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P. F. Goldsmith

Publications and source records attributed to P. F. Goldsmith.

At least 19 recordsLinked to original sources

SIMPLIFI-Study of Interstellar Magnetic Polarization: A Legacy Investigation of Filaments. II. Enhancement of grain alignment near embedded protostars in the DR21 Ridge

Thermal dust continuum polarimetry is a powerful indirect probe of magnetic field geometry in dense molecular clouds while at the same time providing information on the alignment of dust grains with the magnetic field. The leading theory of grain alignment, Radiative Torque Alignment (RAT), has been successful in explaining a variety of observations, including the loss of polarization fraction toward high column densities. One prediction of RAT is that an increase in grain alignment efficiency should be observed in the environments surrounding protostars, due to radiation from the embedded source. However, observational confirmation of this prediction remains scarce. In this study, we sought to test the theoretical prediction of enhanced grain alignment near protostars in the high-mass star forming region DR21 using 214 $\mu m$ SOFIA/HAWC+ observations. We investigated the correlation of the polarization fraction of dust emission, $p$, and the polarization angular dispersion, $S$, with respect to total intensity. We also probed intrinsic dust polarization properties using the product $S\times p$ as a proxy. We detected significant polarization fractions even at the highest intensities, where strong depolarization is typically expected. The polarization fraction-intensity trend flattens at $I > 1.6^{+0.3}_{-0.3} \times 10^4$ MJy/sr ($N_{H_2}$ $\sim 2\times 10^{23}$ ${cm}^{-2}$). We compared the observed trends with predictions from an analytical model of a centrally heated envelope surrounding an embedded luminous protostar. The predictions from the simple model agree well with the observed trends. Our results provide strong support for enhancement of grain alignment by local radiation from embedded sources.

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The [OI] fine structure line profiles in Mon R2 and M17 SW: the puzzling nature of cold foreground material identified by [12CII] self-absorption

Context. Recent studies of the optical depth comparing [12CII] and [13CII] line profiles in Galactic star-forming regions revealed strong self-absorption in [12CII] by low excitation foreground material, implying a large column density of C+ corresponding to an equivalent AV of a few, up to about 10 mag. Aims. As the nature and origin of such a large column of cold C+ foreground gas are difficult to explain, it is essential to constrain the physical conditions of this material. Methods. We conducted high-resolution observations of [OI] 63 um and [OI] 145 um lines in M17 SW and Mon R2. The [OI] 145 um transition traces warm PDR-material, while the [OI] 63 um line traces foreground material as manifested by absorption dips. Results. Comparison of both [OI] line profiles with [CII] isotopic lines confirms warm PDR-origin background emission and a significant column of cold foreground material causing self-absorption visible in [12CII] and [OI] 63 um profiles. In M17 SW, the C+ and O column densities are comparable for both layers. Mon R2 exhibits larger O columns compared to C+, indicating additional material where the carbon is neutral or in molecular form. Small-scale spatial variation of the foreground absorption profiles and the large column density (around 1E18 cm-2 ) of the foreground material suggest emission from high-density regions associated with the cloud complex, not a uniform diffuse foreground cloud. Conclusions. The analysis confirms that the previously detected intense [CII] foreground absorption is attributable to a large column of low excitation dense atomic material, where carbon is ionized, and oxygen is in neutral atomic form.

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A study of Galactic Plane Planck Galactic Cold Clumps observed by SCOPE and the JCMT Plane Survey

We have investigated the physical properties of Planck Galactic Cold Clumps (PGCCs) located in the Galactic Plane, using the JCMT Plane Survey (JPS) and the SCUBA-2 Continuum Observations of Pre-protostellar Evolution (SCOPE) survey. By utilising a suite of molecular-line surveys, velocities and distances were assigned to the compact sources within the PGCCs, placing them in a Galactic context. The properties of these compact sources show no large-scale variations with Galactic environment. Investigating the star-forming content of the sample, we find that the luminosity-to-mass ratio (L/M) is an order of magnitude lower than in other Galactic studies, indicating that these objects are hosting lower levels of star formation. Finally, by comparing ATLASGAL sources that are associated or are not associated with PGCCs, we find that those associated with PGCCs are typically colder, denser, and have a lower L/M ratio, hinting that PGCCs are a distinct population of Galactic Plane sources.

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Cold atomic gas identified by HI self-absorption. Cold atomic clouds toward giant molecular filaments

Stars form in the dense interiors of molecular clouds. The dynamics and physical properties of the atomic interstellar medium (ISM) set the conditions under which molecular clouds and eventually stars will form. It is, therefore, critical to investigate the relationship between the atomic and molecular gas phase to understand the global star formation process. Using the high angular resolution data from The HI/OH/Recombination line survey of the Milky Way (THOR), we aim to constrain the kinematic and physical properties of the cold atomic hydrogen gas phase toward the inner Galactic plane. HI self-absorption (HISA) has proven to be a viable method to detect cold atomic hydrogen clouds in the Galactic plane. With the help of a newly developed self-absorption extraction routine (astroSABER), we build upon previous case studies to identify HI self-absorption toward a sample of Giant Molecular Filaments (GMFs). We find the cold atomic gas to be spatially correlated with the molecular gas on a global scale. The column densities of the cold atomic gas traced by HISA are usually of the order of $10^{20}\rm\,cm^{-2}$ whereas those of molecular hydrogen traced by $\rm^{13}CO$ are at least an order of magnitude higher. The HISA column densities are attributed to a cold gas component that accounts for a fraction of $\sim$5% of the total atomic gas budget within the clouds. The HISA column density distributions show pronounced log-normal shapes that are broader than those traced by HI emission. The cold atomic gas is found to be moderately supersonic with Mach numbers of a $\sim$few. In contrast, highly supersonic dynamics drive the molecular gas within most filaments.

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A panoptic view of the Taurus molecular cloud I. The cloud dynamics revealed by gas emission and 3D dust

We present a study of the three-dimensional (3D) distribution of interstellar dust derived from stellar extinction observations toward the Taurus molecular cloud (MC) and its relation with the neutral atomic hydrogen (HI) emission at 21 cm wavelength and the carbon monoxide $^{12}$CO and $^{13}$CO emission in the $J=1\rightarrow0$ transition. We used the histogram of oriented gradients (HOG) method to match the morphology in a 3D reconstruction of the dust density (3D dust) and the distribution of the gas tracers' emission. The result of the HOG analysis is a map of the relationship between the distances and radial velocities. The HOG comparison between the 3D dust and the HI emission indicates a morphological match at the distance of Taurus but an anti-correlation between the dust density and the HI emission, which uncovers a significant amount of cold HI within the Taurus MC. The HOG between the 3D dust and $^{12}$CO reveals a pattern in radial velocities and distances that is consistent with converging motions of the gas in the Taurus MC, with the near side of the cloud moving at higher velocities and the far side moving at lower velocities. This convergence of flows is likely triggered by the large-scale gas compression caused by the interaction of the Local Bubble and the Per-Tau shell, with Taurus lying at the intersection of the two bubble surfaces.

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CO enhancement by magnetohydrodynamic waves; Striations in the Polaris Flare

The formation of molecular gas in interstellar clouds is a slow process, but is enhanced by gas compression. Magnetohydrodynamic (MHD) waves create compressed quasiperiodic linear structures, referred to as striations. Striations are observed at column densities where the atomic to molecular gas transition takes place. We explore the role of MHD waves in the CO chemistry in regions with striations within molecular clouds. We target a region with striations in the Polaris Flare cloud. We conduct a CO J=2-1 survey in order to probe the molecular gas properties. We use archival starlight polarization data and dust emission maps in order to probe the magnetic field properties and compare against the CO properties. We assess the interaction of compressible MHD wave modes with CO chemistry by comparing their characteristic timescales. The estimated magnetic field is 38 - 76 $μ$G. In the CO integrated intensity map, we observe a dominant quasi-periodic intensity structure, which tends to be parallel to the magnetic field orientation and has a wavelength of one parsec approximately. The periodicity axis is $\sim$ 17 degrees off from the mean magnetic field orientation and is also observed in the dust intensity map. The contrast in the CO integrated intensity map is $\sim 2.4$ times larger than the contrast of the column density map, indicating that CO formation is enhanced locally. We suggest that a dominant slow magnetosonic mode with estimated period $2.1 - 3.4$ Myr, and propagation speed $0.30 - 0.45$ km~s$^{-1}$, is likely to have enhanced the formation of CO, hence created the observed periodic pattern. We also suggest that, within uncertainties, a fast magnetosonic mode with period 0.48 Myr and velocity $2.0$ km~s$^{-1}$ could have played some role in increasing the CO abundance. Quasiperiodic CO structures observed in striation regions may be the imprint of MHD wave modes.

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The Co-Ordinated Radio and Infrared Survey for High-Mass Star Formation. V. The CORNISH-South Survey and Catalogue

We present the first high spatial resolution radio continuum survey of the southern Galactic plane. The CORNISH project has mapped the region defined by $295^{\circ} < l < 350^{\circ}$; $|b| < 1^{\circ}$ at 5.5-GHz, with a resolution of 2.5$^{''}$ (FWHM). As with the CORNISH-North survey, this is designed to primarily provide matching radio data to the Spitzer GLIMPSE survey region. The CORNISH-South survey achieved a root mean square noise level of $\sim$ 0.11 mJy beam$^{-1}$, using the 6A configuration of the Australia Telescope Compact Array (ATCA). In this paper, we discuss the observations, data processing and measurements of the source properties. Above a 7$σ$ detection limit, 4701 sources were detected, and their ensemble properties show similar distributions with their northern counterparts. The catalogue is highly reliable and is complete to 90 per cent at a flux density level of 1.1 mJy. We developed a new way of measuring the integrated flux densities and angular sizes of non-Gaussian sources. The catalogue primarily provides positions, flux density measurements and angular sizes. All sources with IR counterparts at 8$μm$ have been visually classified, utilizing additional imaging data from optical, near-IR, mid-IR, far-IR and sub-millimetre galactic plane surveys. This has resulted in the detection of 524 H II regions of which 255 are ultra-compact H II regions, 287 planetary nebulae, 79 radio stars and 6 massive young stellar objects. The rest of the sources are likely to be extra-galactic. These data are particularly important in the characterization and population studies of compact ionized sources such as UCHII regions and PNe towards the Galactic mid-plane.

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ATOMS: ALMA Three-millimeter Observations of Massive Star-forming regions -XIII. Ongoing triggered star formation within clump-fed scenario found in the massive ($\sim1500$ $\rm M_\odot$) clump

Whether ionization feedback triggers the formation of massive stars is highly debated. Using ALMA 3 mm observations with a spatial resolution of $\sim 0.05$ pc and a mass sensitivity of 1.1 $\rm M_\odot$ beam$^{-1}$ at 20 K, we investigate the star formation and gas flow structures within the ionizing feedback-driven structure, a clump-scale massive ($\gtrsim 1500$ $\rm M_\odot$) bright-rimmed cloud (BRC) associated with IRAS 18290-0924. This BRC is bound only if external compression from ionized gas is considered. A small-scale ($\lesssim1$ pc) age sequence along the direction of ionizing radiation is revealed for the embedded cores and protostars, which suggests triggered star formation via radiation-driven implosion (RDI). Furthermore, filamentary gas structures converge towards the cores located in the BRC's center, indicating that these filaments are fueling mass towards cores. The local core-scale mass infall rate derived from H$^{13}$CO$^+$ $J=1-0$ blue profile is of the same order of magnitude as the filamentary mass inflow rate, approximately 1 $\rm M_\odot$ kyr$^{-1}$. A photodissociation region (PDR) covering the irradiated clump surface is detected in several molecules, such as CCH, HCO$^+$, and CS whereas the spatial distribution stratification of these molecules is indistinct. CCH spectra of the PDR possibly indicate a photoevaporation flow leaving the clump surface with a projected velocity of $\sim2$ km s$^{-1}$. Our new observations show that RDI accompanied by a clump-fed process is operating in this massive BRC. Whether this combined process works in other massive BRCs is worth exploring with dedicated surveys.

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The "Maggie" filament: Physical properties of a giant atomic cloud

The atomic phase of the interstellar medium plays a key role in the formation process of molecular clouds. Due to the line-of-sight confusion in the Galactic plane that is associated with its ubiquity, atomic hydrogen emission has been challenging to study. Employing the high-angular resolution data from the THOR survey, we identify one of the largest, coherent, mostly atomic HI filaments in the Milky Way at the line-of-sight velocities around -54 km/s. The giant atomic filament "Maggie", with a total length of 1.2 kpc, is not detected in most other tracers, and does not show signs of active star formation. At a kinematic distance of 17 kpc, Maggie is situated below (by 500 pc) but parallel to the Galactic HI disk and is trailing the predicted location of the Outer Arm by 5-10 km/s in longitude-velocity space. The centroid velocity exhibits a smooth gradient of less than $\pm$3 km/s /10 pc and a coherent structure to within $\pm$6 km/s. The line widths of 10 km/s along the spine of the filament are dominated by non-thermal effects. After correcting for optical depth effects, the mass of Maggie's dense spine is estimated to be $7.2\times10^5\,M_{\odot}$. The mean number density of the filament is 4$\rm\,cm^{-3}$, which is best explained by the filament being a mix of cold and warm neutral gas. In contrast to molecular filaments, the turbulent Mach number and velocity structure function suggest that Maggie is driven by transonic to moderately supersonic velocities that are likely associated with the Galactic potential rather than being subject to the effects of self-gravity or stellar feedback. The column density PDF displays a log-normal shape around a mean of $N_{\rm HI} = 4.8\times 10^{20}\rm\,cm^{-2}$, thus reflecting the absence of dominating effects of gravitational contraction.

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The Dense Warm Ionized Medium in the Inner Galaxy

Ionized interstellar gas is an important component of the interstellar medium and its lifecycle. The recent evidence for a widely distributed highly ionized warm interstellar gas with a density intermediate between the warm ionized medium (WIM) and compact HII regions suggests that there is a major gap in our understanding of the interstellar gas. Here we investigate the properties of the dense warm ionized medium (D-WIM) in the Milky Way using spectrally resolved SOFIA GREAT [NII] 205 micron line emission and Green Bank Telescope hydrogen radio recombination lines (RRL) data, supplemented by Herschel PACS [NII] 122 micron data, and spectrally resolved 12CO. We observed eight lines of sight in the 20deg 50% of the observed [CII] intensity along these LOS. The kinetic temperatures we derive are too low to explain the presence of N+ resulting from electron collisional ionization and/or proton charge transfer of atomic nitrogen. Rather, these regions most likely are ionized by extreme ultraviolet radiation.

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The Future Of The Arecibo Observatory: The Next Generation Arecibo Telescope

The Arecibo Observatory (AO) is a multidisciplinary research and education facility that is recognized worldwide as a leading facility in astronomy, planetary, and atmospheric and space sciences. AO's cornerstone research instrument was the 305-m William E. Gordon telescope. On December 1, 2020, the 305-m telescope collapsed and was irreparably damaged. In the three weeks following the collapse, AO's scientific and engineering staff and the AO users community initiated extensive discussions on the future of the observatory. The community is in overwhelming agreement that there is a need to build an enhanced, next-generation radar-radio telescope at the AO site. From these discussions, we established the set of science requirements the new facility should enable. These requirements can be summarized briefly as: 5 MW of continuous wave transmitter power at 2 - 6 GHz, 10 MW of peak transmitter power at 430 MHz (also at 220MHz under consideration), zenith angle coverage 0 to 48 deg, frequency coverage 0.2 to 30 GHz and increased Field-of-View. These requirements determine the unique specifications of the proposed new instrument. The telescope design concept we suggest consists of a compact array of fixed dishes on a tiltable, plate-like structure with a collecting area equivalent to a 300m dish. This concept, referred to as the Next Generation Arecibo Telescope (NGAT), meets all of the desired specifications and provides significant new science capabilities to all three research groups at AO. This whitepaper presents a sample of the wide variety of the science that can be achieved with the NGAT, the details of the telescope design concept and the need for the new telescope to be located at the AO site. We also discuss other AO science activities that interlock with the NGAT in the white paper.

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LEGO II: A 3 mm molecular line study covering 100 pc of one of the most actively star-forming portions within the Milky Way Disc

The current generation of (sub)mm-telescopes has allowed molecular line emission to become a major tool for studying the physical, kinematic, and chemical properties of extragalactic systems, yet exploiting these observations requires a detailed understanding of where emission lines originate within the Milky Way. In this paper, we present 60$^{\prime\prime}$ ($\sim$3pc) resolution observations of many 3mm-band molecular lines across a large map of the W49 massive star-forming region ($\sim$100$\times$100pc at 11kpc), which were taken as part of the "LEGO" IRAM-30m large project. We find that the spatial extent or brightness of the molecular line transitions are not well correlated with their critical densities, highlighting abundance and optical depth must be considered when estimating line emission characteristics. We explore how the total emission and emission efficiency (i.e. line brightness per H$_{2}$ column density) of the line emission vary as a function of molecular hydrogen column density and dust temperature. We find that there is not a single region of this parameter space responsible for the brightest and most efficiently emitting gas for all species. For example, we find that the HCN transition shows high emission efficiency at high column density ($10^{22}$cm$^{-2}$) and moderate temperatures (35K), whilst e.g. N$_2$H$^+$ emits most efficiently towards lower temperatures ($10^{22}$cm$^{-2}$; <20K). We determine $X_{\mathrm{CO} (1-0)} \sim 0.3 \times 10^{20} \mathrm{cm^{-2}(Kkms^{-1})^{-1}}$, and $α_{\mathrm{HCN} (1-0)} \sim 30\mathrm{M_\odot(Kkms^{-1}pc^2)^{-1}}$, which both differ significantly from the commonly adopted values. In all, these results suggest caution should be taken when interpreting molecular line emission.

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Atomic and molecular gas properties during cloud formation

Molecular clouds, which harbor the birthplaces of stars, form out of the atomic phase of the interstellar medium (ISM). We aim to characterize the atomic and molecular phases of the ISM and set their physical properties into the context of cloud formation processes. We studied the cold neutral medium (CNM) by means of $\rm HI$ self-absorption (HISA) toward the giant molecular filament GMF20.0-17.9 and compared our results with molecular gas traced by $^{13}\rm CO$ emission. We fitted baselines of HISA features to $\rm HI$ emission spectra using first and second order polynomial functions. The CNM identified by this method spatially correlates with the morphology of the molecular gas toward the western region. However, no spatial correlation between HISA and $^{13}\rm CO$ is evident toward the eastern part of the filament. The distribution of HISA peak velocities and line widths agrees well with $^{13}\rm CO$ within the whole filament. The column density probability density functions (N-PDFs) of HISA (CNM) and $\rm HI$ emission (tracing both the CNM and the warm neutral medium, WNM) have a log-normal shape for all parts of the filament, indicative of turbulent motions as the main driver for these structures. The $\rm H_2$ N-PDFs show a broad log-normal distribution with a power-law tail suggesting the onset of gravitational contraction. The saturation of $\rm HI$ column density is observed at $\sim$25$\rm\,M_{\odot}\,pc^{-2}$. We conjecture that different evolutionary stages are evident within the filament. In the eastern region, we witness the onset of molecular cloud formation out of the atomic gas reservoir while the western part is more evolved, as it reveals pronounced $\rm H_2$ column density peaks and signs of active star formation.

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Cloud formation in the atomic and molecular phase: HI self absorption (HISA) towards a Giant Molecular Filament

Molecular clouds form from the atomic phase of the interstellar medium. However, characterizing the transition between the atomic and the molecular interstellar medium (ISM) is a difficult observational task. Here we address cloud formation processes by combining HSIA with molecular line data. One scenario proposed by numerical simulations is that the column density probability density functions (N-PDF) evolves from a log-normal shape at early times to a power-law-like shape at later times. In this paper, we study the cold atomic component of the giant molecular filament GMF38a (d=3.4 kpc, length$\sim230$ pc). We identify an extended HISA feature, which is partly correlated with the 13CO emission. The peak velocities of the HISA and 13CO observations agree well on the eastern side of the filament, whereas a velocity offset of approximately 4 km s$^{-1}$ is found on the western side. The sonic Mach number we derive from the linewidth measurements shows that a large fraction of the HISA, which is ascribed to the cold neutral medium (CNM), is at subsonic and transonic velocities. The column density of the CNM is on the order of 10$^{20}$ to 10$^{21}$ cm$^{-2}$. The column density of molecular hydrogen is an order of magnitude higher. The N-PDFs from HISA (CNM), HI emission (WNM+CNM), and 13CO (molecular component) are well described by log-normal functions, which is in agreement with turbulent motions being the main driver of cloud dynamics. The N-PDF of the molecular component also shows a power law in the high column-density region, indicating self-gravity. We suggest that we are witnessing two different evolutionary stages within the filament. The eastern subregion seems to be forming a molecular cloud out of the atomic gas, whereas the western subregion already shows high column density peaks, active star formation and evidence of related feedback processes.

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The HI/OH/Recombination line survey of the inner Milky Way (THOR): data release 2 and HI overview

With the $Karl~G.~Jansky$ Very Large Array (VLA) in C-configuration, we observed a large portion of the first Galactic quadrant ($l=14.0-67.4^\circ $ and $\lvert b \rvert \leq 1.25^\circ $) achieving an angular resolution of $\leq 40^{\prime\prime}$. At $L$ Band, the WIDAR correlator at the VLA was set to cover the 21~cm HI line, four OH transitions, a series of H$nα$ radio recombination lines (RRLs; $n=151$ to 186), and eight 128~MHz wide continuum spectral windows (SPWs) simultaneously. The HI emission shows clear filamentary substructures at negative velocities with low velocity crowding. The emission at positive velocities is more smeared-out likely due to higher spatial and velocity crowding of structures at the positive velocities. Comparing to the spiral arm model of the Milky Way, the atomic gas follows the Sagittarius and Perseus Arm well but with significant material in the inter-arm regions. With the C-configuration-only HI+continuum data, we produced a HI optical depth map of the THOR areal coverage from 228 absorption spectra with the nearest-neighbor method. With this $τ$ map, we corrected the HI emission for optical depth and the derived column density is 38% higher than the column density with optically thin assumption. The total HI mass with optical depth correction in the survey region is 4.7$\times10^8~M_\odot$, 31% more than the mass derived assuming the emission is optically thin. If we apply this 31% correction to the whole Milky Way, the total atomic gas mass would be 9.4-10.5$\times 10^9~M_\odot$. Comparing the HI with existing CO data, we find a significant increase in the atomic-to-molecular gas ratio from the spiral arms to the inter-arm regions.

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Astro2020 Activities and Projects White Paper: Arecibo Observatory in the Next Decade

The white paper discusses Arecibo Observatory's plan for facility improvements and activities over the next decade. The facility improvements include: (a) improving the telescope surface, pointing and focusing to achieve superb performance up to ~12.5 GHz; (b) equip the telescope with ultrawide-band feeds; (c) upgrade the instrumentation with a 4 GHz bandwidth high dynamic range digital link and a universal backend and (d) augment the VLBI facility by integrating the 12m telescope for phase referencing. These upgrades to the Arecibo telescope are critical to keep the national facility in the forefront of research in radio astronomy while maintaining its dominance in radar studies of near-Earth asteroids, planets and satellites. In the next decade, the Arecibo telescope will play a synergistic role with the upcoming facilities such as ngVLA, SKA and the now commissioned FAST telescope. Further, the observatory will be actively engaged in mentoring and training programs for students from a diverse background.

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Feedback in W49A diagnosed with radio recombination lines and models

We present images of radio recombination lines (RRLs) at wavelengths around 17 cm from the star-forming region W49A to determine the kinematics of ionized gas in the THOR survey (The HI/OH/Recombination line survey of the inner Milky Way) at an angular resolution of 16.8"x13.8". The distribution of ionized gas appears to be affected by feedback processes from the star clusters in W49A. The velocity structure of the RRLs shows a complex behavior with respect to the molecular gas. We find a shell-like distribution of ionized gas as traced by RRL emission surrounding the central cluster of OB stars in W49A. We describe the evolution of the shell with the recent feedback model code WARPFIELD that includes the important physical processes and has previously been applied to the 30 Doradus region in the Large Magellanic Cloud. The cloud structure and dynamics of W49A are in agreement with a feedback-driven shell that is re-collapsing. The shell may have triggered star formation in other parts of W49A. We suggest that W49A is a potential candidate for star formation regulated by feedback-driven and re-collapsing shells.

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The complexity of Orion: an ALMA view III. The explosion impact

The chemistry of complex organic molecules in interstellar dark clouds is still highly uncertain in part because of the lack of constraining observations. Orion is the closest massive star-forming region, and observations making use of ALMA allow us to separate the emission regions of various complex organic molecules (COMs) in both velocity and space. Orion also benefits from an exceptional situation, in that it is the site of a powerful explosive event that occurred 550 years ago. We show that the closely surrounding Kleinmann-Low region has clearly been influenced by this explosion; some molecular species have been pushed away from the densest parts while others have remained in close proximity. This dynamical segregation reveals the time dependence of the chemistry and, therefore allows us to better constrain the formation sequence of COMs and other species, including deuterated molecules.

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