arXiv subjects

P. Malgaretti

Publications and source records attributed to P. Malgaretti.

At least 19 recordsLinked to original sources

arXiv2026

Bubbles in highly porous media: Clogging and unclogging at constrictions

Gas bubble transport through highly porous transport layers (PTLs) is a key process in electrochemical devices such as proton exchange membrane water electrolyzers, where bubbles generated at catalyst surfaces must migrate through complex porous networks. To understand this process, we focus on model systems, namely the motion of single, paired and multiple bubbles in capillaries and study these by combining analytical modeling, three-dimensional color-gradient lattice Boltzmann simulations, and X-ray radiography. For single bubbles, we derive an analytical expression for the critical Bond number separating passage from clogging and show that, in the low deformation regime, it accurately predicts this transition in circular capillaries. Extending the study to bubble pairs, we uncover additional clogging and unclogging pathways, including hydrodynamic unclogging driven by pressure buildup in the interbubble film, and coalescence-induced clogging and unclogging. By mapping our results as functions of confinement ratio and Bond number, we define distinct dynamical regimes that control bubble passage. Experiments on bubble chains rising through highly porous nickel foams confirm the predicted clogging and unclogging mechanisms.

cond-mat.soft↗

arXiv2026

Swirl flow in microchannels: patterned slip walls enhance heat transport

Microchannel heat sinks (MCHS) are widely used for thermal management in high-power electronics due to their ability to dissipate large heat fluxes with minimal coolant consumption. While numerous strategies - such as geometric modifications, surface disruptions, and enhanced coolant formulations - have been explored to improve heat transfer, many of these approaches increase hydraulic resistance and pumping power requirements. Recent studies have shown that slip/no-slip wall patterns can enhance flow rates and convective heat removal without additional energy input, and that patterned microstructures can induce secondary swirling motions known to promote mixing and heat transfer. Motivated by these findings, we investigate a slip/no-slip pattern specifically designed to generate swirl flow inside a straight microchannel. Building upon prior work on passive chaotic advection and boundary-condition engineering, we assess the hydrodynamic and thermal performance of this patterned configuration under conditions relevant to laminar microchannel cooling. Our results demonstrate that appropriately arranged slip/no-slip regions can induce swirl without geometric perturbations or increased pumping power, ultimately improving heat transfer efficiency at fixed volumetric flow rate. This study highlights the potential of boundary-condition patterning as a simple, energy-neutral strategy for enhancing the performance of microfluidic heat-transfer devices.

physics.flu-dyn↗

arXiv2025

Zigzagging Diffusion and Non-Standard Transport in Particle-laden Nanopores Under Extreme Confinement

Understanding transport subject to molecular-scale confinement is key to advancing nanofluidics, yet classical hydrodynamic laws often fail at these scales. Here, we study a model system: transport of toluene as a solvent and small fullerenes as model particles confined within alumina slit nanopores using molecular dynamics simulations. We find that toluene organizes into discrete layers whose commensurability with the pore width leads to a striking, non-monotonic, zig-zag dependence of transport coefficients on confinement. This layering drives oscillations not only in solvent diffusivity but also in flow velocity and permeability under pressure-driven conditions, breaking the expected scaling relations between diffusion, viscosity, and flow. Surprisingly, introducing a nanoparticle does not wash out these effects - although the fullerene perturbs local layering, the nanoparticle diffusivity retains a zig-zag dependence on pore width. Our results demonstrate how structural commensurability and interfacial effects dominate transport in nanoconfined liquids, and lead to important deviations from continuum expectations. These findings establish a microscopic basis for size-dependent transport in nanopores and highlight the need for beyond-hydrodynamic models in confined soft matter systems.

cond-mat.soft↗

arXiv2025

Transport of electrolytes across nanochannels: the role of slip

We characterize the electrokinetic flow due to the transport of electrolytes embedded in nanochannels of varying cross-section with inhomogeneous slip on their walls, modeled as an effective slip length on the channel wall. We show that, within linear response and Debye-Huckel regime, the transport coefficients, and so the fluxes, can be significantly improved by the presence of a hydrophobic surface coating located at the narrowest section of the nanochannel. Our model indicates that the enhancement is larger when considering electric conductive walls in comparison to dielectric microchannel walls, and it is produced by a synergy between the entropic effects due to the geometry and the presence of the slip boundary layer. Our results show that a tailored hydrophobic coating design can be an effective strategy to improve transport properties in the broad areas of lab-on-a-chip, biophysics, and blue energy harvesting and energy conversion technologies.

physics.flu-dyn↗

arXiv2024

The interplay of shape and catalyst distribution in the yield of compressible flow microreactors

We develop a semi-analytical model for transport in structured catalytic microreactors, where both reactant and product are compressible fluids. Making use of the lubrication and Fick-Jacobs approximations, we reduce the three-dimensional governing equations to an effective one-dimensional set of equations. Our model captures the effect of compressibility, of corrugations in the shape of the reactor, as well as of an inhomogeneous catalytic coating of the reactor walls. We show that in the weakly compressible limit (e.g., liquid-phase reactors), the distribution of catalyst does not influence the reactor yield, which we verify experimentally. Beyond this limit, we show that introducing inhomogeneities in the catalytic coating and corrugations to the reactor walls can improve the yield.

physics.flu-dyn↗

arXiv2024

Coil-to-globule collapse of active polymers: a Rouse perspective

We derive an effective Rouse model for tangentially active polymers, characterized by a constant active force tangent to their backbone. In particular, we show that, once extended to account for finite bending rigidity, such active Rouse model captures the reduction in the gyration radius, or coil-to-globule-like transition, that has been observed numerically in the literature for such active filaments. Interestingly, our analysis identifies the proper definition of the Peclet number, that allows to collapse all numerical data onto a master curve.

cond-mat.soft↗

arXiv2024

A lattice Boltzmann approach for acoustic manipulation

We employ a lattice Boltzmann method to compute the acoustic radiation force produced by standing waves on a compressible object. Instead of simulating the fluid mechanics equations directly, the proposed method uses a lattice Boltzmann model that reproduces the wave equation, together with a kernel interpolation scheme, to compute the first order perturbations of the pressure and velocity fields on the object's surface and, from them, the acoustic radiation force. The procedure reproduces with excellent accuracy the theoretical expressions by Gor'kov and Wei for the sphere and the disk, respectively, even with a modest number of lattice Boltzmann cells. The proposed method shows to be a promising tool for simulating phenomena where the acoustic radiation force plays a relevant role, like acoustic tweezers or the acoustic manipulation of microswimmers, with applications in medicine and engineering.

physics.flu-dyn↗

arXiv2023

Electroneutrality breakdown for electrolytes embedded in varying-section nanopores

We determine the local charge dynamics of a $z-z$ electrolyte embedded in a varying-section channel. By means of an expansion based on the length scale separation between the axial and transverse direction of the channel, we derive closed formulas for the local excess charge for both, dielectric and conducting walls, in $2D$ (planar geometry) as well as in $3D$ (cylindrical geometry). Our results show that, even at equilibrium, the local charge electroneutrality is broken whenever the section of the channel is not homogeneous for both dielectric and conducting walls as well as for $2D$ and $3D$ channels. Interestingly, even within our expansion, the local excess charge in the fluid can be comparable to the net charge on the walls. We critically discuss the onset of such local electroneutrality breakdown in particular with respect to the correction that it induces on the effective free energy profile experienced by tracer ions.

cond-mat.soft↗

arXiv2023

Turning catalytically active pores into active pumps

We develop a semi-analytical model of self-diffusioosmotic transport in active pores, which includes advective transport and the inverse chemical reaction which consumes solute. In previous work (Phys. Rev. Lett. 129, 188003, 2022), we have demonstrated the existence of a spontaneous symmetry breaking in fore-aft symmetric pores that enables them to function as a micropump. We now show that this pumping transition is controlled by three timescales. Two timescales characterize advective and diffusive transport. The third timescale corresponds to how long a solute molecule resides in the pore before being consumed. Introducing asymmetry to the pore (either via the shape or the catalytic coating) reveals a second type of advection-enabled transitions. In asymmetric pores, the flow rate exhibits discontinuous jumps and hysteresis loops upon tuning the parameters that control the asymmetry. This work demonstrates the interconnected roles of shape and catalytic patterning in the dynamics of active pores, and shows how to design a pump for optimum performance.

cond-mat.soft↗

arXiv2023

Splitting probabilities for dynamics in corrugated channels: passive VS active Brownian motion

In many practically important problems which rely on particles' transport in realistic corrugated channels, one is interested to know the probability that either of the extremities, (e.g., the one containing a chemically active site, or connected to a broader channel), is reached before the other one. In mathematical literature, the latter are called the "splitting" probabilities (SPs). Here, within the Fick-Jacobs approach, we study analytically the SPs as functions of system's parameters for dynamics in three-dimensional corrugated channels, confronting standard diffusion and active Brownian motion. Our analysis reveals some similarities in the behavior and also some markedly different features, which can be seen as fingerprints of the activity of particles.

cond-mat.soft↗

arXiv2023

Closed formula for the transport of micro-nano-particle across model porous media

In the last decade the Fick-Jacobs approximation has been exploited to capture the transport across constrictions. Here, we review the derivation of the Fick-Jacobs equation with particular emphasis on its linear response regime. We show that for fore-aft symmetric channels the flux of non-interacting systems is fully captured by its linear response regime. For this case we derive a very simple formula that captures the correct trends and that can be exploited as a simple tool to design experiments or simulations. Finally, we show that higher order corrections in the flux may appear for non-symmetric channels.

cond-mat.soft↗

arXiv2022

Szilard engines and information-based work extraction for active systems

The out of equilibrium nature of active systems can be exploited for the design of information-based engines. We design two types of an active Szilard engine that use a Maxwell daemon to extract work from an active bath composed of non-interacting Active Brownian Particles (ABPs). The two engines exploit either the quasi-static active pressure of ABPs or the long correlation time of their velocities. For both engines the Landauer principle can be violated so that larger work can be extracted compared to conventional Szilard engines operating in quasi thermal equilibrium. For both of our engines,we identify the optimal regimes at which the work extracted and the efficiency are maximized. Finally, we we discuss them in the context of synthetic and biological active systems.

cond-mat.soft↗

arXiv2022

Pumping and mixing in active pores

We show both numerically and analytically that a chemically patterned active pore can act as a micro/nano-pump for fluids, even if it is fore-aft symmetric. This is possible due to a spontaneous symmetry breaking which occurs when advection rather than diffusion is the dominant mechanism of solute transport. We further demonstrate that, for pumping and tuning the flow rate, a combination of geometrical and chemical inhomogeneities is required. For certain parameter values, the flow is unsteady, and persistent oscillations with a tunable frequency appear. Finally, we find that the flow may lose its axial symmetry and hence promotes mixing in the low Reynolds number regime.

cond-mat.soft↗

arXiv2022

Lattice Boltzmann simulations of two linear microswimmers using the immersed boundary method

The performance of a single or the collection of microswimmers strongly depends on the hydrodynamic coupling among their constituents and themselves. We present a numerical study for a single and a pair of microswimmers based on lattice Boltzmann method (LBM) simulations. Our numerical algorithm consists of two separable parts. Lagrange polynomials provide a discretization of the microswimmers and the lattice Boltzmann method captures the dynamics of the surrounding fluid. The two components couple via an immersed boundary method. We present data for a single swimmer system and our data also show the onset of collective effects and, in particular, an overall velocity increment of clusters of swimmers.

cond-mat.soft↗

arXiv2021

Active microrheology in corrugated channels: comparison of thermal and colloidal baths

The dynamics of colloidal suspension confined within porous materials strongly differs from that in the bulk. In particular, within porous materials, the presence of boundaries with complex shapes entangles the longitudinal and transverse degrees of freedom inducing a coupling between the transport of the suspension and the density inhomogeneities induced by the walls. Colloidal suspension confined within model porous media are characterized by means of active microrheology where a net force is applied on a single colloid (tracer particle) whose transport properties are then studied. The trajectories provided by active microrheology are exploited to determine the local transport coefficients. In order to asses the role of the colloid-colloid interactions we compare the case of a tracer embedded in a colloidal suspension to the case of a tracer suspended in an ideal bath. Our results show that the friction coefficient increases and the passage time distribution widens upon increasing the corrugation of the channel. These features are obtained for a tracer suspended in a (thermalized) colloidal bath as well as for the case of an ideal thermal bath. These results highlight the relevance of the confinement on the transport and show a mild dependence on the colloidal/thermal bath. Finally, we rationalize our numerical results with a semi-analytical model. Interestingly, the predictions of the model are quantitatively reliable for mild external forces, hence providing a reliable tool for predicting the transport across porous materials.

cond-mat.soft↗

arXiv2019

Numerical simulations of self-diffusiophoretic colloids at fluid interfaces

The dynamics of active colloids is very sensitive to the presence of boundaries and interfaces which therefore can be used to control their motion. Here we analyze the dynamics of active colloids adsorbed at a fluid-fluid interface. By using a mesoscopic numerical approach which relies on an approximated numerical solution of the Navier-Stokes equation, we show that when adsorbed at a fluid interface, an active colloid experiences a net torque even in the absence of a viscosity contrast between the two adjacent fluids. In particular, we study the dependence of this torque on the contact angle of the colloid with the fluid-fluid interface and on its surface properties. We rationalize our results via an approximate approach which accounts for the appearance of a local friction coefficient. By providing insight into the dynamics of active colloids adsorbed at fluid interfaces, our results are relevant for two-dimensional self assembly and emulsion stabilization by means of active colloids.

cond-mat.soft↗

arXiv2018

Self-diffusiophoresis induced by fluid interfaces

The influence of a fluid-fluid interface on self-phoresis of chemically active, axially symmetric, spherical colloids is analyzed. Distinct from the studies of self-phoresis for colloids trapped at fluid interfaces or in the vicinity of hard walls, here we focus on the issue of self-phoresis close to a fluid-fluid interface. In order to provide physically intuitive results highlighting the role played by the interface, the analysis is carried out for the case that the symmetry axis of the colloid is normal to the interface; moreover, thermal fluctuations are not taken into account. Similarly to what has been observed near hard walls, we find that such colloids can be set into motion even if their whole surface is homogeneously active. This is due to the anisotropy along the direction normal to the interface owing to the partitioning by diffusion, among the coexisting fluid phases, of the product of the chemical reaction taking place at the colloid surface. Different from results corresponding to hard walls, in the case of a fluid interface the direction of motion, i.e., towards the interface or away from it, can be controlled by tuning the physical properties of one of the two fluid phases. This effect is analyzed qualitatively and quantitatively, both by resorting to a far-field approximation and via an exact, analytical calculation which provides the means for a critical assessment of the approximate analysis.

cond-mat.soft↗

arXiv2017

Bistability, oscillations and bidirectional motion of ensemble of hydrodynamically-coupled molecular motors

We analyze the collective behavior of hydrodynamically coupled molecular motors. We show that the local fluxes induced by motors displacement can induce the experimentally observed bidirectional motion of cargoes and vesicles. By means of a mean--field approach we show that sustained oscillations as well as bistable collective motor motion arise even for very large collection of motors, when thermal noise is irrelevant. The analysis clarifies the physical mechanisms responsible for such dynamics by identifying the relevant coupling parameter and its dependence on the geometry of the hydrodynamic coupling as well as on system size. We quantify the phase diagram for the different phases that characterize the collective motion of hydrodynamically coupled motors and show that sustained oscillations can be reached for biologically relevant parameters, hence demonstrating the relevance of hydrodynamic interactions in intracellular transport.

cond-mat.soft↗