arXiv subjects

P. Theulé

Publications and source records attributed to P. Theulé.

17 recordsLinked to original sources

arXiv2026

Multi-tracer exploration of molecular gas in main sequence galaxies at z~4.5

Molecular gas masses in high-z galaxies are inferred from indirect tracers, whose respective reliability remains poorly constrained. In particular, the bright [CII] 158$μ$m line is now widely used as a molecular gas tracer at z>4, yet direct observational tests against CO remain scarce. We search for CO(4-3), CO(5-4), and [CI](1-0) lines in three of the most [CII]-luminous galaxies at z~4.5 from the ALPINE survey to assess the detectability of these lines in high-z main-sequence (MS) galaxies and to test the reliability of [CII] emission as a molecular gas tracer through the cross-comparison of molecular gas masses inferred from six tracers: CO(4-3), CO(5-4), [CI](1-0), [CII], dust continuum, and [CII]-based dynamical mass, adopting standard calibrations and conversion factors. We detect CO(4-3) and CO(5-4) lines at high significance in the near-solar metallicity galaxy DC873756, obtain a tentative CO(4-3) detection in the merging system DC818760, and detect no CO emission in the half-solar metallicity galaxy VC5110377875. [CI] remains undetected in all three galaxies. In DC873756 the molecular gas masses inferred from the six considered tracers agree within their uncertainties despite different systematics inherent to each tracer. The agreement suggests that, at least for some near-solar metallicity MS galaxies at z~4.5, the CO SLED and Milky Way CO-to-H2 conversion factor adopted for MS galaxies at cosmic noon remain applicable and that mid-J CO transitions trace a substantial fraction of the molecular gas reservoir. The CO non-detection in VC5110377875 is consistent with the reduced CO detectability expected at lower metallicities. In DC818760 we find an inconsistency between the [CII]-based molecular gas mass and masses derived from the other tracers, indicating a [CII] excess possibly reflecting enhanced emission from shocks and/or diffuse ionized gas in merger-driven conditions.

astro-ph.GA↗

arXiv2026

Broadband spectroscopy of astrophysical ice analogues: IV. Optical constants of N$_2$ ice in the terahertz and mid-infrared ranges

Context. Understanding the optical properties of astrophysical ices is crucial for modeling dust continuum emission and radiative transfer in cold, dense interstellar environments. Molecular nitrogen (N$_2$), a major nitrogen reservoir in protoplanetary disks, plays a key role in nitrogen chemistry, yet the lack of direct terahertz (THz)--infrared (IR) optical constants for N$_2$ ice introduces uncertainties in radiative transfer models, snowline locations, and disk mass estimates. Aims. We present direct measurements of the optical properties of N$_2$ ice over a broad THz--IR spectral range using terahertz pulsed spectroscopy (TPS) and Fourier-transform infrared spectroscopy (FTIR), supported by density functional theory (DFT) calculations and comparison with literature data. Methods. N$_2$ ice was grown at cryogenic temperatures by gas-phase deposition onto a cold silicon window. The THz complex refractive index was directly reconstructed from TPS data, while the IR response was derived from FTIR measurements using Kramers--Kronig relations. The optical response was parameterized with a Lorentz dielectric model and validated by DFT calculations. Results. The complex refractive index of N$_2$ ice is quantified from $ν= 0.3$--$16$~THz ($λ= 1$~mm--$18.75~μ$m). Resonant absorption peaks at $ν_\mathrm{L} = 1.47$ and $2.13$~THz with damping constants $γ_\mathrm{L} = 0.03$ and $0.22$~THz are attributed to optically active phonons of the $α$-N$_2$ crystal. Conclusions. We provide a complete set of the THz--IR optical constants for \ce{N2} ice by combining TPS and FTIR spectroscopy. Our results have implications for future observational and modeling studies of protoplanetary disk evolution and planet formation.

astro-ph.EP↗

arXiv2024

Comprehensive laboratory constraints on thermal desorption of interstellar ice analogues

To explain grain growth and destruction in warm media, ice mantle formation and sublimation in cold media, and gas line emission spectroscopy, astrochemical models must mimic the gas--solid abundance ratio. Ice-sublimation mechanisms determine the position of snow lines and the nature of gas emitted by and locked inside planetary bodies in star-forming regions. To interpret observations from the interplanetary and extragalactic interstellar mediums, gas phase abundances must be modelled correctly. This study presents comprehensive thermal desorption data for interstellar ice analogues, aiming to refine astrochemical models by generating a set of benchmarks to evaluate both the kinetics and thermodynamics in astrochemical models. Our experiments focused on temperature-programmed desorption of pure and mixed ices, including Ar, CO, CO2, NH3, CH3OH, and H2O, under ultrahigh vacuum (1 x 10^-10 hPa) and low temperatures (10 K). Each experiment includes the experimental parameters, ice desorption kinetics for pure species, and the desorption yield (gas--solid ratio) for ice mixtures. From the desorption yields, we find common trends in the trapping of molecules when their abundance is compared to water: compact amorphous water ices are capable of trapping up to 20 % of volatiles (Ar, CO, and CO2), ~ 3 % of CH3OH, and ~ 5% NH3 in relation to the water content within the ice matrix; ammonium formate is not trapped in the water ice films, and compact amorphous water ice formed in situ has similar trapping capabilities to a compact amorphous water ice deposited using molecular beams. Our results highlight the limited trapping capacity of compact amorphous water ice for gases, crucial for understanding the formation of interstellar complex organic molecules.

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arXiv2023

The ALMA-ALPINE [CII] survey: Kennicutt-Schmidt relation in four massive main-sequence galaxies at z~4.5

The Kennicutt-Schmidt (KS) relation between the gas and the star formation rate (SFR) surface density ($Σ_{\rm gas}$-$Σ_{\rm SFR}$) is essential to understand star formation processes in galaxies. So far, it has been measured up to z~2.5 in main-sequence galaxies. In this letter, we aim to put constraints at z~4.5 using a sample of four massive main-sequence galaxies observed by ALMA at high resolution. We obtained ~0.3"-resolution [CII] and continuum maps of our objects, which we then converted into gas and obscured SFR surface density maps. In addition, we produced unobscured SFR surface density maps by convolving Hubble ancillary data in the rest-frame UV. We then derived the average $Σ_{\rm SFR}$ in various $Σ_{\rm gas}$ bins, and estimated the uncertainties using a Monte Carlo sampling. Our galaxy sample follows the KS relation measured in main-sequence galaxies at lower redshift and is slightly lower than predictions from simulations. Our data points probe the high end both in terms of $Σ_{\rm gas}$ and $Σ_{\rm gas}$, and gas depletion timescales (285-843 Myr) remain similar to z~2 objects. However, three of our objects are clearly morphologically disturbed, and we could have expected shorter gas depletion timescales (~100 Myr) similar to merger-driven starbursts at lower redshifts. This suggests that the mechanisms triggering starbursts at high redshift may be different than in the low- and intermediate-z Universe.

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arXiv2023

Observations of neutral carbon in 29 high-z lensed dusty star forming galaxies and the comparison of gas mass tracers

The nature and evolution of high-redshift dusty star-forming galaxies (high-z DSFGs) remain an open question. Their massive gas reservoirs play an important role in driving the intense star-formation rates hosted in these galaxies. We aim to estimate the molecular gas content of high-z DSFGs by using various gas mass tracers such as the [CI], CO, [CII] emission lines and the dust content. These tracers need to be well calibrated as they are all limited by uncertainties on factors such as aCO, XCI, aCII and GDR, thereby affecting the determination of the gas mass accurately. The main goal of our work is to check the consistency between the gas mass tracers and cross-calibrate the uncertain factors. We observe the two [CI] line transitions for 29 SPT-SMGs with the ALMA-ACA. Additionally, we also present new APEX observations of [CII] line for 9 of these galaxies. We find a nearly linear relation between the infrared luminosity and [CI] luminosity if we fit the starbursts and main-sequence galaxies separately. We measure a median [CI]-derived excitation temperature of 34.5+/-2.1 K. We probe the properties of the interstellar medium (ISM) such as density and radiation field intensity using [CI] to mid- or high-J CO lines and [CI] to infrared luminosity ratio, and find similar values to the SMG populations in literature. Finally, the gas masses estimated from [CI], CO, dust, and [CII] do not exhibit any significant trend with the infrared luminosity or the dust temperature. We provide the various cross-calibrations between these tracers. Our study confirms that [CI] is a suitable tracer of the molecular gas content, and shows an overall agreement between all the classical gas tracers used at high redshift. However, their absolute calibration and thus the gas depletion timescale measurements remain uncertain.

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arXiv2022

Broadband spectroscopy of astrophysical ice analogues: II. Optical constants of CO and CO$_2$ ices in the terahertz and infrared ranges

Context: Broadband optical constants of astrophysical ice analogues in the infrared (IR) and terahertz (THz) ranges are required for modeling the dust continuum emission and radiative transfer in dense and cold regions, where thick icy mantles are formed on the surface of dust grains. Aims: In this paper, the THz time-domain spectroscopy (TDS) and the Fourier-transform IR spectroscopy (FTIR) are combined to study optical constants of CO and CO$_2$ ices in the broad THz-IR spectral range. Methods: The measured ices are grown at cryogenic temperatures by gas deposition on a cold Si window. A method to quantify the broadband THz-IR optical constants of ices is developed based on the direct reconstruction of the complex refractive index of ices in the THz range from the TDS data, and the use of the Kramers-Kronig relation in the IR range for the reconstruction from the FTIR data. Uncertainties of the Kramers-Kronig relation are eliminated by merging the THz and IR spectra. The reconstructed THz-IR response is then analyzed using classical models of complex dielectric permittivity. Results: The complex refractive index of CO and CO$_2$ ices deposited at the temperature of $28$ K is obtained in the range of 0.3--12.0 THz. Based on the measured dielectric constants, opacities of the astrophysical dust with CO and CO$_2$ icy mantles are computed. Conclusions: The developed method can be used for a model-independent reconstruction of optical constants of various astrophysical ice analogs in a broad THz-IR range. Such data can provide important benchmarks to interpret the broadband observations from the existing and future ground-based facilities and space telescopes. The reported results will be useful to model sources that show a drastic molecular freeze-out, such as central regions of prestellar cores and mid-planes of protoplanetary disks, as well as CO and CO$_2$ snow lines in disks.

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arXiv2022

Mass ejection and time variability in protostellar outflows: Cep E. SOLIS XVI

Protostellar jets are an important agent of star formation feedback, tightly connected with the mass-accretion process. The history of jet formation and mass-ejection provides constraints on the mass accretion history and the nature of the driving source. We want to characterize the time-variability of the mass-ejection phenomena at work in the Class 0 protostellar phase, in order to better understand the dynamics of the outflowing gas and bring more constraints on the origin of the jet chemical composition and the mass-accretion history. We have observed the emission of the CO 2-1 and SO N_J=5_4-4_3 rotational transitions with NOEMA, towards the intermediate-mass Class 0 protostellar system Cep E. The CO high-velocity jet emission reveals a central component associated with high-velocity molecular knots, also detected in SO, surrounded by a collimated layer of entrained gas. The gas layer appears to accelerate along the main axis over a length scale delta_0 ~700 au, while its diameter gradually increases up to several 1000au at 2000au from the protostar. The jet is fragmented into 18 knots of mass ~10^-3 Msun, unevenly distributed between the northern and southern lobes, with velocity variations up to 15 km/s close to the protostar, well below the jet terminal velocities. The knot interval distribution is approximately bimodal with a scale of ~50-80yr close to the protostar and ~150-200yr at larger distances >12". The mass-loss rates derived from knot masses are overall steady, with values of 2.7x10^-5 Msun/yr (8.9x10^-6 Msun/yr) in the northern (southern) lobe. The interaction of the ambient protostellar material with high-velocity knots drives the formation of a molecular layer around the jet, which accounts for the higher mass-loss rate in the north. The jet dynamics are well accounted for by a simple precession model with a period of 2000yr and a mass-ejection period of 55yr.

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arXiv2022

High resolution spectral imaging of CO(7-6), [CI](2-1) and continuum of three high-z lensed dusty star-forming galaxies using ALMA

High-redshift dusty star-forming galaxies with very high star formation rates (500 -- 3000 M$_{\odot}$ yr$^{-1}$) are key to understanding the formation of the most extreme galaxies in the early Universe. Characterising the gas reservoir of these systems can reveal the driving factor behind the high star formation. Using molecular gas tracers like high-J CO lines, neutral carbon lines and the dust continuum, we can estimate the gas density and radiation field intensity in their interstellar media. In this paper, we present high resolution ($\sim$0.4$^{\prime\prime}$) observations of CO(7-6), [CI](2-1) and dust continuum of 3 lensed galaxies from the SPT-SMG sample at $z\sim$ 3 with the Atacama Large Millimeter/submillimeter Array. Our sources have high intrinsic star-formation rates ($>$850 M$_{\odot}$yr$^{-1}$) and rather short depletion timescales ($<$100 Myr). Based on the L$_{[\rm CI](2-1)}$/L$_{\rm CO(7-6)}$ and L$_{[\rm CI](2-1)}$/L$_{\rm IR}$ ratios, our galaxy sample has similar radiation field intensities and gas densities compared to other submillimetre galaxies. We perform visibility-based lens modelling on these objects to reconstruct the kinematics in the source plane. We find that the cold gas masses of the sources are compatible with simple dynamical mass estimates using ULIRG-like values of the CO-H$_2$ conversion factor $α_{\rm CO}$ but not Milky Way-like values. We find diverse source kinematics in our sample: SPT0103-45 and SPT2147-50 are likely rotating disks while SPT2357-51 is possibly a major merger. The analysis presented in the paper could be extended to a larger sample to determine better statistics of morphologies and interstellar medium properties of high-$z$ dusty star-forming galaxies.

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arXiv2021

Fitting spectral energy distributions of FMOS-COSMOS emission-line galaxies at z$\sim$1.6: Star formation rates, dust attenuation, and [OIII]$λ$5007 emission-line luminosities

We perform SED fitting analysis on a COSMOS sample covering UV-to-FIR wavelengths with emission lines from the FMOS survey. The sample of 182 objects with H$α$ and [OIII]$\lambda5007$ emission spans over a range of $1.40<\rm{z}<1.68$. We obtain robust estimates of stellar mass ($10^{9.5}-10^{11.5}~\rm{M_\odot}$) and SFR ($10^1-10^3~\rm{M_\odot}~\rm{yr}^{-1}$) from the Bayesian analysis with CIGALE fitting continuum photometry and H$α$. We obtain a median attenuation of A$_\rm{Hα}=1.16\pm0.19$ mag and A$_\rm{[OIII]}=1.41\pm0.22$ mag. H$α$ and [OIII]$\lambda5007$ attenuations are found to increase with stellar mass, confirming previous findings. A difference of $57$% in the attenuation experienced by emission lines and continuum is found in agreement with the lines being more attenuated than the continuum. New CLOUDY HII-region models in CIGALE enable good fits of H$α$, H$β$, [OIII]$\lambda5007$ emission lines with differences smaller than $0.2$ dex. Fitting [NII]$\lambda6584$ line is challenging due to well-known discrepancies in the locus of galaxies in the BPT diagram at intermediate redshifts. We find a positive correlation for SFR and dust-corrected L$_\rm{[OIII]\lambda5007}$ and we derive the linear relation $\log_{10}\rm{(SFR/\rm{M}_\odot~\rm{yr}^{-1})}=\log_{10} (\rm{L}_{[\rm{OIII]}}/\rm{ergs~s^{-1}})-(41.20\pm0.02)$. Leaving the slope as a free parameter leads to $\log_{10}\rm{(SFR/\rm{M}_\odot~\rm{yr}^{-1})}=(0.83\pm0.06)\log_{10}(\rm{L}_{[\rm{OIII]}}/\rm{ergs~s^{-1}})-(34.01\pm2.63)$. Gas-phase metallicity and ionization parameter variations account for a $0.24$ dex and $1.1$ dex of the dispersion, respectively. An average value of $\log\rm{U}\approx-2.85$ is measured for this sample. Including HII-region models to fit simultaneously photometry and emission line fluxes are paramount to analyze future data from surveys such as MOONS and PFS.

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arXiv2021

Polar dust obscuration in broad-line active galaxies from the XMM-XXL field

Dust is observed in the polar regions of nearby AGN and it is known to contribute substantially to their mid-IR emission and to the obscuration of their UV to optical emission. We selected a sample of 1275 BLAGN in the XMM-XXL field, with optical to infrared photometric data. These AGN are seen along their polar direction and we expect a maximal impact of dust located around the poles when it is present. We used X-CIGALE, which introduces a dust component to account for obscuration along the polar directions, modeled as a foreground screen, and an extinction curve that is chosen as it steepens significantly at short wavelengths or is much grayer. By comparing the results of different fits, we are able to define subsamples of sources with positive statistical evidence in favor of or against polar obscuration and described using the gray or steep extinction curve. We find a similar fraction of sources with positive evidence for and against polar dust. Applying statistical corrections, we estimate that half of our sample could contain polar dust and among them, 60% exhibit a steep extinction curve and 40% a flat extinction curve; although these latter percentages are found to depend on the adopted extinction curves. The obscuration in the V-band is not found to correlate with the X-ray column density, while A_V/N_H ratios span a large range of values and higher dust temperatures are found with the flat, rather than with the steep extinction curve. Ignoring this polar dust component in the fit of the spectral energy distribution of these composite systems leads to an overestimation of the stellar contribution. A single fit with a polar dust component described with an SMC extinction curve efficiently overcomes this issue but it fails at identifying all the AGN with polar dust obscuration.

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arXiv2021

Ammonia snow-lines and ammonium salts desorption

Context. The nitrogen reservoir in planetary systems is a long standing problem. Part of the N-bearing molecules is probably incorporated into the ice bulk during the cold phases of the stellar evolution, and may be gradually released into the gas phase when the ice is heated, such as in active comets. The chemical nature of the N-reservoir should greatly influence how, when and in what form N returns to the gas phase, or is incorporated into the refractory material forming planetary bodies. Aims. We present the study the thermal desorption of two ammonium salts: ammonium formate and ammonium acetate from a gold surface and from a water ice substrate. Methods. Temperature-programmed desorption experiments and Fourier transform infrared reflection spectroscopy were conducted to investigate the desorption behavior of ammonium salts. Results. Ammonium salts are semi-volatile species releasing neutral species as major components upon desorption, that is ammonia and the corresponding organic acid (HCOOH and CH3COOH), at temperatures higher than the temperature of thermal desorption of water ice. Their desorption follows a first-order Wigner-Polanyi law. We find the first order kinetic parameters A = 7.7 $\pm$ 0.6 $\times$ 10$^{15}$ s$^{-1}$ and E$_{bind}$ = 68.9 $\pm$ 0.1 kJ~mol$^{-1}$ for ammonium formate and A = 3.0 $\pm$ 0.4 $\times$ 10$^{20}$ s$^{-1}$ and E$_{bind}$ = 83.0 $\pm$ 0.2 kJ~mol$^{-1}$ for ammonium acetate. The presence of a water ice substrate does not influence the desorption kinetics. Ammonia molecules locked in salts desorb as neutral molecules at temperatures much higher than previously expected that are usually attributed to refractory materials. Conclusions. Ammonia snow-line has a smaller radius than the water snow-line. As a result, the NH3/H2O ratio content in solar system bodies can be a hint as to where they formed and subsequently migrated.

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arXiv2020

Ammonium salts are a reservoir of nitrogen on a cometary nucleus and possibly on some asteroids

The measured nitrogen-to-carbon ratio in comets is lower than for the Sun, a discrepancy which could be alleviated if there is an unknown reservoir of nitrogen in comets. The nucleus of comet 67P/Churyumov-Gerasimenko exhibits an unidentified broad spectral reflectance feature around 3.2 micrometers, which is ubiquitous across its surface. On the basis of laboratory experiments, we attribute this absorption band to ammonium salts mixed with dust on the surface. The depth of the band indicates that semivolatile ammonium salts are a substantial reservoir of nitrogen in the comet, potentially dominating over refractory organic matter and more volatile species. Similar absorption features appear in the spectra of some asteroids, implying a compositional link between asteroids, comets, and the parent interstellar cloud.

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arXiv2020

Seeds of Life in Space (SOLIS).VII. Discovery of a cold dense methanol blob toward the L1521F VeLLO system

The SOLIS (Seeds Of Life In Space) IRAM/NOEMA Large Program aims at studying a set of crucial complex organic molecules in a sample of sources, with well-known physical structure, covering the various phases of Solar-type star formation. One representative object of the transition from the prestellar core to the protostar phases has been observed toward the Very Low Luminosity Object (VeLLO) called L1521F. This type of source is important to study to make the link between prestellar cores and Class 0 sources and also to constrain the chemical evolution during the process of star formation. Two frequency windows (81.6-82.6 GHz and 96.65-97.65 GHz) were used to observe the emission from several complex organics toward the L1521F VeLLO. Only 2 transitions of methanol (A+, E2) have been detected in the narrow window centered at 96.7 GHz (with an upper limit on E1) in a very compact emission blob (~7'' corresponding to ~1000au) toward the NE of the L1521F protostar. The CS 2-1 transition is also detected within the WideX bandwidth. Consistently, with what has been found in prestellar cores, the methanol emission appears ~1000au away from the dust peak. The location of the methanol blob coincides with one of the filaments previously reported in the literature. The Tex of the gas inferred from methanol is (10$\pm$2) K, while the H2 gas density (estimated from the detected CS 2-1 emission and previous CS 5-4 ALMA obs.) is a factor >25 higher than the density in the surrounding environment (n(H2) >10$^{7}$ cm$^{-3}$). From its compactness, low excitation temperature and high gas density, we suggest that the methanol emission detected with NOEMA is either a cold and dense shock-induced blob, recently formed ($\leq$ few hundred years) by infalling gas or a cold and dense fragment that may have just been formed as a result of the intense gas dynamics found within the L1521F VeLLO system.

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arXiv2018

SOLIS IV. Hydrocarbons in the OMC-2 FIR 4 region, a probe of energetic particle irradiation of the region

We report new interferometric images of cyclopropenylidene, c-C$_3$H$_2$, towards the young protocluster OMC-2 FIR\,4. The observations were performed at 82 and 85 GHz with the NOrthern Extended Millimeter Array (NOEMA) as part of the project Seeds Of Life In Space (SOLIS). In addition, IRAM-30m data observations were used to investigate the physical structure of OMC-2 FIR\,4. We find that the c-C$_3$H$_2$ gas emits from the same region where previous SOLIS observations showed bright HC$_5$N emission. From a non-LTE analysis of the IRAM-30m data, the c-C$_3$H$_2$ gas has an average temperature of $\sim$40K, a H$_2$ density of $\sim$3$\times$10$^{5}$~cm$^{-3}$, and a c-C$_3$H$_2$ abundance relative to H$_2$ of ($7\pm1$)$\times$10$^{-12}$. In addition, the NOEMA observations provide no sign of significant c-C$_3$H$_2$ excitation temperature gradients across the region (about 3-4 beams), with T$_{ex}$ in the range 8$\pm$3 up to 16$\pm$7K. We thus infer that our observations are inconsistent with a physical interaction of the OMC-2 FIR\,4 envelope with the outflow arising from OMC-2 FIR\,3, as claimed by previous studies. The comparison of the measured c-C$_3$H$_2$ abundance with the predictions from an astrochemical PDR model indicates that OMC-2 FIR\,4 is irradiated by a FUV field $\sim$1000 times larger than the interstellar one, and by a flux of ionising particles $\sim$4000 times larger than the canonical value of $1\times10^{-17}$~s$^{-1}$ from the Galaxy cosmic rays, which is consistent with our previous HC$_5$N observations. This provides an important and independent confirmation of other studies that one or more sources inside the OMC-2 FIR\,4 region emit energetic ($\geq10$~MeV) particles.

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arXiv2017

Seeds of Life in Space (SOLIS) III. Formamide in protostellar shocks: evidence for gas-phase formation

Context: Modern versions of the Miller-Urey experiment claim that formamide (NH$_2$CHO) could be the starting point for the formation of metabolic and genetic macromolecules. Intriguingly, formamide is indeed observed in regions forming Solar-type stars as well as in external galaxies. Aims: How NH$_2$CHO is formed has been a puzzle for decades: our goal is to contribute to the hotly debated question of whether formamide is mostly formed via gas-phase or grain surface chemistry. Methods: We used the NOEMA interferometer to image NH$_2$CHO towards the L1157-B1 blue-shifted shock, a well known interstellar laboratory, to study how the components of dust mantles and cores released into the gas phase triggers the formation of formamide. Results: We report the first spatially resolved image (size $\sim$ 9", $\sim$ 2300 AU) of formamide emission in a shocked region around a Sun-like protostar: the line profiles are blueshifted and have a FWHM $\simeq$ 5 km s$^{-1}$. A column density of $N_{\rm NH_2CHO}$ = 8 $\times$ 10$^{12}$ cm$^{-1}$, and an abundance (with respect to H-nuclei) of 4 $\times$ 10$^{-9}$ are derived. We show a spatial segregation of formamide with respect to other organic species. Our observations, coupled with a chemical modelling analysis, indicate that the formamide observed in L1157-B1 is formed by gas-phase chemical process, and not on grain surfaces as previously suggested. Conclusions: The SOLIS interferometric observations of formamide provide direct evidence that this potentially crucial brick of life is efficiently formed in the gas-phase around Sun-like protostars.

astro-ph.EP↗

arXiv2017

SOLIS II. Carbon-chain growth in the Solar-type protocluster OMC2-FIR4

The interstellar delivery of carbon atoms locked into molecules might be one of the key ingredients for the emergence of life. Cyanopolyynes are carbon chains delimited at their two extremities by an atom of hydrogen and a cyano group, so that they might be excellent reservoirs of carbon. The simplest member, HC3N, is ubiquitous in the galactic interstellar medium and found also in external galaxies. Thus, understanding the growth of cyanopolyynes in regions forming stars similar to our Sun, and what affects it, is particularly relevant. In the framework of the IRAM/NOEMA Large Program SOLIS (Seeds Of Life In Space), we have obtained a map of two cyanopolyynes, HC3N and HC5N, in the protocluster OMC2-FIR4. Because our Sun is thought to be born in a rich cluster, OMC2-FIR4 is one of the closest and best known representatives of the environment in which the Sun may have been born. We find a HC3N/HC5N abundance ratio across the source in the range ~ 1 - 30, with the smallest values (< 10) in FIR5 and in the Eastern region of FIR4. The ratios < 10 can be reproduced by chemical models only if: (1) the cosmic-ray ionisation rate $ζ$ is ~ $4 \times 10^{-14}$ s$^{-1}$; (2) the gaseous elemental ratio C/O is close to unity; (3) O and C are largely depleted. The large $ζ$ is comparable to that measured in FIR4 by previous works and was interpreted as due to a flux of energetic (> 10 MeV) particles from embedded sources. We suggest that these sources could lie East of FIR4 and FIR5. A temperature gradient across FIR4, with T decreasing by about 10 K, could also explain the observed change in the HC3N/HC5N line ratio, without the need of a cosmic ray ionisation rate gradient. However, even in this case, a high constant cosmic-ray ionisation rate (of the order of $10^{-14}$ s$^{-1}$) is necessary to reproduce the observations.

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arXiv2015

Hydrogen isotope exchanges between water and methanol in interstellar ices

The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is predicted to be equal to 3 by standard grain chemistry models, is much larger (~20) in low-mass hot corinos and significantly lower (~1) in high-mass hot cores. This dichotomy in methanol deuteration between low-mass and massive protostars is currently not understood. In this study, we report a simplified rate equation model of the deuterium chemistry occurring in the icy mantles of interstellar grains. We apply this model to the chemistry of hot corinos and hot cores, with IRAS 16293-2422 and the Orion~KL Compact Ridge as prototypes, respectively. The chemistry is based on a statistical initial deuteration at low temperature followed by a warm-up phase during which thermal hydrogen/deuterium (H/D) exchanges occur between water and methanol. The exchange kinetics is incorporated using laboratory data. The [CH2DOH]/[CH3OD] ratio is found to scale inversely with the D/H ratio of water, owing to the H/D exchange equilibrium between the hydroxyl (-OH) functional groups of methanol and water. Our model is able to reproduce the observed [CH2DOH]/[CH3OD] ratios provided that the primitive fractionation of water ice [HDO]/[H2O] is ~ 2% in IRAS 16293-2422 and ~0.6% in Orion~KL. We conclude that the molecular D/H ratios measured in hot cores may not be representative of the original mantles because molecules with exchangeable deuterium atoms can equilibrate with water ice during the warm-up phase.

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