arXiv subjects

Panayotis Lavvas

Publications and source records attributed to Panayotis Lavvas.

At least 19 recordsLinked to original sources

arXiv2026

Helium escape in context: Comparative signatures of four close-in exoplanets

Observations of escaping atmospheres on close-in exoplanets show a wide range in the strength and morphology of He I 10830 A and H I absorption. Scaling relations attempt to link the He I signal to XUV irradiation, mass loss, and bulk planetary parameters. We test these relations with a comparative analysis of HD209458b, HD189733b, HD149026b, and GJ1214b using a 1D hydrodynamic, multi-species, full-atmosphere escape model. For the benchmark HD209458b, our previously validated solution reproduces the observed He I and Ha transit depths without imposing composition constraints. HD189733b exhibits comparable He I depths, but the broadest reported profiles require ~12 km/s of additional non-thermal broadening, whereas more recent measurements are narrower, consistent with our predictions. For HD149026b, despite similar system properties, our model shows that higher gravity suppresses escape and enhances diffusive separation, depleting helium at high altitudes and yielding extremely weak He I absorption. For the sub-Neptune GJ1214b, H/He-only models overestimate He I absorption; including H2 and its ions (H2+, H3+, HeH+) lowers the escape rate and modifies the ion/electron balance, reducing the metastable helium densities. Compared against scaling relations, HD189733b observations and our HD149026b prediction fall below the trend, whereas some observations of HD209458b and GJ1214b are consistent; however, the observed transit depths are variable. Across all targets, we find diffusive separation of helium and hydrogen, which may explain why sub-solar He/H ratios are often required in simplified models. We conclude that interpreting He I and Ha absorption requires first-principles models that include self-consistent temperature and velocity profiles, multi-species transport, and molecular chemistry.

astro-ph.EP↗

arXiv2025

Using SOFIA's EXES to search for C$_6$H$_2$ and C$_4$N$_2$ in Titan's atmosphere

In Titan's atmosphere, the chemistry of small hydrocarbons and nitriles represent an important link from molecular species to the ubiquitous organic haze that gives Titan its characteristic yellow color. Here we present a new search for two previously undetected molecules, triacetylene (C$_{6}$H$_{2}$) and the gas phase dicyanoacetylene (C$_{4}$N$_{2}$), using the Echelon-Cross-Echelle Spectrograph (EXES) instrument aboard the SOFIA (Stratospheric Observatory For Infrared Astronomy) aircraft. We do not detect these two molecules but determine upper limits for their mixing ratios and column abundances. We find the $3\sigma$ upper limits on the uniform volume mixing ratio (VMR) above 100 km for C$_{6}$H$_{2}$ to be $4.3\times10^{-11}$ which is lower than the photochemical model predictions. This new upper limit suggests that the growth of linear molecules is inhibited. We also put a strict upper limit on the uniform VMR for gas phase C$_{4}$N$_{2}$ above 125 km to be $1.0\times10^{-10}$. This upper limit is well below the saturation mixing ratio at this altitude for C$_{4}$N$_{2}$ and greatly limits the feasibility of C$_{4}$N$_{2}$ forming ice from condensation.

astro-ph.EP↗

arXiv2025

Hydrocarbon Hazes on Temperate sub-Neptune K2-18b supported by data from the James Webb Space Telescope

K2-18b, a sub-Neptune orbiting in the habitable zone of an M dwarf, has attracted significant interest following observations with the Hubble Space Telescope (HST) and, more recently, with the James Webb Space Telescope (JWST), which reveal detectable atmospheric features across the near- and mid-infrared. Using free-chemistry Bayesian retrievals, we investigate whether hydrocarbon hazes can explain the apparent mismatch of spectral feature amplitudes between the JWST NIRISS/NIRSpec and MIRI LRS datasets. We additionally assess the impact of stellar parameter uncertainties on the derived bulk properties of the planet and explore how planetary mass uncertainties affect atmospheric retrievals. We find that hazy scenarios can reproduce the combined JWST spectrum and provide a consistent explanation for the reduced NIRISS/NIRSpec feature amplitudes relative to the stronger MIRI features. Across all retrievals, the atmosphere remains consistent with an H$_2$-dominated sub-Neptune, with CH$_4$ and CO$_2$ as the dominant absorbers. Our hazy models retrieve systematically lower molecular abundances compared to haze-free models, reflecting the degeneracy between haze opacity and mean molecular weight. In addition, we identify strong degeneracies between planetary mass, temperature, and mean molecular weight. The retrieved planetary mass is particularly poorly constrained, with $2\sigma$ uncertainties reaching up to $\sim71\%$. We demonstrate that different mass assumptions can significantly bias the inferred atmospheric properties, with higher masses favouring warmer and lower mean molecular weight atmospheres. Breaking these degeneracies will require improved stellar characterisation to obtain more precise mass measurements. More laboratory-focused studies and future JWST observations are essential for interpreting these temperate sub-Neptune atmospheres.

astro-ph.EP↗

arXiv2025

On the synergetic use of Ariel and JWST for exoplanet atmospheric science

This paper explores the potential for strategic synergies between the JWST and the Ariel telescopes, two flagship observatories poised to revolutionise the study of exoplanet atmospheres. Both telescopes have the potential to address common fundamental questions about exoplanets-especially concerning their nature and origins-and serve a growing scientific community. With their operations now anticipated to overlap, starting from 2030, there is a unique opportunity to enhance the scientific outputs of both observatories through coordinated efforts. In this report, authored by the Ariel-JWST Synergy Working Group, part of the Ariel Consortium Science Team, we summarise the capabilities of JWST and Ariel; we highlight their key differences, similarities, synergies, and distinctive strengths. Ariel is designed to conduct a broad survey of exoplanet atmospheres but remains highly flexible, allowing the mission to integrate insights from JWST's discoveries. Findings from JWST, including data from initiatives shaped by NASA's decadal survey priorities and community-driven research themes, will inform the development of Ariel's core survey strategy. Conversely, Ariel's ability to perform broad-wavelength coverage observations for bright targets provides complementary avenues for exoplanet researchers, particularly those interested in time-domain observations and large-scale atmospheric studies. This paper identifies key pathways for fostering JWST-Ariel synergies, many of which can be initiated even before Ariel's launch. Leveraging their complementary designs and scopes, JWST and Ariel can jointly address fundamental questions about the nature, formation, and evolution of exoplanets. Such strategic collaboration has the potential to maximise the scientific returns of both observatories and lay the foundation for future facilities in the roadmap to exoplanet exploration.

astro-ph.IM↗

arXiv2025

A Multi-Species Atmospheric Escape Model with Excited Hydrogen and Helium: Application to HD209458b

Atmospheric escape shapes exoplanet evolution and star-planet interactions, with He I 10830 \AA\ absorption serving as a key tracer of mass loss in hot gas giants. However, transit depths vary significantly across observed systems for reasons that remain poorly understood. HD209458b, the archetypal hot-Jupiter, exhibits relatively weak He I 10830 \AA\ and H$\alpha$ absorption, which has been interpreted as evidence for a high H/He ratio (98/2), possibly due to diffusive separation. To investigate this possibility and other processes that control these transit depths, we reassess excitation and de-excitation rates for metastable helium and explore the impact of diffusion processes, stellar activity, and tidal forces on the upper atmosphere and transit depths using a model framework spanning the whole atmosphere. Our model reproduces the observed He I transit depth and H$\alpha$ upper limit, showing strong diffusive separation. We match the observations assuming a photoelectron efficiency of 20-40\%, depending on the composition of the atmosphere, corresponding to mass-loss rates of $1.9-3\times10^{10}$ g/s. We find that the He I 10830 \AA\ transit depth is sensitive to both stellar activity and diffusion processes, while H$\alpha$ is largely unaffected due to its strong dependence on Lyman-$\alpha$ excitation. These differences may help explain the system-to-system scatter seen in population-level studies of the He I line. While He I data alone may not tightly constrain mass-loss rates or temperatures, they do confirm atmospheric escape and help narrow the viable parameter space when interpreted with physically motivated models. Simultaneous observations of He I, H$\alpha$, and stellar activity indicators provide powerful constraints on upper atmosphere dynamics and composition, even in the absence of full transmission spectra.

astro-ph.EP↗

arXiv2024

Atmospheric characterisation of GJ1214b from transit and eclipse observations

The atmospheric characterisation of GJ1214 b has so far remained uncertain due to the observed flatness of the transit spectra of this planet that is typically attributed to the presence of hazes or clouds in its atmosphere. Here we combine for the first time transit and eclipse observations obtained with JWST to benefit from both type of constraints and advance on the atmospheric characterisation of GJ1214 b. Our results reveal that photochemical hazes can be produced at high enough mass fluxes in the atmosphere of GJ1214 b to explain both type of observations. These hazes have a drastic impact on the atmospheric thermal structure, which has further ramifications on the emitted radiation of the planet, as well as, its Bond albedo. Clouds of KCL, NaCL and ZnS composition also form in this atmosphere but their opacity is too small to explain the observed flatness of the transit spectrum. We find that metallicities in the range 2000-3000x solar provide atmospheric structures that are closest to the observations for haze mass fluxes in the range of (1-3)x1E-11 g cm-2 s-1. Correspondingly the Bond albedo is within 10-20%. Moreover, sulfur photochemistry produces abundant OCS that has a detectable signature in the transit spectra and should be seaked for in future observations. Sulfur should also participate to the haze formation in this atmosphere, therefore optical properties of such compounds are needed.

astro-ph.EP↗

arXiv2023

Coupling haze and cloud microphysics in WASP-39b's atmosphere based on JWST observations

We present a study on the coupling of haze and clouds in the atmosphere of WASP-39b. We developed a cloud microphysics model simulating the formation of Na2S and MgSiO3 condensates over photochemical hazes in gas giant atmospheres. We apply this model to WASP-39b, recently observed with the JWST to study how these heterogeneous components may affect the transit spectrum. We simulate both morning and evening terminators independently and average their transit spectra. While MgSiO3 formation has negligible impact on the spectrum, Na2S condensates produce gray opacities in the water band, in agreement with HST and JWST observations. Moreover, the formation of Na2S on the morning side depletes the atmosphere of its sodium content, decreasing the strength of the Na line. Combining morning and evening profiles results in a good fit of the Na observations. These nominal results assume a small Na2S/haze contact angle (5.7{\deg}). Using a larger value (61{\deg}) reduces the cloud density and opacity, but the effect on the Na profile and spectral line remains identical. In addition, the presence of haze in the upper atmosphere reproduces the UV-visible slope observed in the HST and VLT data and contributes to the opacity between the water bands at wavelengths below 2 microns. The averaged spectra are rather insensitive to the variation of eddy diffusion and haze mass flux tested in this study, though the UV-visible slope, probing the haze layer above the clouds, is affected. Finally, our disequilibrium chemistry model, including photochemistry, reproduces the SO2 and CO2 absorption features observed.

astro-ph.EP↗

arXiv2023

Photochemical hazes dramatically alter temperature structure and atmospheric circulation in 3D simulations of hot Jupiters

Photochemical hazes are expected to form in hot Jupiter atmospheres and may explain the strong scattering slopes and muted spectral features observed in the transmission spectra of many hot Jupiters. Absorption and scattering by photochemical hazes have the potential to drastically alter temperature structure and atmospheric circulation of these planets but have previously been neglected in general circulation models (GCMs). We present GCM simulations of hot Jupiter HD 189733b that include photochemical hazes as a radiatively active tracer fully coupled to atmospheric dynamics. The influence of haze radiative feedback strongly depends on the assumed haze optical properties. For soot hazes, two distinct thermal inversions form, separated by a local temperature minimum around 10$^{-5}$ bar caused by upwelling on the dayside mixing air with low haze abundance upwards. The equatorial jet broadens and slows down. The horizontal distribution of hazes remains relatively similar to simulations with radiatively passive tracers. For Titan-type hazes, the equatorial jet accelerates and extends to much lower pressures, resulting in a dramatically different 3D distribution of hazes compared to radiatively passive or soot hazes. Further experimental and observational studies to constrain the optical properties of photochemical hazes will therefore be crucial for understanding the role of hazes in exoplanet atmospheres. In the dayside emission spectrum, for both types of hazes the amplitude of near-infrared features is reduced, while the emitted flux at longer wavelengths ($>$4 $\mu$m) increases. Haze radiative feedback leads to increased phase curve amplitudes in many infrared wavelength regions, mostly due to stronger dayside emission.

astro-ph.EP↗

arXiv2023

A hydrodynamic study of the escape of metal species and excited hydrogen from the atmosphere of the hot Jupiter WASP-121b

In the near-UV and optical transmission spectrum of the hot Jupiter WASP-121b, recent observations have detected strong absorption features of Mg, Fe, Ca, and H$\alpha$, extending outside of the planet's Roche lobe. Studying these atomic signatures can directly trace the escaping atmosphere and constrain the energy balance of the upper atmosphere. To understand these features, we introduce a detailed forward model by expanding the capability of a one-dimensional model of the upper atmosphere and hydrodynamic escape to include important processes of atomic metal species. The hydrodynamic model is coupled to a Ly$\alpha$ Monte Carlo radiative transfer calculation to simulate the excited hydrogen population and associated heating/ionization effects. Using this model, we interpret the detected atomic features in the transmission spectrum of WASP-121b and explore the impact of metals and excited hydrogen on its upper atmosphere. We demonstrate the use of multiple absorption lines to impose stronger constraints on the properties of the upper atmosphere than the analysis of a single transmission feature can provide. In addition, the model shows that line broadening due to atmospheric outflow driven by the Roche lobe overflow is necessary to explain the observed line widths and highlights the importance of the high mass-loss rate caused by the Roche lobe overflow that requires careful consideration of the structure of the lower and middle atmosphere. We also show that metal species and excited state hydrogen can play an important role in the thermal and ionization balance of ultra-hot Jupiter thermospheres.

astro-ph.EP↗

arXiv2023

A physically derived eddy parameterization for giant planet atmospheres with application on hot-Jupiter atmospheres

We present a parameterization for the eddy diffusion profile of gas giant exoplanets based on physical phenomena and we explore how the parameterized eddy profile impacts the chemical composition, the thermal structure, the haze microphysics, and the transit spectra of 8 hot-Jupiters. Our eddy parameterization depends on the planetary intrinsic temperature (T$_{int}$ ), we thus evaluate how the increase of this parameter to values higher than those typically used ($\sim$100K) impacts the atmospheric structure and composition. Our investigation demonstrates that despite the strong impact of T$_{int}$ on the chemical composition of the deep atmosphere, the upper atmosphere is not affected for T$_{eq}$ $>$ 1300 K owing to high altitude quench levels at these conditions. Below this threshold, however, the larger atmospheric temperatures produced by increasing T$_{int}$ affect the quenched chemical composition. Our parameterization depends on two parameters, the eddy magnitude at the radiative-convective boundary (K$_0$) and the corresponding magnitude at the homopause (K$_{top}$). We demonstrate that, when using common K$_0$ and K$_{top}$ values among most of the different planet cases studied, we derive transit spectra consistent with Hubble Space Telescope observations. Moreover, our simulations show that increasing the eddy profile enhances the photochemical production of haze particles and reduces their average radius, thus providing a steeper UV-Visible slope. Finally, we demonstrate for WASP-39b that the James Webb Space Telescope observations provide improved constraints for the hazes and clouds and we show that both components seem necessary to interpret the combined transit spectrum from HST and JWST observations.

astro-ph.EP↗

arXiv2022

Signatures of Strong Magnetization and Metal-Poor Atmosphere for a Neptune-Size Exoplanet

The magnetosphere of an exoplanet has yet to be unambiguously detected. Investigations of star-planet interaction and neutral atomic hydrogen absorption during transit to detect magnetic fields in hot Jupiters have been inconclusive, and interpretations of the transit absorption non-unique. In contrast, ionized species escaping a magnetized exoplanet, particularly from the polar caps, should populate the magnetosphere, allowing detection of different regions from the plasmasphere to the extended magnetotail, and characterization of the magnetic field producing them. Here, we report ultraviolet observations of HAT-P-11b, a low-mass (0.08 MJ) exoplanet showing strong, phase-extended transit absorption of neutral hydrogen (maximum and tail transit depths of 32 \pm 4%, 27 \pm 4%) and singly ionized carbon (15 \pm 4%, 12.5 \pm 4%). We show that the atmosphere should have less than six times the solar metallicity (at 200 bars), and the exoplanet must also have an extended magnetotail (1.8-3.1 AU). The HAT-P-11b equatorial magnetic field strength should be about 1-5 Gauss. Our panchromatic approach using ionized species to simultaneously derive metallicity and magnetic field strength can now constrain interior and dynamo models of exoplanets, with implications for formation and evolution scenarios.

astro-ph.EP↗

arXiv2022

A large range of haziness conditions in hot-Jupiter atmospheres

We present a study of photochemical hazes of exoplanet atmospheres based on a self-consistent model including haze microphysics, disequilibrium chemistry, and radiative feedbacks. We derive the haze properties required to match HST observations of ten hot-Jupiters. HAT-P-12b, HD-189733b, HD-209458b and WASP-6b require haze mass fluxes between 5x10$^{-15}$ and 9x10$^{-12} g.cm^{-2}.s^{-1}$ to match the observations. WASP-12b and WASP-19b with equilibrium temperatures above 2000 K are incompatible with the presence of haze and are better fitted by heavy metals. HAT-P-1b and WASP-31b do not show clear evidence for the presence of hazes with upper mass fluxes of 10$^{-15}$ and 10$^{-16}g.cm^{-2}.s^{-1}$, respectively, while WASP-17b and WASP-39b present an upper mass flux limit of 10$^{-16} g.cm^{-2}.s^{-1}$. We discuss the implications of the self-consistent model and we derive upper limits for the haze abundances based on photochemistry results. Our results suggest HCN as the main haze precursor up to 1300 K effective temperatures and CO above. Our derived haze mass fluxes based on the fit to the observations are consistent with the photochemistry with formation yields up to $\sim$6.4\%. Disequilibrium chemistry has negligible impact on the spectra considering the low resolution observations used but impacts the chemical composition and temperature profiles. We find that hazes produce hotter upper atmosphere temperatures with a detectable impact on the spectra. Clouds may have implications for interpreting the transit spectra of HD-209458b, WASP-31b and WASP-39b. Nevertheless, the presence of silicate and iron clouds is expected in all studied atmospheres except WASP-12b and WASP-19b.

astro-ph.EP↗

arXiv2022

UV Absorption by Silicate Cloud Precursors in Ultra-hot Jupiter WASP-178b

Aerosols have been found to be nearly ubiquitous in substellar atmospheres. The precise temperature at which these aerosols begin to form in exoplanets has yet to be observationally constrained. Theoretical models and observations of muted spectral features suggest that silicate clouds play an important role in exoplanets between at least 950 and 2,100 K. However, some giant planets are thought to be hot enough to avoid condensation altogether. Here, we present the near-UV transmission spectrum of an ultra-hot Jupiter, WASP-178b ($\sim$2,450~K), that exhibits significant NUV absorption. This short-wavelength absorption is among the largest spectral features ever observed in an exoplanet in terms of atmospheric scale heights. Bayesian retrievals indicate the presence of gaseous refractory species containing silicon and magnesium, which are the precursors to condensate clouds at lower temperatures. SiO in particular has not been detected in exoplanets before, but the presence of SiO in WASP-178b is consistent with theoretical expectation as the dominant Si-bearing species at high temperatures. These observations allow us to re-interpret previous observations of HAT-P-41b and WASP-121b that did not consider SiO to suggest that silicate cloud formation begins on exoplanets with equilibrium temperatures between 1,950 and 2,450~K.

astro-ph.EP↗

arXiv2022

Mass loss by atmospheric escape from extremely close-in planets

We explore atmospheric escape from close-in exoplanets with the highest mass loss rates. First, we locate the transition from stellar X-ray and UV-driven escape to rapid Roche lobe overflow, which occurs once the 10-100 nbar pressure level in the atmosphere reaches the Roche lobe. Planets enter this regime when the ratio of the substellar radius to the polar radius along the visible surface pressure level, that aligns with a surface of constant Roche potential, is X/Z~$\gtrsim$~1.2 for Jovian planets (Mp~$\gtrsim$~100 M$_{\Earth}$) and X/Z~$\gtrsim$~1.02 for sub-Jovian planets ($M_p \approx$~10--100 M$_{\Earth}$). Around a sun-like star, this regime applies to orbital periods of less than two days for planets with radii of about 3--14 R$_{\Earth}$. Our results agree with the properties of known transiting planets and can explain parts of the sub-Jovian desert in the population of known exoplanets. Second, we present detailed numerical simulations of atmospheric escape from a planet like Uranus or Neptune orbiting close to a sun-like star that support the results above and point to interesting qualitative differences between hot Jupiters and sub-Jovian planets. We find that hot Neptunes with solar metallicity hydrogen and helium envelopes have relatively more extended upper atmospheres than typical hot Jupiters, with a lower ionization fraction and higher abundances of escaping molecules. This is consistent with existing ultraviolet transit observations of warm Neptunes and it might provide a way to use future observations and models to distinguish solar metallicity atmospheres from higher metallicity atmospheres.

astro-ph.EP↗

arXiv2021

Science goals and new mission concepts for future exploration of Titan's atmosphere geology and habitability: Titan POlar Scout/orbitEr and In situ lake lander and DrONe explorer (POSEIDON)

In response to ESA Voyage 2050 announcement of opportunity, we propose an ambitious L-class mission to explore one of the most exciting bodies in the Solar System, Saturn largest moon Titan. Titan, a "world with two oceans", is an organic-rich body with interior-surface-atmosphere interactions that are comparable in complexity to the Earth. Titan is also one of the few places in the Solar System with habitability potential. Titan remarkable nature was only partly revealed by the Cassini-Huygens mission and still holds mysteries requiring a complete exploration using a variety of vehicles and instruments. The proposed mission concept POSEIDON (Titan POlar Scout/orbitEr and In situ lake lander DrONe explorer) would perform joint orbital and in situ investigations of Titan. It is designed to build on and exceed the scope and scientific/technological accomplishments of Cassini-Huygens, exploring Titan in ways that were not previously possible, in particular through full close-up and in situ coverage over long periods of time. In the proposed mission architecture, POSEIDON consists of two major elements: a spacecraft with a large set of instruments that would orbit Titan, preferably in a low-eccentricity polar orbit, and a suite of in situ investigation components, i.e. a lake lander, a "heavy" drone (possibly amphibious) and/or a fleet of mini-drones, dedicated to the exploration of the polar regions. The ideal arrival time at Titan would be slightly before the next northern Spring equinox (2039), as equinoxes are the most active periods to monitor still largely unknown atmospheric and surface seasonal changes. The exploration of Titan northern latitudes with an orbiter and in situ element(s) would be highly complementary with the upcoming NASA New Frontiers Dragonfly mission that will provide in situ exploration of Titan equatorial regions in the mid-2030s.

astro-ph.EP↗

arXiv2021

The near-UV transit of HD 189733b with the XMM-Newton Optical Monitor

We present analysis of XMM-Newton Optical Monitor observations in the near-ultraviolet of HD 189733, covering twenty primary transits of its hot Jupiter planet. The transit is clearly detected with both the UVW2 and UVM2 filters, and our fits to the data reveal transit depths in agreement with that observed optically. The measured depths correspond to radii of $1.059^{+0.046}_{-0.050}$ and $0.94^{+0.15}_{-0.17}$ times the optically-measured radius (1.187 R$_{\rm J}$ at 4950 Å) in the UVW2 and UVM2 bandpasses, respectively. We also find no statistically significant variation in the transit depth across the 8 year baseline of the observations. We rule out extended broadband absorption towards or beyond the Roche lobe at the wavelengths investigated, although observations with higher spectral resolution are required to determine if absorption out to those distances from the planet is present in individual near-UV lines.

astro-ph.EP↗

arXiv2021

Impact of photochemical hazes and gases on exoplanet atmospheric thermal structure

We investigate the impact of photochemical hazes and disequilibrium gases on the thermal structure of hot-Jupiters, using a detailed 1-D radiative-convective model. We find that the inclusion of photochemical hazes results in major heating of the upper and cooling of the lower atmosphere. Sulphur containing species, such as SH, S$_2$ and S$_3$ provide significant opacity in the middle atmosphere and lead to local heating near 1 mbar, while OH, CH, NH, and CN radicals produced by the photochemistry affect the thermal structure near 1 $μ$bar. Furthermore we show that the modifications on the thermal structure from photochemical gases and hazes can have important ramifications for the interpretation of transit observations. Specifically, our study for the hazy HD 189733 b shows that the hotter upper atmosphere resulting from the inclusion of photochemical haze opacity imposes an expansion of the atmosphere, thus a steeper transit signature in the UV-Visible part of the spectrum. In addition, the temperature changes in the photosphere also affect the secondary eclipse spectrum. For HD 209458 b we find that a small haze opacity could be present in this atmosphere, at pressures below 1 mbar, which could be a result of both photochemical hazes and condensates. Our results motivate the inclusion of radiative feedback from photochemical hazes in general circulation models for a proper evaluation of atmospheric dynamics.

astro-ph.EP↗

arXiv2020

Heavy Positive Ion Groups in Titan's Ionosphere from Cassini Plasma Spectrometer IBS Observations

Titan's ionosphere contains a plethora of hydrocarbons and nitrile cations and anions as measured by the Ion Neutral Mass Spectrometer and Cassini Plasma Spectrometer (CAPS) onboard the Cassini spacecraft. Data from the CAPS Ion Beam Spectrometer (IBS) sensor have been examined for five close encounters of Titan during 2009. The high relative velocity of Cassini with respect to the cold ions in Titan's ionosphere allows CAPS IBS to function as a mass spectrometer. Positive ion masses between 170 and 310 u/q are examined with ion mass groups identified between 170 and 275 u/q containing between 14 and 21 heavy (carbon/nitrogen/oxygen) atoms. These groups are the heaviest positive ion groups reported so far from the available in situ ion data at Titan. The ion group peaks are found to be consistent with masses associated with Polycyclic Aromatic Compounds (PAC), including Polycyclic Aromatic Hydrocarbon (PAH) and nitrogen-bearing polycyclic aromatic molecular ions. The ion group peak identifications are compared with previously proposed neutral PAHs and are found to be at similar masses, supporting a PAH interpretation. The spacing between the ion group peaks is also investigated, finding a spacing of 12 or 13 u/q indicating the addition of C or CH. Lastly, the occurrence of several ion groups is seen to vary across the five flybys studied, possibly relating to the varying solar radiation conditions observed across the flybys. These findings further the understanding between the low mass ions and the high mass negative ions, as well as with aerosol formation in Titan's atmosphere.

astro-ph.EP↗