SearcharxivSearch

arXiv subjects

P. M. Vora

Publications and source records attributed to P. M. Vora.

2 recordsLinked to original sources

Dynamic phase transition into a mixed-CDW state in 1$T$-TaS$_2$ via a thermal quench

Ultrafast light-matter interaction has emerged as a new mechanism to exert control over the macroscopic properties of quantum materials toward novel functionality. To date, technological applications of these non-thermal phases are limited by their ultrashort lifetimes and low-ordering temperatures. Among the most studied photoinduced metastable phases for their technological promise is the hidden metallic charge density wave (H-CDW) in the model correlated CDW compound 1$T$-TaS$_2$. Despite active study and engineering, the nature of the photoinduced H-CDW remains the subject of debate and is only accessible at cryogenic temperatures. Here, we stabilize the H-CDW phase at thermal equilibrium up to near-room temperature by accessing an intermediate mixed CDW order regime via thermal quenching. Using x-ray high dynamic range reciprocal space mapping (HDRM) and scanning tunneling spectroscopy (STS), we reveal the coexistence of commensurate (C) CDW and H-CDW domains below 180 K during cooling and below 210 K during warming. Our findings show that each order parameter breaks basal plane mirror symmetry with different chiral orientations and induces out-of-plane unit cell tripling in the H-CDW phase. Despite metallic domain walls and a finite density of states at zero bias observed via STS, bulk resistance remains insulating due to CDW stacking disorder. This study establishes the H-CDW as a thermally stable phase and introduces a new mechanism for switchable metallic behavior in thin flakes of 1$T$-TaS$_2$ and similar materials with competing order phases.

cond-mat.mtrl-sci

Chirality Dependence of the $K$-Momentum Dark Excitons in Carbon Nanotubes

Using a collection of twelve semiconducting carbon nanotube samples, each highly enriched in a single chirality, we study the chirality dependence of the $K$-momentum dark singlet exciton using phonon sideband optical spectroscopy. Measurements of bright absorptive and emissive sidebands of this finite momentum exciton identify its energy as 20 - 38 meV above the bright singlet exciton, a separation that exhibits systematic dependencies on tube diameter, $2n+m$ family, and semiconducting type. We present calculations that explain how chiral angle dependence in this energy separation relates to the Coulomb exchange interaction, and elaborate the dominance of the $K_{A_1'}$ phonon sidebands over the zone-center phonon sidebands over a wide range of chiralities. The Kataura plot arising from these data is qualitatively well described by theory, but the energy separation between the sidebands shows a larger chiral dependence than predicted. This latter observation may indicate a larger dispersion for the associated phonon near the $K$ point than expected from finite distance force modeling.

cond-mat.mes-hall