arXiv subjects

P. Ehrenfreund

Publications and source records attributed to P. Ehrenfreund.

15 recordsLinked to original sources

arXiv2025

The EDIBLES survey. X. The 6196 {\AA} diffuse interstellar band: Identification of side DIBs as an indication of a small carrier molecule

Context: Numerous studies of diffuse interstellar band (DIB) profiles have detected substructures, which in turn suggests that large molecules are acting as their carriers. However, some of the narrowest DIBs generally do not show such substructures, suggesting the possibility of very small carriers. Aims: Based on the previously found tight correlation of the three narrow DIBs at 6196, 6440 and 6623 A and the present detection of weaker side DIBs to each of them in the extensive data set from the ESO Diffuse Interstellar Bands Large Exploration Survey, we investigated whether they may stem from small linear carrier molecules. This approach can lead to concrete DIB carrier suggestions, which can be tested in laboratory measurements in future studies. Methods: We suggest that the DIBs we studied here represent individual rotational transitions of a small molecule. We determined the molecular constants from observations and compared them with data from a large set of quantum-chemical calculations to constrain possible carrier candidates. Furthermore, we determined the rotational temperatures by fitting line ratios using the fitted molecular models. Results: We determined molecular constants for three DIB systems and the corresponding transition types. The fitted rotational temperatures lie within the range of known interstellar diatomic molecules. We identified several DIB carrier candidates, almost all of them molecular ions. Some of them are metastable species, indicating the possibility of collision complexes as DIB carriers. Conclusions: If our hypothesis holds, this would be a major step towards the identification of a carrier molecule of the 6196 A DIB, the strongest among the narrow DIBs.

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arXiv2024

The EDIBLES Survey. VIII. Band profile alignment of diffuse interstellar bands

Context: There have been many attempts to identify families of diffuse interstellar bands (DIBs) with perfectly correlating band strengths. Although major efforts have been made to classify broadly based DIB families and important insights have been gained, no family has been identified with sufficient accuracy or statistical significance to prove that a series of selected DIBs originates from the same carrier. This can be attributed in part to the exclusive use of equivalent widths to establish DIB families. Aims: In a change of strategy, we search for DIBs that are highly correlated in both band strength and profile shape. This approach increases the chance of correlating DIBs being members of one family and originating from the same carrier molecule. We also search for correlations between DIB profile families and atomic interstellar lines, with the goal of further chemically constraining possible DIB carriers. Methods: We adapted the well-known method of time-series alignment to perform a spectral alignment; that is, DIB alignment. In a second step, we analysed the alignment results using a clustering analysis. This method required a statistically significant data set of DIB sight lines. The ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) data were perfectly suited for this application. Results: We report eight DIB families with correlating strengths and profiles, as well as four previously unreported DIBs in the visual range, found using DIB alignment. All profile family members show Pearson correlation coefficients in band strength higher than 0.9. In particular, we report the 6614 - 6521 AA DIB pair, in which both DIBs show the same triple-peak substructure and an unprecedented band strength Pearson correlation coefficient of 0.9935. The presented approach opens up new perspectives that can guide the laboratory search for DIB carriers.

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arXiv2019

Dust of comet 67P/Churyumov-Gerasimenko collected by Rosetta/MIDAS: classification and extension to the nanometre scale

The properties of the smallest subunits of cometary dust contain information on their origin and clues to the formation of planetesimals and planets. Compared to IDPs or particles collected during the Stardust mission, dust collected in the coma of comet 67P/Churyumov-Gerasimenko during the Rosetta mission provides a resource of minimally altered material with known origin whose structural properties can be used to further the investigation of our early Solar System. A novel method is presented to achieve the highest spatial resolution of imaging possible with the MIDAS Atomic Force Microscope on-board Rosetta. 3D topographic images with resolutions of down to 8\,nm are analysed to determine the subunit sizes of particles on the nanometre scale. Three morphological classes can be determined, namely (i) fragile agglomerate particles of sizes larger than about 10\,$\mathrm{μm}$ comprised by micrometre-sized subunits that may be again aggregates and show a moderate packing density on the surface of the particles; (ii) a fragile agglomerate with a size about few tens of micrometres comprised by micrometre-sized subunits suggested to be again aggregates and arranged in a structure with a fractal dimension less than two; (iii) small, micrometre-sized particles comprised by subunits in the hundreds of nanometres size range that show surface features suggested to again represent subunits. Their differential size distributions follow a log-normal distribution with means about 100\,nm and standard deviations between 20 and 35\,nm. All micrometre-sized particles are hierarchical dust agglomerates of smaller subunits. The arrangement, appearance and size distribution of the smallest determined surface features are reminiscent of those found in CP IDPs and they represent the smallest directly detected subunits of comet 67P.

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arXiv2019

Confirming interstellar C$_{60}^+$ using the Hubble Space Telescope

Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C60+) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C60+ requires a match between the wavelengths and the expected strengths of all absorption features detectable in the laboratory and in space. Here we present Hubble Space Telescope (HST) spectra of the region covering the C60+ 9348, 9365, 9428 and 9577 Å absorption bands toward seven heavily-reddened stars. We focus in particular on searching for the weaker laboratory C60+ bands, the very presence of which has been a matter for recent debate. Using the novel STIS-scanning technique to obtain ultra-high signal-to-noise spectra without contamination from telluric absorption that afflicted previous ground-based observations, we obtained reliable detections of the (weak) 9365, 9428 Å and (strong) 9577 Å C60+ bands. The band wavelengths and strength ratios are sufficiently similar to those determined in the latest laboratory experiments that we consider this the first robust identification of the 9428 Å band, and a conclusive confirmation of interstellar C60+.

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arXiv2018

EDIBLES II. On the detectability of C60+ bands

Gas phase spectroscopic laboratory experiments for the buckminsterfullerene cation C60+ resulted in accurate rest wavelengths for five C60+ transitions that have been compared with diffuse interstellar bands (DIBs) in the near infra-red. Detecting these in astronomical spectra is difficult due to the strong contamination of ground-based spectra by atmospheric water vapor, to the presence of weak and shallow stellar lines and/or blending with other weak DIBs. The detection of the two strong bands has been claimed by several teams, and the three additional and weaker bands have been detected in a few sources. Certain recent papers have argued against the identification of C60+ based on spectral analyses claiming (i) a large variation in the ratio between the equivalent widths of the 9632 and 9577Å\: bands, (ii) a large redshift of the 9632Å\: band for the Orion star HD 37022, and (iii) the non-detection of the weaker 9428Å~DIB. Here we address these three points. (i) We show that the model stellar line correction for the 9632Å~DIB overestimates the difference between the strengths of the lines in giant and dwarf star spectra, casting doubts on the conclusions about the ratio variability. (ii) Using high quality stellar spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES), recorded with the ESO/Paranal Ultraviolet Echelle Spectrograph (UVES) in about the same atmospheric conditions, we find no wavelength shift in the 9632Å band towards HD 37022. (iii) Using EDIBLES spectra and data from the Echelle SpectroPolarimetric Device for the Observation of Stars (ESPaDOnS) at CFHT we show that the presence of a weak 9428Å band cannot be ruled out, even in the same observations that a previous study claimed it was not present.

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arXiv2014

VLT/X-shooter survey of near-infrared diffuse interstellar bands

This paper presents a spectral survey of diffuse interstellar bands (DIBs) in the NIR range, from 0.9 to 2.5 micron. The observations were designed to detect new DIBs, confirm previously proposed NIR DIBs, and characterise their behaviour with respect to known line-of-sight properties (including the optical DIBs present in our spectra). X-shooter at the VLT was used to obtained medium-resolution spectra of eight known DIB targets and one telluric reference star. In addition to the known 9577, 9632, 10780, 11797, and 13175 Angstroms NIR DIBs, we confirm 9 out of the 13 NIR DIBs that were presented by Geballe and co-workers in 2011. Furthermore, we report 12 new NIR DIB candidates. The strengths of the strongest NIR DIBs show a general correlation with reddening, E(B-V), but with a large scatter. Several NIR DIBs are more strongly correlated with the 5780 Angstroms DIB strength than with E(B-V); this is especially the case for the 15268 Angstroms DIB. The NIR DIBs are strong: the summed equivalent widths of the five strongest NIR DIBs represent a few percent of the total equivalent width of the entire average DIB spectrum (per unit reddening). The NIR DIBs towards the translucent cloud HD 147889 are all weak with respect to the general trend. No direct match was found between observed NIR DIBs and laboratory matrix-isolation spectroscopic data of PAHs. The strong correlation between the 5780-15268 DIB pair implies that (Nf)_5780 / (Nf)_15268 = 14. However, the reduced strength of the 15268 Angstroms DIB in HD 147889 rules out a common carrier for these two DIBs. Since the ionisation fraction for small PAHs in this translucent cloud is known to be low compared to diffuse clouds, the weakness of the 15268 Angstrom DIB suggests that an ionised species could be the carrier of this NIR DIB. (abridged).

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arXiv2011

Diffuse interstellar bands in Upper Scorpius: Probing variations in the DIB spectrum due to changing environmental conditions

We study the effects of local environmental conditions affecting the diffuse interstellar band (DIB) carriers within the Upper Scorpius subgroup of the Sco OB2 association. We obtained optical spectra with FEROS, and measured the equivalent widths of five DIBs (at 5780, 5797, 6196, 6379, and 6613 Angstrom) as well as those of absorption lines of di-atomic molecules (CH, CH+, CN) and atoms (KI, CaI) towards 89 targets in the direction of Upper Scorpius. We construct a simple radiative transfer and chemical network model of the diffuse interstellar medium (ISM) sheet in front of Upp Sco to infer the effective radiation field. Both the interstellar radiation field strength, I_UV, and the molecular hydrogen fraction, f_H2, have been derived for 55 sightlines probing the Upp Sco ISM. We discuss the relations between DIB strengths, CH and CH+ line strengths, E(B-V), I_UV, and f_H2. The ratio between the 5780 and 5797 DIBs reveals a (spatial) dependence on the local environment in terms of cloud density and exposure to the interstellar radiation field, reflecting the molecular nature of these DIB carriers.

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arXiv2011

Linear/circular spectropolarimetry of diffuse interstellar bands

Context. The identification of the carriers of diffuse interstellar bands (DIBs) remains one of the long-standing mysteries in astronomy. The detection of a polarisation signal in a DIB profile can be used to distinguish between a dust or gas-phase carrier. The polarisation profile can give additional information on the grain or molecular properties of the absorber. In order to detect and measure the linear and circular polarisation of the DIBs we observed reddened lines of sight showing continuum polarisation. For this study we selected two stars HD 197770 and HD 194279. We used high-resolution (R~64.000) spectropolarimetry in the wavelength range from 3700 to 10480 Angstrom with the ESPaDOnS echelle spectrograph mounted at the CFHT. Results. High S/N and high resolution Stokes V (circular), Q and U (linear) spectra were obtained. We constrained upper limits by a factor of 10 for previously observed DIBs. Furthermore, we analysed ~30 additional DIBs for which no spectropolarimetry data has been obtained before. This included the 9577 A DIB and the 8621 A DIB. Conclusions. The lack of polarisation in 45 DIB profiles suggests that none of the absorption lines is induced by a grain-type carrier. The strict upper limits, less than ~0.01%, derived for the observed lines-of-sight imply that if DIBs are due to gas-phase molecules these carriers have polarisation efficiencies which are at least 6 times, and up to 300 times, smaller than those predicted for grain-related carriers.

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arXiv2008

Indigenous amino acids in primitive CR meteorites

CR meteorites are among the most primitive meteorites. In this paper, we report the first measurements of amino acids in Antarctic CR meteorites, two of which show the highest amino acid concentrations ever found in a chondrite. EET92042, GRA95229 and GRO95577 were analyzed for their amino acid content using high performance liquid chromatography with UV fluorescence detection (HPLC-FD) and gas chromatographymass spectrometry (GC-MS). Our data show that EET92042 and GRA95229 are the most amino acid-rich chondrites ever analyzed, with total amino acid concentrations ranging from 180 parts-per-million (ppm) to 249 ppm. GRO95577, however, is depleted in amino acids. The most abundant amino acids present in the EET92042 and GRA95229 meteorites are the alpha-amino acids glycine, isovaline, alpha-aminoisobutyric acid (alpha-AIB), and alanine, with delta13C values ranging from +31.6per mil to +50.5per mil. The carbon isotope results together with racemic enantiomeric ratios determined for most amino acids strongly indicate an extraterrestrial origin of these compounds. In addition, the relative abundances of alpha-AIB and beta-alanine in the Antarctic CR meteorites analyzed appear to correspond to the degree of aqueous alteration on their respective parent body.

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arXiv2005

VLT-ISAAC 3-5 micron spectroscopy of embedded young low-mass stars. III. Intermediate-mass sources in Vela

We performed a spectroscopic survey toward five intermediate-mass class I YSOs located in the Southern Vela molecular cloud in the L and M bands at resolving powers 600-800 up to 10,000, using the Infrared Spectrometer and Array Camera mounted on the VLT-ANTU. Lower mass companion objects were observed simultaneously in both bands. Solid H2O at 3 micron is detected in all sources, including the companion objects. CO ice at 4.67 micron is detected in a few main targets and one companion object. One object (LLN 19) shows little CO ice but strong gas-phase CO ro-vibrational lines in absorption. The CO ice profiles are different from source to source. The amount of water ice and CO ice trapped in a water-rich mantle may correlate with the flux ratio at 12 and 25 micron. The abundance of H2O-rich CO likely correlates with that of water ice. A weak feature at 3.54 mu attributed to solid CH3OH and a broad feature near 4.62 mu are observed toward LLN17, but not toward the other sources. The derived abundances of solid CH3OH and OCN- are ~10% and ~1% of the H2O ice abundance respectively. The H2O optical depths do not show an increase with envelope mass, nor do they show lower values for the companion objects compared with the main protostar. The line-of-sight CO ice abundance does not correlate with the source bolometric luminosity. Comparison of the solid CO profile toward LLN17, which shows an extremely broad CO ice feature, and that of its lower mass companion at a few thousand AU, which exhibits a narrow profile, together with the detection of OCN- toward LLN17 provide direct evidences for local thermal processing of the ice.

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arXiv2004

Interstellar Ices

Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust grains. We review identification issues and summarize the techniques required to extract information on the physical and chemical evolution of these ices. Both laboratory simulations and line of sight studies are essential. Examples are given for ice bands observed toward high mass protostars, fields stars and recent work on ices in disks surrounding low mass protostars. A number of clear trends have emerged in recent years. One prominent ice component consists of an intimate mixture between H2O, CH3OH and CO2 molecules. Apparently a stable balance exists between low temperature hydrogenation and oxidation reactions on grain surfaces. In contrast, an equally prominent ice component, consisting almost entirely of CO, must have accreted directly from the gas phase. Thermal processing, i.e. evaporation and crystallization, proves to be readily traceable in both these ice components. The spectroscopic signatures of energetic processing by cosmic rays and high energy photons from nearby protostars are weaker and not as well understood. A fundamental limitation in detecting complex, energetically produced (and also some simple) species is blending of weak features in the spectra of protostars. Sophisticated techniques are required to extract information from blended features. We conclude with a summary of key goals for future research and prospects for observations of ices using future instrumentation, including SIRTF/IRS.

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arXiv2004

Multi-Site observations of SU Aurigae

We present results from the 1996 MUSICOS (MUlti-SIte COntinuous Spectroscopy) campaign on the T Tauri star SU Aurigae. We find a 2.7-d periodicity in the He I (587.6 nm) line and somewhat longer, less well-pronounced periodicities in the Balmer lines and in Na D. Our observations support the suggestion that the wind and infall signatures are out of phase on SU Aur. We present Doppler images of SU Aur that have been obtained from least-squares deconvolved profiles. Images taken about one rotation apart show only limited overlap, in particular at low latitudes. This is in part due to limitations in signal-to-noise, and in part due to line profile deformations that arise from short-lived and/or non-surface features. The agreement at high latitudes is better and suggests that at least some longer-lived features are present. The analysis of Stokes V profiles yields a marginal magnetic field detection during one of the phases.

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arXiv2002

Chemical Processes in Cometary Comae

Recent developments in the chemical modelling of cometary comae are described. We discuss the cyanide chemistry and present new HCN observations of the recent comet C/2002 C1 (Ikeya-Zhang). The connection between interstellar and cometary organic molecules is discussed from the perspective of recent theories of interstellar gas-grain chemistry.

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arXiv2001

Ices in Star-Forming Regions: First Results from VLT-ISAAC

The first results from a VLT-ISAAC program on L- and M-band infrared spectroscopy of deeply-embedded young stellar objects are presented. The advent of 8-m class telescopes allows high S/N spectra of low-luminosity sources to be obtained. In our first observing run, low- and medium-resolution spectra have been measured toward a dozen objects, mostly in the Vela and Chamaeleon molecular clouds. The spectra show strong absorption of H2O and CO ice, as well as weak features at `3.47' and 4.62 mu. No significant solid CH3OH feature at 3.54 mu is found, indicating that the CH3OH/H2O ice abundance is lower than toward some massive protostars. Various evolutionary diagnostics are investigated for a set of sources in Vela.

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arXiv2000

ISO-SWS observations of interstellar solid 13CO2: heated ice and the Galactic 12C/13C abundance ratio

We present observations of the stretching mode of 13CO2 ice along 13 lines of sight in the Galaxy, using the Short Wavelength Spectrometer on board of the Infrared Space Observatory. Remarkable variations are seen in the absorption band profile in the different lines of sight. The main feature is attributed to 13CO2 mixed with polar molecules such as H2O, and CH3OH. Several high-mass protostars show an additional narrow substructure at 4.382 um, which we attribute to a polar CO2 ice, that experienced heating. This heating effect is sustained by a good correlation of the strength of the substructure with dust and CO gas temperatures along the line of sight, and anti-correlation with ice abundances. Thus, our main conclusion is that interstellar CO2 ices around luminous protostars are subjected to, and altered by, thermal processing and that it may reflect the evolutionary stage of the nearby protostar. In contrast, the ices around low mass protostars and in a quiescent cloud in our sample do not show signs of thermal processing. Furthermore, we determine for the first time the Galactic 12C/13C ratio from the solid state. The 12CO2/13CO2 ratio for the local ISM (69+/-15), as well as the dependence on Galacto-centric radius, are in good agreement with gas phase (C18O, H2CO) studies. For the few individual objects for which gas phase values are available, the 12C/13C ratios derived from CO2 tend to be higher compared to CO studies (albeit with 2.5 sigma significance only). We discuss the implications of this possible difference for the chemical origin of interstellar CO2.

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