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P. Gaspard

Publications and source records attributed to P. Gaspard.

33 records · Page 2Linked to original sources

Viscosity in the escape-rate formalism

We apply the escape-rate formalism to compute the shear viscosity in terms of the chaotic properties of the underlying microscopic dynamics. A first passage problem is set up for the escape of the Helfand moment associated with viscosity out of an interval delimited by absorbing boundaries. At the microscopic level of description, the absorbing boundaries generate a fractal repeller. The fractal dimensions of this repeller are directly related to the shear viscosity and the Lyapunov exponent, which allows us to compute its values. We apply this method to the Bunimovich-Spohn minimal model of viscosity which is composed of two hard disks in elastic collision on a torus. These values are in excellent agreement with the values obtained by other methods such as the Green-Kubo and Einstein-Helfand formulas.

cond-mat.stat-mech↗

Spectral Characterization of Anomalous Diffusion of a Periodic Piecewise Linear Intermittent Map

For a piecewise linear version of the periodic map with anomalous diffusion, the evolution of statistical averages of a class of observables with respect to piecewise constant initial densities is investigated and generalized eigenfunctions of the Frobenius-Perron operator are explicitly derived. The evolution of the averages is controlled by real eigenvalues as well as continuous spectra terminating at the unit circle. Appropriate scaling limits are shown to give a normal diffusion if the reduced map is in the stationary regime with normal fluctuations, a Lévy flight if the reduced map is in the stationary regime with Lévy-type fluctuations and a transport of ballistic type if the reduced map is in the non-stationary regime.

nlin.CD↗

Diffusive Lorentz gases and multibaker maps are compatible with irreversible thermodynamics

We show that simple diffusive systems, such as the Lorentz gas and multibaker maps are perfectly compatible with the laws of irreversible thermodynamics, despite the fact that the moving particles, or their equivalents, in these models do not interact with each other, and that the dynamics takes place in low-dimensional phase spaces. The interaction of moving particles with scatterers provides the dynamical mechanism responsible for an approach to equilibrium, under appropriate conditions. This analysis provides a refutation of the criticisms expressed recently by Cohen and Rondoni [Physica A 306 (2002) 117-128].

nlin.CD↗

The fractality of the relaxation modes in deterministic reaction-diffusion systems

In chaotic reaction-diffusion systems with two degrees of freedom, the modes governing the exponential relaxation to the thermodynamic equilibrium present a fractal structure which can be characterized by a Hausdorff dimension. For long wavelength modes, this dimension is related to the Lyapunov exponent and to a reactive diffusion coefficient. This relationship is tested numerically on a reactive multibaker model and on a two-dimensional periodic reactive Lorentz gas. The agreement with the theory is excellent.

cond-mat.stat-mech↗

Entropy production of diffusion in spatially periodic deterministic systems

This paper presents an {\it ab initio} derivation of the expression given by irreversible thermodynamics for the rate of entropy production for different classes of diffusive processes. The first class are Lorentz gases, where non-interacting particles move on a spatially periodic lattice, and collide elastically with fixed scatterers. The second class are periodic systems where $N$ particles interact with each other, and one of them is a tracer particle which diffuses among the cells of the lattice. We assume that, in either case, the dynamics of the system is deterministic and hyperbolic, with positive Lyapunov exponents. This work extends methods originally developed for a chaotic two-dimensional model of diffusion, the multi-baker map, to higher dimensional, continuous time dynamical systems appropriate for systems with one or more moving particles. Here we express the rate of entropy production in terms of hydrodynamic measures that are determined by the fractal properties of microscopic hydrodynamic modes that describe the slowest decay of the system to an equilibrium state.

nlin.CD↗

On the level spacing distribution in quantum graphs

We derive a formula for the level spacing probability distribution in quantum graphs. We apply it to simple examples and we discuss its relation with previous work and its possible application in more general cases. Moreover, we derive an exact and explicit formula for the level spacing distribution of integrable quantum graphs.

quant-ph↗

Classical dynamics on graphs

We consider the classical evolution of a particle on a graph by using a time-continuous Frobenius-Perron operator which generalizes previous propositions. In this way, the relaxation rates as well as the chaotic properties can be defined for the time-continuous classical dynamics on graphs. These properties are given as the zeros of some periodic-orbit zeta functions. We consider in detail the case of infinite periodic graphs where the particle undergoes a diffusion process. The infinite spatial extension is taken into account by Fourier transforms which decompose the observables and probability densities into sectors corresponding to different values of the wave number. The hydrodynamic modes of diffusion are studied by an eigenvalue problem of a Frobenius-Perron operator corresponding to a given sector. The diffusion coefficient is obtained from the hydrodynamic modes of diffusion and has the Green-Kubo form. Moreover, we study finite but large open graphs which converge to the infinite periodic graph when their size goes to infinity. The lifetime of the particle on the open graph is shown to correspond to the lifetime of a system which undergoes a diffusion process before it escapes.

nlin.CD↗

The Fractality of the Hydrodynamic Modes of Diffusion

Transport by normal diffusion can be decomposed into the so-called hydrodynamic modes which relax exponentially toward the equilibrium state. In chaotic systems with two degrees of freedom, the fine scale structure of these hydrodynamic modes is singular and fractal. We characterize them by their Hausdorff dimension which is given in terms of Ruelle's topological pressure. For long-wavelength modes, we derive a striking relation between the Hausdorff dimension, the diffusion coefficient, and the positive Lyapunov exponent of the system. This relation is tested numerically on two chaotic systems exhibiting diffusion, both periodic Lorentz gases, one with hard repulsive forces, the other with attractive, Yukawa forces. The agreement of the data with the theory is excellent.

nlin.CD↗

Entropy Production, Fractals, and Relaxation to Equilibrium

The theory of entropy production in nonequilibrium, Hamiltonian systems, previously described for steady states using partitions of phase space, is here extended to time dependent systems relaxing to equilibrium. We illustrate the main ideas by using a simple multibaker model, with some nonequilibrium initial state, and we study its progress toward equilibrium. The central results are (i) the entropy production is governed by an underlying, exponentially decaying fractal structure in phase space, (ii) the rate of entropy production is largely independent of the scale of resolution used in the partitions, and (iii) the rate of entropy production is in agreement with the predictions of nonequilibrium thermodynamics.

nlin.CD↗

Fractal Dimensions of the Hydrodynamic Modes of Diffusion

We consider the time-dependent statistical distributions of diffusive processes in relaxation to a stationary state for simple, two dimensional chaotic models based upon random walks on a line. We show that the cumulative functions of the hydrodynamic modes of diffusion form fractal curves in the complex plane, with a Hausdorff dimension larger than one. In the limit of vanishing wavenumber, we derive a simple expression of the diffusion coefficient in terms of this Hausdorff dimension and the positive Lyapunov exponent of the chaotic model.

nlin.CD↗

Chaotic and fractal properties of deterministic diffusion-reaction processes

We study the consequences of deterministic chaos for diffusion-controlled reaction. As an example, we analyze a diffusive-reactive deterministic multibaker and a parameter-dependent variation of it. We construct the diffusive and the reactive modes of the models as eigenstates of the Frobenius-Perron operator. The associated eigenvalues provide the dispersion relations of diffusion and reaction and, hence, they determine the reaction rate. For the simplest model we show explicitly that the reaction rate behaves as phenomenologically expected for one-dimensional diffusion-controlled reaction. Under parametric variation, we find that both the diffusion coefficient and the reaction rate have fractal-like dependences on the system parameter.

chao-dyn↗

Scaled Spectroscopy of 1Se and 1Po Highly Excited States of Helium

In this paper, we examine the properties of the 1Se and 1Po states of helium, combining perimetric coordinates and complex rotation methods. We compute Fourier transforms of quantities of physical interest, among them the average of the operator cos(theta_12), which measures the correlation between the two electrons. Graphs obtained for both 1Se and 1Po states show peaks at action of classical periodic orbits, either "frozen planet" orbit or asymmetric stretch orbits. This observation legitimates the semiclassical quantization of helium with those orbits only, not just for S states but also for P states, which is a new result. To emphasize the similarity between the S and P states we show wavefunctions of 1Po states, presenting the same structure as 1Se states, namely the "frozen planet" and asymmetric stretch configurations.

chao-dyn↗

Chaotic Scattering Theory, Thermodynamic Formalism, and Transport Coefficients

The foundations of the chaotic scattering theory for transport and reaction-rate coefficients for classical many-body systems are considered here in some detail. The thermodynamic formalism of Sinai, Bowen, and Ruelle is employed to obtain an expression for the escape-rate for a phase space trajectory to leave a finite open region of phase space for the first time. This expression relates the escape rate to the difference between the sum of the positive Lyapunov exponents and the K-S entropy for the fractal set of trajectories which are trapped forever in the open region. This result is well known for systems of a few degrees of freedom and is here extended to systems of many degrees of freedom. The formalism is applied to smooth hyperbolic systems, to cellular-automata lattice gases, and to hard sphere sytems. In the latter case, the goemetric constructions of Sinai {\it et al} for billiard systems are used to describe the relevant chaotic scattering phenomena. Some applications of this formalism to non-hyperbolic systems are also discussed.

chao-dyn↗

Chaotic Scattering Theory of Transport and Reaction-Rate Coefficients

The chaotic scattering theory is here extended to obtain escape-rate expressions for the transport coefficients appropriate for a simple classical fluid, or for a chemically reacting system. This theory allows various transport coefficients such as the coefficients of viscosity, thermal conductivity, etc., to be expressed in terms of the positive Lyapunov exponents and Kolmogorov-Sinai entropy of a set of phase space trajectories that take place on an appropriate fractal repeller. This work generalizes the previous results of Gaspard and Nicolis for the coefficient of diffusion of a particle moving in a fixed array of scatterers.

chao-dyn↗