arXiv subjects

P. Caselli

Publications and source records attributed to P. Caselli.

At least 55 records · Page 3Linked to original sources

arXiv2025

FAUST XXV. A potential new molecular outflow in [BHB2007] 11

During the early stages of star formation, accretion processes such as infall from the envelope and molecular streamers, and ejection of matter through winds and jets take place simultaneously. The Class 0/I binary [BHB2007] 11 shows evidence for accretion and ejection at the scales of the circumbinary disk and the inner close binary. Recent H$_2$CO observations showed two elongated structures with hints of outflowing motion almost perpendicular to the main CO outflow, which is launched from the circumbinary disk. With the aim of verifying the nature of these elongated structures, we analyze the line emission of H$^{13}$CO$^+$, CCH, c-C$_3$H$_2$ and SiO observed with ALMA within the Large Program FAUST. These molecules trace material moving at velocities close to the ambient cloud velocity. The images of H$^{13}$CO$^+$, CCH, c-C$_3$H$_2$ show the elongated structures, whose gas kinematics are consistent with outflowing motions and with rotation in the opposite sense to the main CO outflow. The derived mass loss rate from these large-scale structures is $(1.8\pm0.5)\times10^{-6}M_{\odot}\textrm{ yr}^{-1}$, in agreement with those measured in outflows driven by Class 0/I protostars. The SiO image reveals compact emission close to the binary system, with a slight elongation aligned with the larger-scale structures. This suggests that SiO is released from the sputtering of dust grains in the shocked material at the base of the potential new outflow, with a relative abundance of $\geq(0.11-2.0)\times10^{-9}$. However, higher angular and spectral resolution observations are needed to accurately estimate the outflow launching radius and its powering source. Given the location and the abundance of the SiO emission, we propose that the second outflow may be launched from inside the circumbinary disk, likely by the less massive companion, which is actively accreting material from its surroundings.

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arXiv2025

SOLIS. XIX. The chemically rich SVS13-B protostellar jet

As part of the IRAM NOEMA Large Program SOLIS, we imaged the protostellar sources SVS13-A and SVS13-B in SiO, SO, CS, and CH3OH at a spatial resolution of 2"-3" (600-900 au). The CS and SO emission traces the 5000 au envelope that hosts the SVS13-A and VLA3 young stellar objects, and CH3OH probes the compact hot corino associated with SVS13-A. In addition, CS blue-shifted emission reveals a molecular shell in the direction of the jet driven by SVS13-A that is revealed by high-velocity SiO, SO and low-velocity H_2 emission. We also imaged the protostellar jet driven by SVS13-B in SiO, and in SO, CS, and CH3OH for the first time as well. The molecules peak at different distances from the driving source: SiO(2-1) peaks at about 1600 au, and SO(2_3-1_2), CS(2--1) and CH3OH(2_k,k-1_k,k) peak at about 2000-2850 au. Moreover, SiO(2-1) emits at larger distances than SiO(5--4), indicating a lower excitation at a larger distance from the protostar. The multi-species observations revealed a stratified chemical structure in the jet of SVS13-B. A jet-like component with a transversal size < 450 au is traced by SiO, which is efficiently formed in high-velocity shocks (> 25 km/s) by sputtering and vaporisation of the grain cores and mantles. A slower and wider (transversal size of about 750 au) component is probed by methanol, which is released from dust mantles at lower shock velocities (< 10 km/s). The SO and CS emission traces an intermediate component with respect to the components probed by SiO and CH3OH. High spatial resolution imaging (down to 10 au) of the jet of SVS13-B in multiple species will aid in reconstructing the chemistry of shocked material in protostellar jets.

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arXiv2025

FAUST-XXII. Deuteration in the VLA1623-2417 protostellar hot-corinos, cavities, and streamers

The study of deuterium fractionation is a valuable tool for reconstructing our chemical history from the early prestellar stages to the formation of planets. In the context of the ALMA Large Programme FAUST, we observed formaldehyde, H$_2$CO, and its singly and doubly deuterated forms, HDCO and D$_2$CO, towards the protostellar cluster VLA1623-2417, on scales of ~ 2000 - 50 au. Formaldehyde probes the inner envelopes of the protostars VLA1623A, B, and W, the rotating cavities opened by the VLA1623A outflow, and several streamers. The HDCO and D$_2$CO emissions are observed towards VLA1623A, in its outflow cavities, and in one of the streamers. We estimate the gas temperature from the HDCO lines: T~ 125 K towards VLA1623A, indicating hot-corino emission, lower temperatures in the outflow cavities (20 - 40 K), and in the streamers ($\le15$ K). The D$_2$CO lines also trace the flattened envelope of VLA1623A, where H$_2$CO and HDCO are fainter. This may be due to D$_2$CO formation on dust grains in the cold prestellar phase, and subsequent photodesorption caused by the enhanced UV flux from two nearby B stars. We inferred the molecular deuteration: [HDCO]/[H$_2$CO] ~ 0.16, ~ 0.07 - 0.13, and ~ 0.3; [D$_2$CO]/[H$_2$CO] ~ 0.003, ~ 0.05 - 0.13, and ~ 0.03 in the hot corino, in the outflow cavities, and in the streamer, respectively. The spatial distribution of D$_2$CO, which points to formation on dust grains, and the similar values of [HDCO]/[H$_2$CO] and [D$_2$CO]/[H$_2$CO] in the components of the system, suggest that deuterium fractionation occurs at the prestellar stage and is then inherited, mostly unaltered, in the protostellar phase.

astro-ph.SR↗

arXiv2025

Hunting pre-stellar cores with APEX: Corona Australis 151, the densest pre-stellar core or the youngest protostar?

Context. Pre-stellar cores are the birthplaces of Sun-like stars and represent the initial conditions for the assembly of protoplanetary systems. Due to their short lifespans, they are rare. In recent efforts to increase the number of such sources identified in the Solar neighbourhood, we have selected a sample of 40 starless cores from the publicly available core catalogs of the Herschel Gould Belt survey. In this work, we focus on one of the sources that stands out for its high central density: Corona Australis 151. Aims. We use molecular lines that trace dense gas (n>=10^6 cm-3) to confirm the exceptionally high density of this object, to study its physical structure, and to understand its evolutionary stage. Methods. We detected the N2H+ 3-2 and 5-4 transitions, and the N2D+ 3-2, 4-3, and 6-5 lines with the APEX telescope. We use the Herschel continuum data to infer a spherically symmetric model of the core's density and temperature. This is used as input to perform non-local-thermodynamic-equilibrium radiative transfer to fit the observed five lines. Results. Our analysis confirms that this core is characterised by very high densities (a few x 10^7 cm-3 at the centre) and cold temperatures. We infer a high deuteration level of N2D+/N2H+=0.50, indicative of an advanced evolutionary stage. In the large bandwidth covered by the APEX data, we detect several other deuterated species, including CHD2OH, D2CO, and ND3. We also detect multiple sulphurated species that present broader lines with signs of high-velocity wings. Conclusions. The observation of high-velocity wings and the fact that the linewidths of N2H+ and N2D+ become larger with increasing frequency can be interpreted either as an indication of supersonic infall motions developing in the central parts of a very evolved pre-stellar core or as the signature of outflows from a very low luminosity object (VeLLO). *SHORTENED*

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arXiv2025

Mapping Synthetic Observations to Prestellar Core Models: An Interpretable Machine Learning Approach

Observations of molecular lines are a key tool to determine the main physical properties of prestellar cores. However, not all the information is retained in the observational process or easily interpretable, especially when a larger number of physical properties and spectral features are involved. We present a methodology to link the information in the synthetic spectra with the actual information in the simulated models (i.e., their physical properties), in particular, to determine where the information resides in the spectra. We employ a 1D gravitational collapse model with advanced thermochemistry, from which we generate synthetic spectra. We then use neural network emulations and the SHapley Additive exPlanations (SHAP), a machine learning technique, to connect the models' properties to the specific spectral features. Thanks to interpretable machine learning, we find several correlations between synthetic lines and some of the key model parameters, such as the cosmic-ray ionization radial profile, the central density, or the abundance of various species, suggesting that most of the information is retained in the observational process. Our procedure can be generalized to similar scenarios to quantify the amount of information lost in the real observations. We also point out the limitations for future applicability.

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arXiv2025

Resolved Gas Temperatures and 12C/13C ratios in SVS13A from ALMA Observations of CH3CN and CH3-13-CN

Context. Multiple systems are common in field stars, and the frequency is found to be higher in early evolutionary stages. Thus, the study of young multiple systems during the embedded stages is key to have a comprehensive understanding of star formation. In particular, how material accretes from the large-scale envelope into the inner region and how this flow interacts with the system physically and chemically has not yet been well characterized observationally. Aims. We aim to provide a snapshot of the forming protobinary system SVS13A, consisting of VLA4A and VLA4B. This includes clear pictures of its kinematic structures, physical conditions, and chemical properties. Methods. We conducted ALMA observations toward SVS13A targeting CH3CN and CH3-13CN J=12-11 K-ladder line emission with a high spatial resolution of ~30 au at a spectral resolution of ~0.08 km s-1 Results. We perform LTE radiative transfer models to fit the spectral features of the line emission. We find the two-layer LTE radiative model including dust absorption is essential to interpret the CH3CN and CH3-13-CN line emission. We identify two major and four small kinematic components, and derive their physical and chemical properties. Conclusions. We find a possible infalling signature toward the bursting secondary source VLA4A, which may be fed by an infalling streamer from the large-scale envelope. The mechanical heating in the binary system, as well as the infalling shocked gas, likely play a role in the thermal structure of the protobinary system. By accumulating mass from the streamer, the system might have experienced a gravitationally unstable phase before the accretion outburst. Finally, the derived CH3CN/CH3-13-CN ratio is lower than the canonical ratio in the ISM and is different between VLA4A and VLA4B.

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arXiv2025

Correlation between formaldehyde and methanol in prestellar cores

Formaldehyde is a key precursor in the formation routes of many complex organic molecules (COMs) in space. It is also an intermediate step in CO hydrogenation sequence that leads to methanol formation on the surface of interstellar grains in cold dense prestellar cores where pristine ices are formed. Various chemical models successfully reproduce the COMs abundances in cold cores, however, they consistently overpredict the abundance of formaldehyde by an order of magnitude. This results in an inverse H2CO:CH3OH abundance ratios obtained in the astrochemical simulations as compared to the observed values. In this work, we present a homogeneous data set of formaldehyde observational maps obtained towards seven dense cores in the L1495 filament with the IRAM 30 m telescope. Resolving the spatial distribution of the molecules is essential to test the chemical models. We carefully estimate the formaldehyde column densities and abundances to put reliable observational constraints on the chemical models of cold cores. Through numerous tests, we aim to constrain the updated chemical model MONACO to better align with the observed formaldehyde abundance and its ratio to methanol. In particular, we elaborate on the branching ratio of the CH3 + O reaction at low temperatures. The revised MONACO model reproduces abundances of both methanol and formaldehyde within an order of magnitude. However the model tends to overproduce formaldehyde and underpredict methanol. Consequently, the model systematically overestimates the H2CO:CH3OH ratio, although it remains within an order of magnitude of the values derived from observations.

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arXiv2025

FAUST XX. The chemical structure and temperature profile of the IRAS 4A2 hot corino at 20-50 au

Young low-mass protostars often possess hot corinos, compact, hot and dense regions bright in interstellar Complex Organic Molecules (iCOMs). Besides of their prebiotic role, iCOMs can be used as a powerful tool to characterize the chemical and physical properties of hot corinos. Using ALMA/FAUST data we aim to explore the iCOMs emission at < 50 au scale around the Class 0 prototypical hot corino IRAS 4A2. We imaged IRAS 4A2 in six abundant, common iCOMs (CH$_3$OH, HCOOCH$_3$, CH$_3$CHO, CH$_3$CH$_2$OH, CH$_2$OHCHO, and NH$_2$CHO), and derived their emitting size. The column density and gas temperature for each species were derived at 1$σ$ from a multi-line analysis by applying a non-LTE approach for CH$_3$OH, and LTE population or rotational diagram analysis for the other iCOMs. Thanks to the unique estimates of the absorption from foreground millimeter dust toward IRAS 4A2, we derived for the first time unbiased gas temperatures and column densities. We resolved the IRAS 4A2 hot corino finding evidence for a chemical spatial distribution in the inner 50 au, with the outer emitting radius increasing from ~ 22-23 au for NH$_2$CHO and CH$_2$OHCHO, followed by CH$_3$CH$_2$OH (~ 27 au), CH$_3$CHO (~ 28 au), HCOOCH$_3$ (~ 36 au), and out to ~ 40 au for CH$_3$OH. Combining our estimate of the gas temperature probed by each iCOM with their beam-deconvolved emission sizes, we inferred the gas temperature profile of the hot corino on scales of 20-50 au in radius, finding a power-law index $q$ of approximately -1. We observed, for the first time, a chemical segregation in iCOMs of the IRAS 4A2 hot corino, and derived the gas temperature profile of its inner envelope. The derived profile is steeper than when considering a simple spherical collapsing and optically-thin envelope, hinting at a partially optically-thick envelope or a gravitationally unstable disk-like structure.

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arXiv2024

Hunting pre-stellar cores with APEX: IRAS16293E (Oph464)

Pre-stellar cores are the first steps in the process of star and planet formation. However, the dynamical and chemical evolution of pre-stellar cores is still not well understood. We aim at estimating the central density of the pre-stellar core IRAS16293E and at carrying out an inventory of molecular species towards the density peak of the core. We observed high-$J$ rotational transitions of N$_2$H$^+$ and N$_2$D$^+$, and several other molecular lines towards the dust emission peak using the Atacama Pathfinder EXperiment (APEX) telescope, and derived the density and temperature profiles of the core using far-infrared surface brightness maps from $Herschel$. The N$_2$H$^+$ and N$_2$D$^+$ lines were analysed by non-LTE radiative transfer modelling. Our best-fit core model consists in a static inner region, embedded in an infalling envelope with an inner radius of approximately 3000 au (21" at 141 pc). The observed high-J lines of N$_2$H$^+$ and N$_2$D$^+$ (with critical densities greater than 10$^6$ cm$^{-3}$) turn out to be very sensitive to depletion; the present single-dish observations are best explained with no depletion of N$_2$H$^+$ and N$_2$D$^+$ in the inner core. The N$_2$D$^+$/N$_2$H$^+$ ratio that best reproduces our observations is 0.44, one of the largest observed to date in pre-stellar cores. Additionally, half of the molecules that we observed are deuterated isotopologues, confirming the high-level of deuteration towards this source. Non-LTE radiative transfer modelling of N$_2$H$^+$ and N$_2$D$^+$ lines proved to be an excellent diagnostic of the chemical structure and dynamics of a pre-stellar core. Probing the physical conditions immediately before the protostellar collapse is a necessary reference for theoretical studies and simulations with the aim of understanding the earliest stages of star and planet formation and the time scale of this process.

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arXiv2024

Ice inventory towards the protostar Ced 110 IRS4 observed with the James Webb Space Telescope. Results from the ERS Ice Age program

This work focuses on the ice features toward the binary protostellar system Ced 110 IRS 4A and 4B, and observed with JWST as part of the Early Release Science Ice Age collaboration. We aim to explore the JWST observations of the binary protostellar system Ced~110~IRS4A and IRS4B to unveil and quantify the ice inventories toward these sources. We compare the ice abundances with those found for the same molecular cloud. The analysis is performed by fitting or comparing laboratory infrared spectra of ices to the observations. Spectral fits are carried out with the ENIIGMA fitting tool that searches for the best fit. For Ced~110~IRS4B, we detected the major ice species H$_2$O, CO, CO$_2$ and NH$_3$. All species are found in a mixture except for CO and CO$_2$, which have both mixed and pure ice components. In the case of Ced~110~IRS4A, we detected the same major species as in Ced~110~IRS4B, as well as the following minor species CH$_4$, SO$_2$, CH$_3$OH, OCN$^-$, NH$_4^+$ and HCOOH. Tentative detection of N$_2$O ice (7.75~$μ$m), forsterite dust (11.2~$μ$m) and CH$_3^+$ gas emission (7.18~$μ$m) in the primary source are also presented. Compared with the two lines of sight toward background stars in the Chameleon I molecular cloud, the protostar has similar ice abundances, except in the case of the ions that are higher in IRS4A. The clearest differences are the absence of the 7.2 and 7.4~$μ$m absorption features due to HCOO$^-$ and icy complex organic molecules in IRS4A and evidence of thermal processing in both IRS4A and IRS4B as probed by the CO$_2$ ice features. We conclude that the binary protostellar system Ced~110~IRS4A and IRS4B has a large inventory of icy species. The similar ice abundances in comparison to the starless regions in the same molecular cloud suggest that the chemical conditions of the protostar were set at earlier stages in the molecular cloud.

astro-ph.SR↗

arXiv2024

Interaction between the Supernova Remnant W44 and the Infrared Dark Cloud G034.77-00.55: shock induced star formation?

How Supernova Remnant (SNR) shocks impact nearby molecular clouds is still poorly observationally constrained. It is unclear if SNRs can positively or negatively affect clouds star formation potential. We have studied the dense gas morphology and kinematics toward the Infrared Dark Cloud (IRDC) G034.77-00.55, shock-interacting with the SNR W44, to identify evidence of early stage star formation induced by the shock. We have used high-angular resolution N2H+(1-0) images across G034.77-00.55, obtained with ALMA. N2H+ is a well known tracer of dense and cold material, optimal to identify gas with the highest potential to harbour star formation. The N2H+ emission is distributed into two elongated structures, one toward the dense ridge at the edge of the source and one toward the inner cloud. Both elongations are spatially associated with well-defined mass-surface density features. The velocities of the gas in the two structures i.e., 38-41 km s-1 and 41-43 km s-1 are consistent with the lowest velocities of the J- and C-type parts of the SNR-driven shock, respectively. A third velocity component is present at 43-45.5 km s-1. The dense gas shows a fragmented morphology with core-like fragments of scales consistent with the Jeans lengths, masses $\sim$1-20 M$_{\odot}$, densities (n(H$_2$)$\geq$10$^5$ cm$^{-3}$) sufficient to host star formation in free-fall time scales (few 10$^4$ yr) and with virial parameters that hint toward possible collapse. The W44 driven shock may have swept up the encountered material which is now seen as a dense ridge, almost detached from the main cloud, and an elongation within the inner cloud, well constrained in both N2H+ emission and mass surface density. This shock compressed material may have then fragmented into cores that are either in a starless or pre-stellar stage. Additional observations are needed to confirm this scenario and the nature of the cores.

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arXiv2024

Evolution of Chemistry in the envelope of HOt CorinoS (ECHOS) II. The puzzling chemistry of isomers as revealed by the HNCS/HSCN ratio

The observational detection of some metastable isomers in the interstellar medium with abundances comparable to those of the most stable isomer, or even when the stable isomer is not detected, highlights the importance of non-equilibrium chemistry. This challenges our understanding of the interstellar chemistry. We present a chemical study of isomers through the sulphur isomer pair HNCS and HSCN, since HSCN has been observed in regions where its stable isomer has not been detected, and the observed HNCS/HSCN ratio seems to significantly vary from cold to warm regions. We have used the Nautilus chemical code to model the formation and destruction paths of HNCS and HSCN in different astrochemical scenarios, and the time evolution of the HNCS/HSCN ratio. We have also analysed the influence of the environmental conditions on their chemical abundances. We present an observational detection of the metastable isomer HSCN in the Class I object B1-a, but not of the stable isomer HNCS, despite HNCS lying 3200 K lower in energy than HSCN. Our results show an HNCS/HSCN ratio sensitive to the gas temperature and the evolutionary time, with the highest values obtained at early stages (t<10^4 yr) and low (Tg<20 K) temperatures. The results suggest a different efficiency of the isomerisation processes depending on the source temperature. The progressive decrease of HNCS/HSCN with gas temperature at early evolutionary times indicates that this ratio may be used as a tracer of cold young objects. This work also demonstrates the key role of grain surface chemistry in the formation of the isomer pair HNCS and HSCN in cold regions, and the importance of the ions H2NCS+ and HNCSH+ in warm/hot regions. Since most of the interstellar regions where HSCN is detected are cold regions, a larger sample including sources characterised by high temperatures are needed to corroborate the theoretical results.

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arXiv2024

PRODIGE -- envelope to disk with NOEMA. IV. An infalling gas bridge surrounding two Class 0/I systems in L1448N

Context. The formation of stars has been subject to extensive studies in the past decades from molecular cloud to protoplanetary disk scales. It is still not fully understood how the surrounding material in a protostellar system, that often shows asymmetric structures with complex kinematic properties, feeds the central protostar(s) and their disk(s). Aims. We study the spatial morphology and kinematic properties of the molecular gas surrounding the IRS3A and IRS3B protostellar systems in the L1448N region located in the Perseus molecular cloud. Methods. We present 1 mm NOEMA observations of the PRODIGE large program and analyze the kinematic properties of molecular lines. Given the complexity of the spectral profiles, the lines are fitted with up to three Gaussian velocity components. The clustering algorithm DBSCAN is used to disentangle the velocity components into the underlying physical structure. Results. We discover an extended gas bridge (~3000 au) surrounding both the IRS3A and IRS3B systems in six molecular line tracers (C18O, SO, DCN, H2CO, HC3N, and CH3OH). This gas bridge is oriented along the northeast-southwest direction and shows clear velocity gradients on the order of 100 km/s/pc towards the IRS3A system. We find that the observed velocity profile is consistent with analytical streamline models of gravitational infall towards IRS3A. The high-velocity C18O (2-1) emission towards IRS3A indicates a protostellar mass of ~1.2 Msun. Conclusions. While high angular resolution continuum data often show IRS3A and IRS3B in isolation, molecular gas observations reveal that these systems are still embedded within a large-scale mass reservoir with a complex spatial morphology as well as velocity profiles. The kinematic properties of the extended gas bridge are consistent with gravitational infall toward the IRS3A protostar.

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arXiv2024

The cool brown dwarf Gliese 229 B is a close binary

Owing to their similarities with giant exoplanets, brown dwarf companions of stars provide insights into the fundamental processes of planet formation and evolution. From their orbits, several brown dwarf companions are found to be more massive than theoretical predictions given their luminosities and the ages of their host stars (e.g. Brandt et al. 2021, Cheetham et al. 2018, Li et al. 2023). Either the theory is incomplete or these objects are not single entities. For example, they could be two brown dwarfs each with a lower mass and intrinsic luminosity (Brandt et al. 2021, Howe et al. 2024). The most problematic example is Gliese 229 B (Nakajima et al. 1995, Oppenheimer et al. 1995), which is at least 2-6 times less luminous than model predictions given its dynamical mass of $71.4\pm0.6$ Jupiter masses ($M_{\rm Jup}$) (Brandt et al. 2021). We observed Gliese 229 B with the GRAVITY interferometer and, separately, the CRIRES+ spectrograph at the Very Large Telescope. Both sets of observations independently resolve Gliese 229 B into two components, Gliese 229 Ba and Bb, settling the conflict between theory and observations. The two objects have a flux ratio of $0.47\pm0.03$ at a wavelength of 2 $μ$m and masses of $38.1\pm1.0$ and $34.4\pm1.5$ $M_{\rm Jup}$, respectively. They orbit each other every 12.1 days with a semimajor axis of 0.042 astronomical units (AU). The discovery of Gliese 229 BaBb, each only a few times more massive than the most massive planets, and separated by 16 times the Earth-moon distance, raises new questions about the formation and prevalence of tight binary brown dwarfs around stars.

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arXiv2024

Gas phase Elemental abundances in Molecular cloudS (GEMS). X. Observational effects of turbulence on the chemistry of molecular clouds

(Abridged) We explore the chemistry of the most abundant C, O, S, and N bearing species in molecular clouds, in the context of the IRAM 30 m Large Programme Gas phase Elemental abundances in Molecular Clouds (GEMS). In this work, we aim to assess the limitations introduced in the observational works when a uniform density is assumed along the line of sight for fitting the observations, developing a very simple numerical model of a turbulent box. We perform a MHD simulation in order to reproduce the turbulent steady-state of a turbulent box with properties typical of a molecular filament before collapse. We post-process the results of the MHD simulation with a chemical code to predict molecular abundances, and then post-process this cube with a radiative transfer code to create synthetic emission maps for a series of rotational transitions observed during the GEMS project. From the chemical point of view, we find that turbulence produces variations on the predicted abundances, but they are more or less critical depending on the chosen transition and the chemical age. When compared to real observations, the results from the turbulent simulation provides a better fit than when assuming a uniform gas distribution along the line of sight. In the view of our results, we conclude that taking into account turbulence when fitting observations might significantly improve the agreement with model predictions. This is especially important for sulfur bearing species that are very sensitive to the variations of density produced by turbulence at early times (0.1 Myr). The abundance of CO is also quite sensitive to turbulence when considering the evolution beyond a few 0.1 Myr.

astro-ph.GA↗

arXiv2024

CHEMOUT: CHEMical complexity in star-forming regions of the OUTer Galaxy. IV. ALMA observations of organic species at Galactocentric radius ~23 kpc

Single-dish observations suggest that the abundances of organic species in star-forming regions of the outer Galaxy, characterised by sub-Solar metallicities, are comparable to those found in the local Galaxy. To understand this counter-intuitive result, and avoid misleading interpretation due to beam dilution effects at such large distances, spatially resolved molecular emission maps are needed to link correctly measured abundances and local physical properties. We observed several organic molecules with the Atacama Large Millimeter Array towards WB89-671, the source with the largest Galactocentric distance (23.4~kpc) of the project "CHEMical complexity in star-forming regions of the OUTer Galaxy" (CHEMOUT), at a resolution of 15000~au. We compared the observed molecular abundances with chemical model predictions. We detected emission of c-C3H2, C4H, CH3OH, H2CO, HCO, H13CO+, HCS+, CS, HN13C, and SO. The emission morphology is complex, extended, and different in each tracer. The most intense emission in H13CO+, H2CO and c-C3H2 arises from two millimeter continuum, infrared-bright cores. The most intense CH3OH and SO emission arises predominantly from the part of the filament with no continuum sources. The narrow linewidths across the filament indicate quiescent gas, despite the two embedded protostars. Derived molecular column densities are comparable with those in local star-forming regions, and suggest anti-correlation between hydrocarbons, ions, HCO, and H2CO on one side, and CH3OH and SO on the other. Static chemical models that best match the observed column densities favour low energetic conditions, expected at large Galactocentric radii, but carbon elemental abundances 3 times higher than that derived extrapolating the [C/H] Galactocentric gradient at 23~kpc. This would indicate a flatter [C/H] trend at large Galactocentric radii, in line with a flat abundance of organics.

astro-ph.GA↗

arXiv2024

Impact of ice growth on the physical and chemical properties of dense cloud cores

We investigated the effect of time-dependent ice growth on dust grains on the opacity and hence on the dust temperature in a collapsing molecular cloud core, with the aim of quantifying the effect of the dust temperature variations on ice abundances as well as the evolution of the collapse. We employed a one-dimensional collapse model that self-consistently and time-dependently combines hydrodynamics with chemical and radiative transfer simulations. The dust opacity was updated on-the-fly based on the ice growth as a function of location in the core. The results of the fully dynamical model were compared against simulations assuming fixed ice thickness. We found that the ice thickness increases fast and reaches a saturation value of approximately 90 monolayers in the central core (volume density $\sim$$10^4\,\rm cm^{-3}$), and several tens of monolayers at a volume density of $\sim$$10^3\,\rm cm^{-3}$, after only a few $10^5\,\rm yr$ of evolution. The results thus exclude the adoption of thin ($\sim$10 monolayer) ices in molecular cloud simulations except at very short timescales. The differences in abundances and dust temperature between the fully dynamic simulation and those with fixed dust opacity are small; abundances change between the solutions generally within a factor of two. The assumptions on the dust opacity do have an effect on the collapse dynamics through the influence of the photoelectric effect on the gas temperature, and the simulations take a different time to reach a common central density. In conclusion, carrying out chemical simulations using a dust temperature corresponding to a fixed opacity seems to be a good approximation. Still, although at least in the present case its effect on the overall results is limited - as long as the grains are monodisperse - ice growth should be considered to obtain the most accurate representation of the collapse dynamics.

astro-ph.GA↗

arXiv2024

Re-evaluation of the cosmic-ray ionization rate in diffuse clouds

All current estimates of the cosmic-ray (CR) ionization rate rely on assessments of the gas density along the probed sight lines. Until now, these have been based on observations of different tracers, with C$_2$ being the most widely used in diffuse molecular clouds for this purpose. However, three-dimensional dust extinction maps have recently reached sufficient accuracy as to give an independent measurement of the gas density on parsec scales. In addition, they allow us to identify the gas clumps along each sight line, thus localizing the regions where CR ionization is probed. We re-evaluate H$_3^+$ observations, which are often considered as the most reliable method to measure the H$_2$ ionization rate $ζ_{\rm H_2}$ in diffuse clouds. The peak density values derived from the extinction maps for 12 analyzed sight lines turn out to be, on average, an order of magnitude lower than the previous estimates, and agree with the values obtained from revised analysis of C$_2$ data. We use the extinction maps in combination with the 3D-PDR code to self-consistently compute the H$_3^+$ and H$_2$ abundances in the identified clumps for different values of $ζ_{\rm H_2}$. For each sight line, we obtain the optimum value by comparing the simulation results with observations. We show that $ζ_{\rm H_2}$ is systematically reduced with respect to the earlier estimates by a factor of $\approx 9$ on average, to $\approx6\times10^{-17}$ s$^{-1}$, primarily as a result of the density reduction. We emphasize that these results have profound consequences for all available measurements of the ionization rate.

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