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P. Gaal

Publications and source records attributed to P. Gaal.

8 recordsLinked to original sources

Linear dichroic soft X-ray microscopy of ferroelectric stripe domains in epitaxial K$_\mathbf{0.6}$Na$_\mathbf{0.4}$NbO$_\mathbf{3}$

Functional properties of ferroelectric thin films are governed by domains that can be engineered by epitaxial strain. Soft X-ray microscopy can image domain structures with elemental and electronic sensitivity, but hitherto its application to strain-stabilized domains has been hindered by the absorption of soft X-rays in epitaxial substrates. Here, it is demonstrated how this limitation can be overcome by locally back-thinning the (110) TbScO$_3$ substrate of epitaxial K$_{0.6}$Na$_{0.4}$NbO$_3$ ferroelectric thin films to achieve soft X-ray transparency at the O K-edge around 530 eV. Strain-induced ferroelectric stripe domains with periods down to 44 nm were resolved by scanning transmission X-ray microscopy and coherent diffractive imaging by exploiting the X-ray linear dichroism of hybridized O 2p-Nb 4d states, providing sensitivity to in-plane polarization components under normal incidence. The results establish soft X-ray microscopy for nanoscale imaging of epitaxial ferroelectric domains structures and open perspectives for time-resolved studies thereof.

cond-mat.mtrl-sci

How does picosecond structural deformation of (Ba,Sr)TiO$_{3}$ relate to the pyroelectric effect?

The pyroelectric effect in ferroelectric thin films is typically composed of different contributions, which are difficult to disentangle. In addition, clamping to the substrate interface plays an important role. We studied epitaxial (Ba,Sr)TiO$_3$ thin films grown on NdScO$_3$ to see if time-resolved measurements can shed more light on the complex interaction. In particular, we compare standard measurements of the pyroelectric coefficient by temperature-dependent hysteresis loops to transient deformation measurements on picosecond timescales in the same material. The advantage of the time-resolved approach lies in its increased sensitivity in thin films compared to that of polarization hysteresis measurements. Whereas a fast thermal expansion of the ferroelectric thin film was observed after femtosecond laser excitation of the intermediate SrRuO$_3$ layer, heat diffusion simulations reveal frustration of the thermal expansion, which might be explained with the charge dynamics at the Schottky barrier formed at the SrRuO$_3$/(Ba,Sr)TiO$_3$. More studies are required to quantitatively assess the individual contributions to the pyroelectric coefficient of the materials used in our layer architecture.

cond-mat.mtrl-sci

Full spatiotemporal control of laser-excited periodic surface deformations

We demonstrate full control of acoustic and thermal periodic deformations at solid surfaces down to sub-nanosecond time scales and few-micrometer length scales via independent variation of the temporal and spatial phase of two optical transient grating (TG) excitations. For this purpose, we introduce an experimental setup that exerts control of the spatial phase of subsequent time-delayed TG excitations depending on their polarization state. Specific exemplary coherent control cases are discussed theoretically and corresponding experimental data are presented in which time-resolved x-ray reflectivity measures the spatiotemporal surface distortion of nanolayered heterostructures. Finally, we discuss examples where the application of our method may enable the control of functional material properties via tailored spatiotemporal strain fields.

physics.app-ph

Demonstration of a picosecond Bragg switch for hard x-rays in a synchrotron-based pump-probe experiment

We report a benchmark experiment that demonstrates shortening of hard x-ray pulses in a synchrotron-based optical pump - x-ray probe experiment. The pulse shortening device, a picosecond Bragg switch, reduces the temporal resolution of an incident x-ray pulse to 7.5 ps. We employ the Bragg switch to monitor propagating sound waves in nanometer-thin epitaxial films. With the experimental data we infer pulse duration, diffraction efficiency and switching contrast of the device. A detailed efficiency analysis shows, that the switch can deliver up to 1010 photons/sec in high-repetition rate synchrotron experiments.

cond-mat.mtrl-sci

Ultrafast X-ray Diffraction Thermometry Measures the Influence of Spin Excitations on the Heat Transport through nanolayers

We investigate the heat transport through a rare earth multilayer system composed of Yttrium (Y), Dysprosium (Dy) and Niobium (Nb) by ultrafast X-ray diffraction. This is an example of a complex heat flow problem on the nanoscale, where several different quasi-particles carry the heat. The Bragg peak positions of each layer represent layer-specific thermometers that measure the energy flow through the sample after excitation of the Y top-layer with fs-laser pulses. In an experiment-based analytic solution to the nonequilibrium heat transport problem, we derive the individual contributions of the spins and the coupled electron-lattice system to the heat conduction. The full characterization of the spatiotemporal energy flow at different starting temperatures reveals that the spin excitations of antiferromagnetic Dy speed up the heat transport into the Dy layer at low temperatures, whereas the heat transport through this layer and further into the Y and Nb layers underneath is slowed down. The experimental findings are compared to the solution of the heat equation using macroscopic temperature-dependent material parameters without separation of spin- and phonon contributions to the heat. We explain, why the simulated energy density matches our experiment-based derivation of the heat transport, although the simulated thermoelastic strain in this simulation is not even in qualitative agreement.

cond-mat.mtrl-sci

Localized excited charge carriers generate ultrafast inhomogeneous strain in the multiferroic BiFeO$_3$

We apply ultrafast X-ray diffraction with femtosecond temporal resolution to monitor the lattice dynamics in a thin film of multiferroic BiFeO$_3$ after above-bandgap photoexcitation. The sound-velocity limited evolution of the observed lattice strains indicates a quasi-instantaneous photoinduced stress which decays on a nanosecond time scale. This stress exhibits an inhomogeneous spatial profile evidenced by the broadening of the Bragg peak. These new data require substantial modification of existing models of photogenerated stresses in BiFeO$_3$: the relevant excited charge carriers must remain localized to be consistent with the data.

cond-mat.mtrl-sci

Thermoelastic study of nanolayered structures using time-resolved x-ray diffraction at high repetition rate

We investigate the thermoelastic response of a nanolayered sample composed of a metallic SrRuO3 (SRO) electrode sandwiched between a ferroelectric Pb(Zr0.2Ti0.8)O3 (PZT) film with negative thermal expansion and a SrTiO3 substrate. SRO is rapidly heated by fs-laser pulses with 208 kHz repetition rate. Diffraction of x-ray pulses derived from a synchrotron measures the transient out-of-plane lattice constant c of all three materials simultaneously from 120 ps to 5 mus with a relative accuracy up to Delta c/c = 10^-6. The in-plane propagation of sound is essential for understanding the delayed out of plane expansion.

cond-mat.mes-hall

Following Strain-Induced Mosaicity Changes of Ferroelectric Thin Films by Ultrafast Reciprocal Space Mapping

We investigate coherent phonon propagation in a thin film of ferroelectric PbZr0.2Ti0.8O3 (PZT) by ultrafast x-ray diffraction (UXRD) experiments, which are analyzed as time-resolved reciprocal space mapping (RSM) in order to observe the in- and out-of-plane structural dynamics simultaneously. The mosaic structure of the PZT leads to a coupling of the excited out-of-plane expansion to in-plane lattice dynamics on a picosecond timescale, which is not observed for out-of-plane compression.

cond-mat.mtrl-sci