arXiv subjects

P. J. van Zwol

Publications and source records attributed to P. J. van Zwol.

At least 19 recordsLinked to original sources

arXiv2015

Emissivity of freestanding membranes with thin metal coatings

Freestanding silicon nitride membranes with thicknesses down to a few tens of nanometers find use as TEM windows or soft X-ray spectral purity filters. As the thickness of a membrane decreases, emissivity vanishes, which limits radiative heat emission and resistance to heat loads. We show that thin metal layers with thicknesses in the order of 1 nm enhance the emissivity of thin membranes by two to three orders of magnitude close to the theoretical limit of 0.5. This considerably increases thermal load capacity of membranes in vacuum environments. Our experimental results are in line with classical theory in which we adapt thickness dependent scattering terms in the Drude and Lorentz oscillators.

cond-mat.mes-hall↗

arXiv2012

Experimental observation of nanoscale radiative heat flow due to surface plasmons in graphene and doped silicon

Owing to its two dimensional electronic structure, graphene exhibits many unique properties. One of them is a wave vector and temperature dependent plasmon in the infrared range. Theory predicts that due to these plasmons, graphene can be used as a universal material to enhance nanoscale radiative heat exchange for any dielectric substrate. Here we report on radiative heat transfer experiments between SiC and a SiO2 sphere which have non matching phonon polariton frequencies, and thus only weakly exchange heat in near field. We observed that the heat flux contribution of graphene epitaxially grown on SiC dominates at short distances. The influence of plasmons on radiative heat transfer is further supported with measurements for doped silicon. These results highlight graphenes strong potential in photonic nearfield and energy conversion devices.

cond-mat.mes-hall↗

arXiv2012

Tuning near field radiative heat flux through surface excitations with a metal insulator transition

The control of heat flow is a formidable challenge due to lack of good thermal insulators. Promising new oppor-tunities for heat flow control were recently theoretically discovered for radiative heat flow in near field, where large heat flow contrasts may be achieved by tuning electronic excitations on surfaces. Here we show experi-mentally that the phase transition of VO2 entails a change of surface polariton states that significantly affects radiative heat transfer in near field. In all cases the Derjaguin approximation correctly predicted radiative heat transfer in near field, but it underestimated the farfield limit. Our results indicate that heat flow contrasts can be realized in near field that can be larger than those obtained in farfield.

cond-mat.mes-hall↗

arXiv2012

Plasmons enhance near-field radiative heat transfer for graphene-covered dielectrics

It is shown that a graphene layer on top of a dielectric slab can dramatically influence the ability of this dielectric for radiative heat exchange. Effect of graphene is related to thermally excited plasmons. Frequency of these resonances lies in the terahertz region and can be tuned by varying the Fermi level through doping or gating. Heat transfer between two dielectrics covered with graphene can be larger than that between best known materials and even much larger at low temperatures. Moreover, high heat transfer can be significantly modulated by electrical means that opens up new possibilities for very fast manipulations with the heat flux.

cond-mat.mes-hall↗

arXiv2011

Fast heat flux modulation at the nanoscale

We introduce a new concept for electrically controlled heat flux modulation. A flux contrast larger than 10 dB is expected with switching time on the order of tens of nanoseconds. Heat flux modulation is based on the interplay between radiative heat transfer at the nanoscale and phase change materials. Such large contrasts are not obtainable in solids, or in far field. As such this opens up new horizons for temperature modulation and actuation at the nanoscale.

cond-mat.mes-hall↗

arXiv2011

Characterization of optical properties and surface roughness profiles: The Casimir force between real materials

The Lifshitz theory provides a method to calculate the Casimir force between two flat plates if the frequency dependent dielectric function of the plates is known. In reality any plate is rough and its optical properties are known only to some degree. For high precision experiments the plates must be carefully characterized otherwise the experimental result cannot be compared with the theory or with other experiments. In this chapter we explain why optical properties of interacting materials are important for the Casimir force, how they can be measured, and how one can calculate the force using these properties. The surface roughness can be characterized, for example, with the atomic force microscope images. We introduce the main characteristics of a rough surface that can be extracted from these images, and explain how one can use them to calculate the roughness correction to the force. At small separations this correction becomes large as our experiments show. Finally we discuss the distance upon contact separating two rough surfaces, and explain the importance of this parameter for determination of the absolute separation between bodies.}

cond-mat.other↗

arXiv2010

Switching Casimir forces with Phase Change Materials

We demonstrate here a controllable variation in the Casimir force. Changes in the force of up to 20% at separations of ~100 nm between Au and AgInSbTe (AIST) surfaces were achieved upon crystallization of an amorphous sample of AIST. This material is well known for its structural transformation, which produces a significant change in the optical properties and is exploited in optical data storage systems. The finding paves the way to the control of forces in nanosystems, such as micro- or nanoswitches by stimulating the phase change transition via localized heat sources.

cond-mat.mtrl-sci↗

arXiv2010

Repulsive Casimir forces between solid materials with high refractive index intervening liquids

In order to explore repulsive Casimir/van der Waals forces between solid materials with liquid as the intervening medium, we analyze dielectric data for a wide range of materials as for example PTFE, polystyrene, silica and more than twenty liquids. Although significant variation in the dielectric data from different sources exist, we provide a scheme based on measured static dielectric constants, refractive indices, and applying Kramers Kronig (KK) consistency to dielectric data to create accurate dielectric functions at imaginary frequencies. The latter is necessary for more accurate force calculations via the Lifshitz theory allowing reliable predictions of repulsive Casimir forces.

cond-mat.mtrl-sci↗

arXiv2009

The distance upon contact: Determination from roughness profile

The point at which two random rough surfaces make contact takes place at the contact of the highest asperities. The distance upon contact d_0 in the limit of zero load has crucial importance for determination of dispersive forces. Using gold films as an example we demonstrate that for two parallel plates d_0 is a function of the nominal size of the contact area L and give a simple expression for d_0(L) via the surface roughness characteristics. In the case of a sphere of fixed radius R and a plate the scale dependence manifests itself as an additional uncertainty δd(L) in the separation, where the scale L is related with the separation d via the effective area of interaction L^2\simπRd. This uncertainty depends on the roughness of interacting bodies and disappears in the limit L\to \infty.

cond-mat.mes-hall↗

arXiv2009

Influence of water adsorbed on gold on van der Waals/Casimir forces

In this paper we investigate the influence of ultra thin water layer (1-1.5 nm) on the van der Waals/Casimir force between gold surfaces. Adsorbed water is inevitably present on gold surfaces at ambient conditions as jump-up-to contact during adhesion experiments demonstrate. Calculations based on the Lifshitz theory give very good agreement with the experiment in absence of any water layer for surface separations d>10 nm. However, a layer of thickness h<1.5 nm is allowed by the error margin in force measurements. At shorter separations, d<10 nm, the water layer can have a strong influence as calculations show for flat surfaces. Nonetheless, in reality the influence of surface roughness must also be considered, and it can overshadow any water layer influence at separations comparable to the total sphere-plate rms roughness w_{shp}+w.

cond-mat.mes-hall↗

arXiv2009

The influence of dielectric properties on van der Waals/Casimir forces in solid-liquid systems

In this article we present calculations of van der Waals/Casimir forces, described by Lifshitz theory, for the solid-liquid-solid system using measured dielectric functions of all involved materials for the wavelength range from millimeters down to subnanometers. It is shown that even if the dielectric function is known over all relevant frequency ranges, the scatter in the dielectric data, can lead to very large scatter in the calculated van der Waals/Casimir forces. Especially when the liquid dielectric function becomes comparable in magnitude to the dielectric function of one of the interacting solids, the associated variation in the force can be up to a factor of two for plate-plate separations 5-500 nm. This corresponds to an uncertainty up to 100% in the theory prediction for a specific system. As a result accuracy testing of the Lifshitz theory under these circumstances is rather questionable. Finally we discuss predictions of Lifshitz theory regarding multiple repulsive-attractive transitions with separation distance, as well as nontrivial scaling of the van der Waals/Casimir force with distance.

cond-mat.soft↗

arXiv2009

Weak dispersive forces between glass-gold macroscopic surfaces in alcohols

In this work we concentrate on an experimental validation of the Lifshitz theory for van der Waals and Casimir forces in gold-alcohol-glass systems. From this theory weak dispersive forces are predicted when the dielectric properties of the intervening medium become comparable to one of the interacting surfaces. Using inverse colloid probe atomic force microscopy dispersive forces were measured occasionally and under controlled conditions by addition of salt to screen the electrostatic double layer force if present. The dispersive force was found to be attractive, and an order of magnitude weaker than that in air. Although the theoretical description of the forces becomes less precise for these systems even with full knowledge of the dielectric properties, we find still our results in reasonable agreement with Lifshitz theory.

cond-mat.soft↗

arXiv2008

Transition from Casimir to van der Waals force between macroscopic bodies

The transition of van der Waals to Casimir forces between macroscopic gold surfaces is investigated by Atomic Force Microscopy in the plane-sphere geometry. It was found that the transition appears to take place at separations about 10 % the plasma wavelength for evaporated gold surfaces, which compares to theoretical predictions by incorporation of experimental optical data and roughness corrections. Moreover, the force data allow estimation of the Hamaker constant AH in the van der Waals regime, which is in good agreement with the Lifshitz theory predictions (even if roughness corrections are taken into account) and former surface force apparatus measurements.

cond-mat.mtrl-sci↗

arXiv2008

Influence of roughness on capillary forces between hydrophilic surfaces

Capillary forces have been measured by Atomic Force Microscopy in the plate-sphere setup between gold, borosilicate glass, GeSbTe, titanium, and UV irradiated amorphous titaniumdioxide surfaces. The force measurements were performed as a function contact time and surface roughness in the range 0.2 - 15 nm rms, and relative humidity ranging between 2 and 40 %. It is found that even for the lowest attainable relative humidity 2 % very large capillary forces are still present. The latter suggests the persistence of a nanometers thick adsorbed water layer that acts as a capillary bridge between contacting surfaces. Moreover, we found a significantly different scaling behavior of the force with rms roughness for materials with different hydrophilicity as compared to gold-gold surfaces.

cond-mat.mtrl-sci↗

arXiv2008

Optical properties of gold films and the Casimir force

Precise optical properties of metals are very important for accurate prediction of the Casimir force acting between two metallic plates. Therefore we measured ellipsometrically the optical responses of Au films in a wide range of wavelengths from 0.14 mum to 33 mum. The films at various thickness were deposited at different conditions on silicon or mica substrates. Considerable variation of the frequency dependent dielectric function from sample to sample was found. Detailed analysis of the dielectric functions was performed to check the Kramers-Kronig consistency, and extract the Drude parameters of the films. It was found that the plasma frequency varies in the range from 6.8 eV to 8.4 eV. It is suggested that this variation is related with the film density. X-ray reflectivity measurements support qualitatively this conclusion. The Casimir force is evaluated for the dielectric functions corresponding to our samples, and for that typically used in the precise prediction of the force. The force for our films was found to be 5-14% smaller at a distance of 100 nm between the plates. Noise in the optical data is responsible for the force variation within 1%. It is concluded that prediction of the Casimir force between metals with a precision better than 10% must be based on the material optical response measured from visible to mid-infrared range.

cond-mat.other↗

arXiv2007

Measurement of dispersive forces between evaporated metal surfaces in the range below 100 nm

In this work we describe dispersion force (van der Waals/Casimir) measurements between gold surfaces at separations as close as 12 nm. The force measurements were performed in the plane-sphere configuration by Atomic Force Microscopy at distances ranging between 12 and 200 nm. This was accomplished by using evaporated smooth metal surfaces for both sphere and plane, and stiff cantilevers to minimize jump-to-contact problems. Finally, it is shown that below separations of 100 nm experiment and theory are found in agreement within 10 % by including in the theory the measured optical properties of gold and contribution from surface roughness.

cond-mat.mtrl-sci↗

arXiv2007

Influence of random roughness on the Casimir force at small separations

The influence of random surface roughness of Au films on the Casimir force is explored with atomic force microscopy in the plate-sphere geometry. The experimental results are compared to theoretical predictions for separations ranging between 20 and 200 nm. The optical response and roughness of the Au films were measured and used as input in theoretical predictions. It is found that at separations below 100 nm, the roughness effect is manifested through a strong deviation from the normal scaling of the force with separation distance. Moreover, deviations from theoretical predictions based on perturbation theory can be larger than 100%.

cond-mat.other↗

arXiv2007

Roughness corrections to the Casimir force: The importance of local surface slope

This paper concentrates on a study where finite conductivity corrections are included in the theoretical description of the effects of roughness on the Casimir force. The roughness data were taken from gold films evaporated onto Silicon and polysterene spheres. We conclude that for a detailed comparison with experimental data, i.e. at the level of at least 5 % at short separations below 200 nm, the lateral dimensions of roughness for real films should be included in the theoretical considerations. Moreover, if the RMS roughness is considerable, high local surface slopes are shown to have a significant effect on the Casimir force.

cond-mat.other↗