arXiv subjects

P. G. J. Irwin

Publications and source records attributed to P. G. J. Irwin.

At least 19 recordsLinked to original sources

arXiv2025

Improved Carbon and Nitrogen Isotopic Ratios for CH$_3$CN in Titan's Atmosphere Using ALMA

Titan, Saturn's largest satellite, maintains an atmosphere composed primarily of nitrogen (N$_2$) and methane (CH$_4$) that leads to a complex organic chemistry. Some of the nitriles (CN-bearing organics) on Titan are known to have substantially enhanced $^{15}$N abundances compared to Earth and to Titan's dominant nitrogen (N$_2$) reservoir. The $^{14}$N/$^{15}$N isotopic ratio in Titan's nitriles can provide better constraints on the synthesis of nitrogen-bearing organics in planetary atmospheres as well as insights into the origin of Titan's large nitrogen abundance. Using high signal-to-noise ratio ($>13$), disk-integrated observations obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) Band 6 receiver (211-275 GHz), we measure the $^{14}$N/$^{15}$N and $^{12}$C/$^{13}$C isotopic ratios of acetonitrile (CH$_3$CN) in Titan's stratosphere. Using the Nonlinear optimal Estimator for MultivariatE spectral analySIS (NEMESIS), we derived the CH$_3$CN/$^{13}$CH$_3$CN ratio to be 89.2 $\pm$ 7.0 and the CH$_3$CN/CH$_3$$^{13}$CN ratio to be 91.2 $\pm$ 6.0, in agreement with the $^{12}$C/$^{13}$C ratio in Titan's methane, and other Solar System species. We found the $^{14}$N/$^{15}$N isotopic ratio to be 68.9 $\pm$ 4.2, consistent with previously derived values for HCN and HC$_3$N, confirming an enhanced $^{15}$N abundance in Titan's nitriles compared with the bulk atmospheric N$_2$ value of $^{14}$N/$^{15}$N = 168, in agreement with chemical models incorporating isotope-selective photodissociation of N$_2$ at high altitudes.

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arXiv2024

Variability in Titan's Mesospheric HCN and Temperature Structure as Observed by ALMA

The temperature structure of Titan's upper atmosphere exhibits large variability resulting from numerous spatially and temporally irregular external energy sources, seasonal changes, and the influence of molecular species produced via photochemistry. In particular, Titan's relatively abundant HCN is thought to provide substantial cooling to the upper atmosphere through rotational emission, balancing UV/EUV heating and thermal conduction. Here, we present the analysis of ALMA observations of Titan from 2012, 2014, 2015, and 2017, corresponding to planetocentric solar longitudes of ~34-89$^{\circ}$, including vertical HCN and temperature profiles retrieved from the lower mesosphere through the thermosphere (~350-1200 km; $3\times10^{-2}$-$2\times10^{-8}$ mbar). Throughout the atmosphere, temperature profiles differ by 10 to 30 K between observations approximately one Earth year apart, particularly from 600-900 km. We find evidence for a large imbalance in Titan's upper atmospheric energy budget between 2014 and 2015, where the mesospheric thermal structure changes significantly and marks the transition between a mesopause located at ~600 km ($2\times10^{-4}$ mbar) and at ~800 km ($3\times10^{-6}$ mbar). The retrieved HCN abundances vary dramatically during the 2012 to 2017 time period as well, showing close to 2 orders of magnitude difference in abundance at 1000 km. However, the change in HCN abundance does not appear to fully account for the variation in mesospheric temperatures over the $L_S\sim$34-89$^{\circ}$ period. These measurements provide additional insight into the variability of Titan's mesospheric composition and thermal structure following its 2009 vernal equinox, and motivate continued investigation of the origins of such rapid changes in Titan's atmosphere throughout its seasonal cycle.

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arXiv2021

Latitudinal variation of methane mole fraction above clouds in Neptune's atmosphere from VLT/MUSE-NFM: Limb-darkening reanalysis

We present a reanalysis of visible/near-infrared (480-930 nm) observations of Neptune, made in 2018 with the MUSE instrument at the Very Large Telescope (VLT) in Narrow Field Adaptive Optics mode, reported by Irwin et al., Icarus, 311, 2019. We find that the inferred variation of methane abundance with latitude in our previous analysis, which was based on central meridian observations only, underestimated the retrieval errors when compared with a more complete assessment of Neptune's limb darkening. In addition, our previous analysis introduced spurious latitudinal variability of both the abundance and its uncertainty, which we reassess here. Our reanalysis of these data incorporates the effects of limb-darkening based upon the Minnaert approximation, which provides a much stronger constraint on the cloud structure and methane mole fraction, makes better use of the available data and is more computationally efficient. We find that away from discrete cloud features, the observed reflectivity spectrum from 800-900 nm is very well approximated by a background cloud model that is latitudinally varying, but zonally symmetric, consisting of a H$_2$S cloud layer, based at 3.6-4.7 bar with variable opacity and scale height, and a stratospheric haze. The background cloud model matches the observed limb darkening seen at all wavelengths and latitudes and we find that the mole fraction of methane at 2-4 bar, above the H$_2$S cloud, but below the methane condensation level, varies from 4-6\% at the equator to 2-4\% at near the south pole, consistent with previous analyses, with a equator/pole ratio of $1.9 \pm 0.2$ for our assumed cloud/methane model. The spectra of discrete cloudy regions are fitted, to a very good approximation, by the addition of a single vertically thin methane ice cloud with opacity ranging from 0 - 0.75 and pressure less than $\sim 0.4$ bar.

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arXiv2020

Detection of CH$_3$C$_3$N in Titan's Atmosphere

Titan harbors a dense, organic-rich atmosphere primarily composed of N$_2$ and CH$_4$, with lesser amounts of hydrocarbons and nitrogen-bearing species. As a result of high sensitivity observations by the Atacama Large Millimeter/submillimeter Array (ALMA) in Band 6 ($\sim$230-272 GHz), we obtained the first spectroscopic detection of CH$_3$C$_3$N (methylcyanoacetylene or cyanopropyne) in Titan's atmosphere through the observation of seven transitions in the $J = 64\rightarrow63$ and $J = 62\rightarrow61$ rotational bands. The presence of CH$_3$C$_3$N on Titan was suggested by the Cassini Ion and Neutral Mass Spectrometer detection of its protonated form: C$_4$H$_3$NH$^+$, but the atmospheric abundance of the associated (deprotonated) neutral product is not well constrained due to the lack of appropriate laboratory reaction data. Here, we derive the column density of CH$_3$C$_3$N to be (3.8-5.7)$\times10^{12}$ cm$^{-2}$ based on radiative transfer models sensitive to altitudes above 400 km Titan's middle atmosphere. When compared with laboratory and photochemical model results, the detection of methylcyanoacetylene provides important constraints for the determination of the associated production pathways (such as those involving CN, CCN, and hydrocarbons), and reaction rate coefficients. These results also further demonstrate the importance of ALMA and (sub)millimeter spectroscopy for future investigations of Titan's organic inventory and atmospheric chemistry, as CH$_3$C$_3$N marks the heaviest polar molecule detected spectroscopically in Titan's atmosphere to date.

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arXiv2019

Toward the Analysis of JWST Exoplanet Spectra: the effective temperature in the context of direct imaging

The current sparse wavelength range coverage of exoplanet direct imaging observations, and the fact that models are defined using a finite wavelength range, lead both to uncertainties on effective temperature determination.We study these effects using black-bodies and atmospheric models and we detail how to infer this parameter. Through highlighting the key wavelength coverage that allows for a more accurate representation of the effective temperature, our analysis can be used to mitigate or manage extra uncertainties being added in the analysis from the models. We find that the wavelength range coverage will soon no longer be a problem. An effective temperature computed by integrating the spectroscopic observations of the James Webb Space Telescope (JWST) will give uncertainties similar to, or better than, the current state-of-the-art, which is to fit models to data. Accurately calculating the effective temperature will help to improve current modelling approaches. Obtaining an independent and precise estimation of this crucial parameter will help the benchmarking process to identify the best practice to model exoplanet atmospheres.

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arXiv2019

Hazes and clouds in a singular triple vortex in Saturn's atmosphere from HST/WFC3 multispectral imaging

In this paper we present a study of the vertical haze and cloud structure over a triple vortex in Saturn's atmosphere in the planetographic latitude range 55N-69N (del Rio- Gaztelurrutia et al. , 2018) using HST/WFC3 multispectral imaging. The observations were taken during 29-30 June and 1 July 2015 at ten different filters covering spectral range from the 225 nm to 937 nm, including the deep methane band at 889 nm. Absolute reflectivity measurements of this region at all wavelengths and under a number of illumination and observation geometries are fitted with the values produced by a radiative transfer model. Most of the reflectivity variations in this wavelength range can be attributed to changes in the tropospheric haze. The anticyclones are optically thicker ($τ\sim$ 25 vs $\sim$ 10), more vertically extended ($\sim$ 3 gas scale heights vs $\sim$ 2) and their bases are located deeper in the atmosphere (550 mbar vs 500 mbar) than the cyclone.

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arXiv2019

Effectively Calculating Gaseous Absorption in Radiative Transfer Models of Exoplanetary and Brown Dwarf Atmospheres

Sophisticated atmospheric retrieval algorithms, such as Nested Sampling, explore large parameter spaces by iterating over millions of radiative transfer (RT) calculations. Probability distribution functions for retrieved parameters are highly sensitive to assumptions made within the RT forward model. One key difference between RT models is the computation of the gaseous absorption throughout the atmosphere. We compare two methods of calculating gaseous absorption, cross-sections and correlated-$k$, by examining their resulting spectra of a number of typical \ce{H2}-He dominated exoplanetary and brown dwarf atmospheres. We also consider the effects of including \ce{H2}-He pressure-broadening in some of these examples. We use NEMESIS to compute forward models. Our $k$-tables are verified by comparison to ExoMol cross-sections provided online and a line-by-line calculation. For test cases with typical resolutions ($Δν= 1$cm$^{-1}$), we show that the cross-section method overestimates the amount of absorption present in the atmosphere and should be used with caution. For mixed-gas atmospheres the morphology of the spectra changes, producing `ghost' features. The two methods produce differences in flux of up to a few orders of magnitude. The addition of pressure broadening of lines adds up to an additional order of magnitude change in flux. These effects are more pronounced for brown dwarfs and secondary eclipse geometries. We note that correlated-$k$ can produce similar results to very high-resolution cross-sections, but is much less computationally expensive. We conclude that inaccurate use of cross-sections and omission of pressure broadening can be key sources of error in the modelling of brown dwarf and exoplanet atmospheres.

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arXiv2019

Seasonal evolution of temperatures in Titan's lower stratosphere

The Cassini mission offered us the opportunity to monitor the seasonal evolution of Titan's atmosphere from 2004 to 2017, i.e. half a Titan year. The lower part of the stratosphere (pressures greater than 10 mbar) is a region of particular interest as there are few available temperature measurements, and because its thermal response to the seasonal and meridional insolation variations undergone by Titan remains poorly known. In this study, we measure temperatures in Titan's lower stratosphere between 6 mbar and 25 mbar using Cassini/CIRS spectra covering the whole duration of the mission (from 2004 to 2017) and the whole latitude range. We can thus characterize the meridional distribution of temperatures in Titan's lower stratosphere, and how it evolves from northern winter (2004) to summer solstice (2017). Our measurements show that Titan's lower stratosphere undergoes significant seasonal changes, especially at the South pole, where temperature decreases by 19 K at 15 mbar in 4 years.

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arXiv2018

Spatial Variations in Titan's Atmospheric Temperature: ALMA and Cassini Comparisons from 2012 to 2015

Submillimeter emission lines of carbon monoxide (CO) in Titan's atmosphere provide excellent probes of atmospheric temperature due to the molecule's long chemical lifetime and stable, well constrained volume mixing ratio. Here we present the analysis of 4 datasets obtained with the Atacama Large Millimeter/Submillimeter Array (ALMA) from 2012 to 2015 that contain strong CO rotational transitions. Utilizing ALMA's high spatial resolution in the 2012, 2014, and 2015 observations, we extract spectra from 3 separate regions on Titan's disk using datasets with beam sizes of ~0.3''. Temperature profiles retrieved by the NEMESIS radiative transfer code are compared to Cassini Composite Infrared Spectrometer (CIRS) and radio occultation science results from similar latitude regions. Small seasonal variations in atmospheric temperature are present from 2012 to 2015 in the stratosphere and mesosphere (~100-500 km) of spatially resolved regions. We measure the stratopause (320 km) to increase in temperature by 5 K in northern latitudes from 2012-2015, while temperatures rise throughout the stratosphere at lower latitudes. While retrieved temperature profiles cover a range of latitudes in these observations, deviations from CIRS nadir maps and radio occultation measurements convolved with the ALMA beam-footprint are not found to be statistically significant, and discrepancies are often found to be less than 5 K throughout the atmosphere. ALMA's excellent sensitivity in the lower stratosphere (60-300 km) provides a highly complementary dataset to contemporary CIRS and radio science observations. The demonstrated utility of CO emission lines in the submillimeter as a tracer of Titan's atmospheric temperature lays the groundwork for future studies of other molecular species, as temperature profiles are found to consistently vary with latitude in all three years by up to 15 K.

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arXiv2018

Abundance Measurements of Titan's Stratospheric HCN, HC$_3$N, C$_3$H$_4$, and CH$_3$CN from ALMA Observations

Previous investigations have employed more than 100 close observations of Titan by the Cassini orbiter to elucidate connections between the production and distribution of Titan's vast, organic-rich chemical inventory and its atmospheric dynamics. However, as Titan transitions into northern summer, the lack of incoming data from the Cassini orbiter presents a potential barrier to the continued study of seasonal changes in Titan's atmosphere. In our previous work (Thelen et al., 2018), we demonstrated that the Atacama Large Millimeter/submillimeter Array (ALMA) is well suited for measurements of Titan's atmosphere in the stratosphere and lower mesosphere (~100-500 km) through the use of spatially resolved (beam sizes <1'') flux calibration observations of Titan. Here, we derive vertical abundance profiles of four of Titan's trace atmospheric species from the same 3 independent spatial regions across Titan's disk during the same epoch (2012 to 2015): HCN, HC$_3$N, C$_3$H$_4$, and CH$_3$CN. We find that Titan's minor constituents exhibit large latitudinal variations, with enhanced abundances at high latitudes compared to equatorial measurements; this includes CH$_3$CN, which eluded previous detection by Cassini in the stratosphere, and thus spatially resolved abundance measurements were unattainable. Even over the short 3-year period, vertical profiles and integrated emission maps of these molecules allow us to observe temporal changes in Titan's atmospheric circulation during northern spring. Our derived abundance profiles are comparable to contemporary measurements from Cassini infrared observations, and we find additional evidence for subsidence of enriched air onto Titan's south pole during this time period. Continued observations of Titan with ALMA beyond the summer solstice will enable further study of how Titan's atmospheric composition and dynamics respond to seasonal changes.

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arXiv2018

A Hexagon in Saturn's Northern Stratosphere Surrounding the Emerging Summertime Polar Vortex

Saturn's polar stratosphere exhibits the seasonal growth and dissipation of broad, warm, vortices poleward of $\sim75^\circ$ latitude, which are strongest in the summer and absent in winter. The longevity of the exploration of the Saturn system by Cassini allows the use of infrared spectroscopy to trace the formation of the North Polar Stratospheric Vortex (NPSV), a region of enhanced temperatures and elevated hydrocarbon abundances at millibar pressures. We constrain the timescales of stratospheric vortex formation and dissipation in both hemispheres. Although the NPSV formed during late northern spring, by the end of Cassini's reconnaissance (shortly after northern summer solstice), it still did not display the contrasts in temperature and composition that were evident at the south pole during southern summer. The newly-formed NPSV was bounded by a strengthening stratospheric thermal gradient near $78^\circ$N. The emergent boundary was hexagonal, suggesting that the Rossby wave responsible for Saturn's long-lived polar hexagon - which was previously expected to be trapped in the troposphere - can influence the stratospheric temperatures some 300 km above Saturn's clouds.

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arXiv2018

Venus upper clouds and the UV-absorber from MESSENGER/MASCS observations

One of the most intriguing, long-standing questions regarding Venus' atmosphere is the origin and distribution of the unknown UV-absorber, responsible for the absorption band detected at the near-UV and blue range of Venus' spectrum. In this work, we use data collected by MASCS spectrograph on board the MESSENGER mission during its second Venus flyby in June 2007 to address this issue. Spectra range from 0.3 μm to 1.5 μm including some gaseous H2O and CO2 bands, as well as part of the SO2 absorption band and the core of the UV absorption. We used the NEMESIS radiative transfer code and retrieval suite to investigate the vertical distribution of particles in the Equatorial atmosphere and to retrieve the imaginary refractive indices of the UV-absorber, assumed to be well mixed with Venus' small mode-1 particles. The results show an homogeneous Equatorial atmosphere, with cloud tops (height for unity optical depth) at 75+/-2 km above surface. The UV absorption is found to be centered at 0.34+/-0.03 μm with a full width half maximum of 0.14+/-0.01 μm. Our values are compared with previous candidates for the UV aerosol absorber, among which disulfur oxide (S2O) and dioxide disulfur (S2O2) provide the best agreement with our results.

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arXiv2018

Assessing the long-term variability of acetylene and ethane in the stratosphere of Jupiter

Acetylene (C$_2$H$_2$) and ethane (C$_2$H$_6$) are both produced in the stratosphere of Jupiter via photolysis of methane (CH$_4$). Despite this common source, the latitudinal distribution of the two species is radically different, with acetylene decreasing in abundance towards the pole, and ethane increasing towards the pole. We present six years of NASA IRTF TEXES mid-infrared observations of the zonally-averaged emission of methane, acetylene and ethane. We confirm that the latitudinal distributions of ethane and acetylene are decoupled, and that this is a persistent feature over multiple years. The acetylene distribution falls off towards the pole, peaking at $\sim$30$^{\circ}$N with a volume mixing ratio (VMR) of $\sim$0.8 parts per million (ppm) at 1 mbar and still falling off at $\pm70^\circ$ with a VMR of $\sim$0.3 ppm. The acetylene distributions are asymmetric on average, but as we move from 2013 to 2017, the zonally-averaged abundance becomes more symmetric about the equator. We suggest that both the short term changes in acetylene and its latitudinal asymmetry is driven by changes to the vertical stratospheric mixing, potentially related to propagating wave phenomena. Unlike acetylene, ethane has a symmetric distribution about the equator that increases toward the pole, with a peak mole fraction of $\sim$18 ppm at about $\pm50^{\circ}$ latitude, with a minimum at the equator of $\sim$10 ppm at 1 mbar. [...] The equator-to-pole distributions of acetylene and ethane are consistent with acetylene having a shorter lifetime than ethane that is not sensitive to longer advective timescales, but is augmented by short-term dynamics, such as vertical mixing. Conversely, the long lifetime of ethane allows it to be transported to higher latitudes faster than it can be chemically depleted.

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arXiv2017

LRG-BEASTS III: Ground-based transmission spectrum of the gas giant orbiting the cool dwarf WASP-80

We have performed ground-based transmission spectroscopy of the hot Jupiter orbiting the cool dwarf WASP-80 using the ACAM instrument on the William Herschel Telescope (WHT) as part of the LRG-BEASTS programme. This is the third paper of a ground-based transmission spectroscopy survey of hot Jupiters using low-resolution grism spectrographs. We observed two transits of the planet and have constructed transmission spectra spanning a wavelength range of 4640-8840A. Our transmission spectrum is inconsistent with a previously claimed detection of potassium in WASP-80b's atmosphere, and is instead most consistent with a haze. We also do not see evidence for sodium absorption at a resolution of 100A.

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arXiv2017

Mapping Vinyl Cyanide and Other Nitriles in Titan's Atmosphere Using ALMA

Vinyl cyanide (C$_2$H$_3$CN) is theorized to form in Titan's atmosphere via high-altitude photochemistry and is of interest regarding the astrobiology of cold planetary surfaces due to its predicted ability to form cell membrane-like structures (azotosomes) in liquid methane. In this work, we follow up on the initial spectroscopic detection of C$_2$H$_3$CN on Titan by Palmer et al. (2017) with the detection of three new C$_2$H$_3$CN rotational emission lines at submillimeter frequencies. These new, high-resolution detections have allowed for the first spatial distribution mapping of C$_2$H$_3$CN on Titan. We present simultaneous observations of C$_2$H$_5$CN, HC$_3$N, and CH$_3$CN emission, and obtain the first (tentative) detection of C$_3$H$_8$ (propane) at radio wavelengths. We present disk-averaged vertical abundance profiles, two-dimensional spatial maps, and latitudinal flux profiles for the observed nitriles. Similarly to HC$_3$N and C$_2$H$_5$CN, which are theorized to be short-lived in Titan's atmosphere, C$_2$H$_3$CN is most abundant over the southern (winter) pole, whereas the longer-lived CH$_3$CN is more concentrated in the north. This abundance pattern is consistent with the combined effects of high-altitude photochemical production, poleward advection, and the subsequent reversal of Titan's atmospheric circulation system following the recent transition from northern to southern winter. We confirm that C$_2$H$_3$CN and C$_2$H$_5$CN are most abundant at altitudes above 200 km. Using a 300 km step model, the average abundance of C$_2$H$_3$CN is found to be $3.03\pm0.29$ ppb, with a C$_2$H$_5$CN/C$_2$H$_3$CN abundance ratio of $2.43\pm0.26$. Our HC$_3$N and CH$_3$CN spectra can be accurately modeled using abundance gradients above the tropopause, with fractional scale-heights of $2.05\pm0.16$ and $1.63\pm0.02$, respectively.

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arXiv2017

Seasonal evolution of $\mathrm{C_2N_2}$, $\mathrm{C_3H_4}$, and $\mathrm{C_4H_2}$ abundances in Titan's lower stratosphere

We study the seasonal evolution of Titan's lower stratosphere (around 15~mbar) in order to better understand the atmospheric dynamics and chemistry in this part of the atmosphere. We analysed Cassini/CIRS far-IR observations from 2006 to 2016 in order to measure the seasonal variations of three photochemical by-products: $\mathrm{C_4H_2}$, $\mathrm{C_3H_4}$, and $\mathrm{C_2N_2}$. We show that the abundances of these three gases have evolved significantly at northern and southern high latitudes since 2006. We measure a sudden and steep increase of the volume mixing ratios of $\mathrm{C_4H_2}$, $\mathrm{C_3H_4}$, and $\mathrm{C_2N_2}$ at the south pole from 2012 to 2013, whereas the abundances of these gases remained approximately constant at the north pole over the same period. At northern mid-latitudes, $\mathrm{C_2N_2}$ and $\mathrm{C_4H_2}$ abundances decrease after 2012 while $\mathrm{C_3H_4}$ abundances stay constant. The comparison of these volume mixing ratio variations with the predictions of photochemical and dynamical models provides constraints on the seasonal evolution of atmospheric circulation and chemical processes at play.

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arXiv2017

Jupiter's North Equatorial Belt expansion and thermal wave activity ahead of Juno's arrival

The dark colors of Jupiter's North Equatorial Belt (NEB, $7-17^\circ$N) appeared to expand northward into the neighboring zone in 2015, consistent with a 3-5 year cycle of activity in the NEB. Inversions of thermal-IR imaging from the Very Large Telescope revealed a moderate warming and reduction of aerosol opacity at the cloud tops at $17-20^\circ$N, suggesting subsidence and drying in the expanded sector. Two new thermal waves were identified during this period: (i) an upper tropospheric thermal wave (wavenumber 16-17, amplitude 2.5 K at 170 mbar) in the mid-NEB that was anti-correlated with haze reflectivity; and (ii) a stratospheric wave (wavenumber 13-14, amplitude 7.3 K at 5 mbar) at $20-30^\circ$N. Both were quasi-stationary, confined to regions of eastward zonal flow, and are morphologically similar to waves observed during previous expansion events.

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arXiv2017

Mid-Infrared Mapping of Jupiter's Temperatures, Aerosol Opacity and Chemical Distributions with IRTF/TEXES

Global maps of Jupiter's atmospheric temperatures, gaseous composition and aerosol opacity are derived from a programme of 5-20 $μ$m mid-infrared spectroscopic observations using the Texas Echelon Cross Echelle Spectrograph (TEXES) on NASA's Infrared Telescope Facility (IRTF). Image cubes from December 2014 in eight spectral channels, with spectral resolutions of $R\sim2000-12000$ and spatial resolutions of $2-4^\circ$ latitude, are inverted to generate 3D maps of tropospheric and stratospheric temperatures, 2D maps of upper tropospheric aerosols, phosphine and ammonia, and 2D maps of stratospheric ethane and acetylene. The results are compared to a re-analysis of Cassini Composite Infrared Spectrometer (CIRS) observations acquired during Cassini's closest approach to Jupiter in December 2000, demonstrating that this new archive of ground-based mapping spectroscopy can match and surpass the quality of previous investigations, and will permit future studies of Jupiter's evolving atmosphere. We identify mid-infrared signatures of Jupiter's 5-$μ$m hotspots via simultaneous M, N and Q-band observations, which are interpreted as temperature and ammonia variations in the northern Equatorial Zone and on the edge of the North Equatorial Belt (NEB). Equatorial plumes enriched in NH$_3$ gas are located south-east of NH$_3$-desiccated `hotspots' on the edge of the NEB. Comparison of the hotspot locations in several channels across the 5-20 $μ$m range indicate that these anomalous regions tilt westward with altitude. Aerosols and PH$_3$ are both enriched at the equator but are not co-located with the NH$_3$ plumes. We find hemispheric asymmetries in the distribution of tropospheric PH$_3$, stratospheric hydrocarbons and the 2D wind field. Jupiter's stratosphere is notably warmer at northern mid-latitudes than in the south in both 2000 and 2014. [Abridged]

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