arXiv subjects

P. Sonnentrucker

Publications and source records attributed to P. Sonnentrucker.

At least 19 recordsLinked to original sources

arXiv2023

A High Precision Survey of the D/H Ratio in the Nearby Interstellar Medium

We present high S/N measurements of the H I Ly alpha absorption line toward 16 Galactic targets which are at distances between approximately 190 and 2200 pc, all beyond the wall of the Local Bubble. We describe the models used to remove stellar emission and absorption features and the methods used to account for all known sources of error in order to compute high precision values of the H I column density with robust determinations of uncertainties. When combined with H2 column densities from other sources, we find total H column densities ranging from 10^20.01 to 10^21.25/cm2. Using deuterium column densities from FUSE observations we determine the D/H ratio along the sight lines. We confirm and strengthen the conclusion that D/H is spatially variable over these H I column density and target distance regimes, which predominantly probe the ISM outside the Local Bubble. We discuss how these results affect models of Galactic chemical evolution. We also present an analysis of metal lines along the five sight lines for which we have high resolution spectra and, along with results reported in the literature, discuss the corresponding column densities in the context of a generalized depletion analysis. We find that D/H is only weakly correlated with metal depletion and conclude that the spatial D/H variability is not solely due to dust depletion. A bifurcation of D/Htot as a function of depletion at high depletion levels provides modest support that deuterium-rich gas is infalling onto the Galactic plane.

astro-ph.GA↗

arXiv2022

HyGAL: Characterizing the Galactic ISM with observations of hydrides and other small molecules -- I. Survey description and a first look toward W3(OH), W3 IRS5 and NGC 7538 IRS1

The HyGAL SOFIA legacy program surveys six hydride molecules -- ArH+, OH+, H2O+, SH, OH, and CH -- and two atomic constituents -- C+ and O -- within the diffuse interstellar medium (ISM) by means of absorption-line spectroscopy toward 25 bright Galactic background continuum sources. This detailed spectroscopic study is designed to exploit the unique value of specific hydrides as tracers and probes of different phases of the ISM, as demonstrated by recent studies with the Herschel Space Observatory. The observations performed under the HyGAL program will allow us to address several questions related to the lifecycle of molecular material in the ISM and the physical processes that impact its phase transition, such as: (1) What is the distribution function of the H2 fraction in the ISM? (2) How does the ionization rate due to low-energy cosmic-rays vary within the Galaxy? (3) What is the nature of interstellar turbulence, and what mechanisms lead to its dissipation? This overview discusses the observing strategy, synergies with ancillary and archival observations, the data reduction and analysis schemes adopted; and presents the first results obtained toward three of the survey targets, W3(OH), W3IRS5 and NGC7538IRS1. Robust measurements of the column densities of these hydrides -- obtained through widespread observations of absorption lines-- help address the questions raised, and there is a timely synergy between these observations and the development of theoretical models, particularly pertaining to the formation of H2 within the turbulent ISM. The provision of enhanced HyGAL data products will therefore serve as a legacy for future ISM studies.

astro-ph.GA↗

arXiv2019

The Hubble Catalog of Variables (HCV)

The Hubble Space Telescope (HST) has obtained multi-epoch observations providing the opportunity for a comprehensive variability search aiming to uncover new variables. We have therefore undertaken the task of creating a catalog of variable sources based on version 3 of the Hubble Source Catalog (HSC), which relies on publicly available images obtained with the WFPC2, ACS, and WFC3 instruments onboard the HST. We adopted magnitude-dependent thresholding in median absolute deviation (a robust measure of light curve scatter) combined with sophisticated preprocessing techniques and visual quality control to identify and validate variable sources observed by Hubble with the same instrument and filter combination five or more times. The Hubble Catalog of Variables (HCV) includes 84,428 candidate variable sources (out of 3.7 million HSC sources that were searched for variability) with $V \leq 27$ mag; for 11,115 of them the variability is detected in more than one filter. The data points in the light curves of the variables in the HCV catalog range from five to 120 points (typically having less than ten points); the time baseline ranges from under a day to over 15 years; while $\sim$8% of all variables have amplitudes in excess of 1 mag. Visual inspection performed on a subset of the candidate variables suggests that at least 80% of the candidate variables that passed our automated quality control are true variable sources rather than spurious detections resulting from blending, residual cosmic rays, and calibration errors. The HCV is the first, homogeneous catalog of variable sources created from archival HST data and currently is the deepest catalog of variables available. The catalog includes variable stars in our Galaxy and nearby galaxies, as well as transients and variable active galactic nuclei. (abbreviated)

astro-ph.SR↗

arXiv2018

Molecular ion abundances in the diffuse ISM : CF+, HCO+, HOC+, and C3H+

The transition between atomic and molecular hydrogen is associated with important changes in the structure of interstellar clouds, and marks the beginning of interstellar chemistry. Because of the relatively simple networks controlling their abundances, molecular ions are usually good probes of the underlying physical conditions including for instance the fraction of gas in molecular form or the fractional ionization. In this paper we focus on three possible probes of the molecular hydrogen column density, HCO+, HOC+, and CF+. We presented high sensitivity ALMA absorption data toward a sample of compact HII regions and bright QSOs with prominent foreground absorption, in the ground state transitions of the molecular ions HCO+, HOC+, and CF+ and the neutral species HCN and HNC, and from the excited state transitions of C3H+(4-3) and 13CS(2-1). These data are compared with Herschel absorption spectra of the ground state transition of HF and p-H2O. We show that the HCO+, HOC+, and CF+ column densities are well correlated with each other. HCO+ and HOC+ are tightly correlated with p-H2O, while they exhibit a different correlation pattern with HF depending on whether the absorbing matter is located in the Galactic disk or in the central molecular zone. We report new detections of C3H+ confirming that this ion is ubiquitous in the diffuse matter, with an abundance relative to H2 of ~7E-11. We confirm that the CF+ abundance is lower than predicted by simple chemical models and propose that the rate of the main formation reaction is lower by a factor of about 3 than usually assumed. In the absence of CH or HF data, we recommend to use the ground state transitions of HCO+, CCH, and HOC+ to trace diffuse molecular hydrogen, with mean abundances relative to H2 of 3E-9, 4E-8 and 4E-11.

astro-ph.GA↗

arXiv2015

A Herschel/HIFI Legacy Survey of HF and H2O in the Galaxy: Probing Diffuse Molecular Cloud Chemistry

We combine Herschel observations of a total of 12 sources to construct the most uniform survey of HF and H2O in our Galactic disk. Both molecules are detected in absorption along all sight lines. The high spectral resolution of the Heterodyne Instrument for the Far-Infrared (HIFI) allows us to compare the HF and H2O distributions in 47 diffuse cloud components sampling the disk. We find that the HF and H2O velocity distributions follow each other almost perfectly and establish that HF and H2O probe the same gas-phase volume. Our observations corroborate theoretical predictions that HF is a sensitive tracer of H2 in diffuse clouds, down to molecular fractions of only a few percent. Using HF to trace H2 in our sample, we find that the N(H2O)-to-N(HF) ratio shows a narrow distribution with a median value of 1.51. Our results further suggest that H2O might be used as a tracer of H2 -within a factor 2.5- in the diffuse interstellar medium. We show that the measured factor of ~2.5 variation around the median is driven by true local variations in the H2O abundance relative to H2 throughout the disk. The latter variability allows us to test our theoretical understanding of the chemistry of oxygen-bearing molecules in the diffuse gas. We show that both gas-phase and grain-surface chemistry are required to reproduce our H2O observations. This survey thus confirms that grain surface reactions can play a significant role in the chemistry occurring in the diffuse interstellar medium n_H < 1000 cm^-3.

astro-ph.GA↗

arXiv2015

Sulphur-bearing molecules in diffuse molecular clouds: new results from SOFIA/GREAT and the IRAM 30 m telescope

We have observed five sulphur-bearing molecules in foreground diffuse molecular clouds lying along the sight-lines to five bright continuum sources. We have used the GREAT instrument on SOFIA to observe the 1383 GHz $^2Π_{3/2} J=5/2-3/2$ transitions of SH towards the star-forming regions W31C, G29.96-0.02, G34.3+0.1, W49N and W51, detecting foreground absorption towards all five sources; and the EMIR receivers on the IRAM 30m telescope at Pico Veleta to detect the H$_2$S 1(10)-1(01), CS J=2-1 and SO 3(2)-2(1) transitions. In nine foreground absorption components detected towards these sources, the inferred column densities of the four detected molecules showed relatively constant ratios, with N(SH)/N(H$_2$S) in the range 1.1 - 3.0, N(CS)/N(H$_2$S) in the range 0.32 - 0.61, and N(SO)/N(H$_2$S) in the range 0.08 - 0.30. The observed SH/H$_2$ ratios - in the range (0.5-2.6) $\times 10^{-8}$ - indicate that SH (and other sulphur-bearing molecules) account for << 1% of the gas-phase sulphur nuclei. The observed abundances of sulphur-bearing molecules, however, greatly exceed those predicted by standard models of cold diffuse molecular clouds, providing further evidence for the enhancement of endothermic reaction rates by elevated temperatures or ion-neutral drift. We have considered the observed abundance ratios in the context of shock and turbulent dissipation region (TDR) models. Using the TDR model, we find that the turbulent energy available at large scale in the diffuse ISM is sufficient to explain the observed column densities of SH and CS. Standard shock and TDR models, however, fail to reproduce the column densities of H$_2$S and SO by a factor of about 10; more elaborate shock models - in which account is taken of the velocity drift, relative to H$_2$, of SH molecules produced by the dissociative recombination of H$_3$S$^+$ - reduce this discrepancy to a factor ~ 3.

astro-ph.GA↗

arXiv2014

Herschel Survey of Galactic OH+, H2O+, and H3O+: Probing the Molecular Hydrogen Fraction and Cosmic-Ray Ionization Rate

In diffuse interstellar clouds the chemistry that leads to the formation of the oxygen bearing ions OH+, H2O+, and H3O+ begins with the ionization of atomic hydrogen by cosmic rays, and continues through subsequent hydrogen abstraction reactions involving H2. Given these reaction pathways, the observed abundances of these molecules are useful in constraining both the total cosmic-ray ionization rate of atomic hydrogen (zeta_H) and molecular hydrogen fraction, f(H2). We present observations targeting transitions of OH+, H2O+, and H3O+ made with the Herschel Space Observatory along 20 Galactic sight lines toward bright submillimeter continuum sources. Both OH+ and H2O+ are detected in absorption in multiple velocity components along every sight line, but H3O+ is only detected along 7 sight lines. From the molecular abundances we compute f(H2) in multiple distinct components along each line of sight, and find a Gaussian distribution with mean and standard deviation 0.042+-0.018. This confirms previous findings that OH+ and H2O+ primarily reside in gas with low H2 fractions. We also infer zeta_H throughout our sample, and find a log-normal distribution with mean log(zeta_H)=-15.75, (zeta_H=1.78x10^-16 s^-1), and standard deviation 0.29 for gas within the Galactic disk, but outside of the Galactic center. This is in good agreement with the mean and distribution of cosmic-ray ionization rates previously inferred from H3+ observations. Ionization rates in the Galactic center tend to be 10--100 times larger than found in the Galactic disk, also in accord with prior studies.

astro-ph.GA↗

arXiv2013

Far-Infrared Spectroscopy of the Galactic Center. Hot Molecular Gas: Shocks versus Radiation near SgrA*

We present a 52-671um spectral scan toward SgrA* taken with the PACS and SPIRE spectrometers onboard Herschel. The achieved angular resolution allows us to separate, for the first time at far-IR wavelengths, the emission toward the central cavity (gas in the inner central parsec of the galaxy) from that of the surrounding circum-nuclear disk. The spectrum toward SgrA* is dominated by strong [OIII], [OI], [CII], [NIII], [NII], and [CI] fine structure lines (in decreasing order of luminosity) arising in gas irradiated by UV-photons from the central stellar cluster. In addition, rotationally excited lines of 12CO (from J=4-3 to 24-23), 13CO, H2O, OH, H3O+, HCO+ and HCN, as well as ground-state absorption lines of OH+, H2O+, H3O+, CH+, H2O, OH, HF, CH and NH are detected. The excitation of the 12CO ladder is consistent with a hot isothermal component at Tk ~ 10^{3.1} K and n(H2)< 10^4 cm^{-3}. It is also consistent with a distribution of temperature components at higher density with most CO at Tk<300 K. The detected molecular features suggest that, at present, neither very enhanced X-ray, nor cosmic-ray fluxes play a dominant role in the heating of the hot molecular gas. The hot CO component (either the bulk of the CO column or just a small fraction depending on the above scenario) results from a combination of UV- and shock-driven heating. If irradiated dense clumps/clouds do not exist, shocks likely dominate the heating of the hot molecular gas. This is consistent with the high-velocity gas detected toward SgrA*.

astro-ph.GA↗

arXiv2012

Water absorption in Galactic translucent clouds: conditions and history of the gas derived from Herschel/HIFI PRISMAS observations

We present Herschel/HIFI observations of nine transitions of \hho and \hheo towards six high-mass star-forming regions, obtained as part of the PRISMAS Key Program. Water vapor in translucent clouds is detected in absorption along every sightline. We derive the column density of \hho or \hheo for the lower energy level of each transition observed. The total water column density is about a few $10^{13} \rm{cm^{-2}}$. We find that the abundance of water relative to hydrogen nuclei is $1\times10^{-8}$ in agreement with models for oxygen chemistry with high cosmic ray ionization rates. Relative to \hh, the abundance of water is remarkably constant at $5\times10^{-8}$. The abundance of water in excited levels is at most 15%, implying that the excitation temperature $T_{ex}$ in the ground state transitions is below 10 K. The column densities derived from the two ortho ground state transitions indicates that $T_{ex}\simeq5$ K and that the density $n($\hh$)$ in the clouds is $\le10^4 \rm{cm^{-3}}$. For most clouds we derive a water ortho-to-para ratio consistent with the value of 3 expected in thermodynamic equilibrium in the high temperature limit. Two clouds with large column densities exhibit a ratio significantly below 3. This may argue that the history of water molecules includes a cold phase, either when the molecules were formed on cold grains, or when they later become at least partially thermalized with the cold gas ($\sim25$ K) in the shielded, low temperature regions of the clouds; evidently, they have not yet fully thermalized with the warmer ($\sim50$ K) translucent portions of the clouds.

astro-ph.GA↗

arXiv2011

Herschel/HIFI Observations of Hydrogen Fluoride Toward Sagittarius B2(M)

Herschel/HIFI observations have revealed the presence of widespread absorption by hydrogen fluoride (HF) J = 1-0 rotational transition, toward a number of Galactic sources. We present observations of HF J = 1-0 toward the high-mass star-forming region Sagittarius B2(M). The spectrum obtained shows a complex pattern of absorption, with numerous features covering a wide range of local standard of rest velocities (-130 to 100 km -1). An analysis of this absorption yields HF abundances relative to H2 of ~1.3 {\times}10-8, in most velocity intervals. This result is in good agreement with estimates from chemical models, which predict that HF should be the main reservoir of gas-phase fluorine under a wide variety of interstellar conditions. Interestingly, we also find velocity intervals in which the HF spectrum shows strong absorption features that are not present, or are very weak, in spectra of other molecules, such as 13CO (1-0) and CS (2-1). HF absorption reveals components of diffuse clouds with small extinction that can be studied for the first time. Another interesting observation is that water is significantly more abundant than hydrogen fluoride over a wide range of velocities toward Sagittarius B2(M), in contrast to the remarkably constant H2O/HF abundance ratio with average value close to unity measured toward other Galactic sources.

astro-ph.GA↗

arXiv2011

Uncovering Obscured Active Galactic Nuclei in Homogeneously Selected Samples of Seyfert 2 Galaxies

We have analyzed archival \textit{Chandra} and \textit{XMM-Newton} data for two nearly complete homogeneously selected samples of type 2 Seyfert galaxies (Sy2s). These samples were selected based on intrinsic Active Galactic Nuclei (AGN) flux proxies: a mid-infrared (MIR) sample from the original IRAS 12$μ$m survey and an optical ([OIII]$λ$ 5007 Å flux limited) sample from the Sloan Digital Sky Survey (SDSS), providing a total of 45 Sy2s. As the MIR and [OIII] fluxes are largely unaffected by AGN obscuration, these samples can present an unbiased estimate of the Compton-thick (column density N$_H > 10^{24}$ cm$^{-2}$) subpopulation. We find that the majority of this combined sample is likely heavily obscured, as evidenced by the 2-10 keV X-ray attenuation (normalized by intrinsic flux diagnostics) and the large Fe K$α$ equivalent widths (several hundred eV to over 1 keV). A wide range of these obscuration diagnostics is present, showing a continuum of column densities, rather than a clear segregation into Compton-thick and Compton-thin sub-populations. We find that in several instances, the fitted column densities severely under-represent the attenuation implied by these obscuration diagnostics, indicating that simple X-ray models may not always recover the intrinsic absorption. We compared AGN and host galaxy properties, such as intrinsic luminosity, central black hole mass, accretion rate, and star formation rate with obscuration diagnostics. No convincing evidence exists to link obscured sources with unique host galaxy populations from their less absorbed counterparts. Finally, we estimate that a majority of these Seyfert 2s will be detectable in the 10-40 keV range by the future NuSTAR mission, which would confirm whether these heavily absorbed sources are indeed Compton-thick.

astro-ph.CO↗

arXiv2010

GGD 37: An Extreme Protostellar Outflow

We present the first Spitzer-IRS spectral maps of the Herbig-Haro flow GGD 37 detected in lines of [Ne III], [O IV], [Ar III], and [Ne V]. The detection of extended [O IV] (55 eV) and some extended emission in [Ne V] (97 eV) indicates a shock temperature in excess of 100,000 K, in agreement with X-ray observations, and a shock speed in excess of 200 km s-1. The presence of an extended pho- toionization or collisional ionization region indicates that GGD 37 is a highly unusual protostellar outflow.

astro-ph.GA↗

arXiv2010

Nitrogen hydrides in interstellar gas: Herschel/HIFI observations towards G10.6-0.4 (W31C)

The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6-0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We report observations of absorption in NH N=1-0, J=2-1 and ortho-NH2 1_1,1-0_0,0. We also observed ortho-NH3 1_0-0_0, and 2_0-1_0, para-NH3 2_1-1_1, and searched unsuccessfully for NH+. All detections show emission and absorption associated directly with the hot-core source itself as well as absorption by foreground material over a wide range of velocities. All spectra show similar, non-saturated, absorption features, which we attribute to diffuse molecular gas. Total column densities over the velocity range 11-54 km/s are estimated. The similar profiles suggest fairly uniform abundances relative to hydrogen, approximately 6*10^-9, 3*10^-9, and 3*10^-9 for NH, NH2, and NH3, respectively. These abundances are discussed with reference to models of gas-phase and surface chemistry.

astro-ph.GA↗

arXiv2010

Detection of hydrogen fluoride absorption in diffuse molecular clouds with Herschel/HIFI: a ubiquitous tracer of molecular gas

We discuss the detection of absorption by interstellar hydrogen fluoride (HF) along the sight line to the submillimeter continuum sources W49N and W51. We have used Herschel's HIFI instrument in dual beam switch mode to observe the 1232.4762 GHz J = 1 - 0 HF transition in the upper sideband of the band 5a receiver. We detected foreground absorption by HF toward both sources over a wide range of velocities. Optically thin absorption components were detected on both sight lines, allowing us to measure - as opposed to obtain a lower limit on - the column density of HF for the first time. As in previous observations of HF toward the source G10.6-0.4, the derived HF column density is typically comparable to that of water vapor, even though the elemental abundance of oxygen is greater than that of fluorine by four orders of magnitude. We used the rather uncertain N(CH)-N(H2) relationship derived previously toward diffuse molecular clouds to infer the molecular hydrogen column density in the clouds exhibiting HF absorption. Within the uncertainties, we find that the abundance of HF with respect to H2 is consistent with the theoretical prediction that HF is the main reservoir of gas-phase fluorine for these clouds. Thus, hydrogen fluoride has the potential to become an excellent tracer of molecular hydrogen, and provides a sensitive probe of clouds of small H2 column density. Indeed, the observations of hydrogen fluoride reported here reveal the presence of a low column density diffuse molecular cloud along the W51 sight line, at an LSR velocity of ~ 24kms-1, that had not been identified in molecular absorption line studies prior to the launch of Herschel.

astro-ph.GA↗

arXiv2010

Herschel/HIFI measurements of the ortho/para ratio in water towards Sagittarius B2(M) and W31C

We present Herschel/HIFI observations of the fundamental rotational transitions of ortho- and para-H$_2^{16}$O and H$_2^{18}$O in absorption towards Sagittarius~B2(M) and W31C. The ortho/para ratio in water in the foreground clouds on the line of sight towards these bright continuum sources is generally consistent with the statistical high-temperature ratio of 3, within the observational uncertainties. However, somewhat unexpectedly, we derive a low ortho/para ratio of $2.35 \pm 0.35$, corresponding to a spin temperature of $\sim$27~K, towards Sagittarius~B2(M) at velocities of the expanding molecular ring. Water molecules in this region appear to have formed with, or relaxed to, an ortho/para ratio close to the value corresponding to the local temperature of the gas and dust.

astro-ph.GA↗

arXiv2010

Herschel/HIFI observations of interstellar OH+ and H2O+ towards W49N: a probe of diffuse clouds with a small molecular fraction

We report the detection of absorption by interstellar hydroxyl cations and water cations, along the sight-line to the bright continuum source W49N. We have used Herschel's HIFI instrument, in dual beam switch mode, to observe the 972 GHz N = 1 - 0 transition of OH+ and the 1115 GHz 1(11) - 0(00) transition of ortho-H2O+. The resultant spectra show absorption by ortho-H2O+, and strong absorption by OH+, in foreground material at velocities in the range 0 to 70 km/s with respect to the local standard of rest. The inferred OH+/H2O+ abundance ratio ranges from ~ 3 to ~ 15, implying that the observed OH+ arises in clouds of small molecular fraction, in the 2 - 8% range. This conclusion is confirmed by the distribution of OH+ and H2O+ in Doppler velocity space, which is similar to that of atomic hydrogen, as observed by means of 21 cm absorption measurements, and dissimilar from that typical of other molecular tracers. The observed OH+/H abundance ratio of a few E-8 suggests a cosmic ray ionization rate for atomic hydrogen of (0.6 - 2.4) E-16 s-1, in good agreement with estimates inferred previously for diffuse clouds in the Galactic disk from observations of interstellar H3+ and other species.

astro-ph.GA↗

arXiv2010

Excitation and Abundance of C3 in star forming cores:Herschel/HIFI observations of the sight-lines to W31C and W49N

We present spectrally resolved observations of triatomic carbon (C3) in several ro-vibrational transitions between the vibrational ground state and the low-energy nu2 bending mode at frequencies between 1654-1897 GHz along the sight-lines to the submillimeter continuum sources W31C and W49N, using Herschel's HIFI instrument. We detect C3 in absorption arising from the warm envelope surrounding the hot core, as indicated by the velocity peak position and shape of the line profile. The sensitivity does not allow to detect C3 absorption due to diffuse foreground clouds. From the column densities of the rotational levels in the vibrational ground state probed by the absorption we derive a rotation temperature (T_rot) of ~50--70 K, which is a good measure of the kinetic temperature of the absorbing gas, as radiative transitions within the vibrational ground state are forbidden. It is also in good agreement with the dust temperatures for W31C and W49N. Applying the partition function correction based on the derived T_rot, we get column densities N(C3) ~7-9x10^{14} cm^{-2} and abundance x(C3)~10^{-8} with respect to H2. For W31C, using a radiative transfer model including far-infrared pumping by the dust continuum and a temperature gradient within the source along the line of sight we find that a model with x(C3)=10^{-8}, T_kin=30-50 K, N(C3)=1.5 10^{15} cm^{-2} fits the observations reasonably well and provides parameters in very good agreement with the simple excitation analysis.

astro-ph.GA↗

arXiv2010

Strong absorption by interstellar hydrogen fluoride: Herschel/HIFI observations of the sight-line to G10.6-0.4 (W31C)

We report the detection of strong absorption by interstellar hydrogen fluoride along the sight-line to the submillimeter continuum source G10.6-0.4 (W31C). We have used Herschel's HIFI instrument, in dual beam switch mode, to observe the 1232.4763 GHz J=1-0 HF transition in the upper sideband of the Band 5a receiver. The resultant spectrum shows weak HF emission from G10.6-0.4 at LSR velocities in the range -10 to -3 km/s, accompanied by strong absorption by foreground material at LSR velocities in the range 15 to 50 km/s. The spectrum is similar to that of the 1113.3430 GHz 1(11)-0(00) transition of para-water, although at some frequencies the HF (hydrogen fluoride) optical depth clearly exceeds that of para-H2O. The optically-thick HF absorption that we have observed places a conservative lower limit of 1.6E+14 cm-2 on the HF column density along the sight-line to G10.6-0.4. Our lower limit on the HF abundance, 6E-9 relative to hydrogen nuclei, implies that hydrogen fluoride accounts for between ~ 30 and 100% of the fluorine nuclei in the gas phase along this sight-line. This observation corroborates theoretical predictions that - because the unique thermochemistry of fluorine permits the exothermic reaction of F atoms with molecular hydrogen - HF will be the dominant reservoir of interstellar fluorine under a wide range of conditions.

astro-ph.GA↗