arXiv subjects

P. K. Biswas

Publications and source records attributed to P. K. Biswas.

At least 19 recordsLinked to original sources

arXiv2025

Time reversal symmetry breaking and s-wave superconductivity in CaPd2Ge2: A $μ$SR study

${\rm CaPd_2Ge_2}$ which crystallizes in ${\rm ThCr_2Si_2}$-type body-centered tetragonal structure exhibits superconductivity below the critical temperature $T_{\rm c} = 1.69$~K\@. We have investigated the superconducting gap structure and time reversal symmetry of the ground state in ${\rm CaPd_2Ge_2}$ by means of muon spin relaxation and rotation ($μ$SR) measurements. Our analysis of $μ$SR data collected in transverse magnetic field reveals BCS superconductivity with a single-band $s$-wave singlet pairing and an isotropic energy gap having the value $2Δ(0)/k_{\rm B}T_{\rm c} = 3.50(1)$. Further, an increased relaxation rate in zero field $μ$SR asymmetry spectra below $T_{\rm c} $ provides evidence for the presence of a spontaneous magnetic field in the superconducting state revealing that the time-reversal symmetry is broken in ${\rm CaPd_2Ge_2}$.

cond-mat.supr-con↗

arXiv2024

Time-Reversal Symmetry Breaking in Re-Based Kagome Lattice Superconductor

We investigated the Re-based kagome superconductor Re$_2$Zr through various measurements, including resistivity, magnetization, specific heat, and muon spin rotation and relaxation spectroscopy. These results suggest that Re$_2$Zr is a moderately coupled potential two-gap superconductor. Zero-field muon relaxation data indicate the possible presence of a time-reversal symmetry-breaking state in the superconducting ground state. Our investigation identifies Re$_{2}$Zr as a new unconventional superconductor with a potential complex order parameter that warrants considerable experimental and theoretical interest.

cond-mat.supr-con↗

arXiv2024

Exploring Superconductivity in Ba$_{3}$Ir$_{4}$Ge$_{16}$: Experimental and Theoretical Insights

We explore both experimental and theoretical aspects of the superconducting properties in the distinctive layered caged compound, Ba$_{3}$Ir$_{4}$Ge$_{16}$. Our approach integrates muon spin rotation and relaxation ($μ$SR) measurements with magnetization and heat capacity experiments, accompanied by first-principle calculations. The compound's bulk superconductivity is unequivocally established through DC magnetization measurements, revealing a critical temperature ($T_\mathrm{C}$) of 5.7 K. A noteworthy characteristic observed in the low-temperature superfluid density is its saturating behavior, aligning with the features typical of conventional Bardeen-Cooper-Schrieffer (BCS) superconductors. The assessment of moderate electron-phonon coupling superconductivity is conducted through transverse field $μ$SR measurements, yielding a superconducting gap to $T_\mathrm{C}$ ratio ($2Δ(0)/k_\mathrm{B}T_\mathrm{C}$) of 4.04, a value corroborated by heat capacity measurements. Crucially, zero field $μ$SR measurements dismiss the possibility of any spontaneous magnetic field emergence below $T_\mathrm{C}$, highlighting the preservation of time-reversal symmetry. Our experimental results are reinforced by first-principles density functional calculations, underscoring the intricate interplay between crystal structure and superconducting order parameter symmetry in polyhedral caged compounds. This comprehensive investigation enhances our understanding of the nuanced relationship between crystal structure and superconductivity in such unique compounds.

cond-mat.supr-con↗

arXiv2023

Repulsive Tomonaga-Luttinger Liquid in Quasi-one-dimensional Alternating Spin-$1/2$ Antiferromagnet NaVOPO$_4$

We probe the magnetic field-induced Tomonaga-Luttinger liquid (TLL) state in the bond-alternating spin-$1/2$ antiferromagnetic (AFM) chain compound NaVOPO$_4$ using thermodynamic as well as local $μ$SR and $^{31}$P NMR probes down to milli-K temperatures in magnetic fields up to 14~T. The $μ$SR and NMR relaxation rates in the gapless TLL regime decay slowly following characteristic power-law behaviour, enabling us to directly determine the interaction parameter $K$ as a function of the magnetic field. These estimates are cross-checked using magnetization and specific heat data. The field-dependent $K$ lies in the range of $0.4 < K < 1$ and indicates repulsive nature of interactions between the spinless fermions, in line with the theoretical predictions. This renders NaVOPO$_4$ the first experimental realization of TLL with repulsive fermionic interactions in hitherto studied $S=1/2$ bond-alternating AFM-AFM chain compounds.

cond-mat.str-el↗

arXiv2023

ZrOsSi: A $Z_2$ topological metal with a superconducting ground state

The silicide superconductors (Ta, Nb, Zr)OsSi are among the best candidate materials for investigating the interplay of topological order and superconductivity. Here, we investigate in detail the normal-state topological properties of (Ta, Nb, Zr)OsSi, focusing on ZrOsSi, by employing a combination of $^{29}$Si nuclear magnetic resonance (NMR) measurements and first-principles band-structure calculations. We show that, while (Ta, Nb)OsSi behave as almost ideal metals, characterized by weak electronic correlations and a relatively low density of states, the replacement of Ta (or Nb) with Zr expands the crystal lattice and shifts ZrOsSi towards an insulator. Our ab initio calculations indicate that ZrOsSi is a $Z_2$ topological metal with clear surface Dirac cones and properties similar to a doped strong topological insulator.

cond-mat.supr-con↗

arXiv2023

Superconducting Gap Structure of Filled Skutterudite LaOs$_4$As$_{12}$ Compound through $μ$SR Investigations

Filled skutterudite compounds have gained attention recently as an innovative platforms for studying intriguing low-temperature superconducting properties. Regarding the symmetry of the superconducting gap, contradicting findings from several experiments have been made for LaRu$_{4}$As$_{12}$ and its isoelectronic counterpart, LaOs$_{4}$As$_{12}$. In this vein, we report comprehensive bulk and microscopic results on LaOs$_{4}$As$_{12}$ utilizing specific heat analysis and muon-spin rotation/relaxation ($μ$SR) measurements. Bulk superconductivity with $T_C$ = 3.2 K was confirmed by heat capacity. The superconducting ground state of the filled-skutterudite LaOs$_{4}$As$_{12}$ compound is found to have two key characteristics: superfluid density exhibits saturation type behavior at low temperature, which points to a fully gapped superconductivity with gap value of $2Δ/k_BT_C$ = 3.26; additionally, the superconducting state does not show any sign of spontaneous magnetic field, supporting the preservation of time-reversal symmetry. These results open the door for the development of La-based skutterudites as special probes for examining the interplay of single- and multiband superconductivity in classical electron-phonon systems.

cond-mat.supr-con↗

arXiv2023

Quantum Griffiths singularity in the stoichiometric heavy-fermion system CeRh$_4$Al$_{15}$

We present a detailed investigation of the stoichiometric CeRh$_4$Al$_{15}$ single crystal compound using the temperature dependence of the heat capacity [$C_{\text{P}}$($T$)], electrical resistivity [$ρ$($T$)], magnetic susceptibility [$χ$($T$)], and magnetization [$M$($H$)] measurements for a magnetic field ($H$) applied in the basal plane and along the $c$-axis. The low temperature power-law behavior of $C$/$T$ $\propto$ $χ$ $\propto$ $T^{-1+α}$, the isotherm magnetization, $M \sim H^α$ with the exponent $α$ = 0.45 - 0.55, and the $T$-linear resistivity $Δρ$ $\sim$ $T^ε$ with $ε\sim$ 1 are found to be consistent with the formation of quantum Griffiths singularities in the non-Fermi-liquid (NFL) regime. We further investigated the spin dynamics of a polycrystalline sample of CeRh$_4$Al$_{15}$, using zero-field (ZF) and longitudinal-field (LF) muon spin relaxation ($μ$SR) measurements. ZF-$μ$SR measurements do not reveal any sign of long-range magnetic ordering down to 70~mK. The electronic relaxation rate ($λ$) below 0.5~K increases rapidly and shows a thermal activation-like characteristic [$T$log($λ$)$\sim$ $T$] over the entire measured temperature range between 70~mK to 4~K, indicating the presence of low energy spin fluctuations in CeRh$_4$Al$_{15}$. LF-$μ$SR measurements show a time-field ($t/H^η$) scaling of the $μ$SR asymmetry indicating a quantum critical behavior of this compound. Furthermore, inelastic neutron scattering study on the polycrystalline sample reveals two crystal field excitations near 19 and 33~meV. These features collectively provide strong evidence of NFL behavior in CeRh$_4$Al$_{15}$ due to the formation of Griffiths phase close to a $T$ $\rightarrow$ 0~K quantum critical point.

cond-mat.str-el↗

arXiv2023

Nodeless superconductivity in noncentrosymmetric LaRhSn

The superconducting order parameter of the noncentrosymmetric superconductor LaRhSn is investigated by means of low temperature measurements of the specific heat, muon-spin relaxation/rotation ($μ$SR) and the tunnel-diode oscillator (TDO) based method. The specific heat and magnetic penetration depth [$λ(T)$] show an exponentially activated temperature dependence, demonstrating fully gapped superconductivity in LaRhSn. The temperature dependence of $λ^{-2}(T)$ deduced from the TDO based method and $μ$SR show nearly identical behavior, which can be well described by a single-gap $s$-wave model, with a zero temperature gap value of $Δ(0)=1.77(4)k_BT_c$. The zero-field $μ$SR spectra do not show detectable changes upon cooling below $T_c$, and therefore there is no evidence for time-reversal-symmetry breaking in the superconducting state.

cond-mat.supr-con↗

arXiv2022

Nodeless time-reversal symmetry breaking in the centrosymmetric superconductor Sc$_5$Co$_4$Si$_{10}$ probed by muon-spin spectroscopy

We investigate the superconducting properties of Sc$_{5}$Co$_{4}$Si$_{10}$ using low-temperature resistivity, magnetization, heat capacity, and muon-spin rotation and relaxation ($μ$SR) measurements. We find that Sc$_{5}$Co$_{4}$Si$_{10}$ {exhibits type-II} superconductivity with a superconducting transition temperature $T_\mathrm{C}= 3.5 (1)$\,K. The temperature dependence of the superfluid density obtained from transverse-field $μ$SR spectra is best modeled using an isotropic Bardeen-Cooper-Schrieffer type $s$-wave gap symmetry with $2Δ/k_\mathrm{B}T_\mathrm{C} = 2.84(2)$. However, the zero-field muon-spin relaxation asymmetry reveals the appearance of a spontaneous magnetic field below $T_\mathrm{C}$, indicating that time-reversal symmetry (TRS) is broken in the superconducting state. Although this behavior is commonly associated with non-unitary or mixed singlet-triplet pairing, our group-theoretical analysis of the Ginzburg-Landau free energy alongside density functional theory calculations indicates that unconventional mechanisms are pretty unlikely. Therefore, we have hypothesized that TRS breaking may occur via a conventional electron-phonon process.

cond-mat.supr-con↗

arXiv2022

Quantum muon diffusion and the preservation of time-reversal symmetry in the superconducting state of type-I rhenium

Elemental rhenium exhibiting type-II superconductivity has been previously reported to break time-reversal symmetry in the superconducting state. We have investigated an arc-melted sample of rhenium exhibiting type-I superconductivity. Low temperature zero-field muon-spin relaxation measurements indicate that time-reversal symmetry is preserved in the superconducting state. Muon diffusion is observed, which is due to quantum mechanical tunneling between interstitial sites. The normal state behavior is characterized by the conduction electrons screening the muons and thermal broadening, and is typical for a metal. Energy asymmetries between muon trapping sites and the superconducting energy gap also characterize the superconducting state behavior.

cond-mat.supr-con↗

arXiv2022

Time-Reversal Symmetry Breaking Superconductivity in Three-Dimensional Dirac Semimetallic Silicides

Superconductors with broken time-reversal symmetry represent arguably one of the most promising venues for realizing highly sought-after topological superconductivity that is vital to fault-tolerant quantum computation. Here, by using extensive muon-spin relaxation and rotation measurements, we report that the isostructural silicide superconductors (Ta, Nb)OsSi spontaneously break time-reversal symmetry at the superconducting transition while surprisingly showing a fully-gapped superconductivity characteristic of conventional superconductors. The first-principles calculations show that (Ta, Nb)OsSi are three-dimensional Dirac semimetals protected by nonsymmorphic symmetries. Taking advantage of the exceptional low symmetry crystal structure of these materials, we have performed detailed theoretical calculations to establish that the superconducting ground state for both (Ta, Nb)OsSi is most likely a nonunitary triplet state.

cond-mat.supr-con↗

arXiv2022

Time-reversal symmetry breaking in frustrated superconductor Re$_2$Hf

Geometrical frustration leads to novel quantum phenomena such as the spin-liquid phase in triangular and Kagomé lattices. Intra-band and inter-band Fermi surface (FS) nesting can drive unique superconducting (SC) ground states with $d$-wave and $s^{\pm}$ pairing symmetries, respectively, according to the criterion that the SC gap changes sign across the nesting wavevector. For an odd number of FSs, when multiple inter-band nesting is of comparable strength, the sign-reversal criterion between different FS sheets can leads to frustration, which promotes novel SC order parameters. Here we report the experimental observation of a time-reversal symmetry breaking pairing state in Re$_2$Hf resulting from FS nesting frustration. Furthermore, our electronic specific heat and transverse-field $μ$SR experiments suggest a fully gaped pairing symmetry. The first-principle electronic structure calculation reveals multiple Fermi surface sheets with comparable inter-band nesting strength. Implementing the {\it ab-initio} band structure, we compute spin-fluctuation mediated SC pairing symmetry which reveals a $s+is'$-pairing state - consistent with experimental observations. Our investigation demonstrates a novel SC state which provides a putative setting for both applied and fundamental study.

cond-mat.supr-con↗

arXiv2021

Non-Fermi liquid behavior in a mixed valent metallic pyrochlore iridate Pb$_2$Ir$_2$O$_{7-δ}$

Non-Fermi liquid behavior in some fermionic systems have attracted significant interest in last few decades. Certain pyrochlore iridates with stronger spin-orbit coupling strength have recently been added to the list. Here, we provide evidence of such a non-Fermi liquid ground state in another mixed valent metallic pyrochlore iridate Pb$_2$Ir$_2$O$_{7-δ}$, through the combined investigation of electronic, magnetic and thermodynamic properties as a function of temperature ($T$) and applied magnetic field ($H$). Resistivity measurement showed a linear temperature dependence down to 15~K below which it shows $ρ\sim T^{3/2}$ dependence while magnetic susceptibility diverges as $χ$(T) $\sim$ $T^{-α}$ ($α< 1$) below 10~K. While a strong negative $Θ_{CW}$ has been observed from Curie-Weiss fitting, absence of any long range order down to 80~mK only indicates presence of strong inherent geometric frustration in the system. Heat capacity data showed $C_p$ $\sim$ $T\ln(T_0/T)$ + $βT^3$ dependence below 15~K down to 1.8~K. More importantly spin-orbit coupling strength by x-ray absorption spectroscopy was found to be weaker in Pb$_2$Ir$_2$O$_{7-δ}$ compared to other pyrochlore iridates. In absence of any large moment rare earth magnetic ion, Pb$_2$Ir$_2$O$_{7-δ}$ presents a rare example of an irirdate system showing non-Fermi liquid behaviour due to disordered distribution of Ir$^{4+}$ and Ir$^{5+}$ having markedly different strengths of spin-orbit coupling which might offer a prescription for achieving new non-Fermi liquid systems.

cond-mat.str-el↗

arXiv2021

Muon spin rotation and relaxation study on topological noncentrosymmetric superconductor PbTaSe$_2$

Topological superconductivity is an exotic phenomenon due to the symmetry-protected topological surface state, in which a quantum system has an energy gap in the bulk but supports gapless excitations confined to its boundary. Symmetries including central and time-reversal (TRS), along with their relations with topology, are crucial for topological superconductivity. We report muon spin relaxation/rotation ($μ$SR) experiments on a topological noncentrosymmetric superconductor PbTaSe$_2$ to study its TRS and gap symmetry. Zero-field $μ$SR experiments indicate the absence of internal magnetic field in the superconducting state, consistent with previous $μ$SR results. Furthermore, transverse-field $μ$SR measurements reveals that the superconducting gap of PbTaSe$_2$ is an isotropic three-dimensional fully-gapped single-band. The fully-gapped results can help understand the pairing mechanism and further classify the topological superconductivity in this system.

cond-mat.supr-con↗

arXiv2021

Crystal Electic Field and Possible Coupling with Phonon in Kondo lattice CeCuGa3

We investigate the magnetic and crystal electric field (CEF) states of the Kondo lattice system CeCuGa3 by muon spin relaxation (muSR), neutron diffraction, and inelastic neutron scattering (INS) measurements. A noncentrosymmetric BaNiSn3-type tetragonal crystal structure (space group I4mm) is inferred from x-ray as well as from neutron powder diffraction. The low-temperature magnetic susceptibility and heat capacity data show an anomaly near 2.3 - 2.5~K associated with long range magnetic ordering, which is further confirmed by muSR and neutron diffraction data. The neutron powder diffraction collected at 1.7 K shows the presence of magnetic Bragg peaks indexed by an incommensurate magnetic propagation vector k = (0.148, 0.148, 0) and the magnetic structure is best described by a longitudinal spin density wave with ordered moments lying in ab-plane. An analysis of the INS data based on a CEF model reveals the presence of two magnetic excitations near 4.5 meV and 6.9 meV. The magnetic heat capacity data suggest an overall CEF splitting of 20.7 meV, however the excitation between 20 and 30 meV is very broad and weak in our INS data, but could provide an evidence of CEF level in this energy range in agreement with the magnetic entropy. Our analysis of INS data based on the CEF-phonon model indicates that the two excitations at 4.5 meV and 6.9 meV have their origin in CEF-phonon coupling (i.e. splitting of one CEF peak into two peaks, called vibron), with an overall splitting of 28.16 meV, similar to the case of CeCuAl3 and CeAuAl3.

cond-mat.str-el↗

arXiv2021

Superconducting and normal state properties of high entropy alloy Nb-Re-Hf-Zr-Tiinvestigated by muon spin relaxation and rotation

Superconducting high entropy alloy (HEA) are emerging as a new class of superconducting materials. It provides a unique opportunity to understand the complex interplay of disorder and superconductivity. We report the synthesis and detail bulk and microscopic characterization of Nb$_{60}$Re$_{10}$Zr$_{10}$Hf$_{10}$Ti$_{10}$ HEA alloy using transport, magnetization, specific heat, and muon spin rotation/relaxation ($μ$SR) measurements. Bulk superconductivity with transition temperature $T_{C}$ = 5.7 K confirmed by magnetization, resistivity, and heat capacity measurements. Zero-field $μ$SR measurement shows that the superconducting state preserves time-reversal symmetry, and transverse-field measurements of the superfluid density are well described by an isotropic s-wave model.

cond-mat.supr-con↗

arXiv2021

Superconductivity in the layered cage compound Ba3Rh4Ge16

We report the synthesis and superconducting properties of a layered cage compound Ba3Rh4Ge16. Similar to Ba3Ir4Ge16, the compound is composed of 2D networks of cage units, formed by noncubic Rh-Ge building blocks, in marked contrast to the reported rattling compounds. The electrical resistivity, magnetization, specific heat capacity, and muSR measurements unveiled moderately coupled s-wave superconductivity with a critical temperature Tc = 7.0 K, the upper critical field ~ 2.5 T, the electron-phonon coupling strength ~ 0.80, and the Ginzburg-Landau parameter ~ 7.89. The mass reduction by the substitution of Ir by Rh is believed to be responsible for the enhancement of Tc and coupling between the cage and guest atoms. Our results highlight the importance of the atomic weight of the framework in cage compounds in controlling the electron-phonon coupling strength and Tc.

cond-mat.supr-con↗

arXiv2021

Coupling between Antiferromagnetic and Spin Glass Orders in the Quasi-One-Dimensional Iron Telluride TaFe$_{1+x}$Te$_3$ ($x$=0.25)

Understanding the interplay among different magnetic exchange interactions and its physical consequences, especially in the presence of itinerant electrons and disorders, remains one of the central themes in condensed matter physics. In this vein, the coupling between antiferromagnetic and spin glass orders may lead to large exchange bias, a property of potential broad technological applications. In this article, we report the coexistence of antiferromagnetic order and spin glass behaviors in a quasi-one-dimensional iron telluride TaFe$_{1+x}$Te$_3$ ($x$=0.25). Its antiferromagnetism is believed to arise from the antiferromagnetic interchain coupling between the ferromagnetically aligned FeTe chains along the $b$-axis, while the spin glassy state stems from the disordered Fe interstitials. This dichotomic role of chain and interstitial sublattices is responsible for the large exchange bias observed at low temperatures, with the interstitial Fe acting as the uncompensated moment and its neighboring Fe chain providing the source for its pinning. This iron-based telluride may thereby represent a new paradigm to study the large family of transition metal chalcogenides whose magnetic order or even the dimensionality can be tuned to a large extent, forming a fertile playground to manipulate or switch the spin degrees of freedom thereof.

cond-mat.mtrl-sci↗