2-15 times lower than that derived from the dust continuum emission, indicating CO depletion from the gas-phase. The mean H$_{2}$CO ortho-to-para ratio is $\sim$3 for the proto-BDs and indicates gas-phase formation for H$_{2}$CO. We have investigated the correlations in the molecular abundances between the proto-BDs and protostars. Proto-BDs on average show a factor of $\sim$2 higher ortho-to-para H$_{2}$CO ratio than the protostars. Possible explanations include a difference in the H$_{2}$CO formation mechanism, spin-selective photo-dissociation, self-shielding effects, or different emitting regions for the ortho and para species. There is a tentative trend of a decline in the HCO$^{+}$ and H$_{2}$CO abundances with decreasing bolometric luminosity, while the CS and CO abundances show no particular difference between the proto-BDs and protostars. These trends reflect the scaled-down physical structures for the proto-BDs compared to protostars and differences in the peak emitting regions for these species. The C$^{17}$O isotopologue is detected in all of the proto-BDs as well as the more evolved Class Flat/Class II BDs in our sample, and can probe the quiescent gas at both early and late evolutionary stages.

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O2 signature in thin and thick O2-H2O ices

Aims. In this paper we investigate the detectability of the molecular oxygen in icy dust grain mantles towards astronomical objects. Methods. We present a systematic set of experiments with O2-H2O ice mixtures designed to disentangle how the molecular ratio affects the O2 signature in the mid- and near-infrared spectral regions. All the experiments were conducted in a closed-cycle helium cryostat coupled to a Fourier transform infrared spectrometer. The ice mixtures comprise varying thicknesses from 8 $\times$ 10$^{-3}$ to 3 $μ$m. The absorption spectra of the O2-H2O mixtures are also compared to the one of pure water. In addition, the possibility to detect the O2 in icy bodies and in the interstellar medium is discussed. Results. We are able to see the O2 feature at 1551 cm$^{-1}$ even for the most diluted mixture of H2O : O2 = 9 : 1, comparable to a ratio of O2/H2O = 10 % which has already been detected in situ in the coma of the comet 67P/Churyumov-Gerasimenko. We provide an estimate for the detection of O2 with the future mission of the James Webb Space Telescope (JWST).

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Gravitational instabilities in a protosolar-like disc III: molecular line detection and sensitivities

At the time of formation, protoplanetary discs likely contain a comparable mass to their host protostars. As a result, gravitational instabilities (GIs) are expected to play a pivotal role in the early phases of disc evolution. However, as these young objects are heavily embedded, confirmation of GIs has remained elusive. Therefore, we use the radiative transfer code LIME to produce line images of a $0.17\,\mathrm{M}_{\odot}$ self-gravitating protosolar-like disc. We note the limitations of using LIME and explore methods to improve upon the default gridding. We synthesise noiseless observations to determine the sensitivities required to detect the spiral flux, and find that the line flux distribution does not necessarily correlate to the abundance density distribution; hence performing radiative transfer calculations is imperative. Moreover, the spiral features are seen in absorption, due to the GI-heated midplane and high extinction, which could be indicative of GI activity. If a small beamsize and appropriate molecular line are used then spatially resolving spirals in a protosolar-like disc should be possible with ALMA for an on-source time of 30 hr. Spectrally resolving non-axisymmetric structure takes only a tenth as long for a reasonable noise level, but attributing this structure to GI-induced activity would be tentative. Finally, we find that identifying finger-like features in PV diagrams of nearly edge-on discs, which are a direct indicator of spirals, is feasible with an on-source time of 19 hr, and hence likely offers the most promising means of confirming GI-driven spiral structure in young, embedded protoplanetary discs.

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Chemical tracers in proto-brown dwarfs: CN, HCN, and HNC observations

We present results from a study of nitrogen chemistry in Class 0/I proto-brown dwarfs (proto-BDs). We have used the IRAM 30 m telescope to observe the CN (2-1), HCN (3-2), and HNC (3-2) lines in 7 proto-BDs. All proto-BDs show a large CN/HCN abundance ratio of >20, and a HNC/HCN abundance ratio close to or larger than unity. The enhanced CN/HCN ratios can be explained by high UV flux originating from an active accretion zone in the proto-BDs. The larger than unity HNC/HCN ratio for the proto-BDs is likely caused by a combination of low temperature and high density. Both CN and HNC show a flat distribution with CO, indicating that these species can survive in regions where CO is depleted. We have investigated the correlations in the molecular abundances of these species for the proto-BDs with Class 0/I protostars. We find tentative trends of CN (HCN) abundances being about an order of magnitude higher (lower) in the proto-BDs compared to protostars. HNC for the proto-BDs shows a nearly constant abundance unlike the large spread of ~2 orders of magnitude seen for the protostars. Also notable is a rise in the HNC/HCN abundance ratio for the lowest luminosity objects, suggesting that this ratio is higher under low-temperature environments. None of the relatively evolved Class Flat/Class II brown dwarfs in our sample show emission in HNC. The HNC molecule can be considered as an efficient tracer to search and identify early stage sub-stellar mass objects.

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Protonated CO2 in massive star-forming clumps

Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated form, HOCO+, is believed to be a good proxy for gaseous CO2. However, it has been detected in only a few star-forming regions so far, so that its interstellar chemistry is not well understood. We present new detections of HOCO+ lines in 11 high-mass star-forming clumps. Our observations increase by more than three times the number of detections in star-forming regions so far. We have derived beam-averaged abundances relative to H2 in between 0.3 and 3.8 x 10^{-11}. We have compared these values with the abundances of H13CO+, a possible gas-phase precursor of HOCO+, and CH3OH, a product of surface chemistry. We have found a positive correlation with H13CO+, while with CH3OH there is no correlation. We suggest that the gas-phase formation route starting from HCO+ plays an important role in the formation of HOCO+, perhaps more relevant than protonation of CO2 (upon evaporation of this latter from icy dust mantles).

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Mapping deuterated methanol toward L1544: I. Deuterium fraction and comparison with modeling

The study of deuteration in pre-stellar cores is important to understand the physical and chemical initial conditions in the process of star formation. In particular, observations toward pre-stellar cores of methanol and deuterated methanol, solely formed on the surface of dust grains, may provide useful insights on surface processes at low temperatures. Here we analyze maps of CO, methanol, formaldehyde and their deuterated isotopologues toward a well-known pre-stellar core. This study allows us to test current gas-dust chemical models. Single-dish observations of CH$_3$OH, CH$_2$DOH, H$_2$CO, H$_2\,^{13}$CO, HDCO, D$_2$CO and C$^{17}$O toward the prototypical pre-stellar core L1544 were performed at the IRAM 30 m telescope. We analyze their column densities, distributions, and compare these observations with gas-grain chemical models. The maximum deuterium fraction derived for methanol is [CH$_2$DOH]/[CH$_3$OH] $\sim$ 0.08$\pm$0.02, while the measured deuterium fractions of formaldehyde at the dust peak are [HDCO]/[H$_2$CO] $\sim$ 0.03$\pm$0.02, [D$_2$CO]/[H$_2$CO] $\sim$ 0.04$\pm$0.03 and [D$_2$CO]/[HDCO] $\sim$ 1.2$\pm$0.3. Observations differ significantly from the predictions of models, finding discrepancies between a factor of 10 and a factor of 100 in most cases. It is clear though that to efficiently produce methanol on the surface of dust grains, quantum tunneling diffusion of H atoms must be switched on. It also appears that the currently adopted reactive desorption efficiency of methanol is overestimated and/or that abstraction reactions play an important role. More laboratory work is needed to shed light on the chemistry of methanol, an important precursor of complex organic molecules in space.

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A study of the $c$-$\mathrm{C_{3}HD}$/$c$-$\mathrm{C_{3}H_{2}}$ ratio in low-mass star forming regions

We use the deuteration of $c$-$\mathrm{C_{3}H_{2}}$ to probe the physical parameters of starless and protostellar cores, related to their evolutionary states, and compare it to the $\mathrm{N_{2}H^{+}}$-deuteration in order to study possible differences between the deuteration of C- and N-bearing species. We observed the main species $c$-$\mathrm{C_{3}H_{2}}$, the singly and doubly deuterated species $c$-$\mathrm{C_{3}HD}$ and $c$-$\mathrm{C_{3}D_{2}}$, as well as the isotopologue $c$-$\mathrm{{H^{13}CC_{2}H}}$ toward 10 starless cores and 5 protostars in the Taurus and Perseus Complexes. We examined the correlation between the $N$($c$-$\mathrm{C_{3}HD}$)/$N$($c$-$\mathrm{C_{3}H_{2}}$) ratio and the dust temperature along with the $\mathrm{H_2}$ column density and the CO depletion factor. The resulting $N$($c$-$\mathrm{C_{3}HD}$)/$N$($c$-$\mathrm{C_{3}H_{2}}$) ratio is within the error bars consistent with $10\%$ in all starless cores with detected $c$-$\mathrm{C_{3}HD}$. This also accounts for the protostars except for the source HH211, where we measure a high deuteration level of $23\%$. The deuteration of $\mathrm{N_{2}H^{+}}$ follows the same trend but is considerably higher in the dynamically evolved core L1544. Toward the protostellar cores the coolest objects show the largest deuterium fraction in $c$-$\mathrm{C_{3}H_{2}}$. We show that the deuteration of $c$-$\mathrm{C_{3}H_{2}}$ can trace the early phases of star formation and is comparable to that of $\mathrm{N_{2}H^{+}}$. However, the largest $c$-$\mathrm{C_{3}H_{2}}$ deuteration level is found toward protostellar cores, suggesting that while $c$-$\mathrm{C_{3}H_{2}}$ is mainly frozen onto dust grains in the central regions of starless cores, active deuteration is taking place on ice.

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Kinematics of dense gas in the L1495 filament

We study the kinematics of the dense gas of starless and protostellar cores traced by the N2D+(2-1), N2H+(1-0), DCO+(2-1), and H13CO+(1-0) transitions along the L1495 filament and the kinematic links between the cores and the surrounding molecular cloud. We measure velocity dispersions, local and total velocity gradients and estimate the specific angular momenta of 13 dense cores in the four transitions using the on-the-fly observations with the IRAM 30 m antenna. To study a possible connection to the filament gas, we use the fit results of the C18O(1-0) survey performed by Hacar et al. (2013). All cores show similar properties along the 10 pc-long filament. N2D+(2-1) shows the most centrally concentrated structure, followed by N2H+(1-0) and DCO+(2-1), which show similar spatial extent, and H13CO+(1-0). The non-thermal contribution to the velocity dispersion increases from higher to lower density tracers. The change of magnitude and direction of the total velocity gradients depending on the tracer used indicates that internal motions change at different depths within the cloud. N2D+ and N2H+ show smaller gradients than the lower density tracers DCO+ and H13CO+, implying a loss of specific angular momentum at small scales. At the level of cloud-core transition, the core's external envelope traced by DCO+ and H13CO+ is spinning up, consistent with conservation of angular momentum during core contraction. C18O traces the more extended cloud material whose kinematics is not affected by the presence of dense cores. The decrease in specific angular momentum towards the centres of the cores shows the importance of local magnetic fields to the small scale dynamics of the cores. The random distributions of angles between the total velocity gradient and large scale magnetic field suggests that the magnetic fields may become important only in the high density gas within dense cores.

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Compact dusty clouds and efficient H$_2$ formation in diffuse ISM

The formation of compact dusty clouds in diffuse interstellar medium (ISM) has been recently proposed and studied by Tsytovich et al. (2014). In the present paper, an effect of the clouds on the rate of H$\to$H$_2$ transition in the ISM is examined. We discuss the mechanisms leading to the formation of the clouds and the creation of gaseous clumps around them, analyze the main processes determining the efficiency of the recombination of atomic hydrogen on dust grains, and estimate the expected enhancement of the global H$_2$ formation due to the presence of the clouds. In conclusion, we argue that the compact dusty clouds provide optimum conditions for the atomic recombination in diffuse ISM, and point out some astrophysical implications of the resulting H$_2$ formation enhancement.

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SOLIS IV. Hydrocarbons in the OMC-2 FIR 4 region, a probe of energetic particle irradiation of the region

We report new interferometric images of cyclopropenylidene, c-C$_3$H$_2$, towards the young protocluster OMC-2 FIR\,4. The observations were performed at 82 and 85 GHz with the NOrthern Extended Millimeter Array (NOEMA) as part of the project Seeds Of Life In Space (SOLIS). In addition, IRAM-30m data observations were used to investigate the physical structure of OMC-2 FIR\,4. We find that the c-C$_3$H$_2$ gas emits from the same region where previous SOLIS observations showed bright HC$_5$N emission. From a non-LTE analysis of the IRAM-30m data, the c-C$_3$H$_2$ gas has an average temperature of $\sim$40K, a H$_2$ density of $\sim$3$\times$10$^{5}$~cm$^{-3}$, and a c-C$_3$H$_2$ abundance relative to H$_2$ of ($7\pm1$)$\times$10$^{-12}$. In addition, the NOEMA observations provide no sign of significant c-C$_3$H$_2$ excitation temperature gradients across the region (about 3-4 beams), with T$_{ex}$ in the range 8$\pm$3 up to 16$\pm$7K. We thus infer that our observations are inconsistent with a physical interaction of the OMC-2 FIR\,4 envelope with the outflow arising from OMC-2 FIR\,3, as claimed by previous studies. The comparison of the measured c-C$_3$H$_2$ abundance with the predictions from an astrochemical PDR model indicates that OMC-2 FIR\,4 is irradiated by a FUV field $\sim$1000 times larger than the interstellar one, and by a flux of ionising particles $\sim$4000 times larger than the canonical value of $1\times10^{-17}$~s$^{-1}$ from the Galaxy cosmic rays, which is consistent with our previous HC$_5$N observations. This provides an important and independent confirmation of other studies that one or more sources inside the OMC-2 FIR\,4 region emit energetic ($\geq10$~MeV) particles.

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Nitrogen fractionation in high-mass star-forming cores across the Galaxy

The fractionation of nitrogen (N) in star-forming regions is a poorly understood process. To put more stringent observational constraints on the N-fractionation, we have observed with the IRAM-30m telescope a large sample of 66 cores in massive star-forming regions. We targeted the (1-0) rotational transition of HN$^{13}$C, HC$^{15}$N, H$^{13}$CN and HC$^{15}$N, and derived the $^{14}$N/$^{15}$N ratio for both HCN and HNC. We have completed this sample with that already observed by Colzi et al. (2018), and thus analysed a total sample of 87 sources. The $^{14}$N/$^{15}$N ratios are distributed around the Proto-Solar Nebula value with a lower limit near the terrestrial atmosphere value ($\sim$272). We have also derived the $^{14}$N/$^{15}$N ratio as a function of the Galactocentric distance and deduced a linear trend based on unprecedented statistics. The Galactocentric dependences that we have found are consistent, in the slope, with past works but we have found a new local $^{14}$N/$^{15}$N value of $\sim$400, i.e. closer to the Prosolar Nebula value. A second analysis was done, and a parabolic Galactocentric trend was found. Comparison with Galactic chemical evolution models shows that the slope until 8 kpc is consistent with the linear analysis, while the flattening trend above 8 kpc is well reproduced by the parabolic analysis.

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Penetration of cosmic rays into dense molecular clouds: role of diffuse envelope

A flux of cosmic rays (CRs) propagating through a diffuse ionized gas can excite MHD waves, thus generating magnetic disturbances. We propose a generic model of CR penetration into molecular clouds through their diffuse envelopes, and identify the leading physical processes controlling their transport on the way from a highly ionized interstellar medium to a dense interior of the cloud. The model allows us to describe a transition between a free streaming of CRs and their diffusive propagation, determined by the scattering on the self-generated disturbances. A self consistent set of equations, governing the diffusive transport regime in an envelope and the MHD turbulence generated by the modulated CR flux, is essentially characterized by two dimensionless numbers. We demonstrate a remarkable mutual complementarity of different mechanisms leading to the onset of the diffusive regime, which results in a universal energy spectrum of the modulated CRs. In conclusion, we briefly discuss implications of our results for several fundamental astrophysical problems, such as the spatial distribution of CRs in the Galaxy as well as the ionization, heating, and chemistry in dense molecular clouds.

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On the origin of phosphorus nitride in star-forming regions

We present multi-transition observations of PN towards a sample of nine massive dense cores in different evolutionary stages. Using transitions with different excitation conditions, we have found for the first time that the excitation temperatures of PN are in the range 5-30 K. To investigate the main chemical route for the PN formation (surface-chemistry vs. gas-phase chemistry), and the dominant desorption mechanism (thermal vs. shock), we have compared our results with those obtained from molecules tracing different chemical and physical conditions (SiO, SO, CH3OH, and N2H+). We have found that the PN line profiles are very well correlated with those of SiO and SO in six out of the nine targets, which indicates that PN may be released by sputtering of dust grains due to shocks. This finding is corroborated by a faint but statistically significant positive trend between the PN abundance and those of SiO and SO. However, in three objects the PN lines have no hints of high velocity wings, which indicates an alternative origin of PN. Overall, our results indicate that the origin of PN is not unique, as it can be formed in protostellar shocks, but also in colder and more quiescent gas through alternative pathways.

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Hydrodynamics with gas-grain chemistry and radiative transfer: comparing dynamical and static models

We quantify if the chemical abundance gradients given by a dynamical model of core collapse including time-dependent changes in density and temperature differ greatly from abundances derived from static models, where the density and temperature structures of the core are kept fixed as the chemistry evolves. For this study we developed a new one-dimensional spherically symmetric hydrodynamics code that couples the hydrodynamics equations with a comprehensive time-dependent gas-grain chemical model, including deuterium and spin-state chemistry, and radiative transfer calculations to derive self-consistent time-dependent chemical abundance gradients. We applied the code to model the collapse of a starless core up to the point when the infall flow becomes supersonic. The abundances predicted by the dynamical and static models are almost identical during the quiescent phase of core evolution, but the results start to diverge after the onset of core collapse, where the static model underestimates abundances at high medium density (inner core) and underestimates them at low density (outer core), and this is clearly reflected in simulated lines. The static model generally overestimates deuteration, which is increasingly evident the more D atoms are substituted in the molecule. We also find that using a limited chemical network, or a limited set of cooling molecules, may lead to an overestimate of the collapse timescale, and in some cases may prevent the collapse altogether. In our model, most of the line cooling near the center of the core is due to HCN, CO, and NO. In conclusion, the use of a static physical model is not a reliable method of simulating chemical abundances in starless cores after the onset of gravitational collapse. The adoption of complex chemistry and a comprehensive set of cooling molecules is necessary to model the collapse adequately.

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Similar complex kinematics within two massive, filamentary infrared dark clouds

Infrared dark clouds (IRDCs) are thought to be potential hosts of the elusive early phases of high-mass star formation. Here we conduct an in-depth kinematic analysis of one such IRDC, G034.43+00.24 (Cloud F), using high sensitivity and high spectral resolution IRAM-30m N$_2$H$^+$ ($1-0$) and C$^{18}$O ($1-0$) observations. To disentangle the complex velocity structure within this cloud we use Gaussian decomposition and hierarchical clustering algorithms. We find that four distinct coherent velocity components are present within Cloud F. The properties of these components are compared to those found in a similar IRDC, G035.39-00.33 (Cloud H). We find that the components in both clouds have: high densities (inferred by their identification in N$_2$H$^+$), trans-to-supersonic non-thermal velocity dispersions with Mach numbers of $\sim$ $1.5-4$, a separation in velocity of $\sim$3 km s$^{-1}$, and a mean red-shift of $\sim$ 0.3 km s$^{-1}$ between the N$_2$H$^+$ (dense gas) and C$^{18}$O emission (envelope gas). The latter of these could suggest that these clouds share a common formation scenario. We investigate the kinematics of the larger-scale Cloud F structures, using lower-density-tracing $^{13}$CO ($1-0$) observations. A good correspondence is found between the components identified in the IRAM-30m observations and the most prominent component in the$^{13}$CO data. We find that the IRDC Cloud F is only a small part of a much larger structure, which appears to be an inter-arm filament of the Milky Way.

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Accurate millimetre and submillimetre rest frequencies for $cis$- and $trans$-dithioformic acid, HCSSH

A better understanding of sulphur chemistry is needed to solve the interstellar sulphur depletion problem. A way to achieve this goal is to study new S-bearing molecules in the laboratory, obtaining accurate rest frequencies for an astronomical search. We focus on dithioformic acid, HCSSH, which is the sulphur analogue of formic acid. The aim of this study is to provide an accurate line list of the two HCSSH $trans$ and $cis$ isomers in their electronic ground state and a comprehensive centrifugal distortion analysis with an extension of measurements in the millimetre and submillimetre range. We studied the two isomers in the laboratory using an absorption spectrometer employing the frequency-modulation technique. The molecules were produced directly within a free-space cell by glow discharge of a gas mixture. We measured lines belonging to the electronic ground state up to 478 GHz, with a total number of 204 and 139 new rotational transitions, respectively, for $trans$ and $cis$ isomers. The final dataset also includes lines in the centimetre range available from literature. The extension of the measurements in the mm and submm range lead to an accurate set of rotational and centrifugal distortion parameters. This allows us to predict frequencies with estimated uncertainties as low as 5 kHz at 1 mm wavelength. Hence, the new dataset provided by this study can be used for astronomical search.

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Widespread SiO and CH3OH emission in Filamentary Infrared Dark Clouds

Infrared-Dark Clouds (IRDCs) are cold, dense regions of high (optical and infrared) extinction, believed to be the birthplace of high-mass stars and stellar clusters. The physical mechanisms leading to the formation of these IRDCs are not completely understood and it is thus important to study their molecular gas kinematics and chemical content to search for any signature of the IRDCs formation process. Using the 30m-diameter antenna at the Instituto de Radioastronomía Milimétrica, we have obtained emission maps of dense gas tracers (H$^{13}$CO$^{+}$ and HN$^{13}$C) and typical shock tracers (SiO and CH$_3$OH) toward three IRDCs, G028.37+00.07, G034.43+00.24 and G034.77-00.55 (clouds C, F and G, respectively). We have studied the molecular gas kinematics in these clouds and, consistent with previous works toward other IRDCs, the clouds show complex gas kinematics with several velocity-coherent sub-structures separated in velocity space by a few km s$^{-1}$. Correlated with these complex kinematic structures, widespread (parsec-scale) emission of SiO and CH$_3$OH is present in all the three clouds. For clouds C and F, known to be actively forming stars, widespread SiO and CH$_3$OH is likely associated with on-going star formation activity. However, for cloud G, which lacks either 8 $μ$m or 24 $μ$m sources and 4.5 $μ$m H$_2$ shock-excited emission, the detected widespread SiO and CH$_3$OH emission may have originated in a large-scale shock interaction, although a scenario involving a population of low-mass stars driving molecular outflows cannot be fully ruled out.

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The Green Bank Ammonia Survey: Unveiling the Dynamics of the Barnard 59 star-forming Clump

Understanding the early stages of star formation is a research field of ongoing development, both theoretically and observationally. In this context, molecular data have been continuously providing observational constraints on the gas dynamics at different excitation conditions and depths in the sources. We have investigated the Barnard 59 core, the only active site of star formation in the Pipe Nebula, to achieve a comprehensive view of the kinematic properties of the source. These information were derived by simultaneously fitting ammonia inversion transition lines (1,1) and (2,2). Our analysis unveils the imprint of protostellar feedback, such as increasing line widths, temperature and turbulent motions in our molecular data. Combined with complementary observations of dust thermal emission, we estimate that the core is gravitationally bound following a virial analysis. If the core is not contracting, another source of internal pressure, most likely the magnetic field, is supporting it against gravitational collapse and limits its star formation efficiency.

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