arXiv subjects

Paola Cappellaro

Publications and source records attributed to Paola Cappellaro.

At least 19 recordsLinked to original sources

arXiv2026

Control incompatibility in multiparameter quantum metrology

In practical applications like quantum sensing and quantum imaging, there is often a necessity to estimate multiple parameters simultaneously. Although the ultimate precision limits for single-parameter estimation are well established, the precision limit of multi-parameter estimation is much less understood. This is primarily due to the inherent incompatibility of the optimal strategies for the estimation of different parameters, particularly those pertaining to optimal control.In this study, we tackle the critical issue of control incompatibility in multi-parameter estimation by presenting explicit cases that expose this challenge. Our research not only pioneers the exploration of control incompatibility but also highlights its pivotal role in the field. Furthermore, our work offers valuable insights into how to minimize trade-offs induced by control incompatibility and enhance precision. This paves the way for future investigations into control strategies that enable optimal estimation of multiple parameters that are incompatible.

quant-ph↗

arXiv2026

Agentic AI for Scientific Reasoning in Autonomous Quantum Sensing Experiments

We implement an agentic AI workflow built around a large language model (LLM) agent for autonomous experiments with nitrogen-vacancy (NV) centers in diamond. NV centers are a widely used platform for quantum sensing, and the ability to control many measurements from a computer makes NV experiments a natural setting for autonomous workflows. We make two main contributions. First, we demonstrate an autonomous NV experiment workflow that combines persistent project records, quantitative calculation and data analysis tools, and deterministic experiment control. In one autonomous experiment, the agent selected a single NV center, calibrated its resonant frequency, measured $T_2^\ast$ with Ramsey measurements, and added a Carr--Purcell--Meiboom--Gill (CPMG) measurement to check a weak feature that could be related to nearby $^{13}\mathrm{C}$. Second, we introduce two offline benchmarks that evaluate the agent's reasoning separately from laboratory execution. We evaluated both benchmarks with GPT-5.4, GPT-5.5, and GPT-5.6 Sol. In the Ramsey checkpoint benchmark, greater reasoning effort generally improved recognition of a residual resonance calibration offset. By contrast, in the pulsed optically detected magnetic resonance (pODMR) data evaluation benchmark, pulse sequence information alone produced more false positive resonance judgments at higher reasoning effort. Requiring an expected signal calculation kept false positive rates low across all three models and reasoning settings. The results suggest a clear division of labor for autonomous experiments. The agent forms scientific hypotheses and uses quantitative tools to evaluate data, while deterministic code controls the hardware and enforces safety constraints.

quant-ph↗

arXiv2026

Strategic Plan for Neutral Atom Quantum Computation

We present a strategic plan for neutral atom quantum computation, bringing together hardware development and theory advancements to achieve the goal of practical quantum advantage. The concept of practical quantum advantage is defined, along with how to verify claims of advantage, and approaches to designing quantum algorithms that deliver practical advantage. Future directions for neutral atom quantum processor hardware are described: scaling-up system size, Qubit encodings and atomic platforms, going further below threshold with neutral-atom logical-qubit performance, continuous reloading of qubits, and fast readout. We also explore opportunities for scalable integrated photonic control technologies. Alongside hardware advancements, new developments in quantum error correction and compilation of quantum circuits are proposed. Finally, we examine the opportunity of networking multiple neutral atom quantum processors together to perform distributed quantum computing and overcome possible limitations of a single system.

quant-ph↗

arXiv2026

Entanglement transition in unitary system-bath dynamics

The evolution of a system coupled to baths is commonly described by a master equation that, in the long-time limit, yields a steady-state density matrix. However, when the same evolution is unraveled into quantum trajectories, it is possible to observe a transition in the scaling of entanglement within the system as the system-bath coupling increases - a phenomenon that is invisible in the trajectory-averaged reduced density matrix of the system. Here, we go beyond the paradigm of trajectories from master equations and explore whether a qualitatively analogous entanglement-scaling transition emerges in a single unitary evolution of the combined system-bath setup, without monitoring the dynamics of the system. We investigate the scaling of entanglement in a unitary quantum setup composed of a two-dimensional lattice of free fermions, where each site is coupled to a fermionic bath. As the system-bath coupling increases, the logarithmic fermionic negativity reveals an entanglement transition from logarithmic-law to area-law scaling. This occurs while the system's steady-state properties are trivial, highlighting that the signatures of these different scalings are within the bath-bath correlations. Evidence of the transition is also found in the mutual information and the correlations of the full system-bath setup, suggesting that the entanglement transition is underpinned by a change in the spatial structure of quantum information.

quant-ph↗

arXiv2026

Numerically Optimizing Shortcuts to Adiabaticity: A Hybrid Control Strategy

Achieving fast, excitation-free quantum control is a vital challenge in modern quantum technologies. In many cases, shortcuts to adiabaticity enable fast adiabatic-like protocols, yet determining control parameters that satisfy practical constraints is often challenging in complex systems. Here, we combine an analytical shortcut to adiabaticity approach with several numerical optimization methods to boost the performance of the protocol. As a proof-of-principle for this hybrid approach, we study a particularly intricate control problem, the separation of two trapped ions. We show that this analytical-numerical approach, along with the physical insight gained through the variety of suboptimal solutions, leads to the exploration of new solutions in a complex landscape that yield improvements of up to 3 orders of magnitude. Moreover, this improvement comes with no additional cost from an experimental point of view.

quant-ph↗

arXiv2026

Zero-field identification and control of hydrogen-related electron-nuclear spin registers in diamond

Spin defects in diamond serve as powerful building blocks for quantum technologies, especially for applications in quantum sensing and quantum networking. Electron-nuclear defects formed in the environment of optically active spins, such as the nitrogen-vacancy (NV) center, provide a resource for multi-qubit quantum registers. However, many of these defects have yet to be characterized, limiting their control and integration in quantum devices. Here, we apply two hybrid electron-nuclear spin control schemes to self-consistently characterize unknown spin defects at the single-spin level. We perform double electron-electron resonance at zero field (ZF-DEER) to extract hyperfine components and introduce a nuclear-electron-electron triple resonance (NEETR) protocol to control and identify the nuclear spin through the stronger electronic spin interaction. These results provide a guide to resolving the defect structures using ab initio calculations, leading to the identification of a new hydrogen-related defect structure as well as an accurate match to a previously identified nitrogen-related defect. We further apply our NEETR protocol to demonstrate initialization, unitary control, and long-lived coherence of the hydrogen nuclear spin qubit with $T_2 = 1.0(3)\,\mathrm{ms}$. Together, these characterization and control tools establish a framework to harness previously unknown electron-nuclear defects for quantum register applications.

quant-ph↗

arXiv2026

Enhancing Spin Coherence of Optically-Addressed Molecular Qubit by Nuclear Spin Hyperpolarization

Optically addressable molecular triplet spins provide a chemically tunable platform for quantum application, but their coherence is often limited by interactions with surrounding spin baths. Here we demonstrate controlled suppression of nuclear-bath-induced decoherence in photoexcited triplet spins of pentacene co-crystallized in high-purity naphthalene single crystals. By hyperpolarizing the proton spin bath through triplet dynamic nuclear polarization (triplet-DNP), magnetic noise generated by the nuclear spins is suppressed, leading to an extension of the electron spin transverse coherence time. Experimentally, we observe a 25\% enhancement of the spin-echo decay time with $60\%$ polarization of the proton spin bath. The measured scaling of the spin-echo decay time ($T_2$) with nuclear polarization quantitatively follows the predicted dependence derived from the polarization-controlled nuclear second moment. Both the enhancement and the absolute value of the coherence time are quantitatively reproduced by cluster correlation expansion (CCE) simulations. These results establish nuclear spin hyperpolarization as a general and actively tunable approach to engineering coherence in molecular qubits. This work provides a broadly applicable design framework for high-coherence molecular and solid-state spin systems.

physics.chem-ph↗

arXiv2026

Approaching the Limit in Multiparameter AC Magnetometry with Quantum Control

Simultaneously estimating multiple parameters at the ultimate limit is a central challenge in quantum metrology, often hindered by inherent incompatibilities in optimal estimation strategies. At its most extreme, this incompatibility culminates in a fundamental impossibility when the quantum Fisher information matrix (QFIM) becomes singular, rendering joint estimation unattainable. This is the case for a canonical problem: estimating the amplitude and frequency of an AC magnetic field, where the generators are parallel to each other. Here, we introduce a quantum control protocol that resolves this singularity. Our control protocol strategically engineers the sensor's time evolution so the generators for the two parameters become orthogonal. It not only removes the singularity but also restores the optimal scaling of precision with interrogation time for both parameters simultaneously. We experimentally validate this protocol using a nitrogen-vacancy center in diamond at room temperature, demonstrating the concurrent achievement of the optimal scaling for both parameters under realistic conditions.

quant-ph↗

arXiv2025

Robust AC vector sensing at zero magnetic field with pentacene

Quantum sensors based on electronic spins have emerged as powerful probes of microwave-frequency fields. Among other solid-state platforms, spins in molecular crystals offer a range of advantages, from high spin density to functionalization via chemical tunability. Here, we demonstrate microwave vector magnetometry using the photoexcited spin triplet of deuterated pentacene molecules, operating at zero external magnetic field and room temperature. We achieve full three-dimensional microwave field reconstruction by detecting the Rabi frequencies of anisotropic spin-triplet transitions associated with two crystallographic orientations of pentacene in naphthalene crystals. We further introduce a phase alternated protocol that extends the rotating-frame coherence time by an order of magnitude and enables sensitivities of $1~μ\mathrm{T}/\sqrt{\mathrm{Hz}}$ with sub-micrometer spatial resolution. These results establish pentacene-based molecular spins as a practical and high-performance platform for microwave quantum sensing, and the control techniques are broadly applicable to other molecular and solid-state spin systems.

cond-mat.mes-hall↗

arXiv2025

Optimal Control of Coupled Sensor-Ancilla Qubits for Multiparameter Estimation

Designing optimal control for multiparameter quantum sensing is essential for approaching the ultimate precision limits. However, analytical solutions are generally available only for simple systems, while realistic scenarios often involve coupled qubits and time-dependent Hamiltonians. Here we numerically investigate optimal control of a two-qubit sensor-ancilla system coupled via an Ising term using Gradient Ascent Pulse Engineering (GRAPE) to minimize the objective function. By seeding the optimization recursively with solutions obtained for smaller coupling strengths and selecting a suitable initial guess, we achieve robust convergence and high precision across a wide range of interaction strengths and field configurations. The proposed approach offers a practical route toward high-sensitivity, robust multiparameter magnetometry and it is applicable to solid-state quantum sensors such as nitrogen-vacancy (NV) centers in realistic experimental settings.

quant-ph↗

arXiv2025

Exploring the mechanisms of transverse relaxation of copper(II)-phthalocyanine spin qubits

Molecular spin qubits are promising candidates for quantum technologies, but their performance is limited by decoherence arising from diverse mechanisms. The complexity of the environment makes it challenging to identify the main source of noise and target it for mitigation. Here we present a systematic experimental and theoretical framework for analyzing the mechanisms of transverse relaxation in copper(II) phthalocyanine (CuPc) diluted into diamagnetic phthalocyanine hosts. Using pulsed EPR spectroscopy together with first-principles cluster correlation expansion simulations, we quantitatively separate the contributions from hyperfine-coupled nuclear spins, spin--lattice relaxation, and electron--electron dipolar interactions. Our detailed modeling shows that both strongly and weakly coupled nuclei contribute negligibly to $T_2$, while longitudinal dipolar interactions with electronic spins, through instantaneous and spectral diffusion, constitute the main decoherence channel even at moderate spin densities. This conclusion is validated by direct comparison between simulated spin-echo dynamics and experimental data. By providing a robust modeling and experimental approach, our work identifies favorable values of the electron spin density for quantum applications, and provides a transferable methodology for predicting ensemble coherence times. These insights will guide the design and optimization of molecular spin qubits for scalable quantum devices.

physics.chem-ph↗

arXiv2025

Quantum Sensing of Copper-Phthalocyanine Electron Spins via NV Relaxometry

Molecular spin systems are promising candidates for quantum information processing and nanoscale sensing, yet their characterization at room temperature remains challenging due to fast spin decoherence. In this work, we use $T_1$ relaxometry of shallow nitrogen-vacancy (NV) centers in diamond to probe the electron spin ensemble of a polycrystalline copper phthalocyanine (CuPc) thin film. In addition to unequivocally identifying the NV-CuPc interaction thanks to its hyperfine spectrum, we further extract key parameters of the CuPc spin ensemble, including its correlation time and local lattice orientation, that cannot be measured in bulk electron resonance experiments. The analysis of our experimental results confirms that electron-electron interactions dominate the decoherence dynamics of CuPc at room temperature. Additionally, we demonstrate that the CuPc-enhanced NV relaxometry can serve as a robust method to estimate the NV depth with $\sim1$~nm precision. Our results establish NV centers as powerful probes for molecular spin systems, providing insights into molecular qubits, spin bath engineering, and hybrid quantum materials, and offering a potential pathway toward their applications such as molecular-scale quantum processors and spin-based quantum networks.

quant-ph↗

arXiv2025

Machine Learning Enables Optimization of Diamond for Quantum Applications

Spins in solid-state materials, molecules, and other chemical systems have the potential to impact the fields of quantum sensing, communication, simulation, and computing. In particular, color centers in diamond, such as negatively charged nitrogen vacancy (NV$^-$) and silicon vacancy centers (SiV$^-$), are emerging as quantum platforms poised for transition to commercial devices. A key enabler stems from the semiconductor-like platform that can be tailored at the time of growth. The large growth parameter space makes it challenging to use intuition to optimize growth conditions for quantum performance. In this paper, we use supervised machine learning to train regression models using different synthesis parameters in over 100 quantum diamond samples. We train models to optimize NV$^-$ defects in diamond for high sensitivity magnetometry. Importantly, we utilize a magnetic-field sensitivity figure of merit (FOM) for NV magnetometry and use Bayesian optimization to identify critical growth parameters that lead to a 300% improvement over an average sample and a 55% improvement over the previous champion sample. Furthermore, using Shapley importance rankings, we gain new physical insights into the most impactful growth and post-processing parameters, namely electron irradiation dose, diamond seed depth relative to the plasma, seed miscut angle, and reactor nitrogen concentration. As various quantum devices can have significantly different material requirements, advanced growth techniques such as plasma-enhanced chemical vapor deposition (PE-CVD) can provide the ability to tailor material development specifically for quantum applications.

cond-mat.mtrl-sci↗

arXiv2025

Disorder-Induced Anomalous Diffusion in a 3D Spin Network

Emergent hydrodynamics (EHD) bridges short-time unitarity with late-time thermodynamics, universal transport phenomena characterize the manner and speed of transport and thermalization. Typical non-integrable systems with few conserved local quantities are expected to be diffusive. In contrast, strongly disordered systems which admit phases such as many-body localization, are predicted to inhibit thermalization and thus slow dynamical transport. Disordered systems represent a uniquely poised platform to probe the quantum-to-classical transition and the emergence of irreversible thermodynamics from the underlying unitary structure. Here, we study a strongly disordered nuclear spin ensemble, using local measurements enabled by the disordered-state technique. We observe an apparent phase transition into a sub-diffusive regime, which we model as a random walk on the emergent fractal structure of a percolating network in the dipolar spin ensemble. Our novel theoretical model provides a framework for characterizing the emergence of thermalization in closed quantum systems, even in the presence of strong disorder.

cond-mat.dis-nn↗

arXiv2025

No-go theorem for environment-assisted invariance in non-unitary dynamics

We elucidate the requirements for quantum operations that achieve environment-assisted invariance (envariance), a symmetry of entanglement. While envariance has traditionally been studied within the framework of local unitary operations, we extend the analysis to consider non-unitary local operations. First, we investigate the conditions imposed on operators acting on pure bipartite entanglement to attain envariance. We show that the local operations must take a direct-sum form in their Kraus operator representations, establishing decoherence-free subspaces. Furthermore, we prove that this also holds for the multipartite scenario. As an immediate consequence, we demonstrate that environment-assisted shortcuts to adiabaticity cannot be achieved through non-unitary operations. In addition, we show that the static condition of the eternal black hole in AdS/CFT is violated when the CFTs are coupled to the external baths.

quant-ph↗

arXiv2025

Entanglement-assisted multiparameter estimation with a solid-state quantum sensor

Quantum multiparameter estimation promises to extend quantum advantage to the simultaneous high-precision measurements of multiple physical quantities. However, realizing this capability in practical quantum sensors under realistic conditions remains challenging due to intrinsic system imperfections. Here, we experimentally demonstrate multiparameter estimation using a nitrogen-vacancy (NV) center in diamond, a widely adopted solid-state quantum sensor. Leveraging electronic-nuclear spin entanglement and optimized Bell state measurement at room temperature, we simultaneously estimate the amplitude, detuning, and phase of a microwave drive from a single measurement sequence. Despite practical constraints, our results achieve linear sensitivity scaling for all parameters with respect to interrogation time. This work bridges the gap between foundational quantum estimation theory and real-world quantum sensing, opening pathways toward enhanced multiparameter quantum sensors suitable for diverse scientific and technological applications.

quant-ph↗

arXiv2025

Quantum sensing with arbitrary frequency resolution via correlation measurements

Achieving high-frequency spectral resolution with quantum sensors, while crucial in fields ranging from physical to biological sciences, is challenging due to their finite coherence time. Here, we introduce a novel protocol that achieves this goal by measuring phase correlations of AC magnetic fields using ensembles of NV centers. Our method extends the sensing dynamic range to frequencies higher than the system's Rabi frequency while achieving arbitrary frequency resolution, limited only by the target field coherence time. Moreover, our approach operates more robustly with respect to the magnetic field's amplitude. Thanks to this robustness, our protocol allows the application of more $π$-pulses in pulse sequences such as CPMG, enabling the decoupling of a broader range of frequency noise. The higher harmonics generated in this process continue to act as a part of the signal, ultimately improving the frequency resolution. This method paves the way for achieving arbitrary frequency resolution with improved performances, making it highly versatile for quantum sensing applications across diverse scientific fields.

quant-ph↗

arXiv2025

Electron spin dynamics guide cell motility

Diverse organisms exploit the geomagnetic field (GMF) for migration. Migrating birds employ an intrinsically quantum mechanical mechanism for detecting the geomagnetic field: absorption of a blue photon generates a radical pair whose two electrons precess at different rates in the magnetic field, thereby sensitizing cells to the direction of the GMF. In this work, using an in vitro injury model, we discovered a quantum-based mechanism of cellular migration. Specifically, we show that migrating cells detect the GMF via an optically activated, electron spin-based mechanism. Cell injury provokes acute emission of blue photons, and these photons sensitize muscle progenitor cells to the magnetic field. We show that the magnetosensitivity of muscle progenitor cells is (a) activated by blue light, but not by green or red light, and (b) disrupted by the application of an oscillatory field at the frequency corresponding to the energy of the electron-spin/magnetic field interaction. A comprehensive analysis of protein expression reveals that the ability of blue photons to promote cell motility is mediated by activation of calmodulin calcium sensors. Collectively, these data suggest that cells possess a light-dependent magnetic compass driven by electron spin dynamics.

physics.bio-ph↗