arXiv subjects

P. E. Brandyshev

Publications and source records attributed to P. E. Brandyshev.

6 recordsLinked to original sources

arXiv2025

Theory of Casimir Forces: A Unified Approach Using Finite-Temperature Field Theory

We present a quantum theory of Casimir forces between perfect electrical conductors, based on quantum electrodynamics and quantum statistical physics. This theory utilizes Kapusta's finite-temperature field theory, combined with the Faddeev-Popov ghost formalism. This approach allows us to calculate Casimir forces at finite temperatures, providing both previously known and new physical insights from a unified perspective. Furthermore, our method enables us to compute the stress tensor associated with Casimir forces, in accordance with the Helmholtz free energy of an equilibrium quantum electromagnetic field. Using this method, we calculate the tangential pressure in a slit-like pore due to the Casimir effect.

cond-mat.stat-mech↗

arXiv2025

First-principle theory of the Casimir screening effect

In this paper, we use the formalism of finite-temperature quantum field theory to investigate the Casimir force between flat, ideally conductive surfaces containing confined, but mobile ions. We demonstrate that, in the Gaussian approximation, the ionic fluctuations contribute separately from the electromagnetic fluctuations that are responsible for the standard Casimir effect. This is in line with the "separation hypothesis", has been previously applied on a purely intuitive basis. Our analysis demonstrates the significance of calculating the zero Matsubara frequency component in the electromagnetic contribution, using the formula developed by Schwinger et al., as opposed to the approach based on Lifshitz theory used by other researchers.

quant-ph↗

arXiv2024

Thermomechanical Approach to Calculating Mechanical Stresses in Inhomogeneous Fluids and Its Applications to Ionic Fluids

This extended article presents a thermomechanical approach for calculating the stress tensor from the thermodynamic potential of inhomogeneous fluids and some applications to ionic fluids. The technique, based on the invariance of the fluid's thermodynamic potential with respect to spatial transformations of translation and rotation, offers an alternative to the general covariant approach developed by two of the authors. We apply this technique to both pure mean-field theories of fluids in general and a theory that includes thermal fluctuations of the order parameter, using the example of ionic fluids. Additionally, we apply the thermomechanical approach to fluid models with vector order parameters, such as liquid dielectrics. For this case, we obtain a general expression for the stress tensor. Furthermore, we discuss specific issues related to the calculation of disjoining pressure in ionic fluids confined in nanoscale slit-like pores with metal or dielectric walls, using the Coulomb gas model. To test the robustness of the proposed approach, we reproduce a number of known results from the statistical theory of inhomogeneous fluids and obtain several new ones.

cond-mat.soft↗

arXiv2023

Statistical field theory of mechanical stresses in Coulomb fluids. Noether's theorem {\sl vs} General covariant approach

In this paper, we introduce a statistical field theory that describes the macroscopic mechanical forces in inhomogeneous Coulomb fluids. Our approach employs the generalization of Noether's first theorem for the case of fluctuating order parameter, to calculate the stress tensor for Coulomb fluids. This tensor encompasses the mean-field stress tensor and the fluctuation corrections derived through the one-loop approximation. The correction for fluctuations includes a term that accounts for the thermal fluctuations of the local electrostatic potential and field in the vicinity of the mean-field configuration. This correlation stress tensor determines how electrostatic correlation affects local stresses in a nonuniform Coulomb fluid. We also use previously formulated general covariant methodology [P.E. Brandyshev and Yu.A. Budkov, J. Chem. Phys. 158, 174114 (2023)] in conjunction with a functional Legendre transformation method and derive within it the same total stress tensor. We would like to emphasize that our general approaches are applicable not only to Coulomb fluids but also to nonionic simple or complex fluids, for which the field-theoretic Hamiltonian is known as a functional of the relevant scalar order parameters.

cond-mat.stat-mech↗

arXiv2023

Noether's second theorem and covariant field theory of mechanical stresses in inhomogeneous ionic liquids

In this paper, we present a covariant approach that utilizes Noether's second theorem to derive a symmetric stress tensor from the grand thermodynamic potential functional. We focus on the practical case where the density of the grand thermodynamic potential is dependent on the first and second coordinate derivatives of the scalar order parameters. Our approach is applied to several models of inhomogeneous ionic liquids that consider electrostatic correlations of ions or short-range correlations related to packing effects. Specifically, we derive analytical expressions for the symmetric stress tensors of the Cahn-Hilliard-like model, Bazant-Storey-Kornyshev model, and Maggs-Podgornik-Blossey model. All of these expressions are found to be consistent with respective self-consistent field equations.

cond-mat.stat-mech↗

arXiv2023

Theory of self-coacervation in semi-dilute and concentrated zwitterionic polymer solutions

Based on the random phase approximation, we develop a molecular theory of self-coacervation in zwitterionic polymer solutions. We show that the interplay between the volume interactions of the monomeric units and electrostatic correlations of charged groups on a polymer backbone can result in liquid-liquid phase separation (self-coacervation). We analyse the behavior of the coacervate phase polymer concentration depending on the electrostatic interaction strength -- the ratio of the Bjerrum length to the bond length of the chain. We establish that in a wide range of polymer concentration values -- from a semi-dilute to a rather concentrated solution -- the chain connectivity and excluded volume interaction of the monomeric units have an extremely weak effect on the contribution of the electrostatic interactions of the dipolar monomeric units to the total free energy. We show that for rather weak electrostatic interactions, the electrostatic correlations manifest themselves as Keesom interactions of point-like freely rotating dipoles (Keesom regime), while in the region of strong electrostatic interactions the electrostatic free energy is described by the Debye-H{ü}ckel limiting law (Debye regime). We show that for real zwitterionic coacervates the Keesom regime is realized only for sufficiently small polymer concentrations of the coacervate phase, while the Debye regime is approximately realized for rather dense coacervates. Using the mean-field variant of the density functional theory, we calculate the surface tension (surface free energy) of the $"$coacervate-solvent$"$ interface as a function of the bulk polymer concentration. Obtained results can be used to estimate the parameters of the polymer chains needed for practical applications such as drug encapsulation and delivery, as well as the design of adhesive materials.

cond-mat.soft↗