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Panpan Zhou

Publications and source records attributed to Panpan Zhou.

11 recordsLinked to original sources

Building a physics-aware AI ecosystem for solid-state hydrogen storage materials

Hydrogen storage remains a central bottleneck for scalable hydrogen energy systems due to the multiscale and coupled nature of the thermodynamics, kinetics, and microstructural evolution of hydrogen storage materials (HSMs). Although artificial intelligence (AI) has accelerated materials discovery, current approaches remain constrained by fragmented data, limited physical consistency, and weak integration with experimental validation. Here, we propose a unified framework that integrates coherent data infrastructure, physics-grounded modeling, and AI-driven inverse design within a closed-loop discovery paradigm. By embedding physical constraints and experimental feedback, this approach enables adaptive, physically consistent optimization, thereby establishing a pathway toward autonomous, digital-twin-enabled discovery of HSMs.

cond-mat.mtrl-sci

Optimal intrinsic formation using exogenous systems

This paper investigates the intrinsic formation problem of a multi-agent system using an exogenous system. The problem is formulated as an intrinsic infinite time-horizon linear quadratic optimal control problem, namely, no formation error information is incorporated in the performance index. Convergence to the formation is achieved by utilizing an exogenous system, thus expanding the steady-state formation space of the system. For the forward problem, we provide the existence condition for a nonzero steady state and characterize the steady-state space. For the inverse problem, we design both the input matrix and the exogenous system so that the desired formation can be achieved. Finally, numerical simulations are provided to illustrate the effectiveness of the proposed results.

math.OC

A differential game approach to intrinsic encirclement control

This paper investigates the encirclement control problem involving two groups using a non-cooperative differential game approach. The active group seeks to chase and encircle the passive group, while the passive group responds by fleeing cooperatively and simultaneously encircling the active group. Instead of prescribing an expected radius or a predefined path for encirclement, we focus on the whole formation manifold of the desired relative configuration, two concentric circles, by allowing permutation, rotation, and translation of players. The desired relative configurations arise as the steady state resulting from Nash equilibrium strategies and are achieved in an intrinsic way by designing the interaction graphs and weight function of each edge. Furthermore, the asymptotic convergence to the desired manifold is guaranteed. Finally, numerical simulations demonstrate encirclement and counter-encirclement scenarios, verifying the effectiveness of our strategies.

math.OC

Nature-inspired dynamic control for pursuit-evasion of robots

The pursuit-evasion problem is widespread in nature, engineering, and societal applications. It is commonly observed in nature that predators often exhibit faster speeds than their prey but have less agile maneuverability. Over millions of years of evolution, animals have developed effective and efficient strategies for both pursuit and evasion. In this paper, we provide a dynamic framework for the pursuit-evasion problem of unicycle systems, drawing inspiration from nature. First, we address the scenario involving one pursuer and one evader by proposing an Alert-Turn control strategy, which consists of two efficient ingredients: a sudden turning maneuver and an alert condition for starting and maintaining the maneuver. We present and analyze the escape and capture results at two levels: a lower level of a single run and a higher level with respect to parameters' changes. In addition, we provide a theorem with sufficient conditions for capture. The Alert-Turn strategy is then extended to more complex scenarios involving multiple pursuers and evaders by integrating aggregation control laws and a target-changing mechanism. By adjusting a 'selfish parameter', the aggregation control commands produce various escape patterns of evaders: cooperative mode, selfish mode, as well as their combinations. The influence of the selfish parameter is quantified, and the effects of the number of pursuers and the target-changing mechanism are explored from a statistical perspective. Our findings align closely with observations in nature. Finally, the proposed control strategies are validated through numerical simulations that replicate some chasing behaviors of animals in nature.

eess.SY

Contest for system observability as an infinitely repeated game

This paper studies a system security problem in the context of observability based on a two-person noncooperative infinitely repeated game. Both the attacker and the defender have means to modify the dimension of the unobservable subspace, which is set as the value function. Utilizing tools from geometric control, we construct the best response sets considering one-step and two-step optimality respectively to maximize or minimize the value function. We establish a unified necessary-and-sufficient condition for Nash equilibrium that holds for both one-step and two-step optimizations. Our analysis further uncovers two evolutionary patterns, lock and loop modes, and shows an asymmetry between defense and attack. The defender can lock the game into equilibrium, whereas the attacker can disrupt it by sacrificing short-term utility for longer-term advantage. Six representative numerical examples corroborate the theoretical results and highlight the complexity of possible game outcomes.

math.OC

Electron pairing in the pseudogap state revealed by shot noise in copper-oxide junctions

In the quest to understand high-temperature superconductivity in copper oxides, a vigorous debate has been focused on the pseudogap - a partial gap that opens over portions of the Fermi surface in the 'normal' state above the bulk critical temperature ($T_{c}$). The pseudogap has been attributed to precursor superconductivity, to the existence of preformed pairs, or to competing orders such as charge-density waves. A direct determination of the charge of carriers as a function of temperature and bias could help resolve among these alternatives. Here, we report measurements of the shot noise of tunneling current in high-quality La$_{2-x}$Sr$_{x}$CuO$_{4}$/La$_{2}$CuO$_{4}$/La$_{2-x}$Sr$_{x}$CuO$_{4}$ (LSCO/LCO/LSCO) heterostructures fabricated using atomic-layer-by-layer molecular beam epitaxy, for several doping levels. The data delineate three distinct regions in the bias voltage-temperature ($V-T$) space. Well outside the superconducting gap region, the shot noise agrees quantitatively with independent tunneling of charge-e carriers. Deep within the gap, shot noise is greatly enhanced, reminiscent of multiple Andreev reflections. Starting above $T_{c}$ and extending to biases much larger than the gap, there is a broad region in which the noise substantially exceeds the expectations of single-charge tunneling, indicating pairing of carriers. Pairs are detectable deep into the pseudogap region of temperature and bias.

cond-mat.supr-con

Tunneling spectroscopy of c-axis epitaxial cuprate junctions

Atomically precise epitaxial structures are unique systems for tunneling spectroscopy that minimize extrinsic effects of disorder. We present a systematic tunneling spectroscopy study, over a broad doping, temperature, and bias range, in epitaxial c-axis La$_{2-x}$Sr$_{x}$CuO$_{4}$/La$_{2}$CuO$_{4}$/La$_{2-x}$Sr$_{x}$CuO$_{4}$ heterostructures. The behavior of these superconductor/insulator/superconductor (SIS) devices is unusual. Down to 20 mK there is complete suppression of c-axis Josephson critical current with a barrier of only 2 nm of La$_{2}$CuO$_{4}$, and the zero-bias conductance remains at 20-30% of the normal-state conductance, implying a substantial population of in-gap states. Tunneling spectra show greatly suppressed coherence peaks. As the temperature is raised, the superconducting gap fills in rather than closing at $T_{c}$. For all doping levels, the spectra show an inelastic tunneling feature at $\sim$ 80 meV, suppressed as $T$ exceeds $T_{c}$. These nominally simple epitaxial cuprate junctions deviate markedly from expectations based on the standard Bardeen-Cooper-Schrieffer (BCS) theory.

cond-mat.supr-con

c-axis pressure induced antiferromagnetic order in optimally P-doped BaFe2(As0.70P0.30)2 superconductor

Superconductivity in BaFe2(As1-xPx)2 iron pnictides emerges when its in-plane two-dimensional (2D) orthorhombic lattice distortion associated with nematic phase at Ts and three-dimensional (3D) collinear antiferromagnetic (AF) order at TN (Ts = TN) are gradually suppressed with increasing x, reaching optimal superconductivity around x = 0.30 with Tc $\approx$ 30 K. Here we show that a moderate uniaxial pressure along the c-axis in BaFe2(As0.70P0.30)2 spontaneously induces a 3D collinear AF order with TN = Ts > 30 K, while only slightly suppresses Tc. Although a ~ 400 MPa pressure compresses the c-axis lattice while expanding the in-plane lattice and increasing the nearest-neighbor Fe-Fe distance, it barely changes the average iron-pnictogen height in BaFe2(As0.70P0.30)2. Therefore, the pressure- induced AF order must arise from a strong in-plane magnetoelastic coupling, suggesting that the 2D nematic phase is a competing state with superconductivity.

cond-mat.supr-con

Potential Fluctuations at Low Temperatures in Mesoscopic-Scale SmTiO$_{3}$/SrTiO$_{3}$/SmTiO$_{3}$ Quantum Well Structures

Heterointerfaces of SrTiO$_{3}$ with other transition metal oxides make up an intriguing family of systems with a bounty of coexisting and competing physical orders. Some examples, such as LaAlO$_{3}$/SrTiO$_{3}$, support a high carrier density electron gas at the interface whose electronic properties are determined by a combination of lattice distortions, spin-orbit coupling, defects, and various regimes of magnetic and charge ordering. Here, we study electronic transport in mesoscale devices made with heterostructures of SrTiO$_{3}$ sandwiched between layers of SmTiO$_{3}$, in which the transport properties can be tuned from a regime of Fermi-liquid like resistivity ($ρ\sim T^{2}$) to a non-Fermi liquid ($ρ\sim T^{5/3}$) by controlling the SrTiO$_{3}$ thickness. In mesoscale devices at low temperatures, we find unexpected voltage fluctuations that grow in magnitude as $T$ is decreased below 20 K, are suppressed with increasing contact electrode size, and are independent of the drive current and contact spacing distance. Magnetoresistance fluctuations are also observed, which are reminiscent of universal conductance fluctuations but not entirely consistent with their conventional properties. Candidate explanations are considered, and a mechanism is suggested based on mesoscopic temporal fluctuations of the Seebeck coefficient. An improved understanding of charge transport in these model systems, especially their quantum coherent properties, may lead to insights into the nature of transport in strongly correlated materials that deviate from Fermi liquid theory.

cond-mat.mes-hall

Shot noise detection in hBN-based tunnel junctions

High quality Au/hBN/Au tunnel devices are fabricated using transferred atomically thin hexagonal boron nitride as the tunneling barrier. All tunnel junctions show tunneling resistance on the order of several k$Ω$/$μ$m$^{2}$. Ohmic I-V curves at small bias with no signs of resonances indicate the sparsity of defects. Tunneling current shot noise is measured in these devices, and the excess shot noise shows consistency with theoretical expectations. These results show that atomically thin hBN is an excellent tunnel barrier, especially for the study of shot noise properties, and this can enable the study of tunneling density of states and shot noise spectroscopy in more complex systems.

cond-mat.mes-hall

Thickness-Dependent and Magnetic-Field-Driven Suppression of Antiferromagnetic Order in Thin V$_{5}$S$_{8}$ Single Crystals

With materials approaching the 2d limit yielding many exciting systems with intriguing physical properties and promising technological functionalities, understanding and engineering magnetic order in nanoscale, layered materials is generating keen interest. One such material is V$_{5}$S$_{8}$, a metal with an antiferromagnetic ground state below the Néel temperature $T_{N} \sim$ 32 K and a prominent spin-flop signature in the magnetoresistance (MR) when $H||c \sim$ 4.2 T. Here we study nanoscale-thickness single crystals of V$_{5}$S$_{8}$, focusing on temperatures close to $T_{N}$ and the evolution of material properties in response to systematic reduction in crystal thickness. Transport measurements just below $T_{N}$ reveal magnetic hysteresis that we ascribe to a metamagnetic transition, the first-order magnetic field-driven breakdown of the ordered state. The reduction of crystal thickness to $\sim$ 10 nm coincides with systematic changes in the magnetic response: $T_{N}$ falls, implying that antiferromagnetism is suppressed; and while the spin-flop signature remains, the hysteresis disappears, implying that the metamagnetic transition becomes second order as the thickness approaches the 2d limit. This work demonstrates that single crystals of magnetic materials with nanometer thicknesses are promising systems for future studies of magnetism in reduced dimensionality and quantum phase transitions.

cond-mat.str-el